CA1112929A - Utilisation d'esters d'hydroquinone comme revelateurs competitifs bloques pour les assemblages de transfert de couleur - Google Patents

Utilisation d'esters d'hydroquinone comme revelateurs competitifs bloques pour les assemblages de transfert de couleur

Info

Publication number: CA1112929A
Authority: CA; Canada
Prior art keywords: layer; carbon atoms; assemblage; timing; silver halide
Prior art date: 1977-11-03
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA312,741A

Other languages

English (en)

Inventor

Thomas I. Abbott

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Eastman Kodak Co

Original Assignee

Eastman Kodak Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-11-03

Filing date

1978-10-05

Publication date

1981-11-24

1978-10-05 Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co

1981-11-24 Application granted granted Critical

1981-11-24 Publication of CA1112929A publication Critical patent/CA1112929A/fr

Status Expired legal-status Critical Current

Links

238000012546 transfer Methods 0.000 title claims description 17
125000000687 hydroquinonyl group Chemical class C1(O)=C(C=C(O)C=C1)* 0.000 title abstract 2
239000000203 mixture Substances 0.000 claims abstract description 58
238000012545 processing Methods 0.000 claims abstract description 57
230000004913 activation Effects 0.000 claims abstract description 24
239000000975 dye Substances 0.000 claims description 85
-1 silver halide Chemical class 0.000 claims description 72
229910052709 silver Inorganic materials 0.000 claims description 48
239000004332 silver Substances 0.000 claims description 48
239000000839 emulsion Substances 0.000 claims description 43
239000000463 material Substances 0.000 claims description 37
125000004432 carbon atom Chemical group C* 0.000 claims description 33
QIGBRXMKCJKVMJ-UHFFFAOYSA-N 1,4-Benzenediol Natural products OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 28
229960004337 hydroquinone Drugs 0.000 claims description 24
230000003472 neutralizing effect Effects 0.000 claims description 23
238000011161 development Methods 0.000 claims description 22
229910052739 hydrogen Inorganic materials 0.000 claims description 22
239000001257 hydrogen Substances 0.000 claims description 22
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 21
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150000001875 compounds Chemical class 0.000 claims description 20
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238000000034 method Methods 0.000 claims description 15
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HBMCQTHGYMTCOF-UHFFFAOYSA-N 4-hydroxyphenyl acetate Chemical compound CC(=O)OC1=CC=C(O)C=C1 HBMCQTHGYMTCOF-UHFFFAOYSA-N 0.000 claims description 8
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OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 6
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VUNCUOUBPZVRDO-UHFFFAOYSA-N (2-hydroxy-5-methylphenyl) benzoate Chemical compound CC1=CC=C(O)C(OC(=O)C=2C=CC=CC=2)=C1 VUNCUOUBPZVRDO-UHFFFAOYSA-N 0.000 claims description 3
DSIBRHDTGCDPAC-UHFFFAOYSA-N (3-tert-butyl-4-hydroxyphenyl) acetate Chemical compound CC(=O)OC1=CC=C(O)C(C(C)(C)C)=C1 DSIBRHDTGCDPAC-UHFFFAOYSA-N 0.000 claims description 3
AKOGNYJNGMLDOA-UHFFFAOYSA-N (4-acetyloxyphenyl) acetate Chemical group CC(=O)OC1=CC=C(OC(C)=O)C=C1 AKOGNYJNGMLDOA-UHFFFAOYSA-N 0.000 claims description 3
JFAXJRJMFOACBO-UHFFFAOYSA-N (4-hydroxyphenyl) benzoate Chemical compound C1=CC(O)=CC=C1OC(=O)C1=CC=CC=C1 JFAXJRJMFOACBO-UHFFFAOYSA-N 0.000 claims description 3
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
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TYJGWROHBVLFEC-UHFFFAOYSA-N benzene-1,4-diol;hexanoic acid Chemical compound CCCCCC(O)=O.OC1=CC=C(O)C=C1 TYJGWROHBVLFEC-UHFFFAOYSA-N 0.000 claims description 3
AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 claims description 3
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238000009826 distribution Methods 0.000 claims description 2
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239000002253 acid Substances 0.000 description 8
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GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
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CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
229920000147 Styrene maleic anhydride Polymers 0.000 description 3
LDKDGDIWEUUXSH-UHFFFAOYSA-N Thymophthalein Chemical compound C1=C(O)C(C(C)C)=CC(C2(C3=CC=CC=C3C(=O)O2)C=2C(=CC(O)=C(C(C)C)C=2)C)=C1C LDKDGDIWEUUXSH-UHFFFAOYSA-N 0.000 description 3
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
OBRMNDMBJQTZHV-UHFFFAOYSA-N cresol red Chemical compound C1=C(O)C(C)=CC(C2(C3=CC=CC=C3S(=O)(=O)O2)C=2C=C(C)C(O)=CC=2)=C1 OBRMNDMBJQTZHV-UHFFFAOYSA-N 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
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125000006850 spacer group Chemical group 0.000 description 3
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KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 2
239000003513 alkali Substances 0.000 description 2
FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 2
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125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
NWVVVBRKAWDGAB-UHFFFAOYSA-N hydroquinone methyl ether Natural products COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 2
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CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
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VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
RAGRPVMAKIWULP-UHFFFAOYSA-N n'-ethenylbutanediamide Chemical compound NC(=O)CCC(=O)NC=C RAGRPVMAKIWULP-UHFFFAOYSA-N 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
239000005445 natural material Substances 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
150000004893 oxazines Chemical class 0.000 description 1
239000002245 particle Substances 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
239000002491 polymer binding agent Substances 0.000 description 1
239000011698 potassium fluoride Substances 0.000 description 1
235000003270 potassium fluoride Nutrition 0.000 description 1
125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical compound O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 1
230000005855 radiation Effects 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
230000035945 sensitivity Effects 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
235000010265 sodium sulphite Nutrition 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000000126 substance Substances 0.000 description 1
125000000547 substituted alkyl group Chemical group 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
229920001059 synthetic polymer Polymers 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
238000001429 visible spectrum Methods 0.000 description 1

Classifications

- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/32—Development processes or agents therefor
- G03C8/36—Developers
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/42—Structural details
- G03C8/52—Bases or auxiliary layers; Substances therefor

Landscapes

Physics & Mathematics (AREA)
General Physics & Mathematics (AREA)
Engineering & Computer Science (AREA)
Architecture (AREA)
Structural Engineering (AREA)
Silver Salt Photography Or Processing Solution Therefor (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)

CA312,741A 1977-11-03 1978-10-05 Utilisation d'esters d'hydroquinone comme revelateurs competitifs bloques pour les assemblages de transfert de couleur Expired CA1112929A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US84806177A	1977-11-03	1977-11-03
US848,061		1977-11-03

Publications (1)

Publication Number	Publication Date
CA1112929A true CA1112929A (fr)	1981-11-24

Family

ID=25302227

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA312,741A Expired CA1112929A (fr)	1977-11-03	1978-10-05	Utilisation d'esters d'hydroquinone comme revelateurs competitifs bloques pour les assemblages de transfert de couleur

Country Status (5)

Country	Link
JP (1)	JPS5931695B2 (fr)
CA (1)	CA1112929A (fr)
DE (1)	DE2847637A1 (fr)
FR (1)	FR2408162A1 (fr)
GB (1)	GB2007862B (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5674247A (en) *	1979-11-22	1981-06-19	Konishiroku Photo Ind Co Ltd	Method for continuously processing silver halide photographic material
US4314020A (en)	1980-08-04	1982-02-02	Eastman Kodak Company	Color transfers assemblages with two timing layers and a neutralizing layer
EP0049685B1 (fr) *	1980-10-02	1984-07-18	Ciba-Geigy Ag	Dérivés d'hydroquinone, leur préparation et leur utilisation dans des matériaux photographiques
US4446216A (en) *	1981-12-10	1984-05-01	Smith Norman A	Photographic material

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3243294A (en) *	1963-11-06	1966-03-29	Eastman Kodak Co	Photographic direct-positive color process
US3375253A (en) *	1964-05-20	1968-03-26	Eastman Kodak Co	Azonia salts
US3462266A (en) *	1967-09-05	1969-08-19	Eastman Kodak Co	Photographic color diffusion transfer processes and elements
GB1258924A (fr) *	1968-06-10	1971-12-30
US3816126A (en) *	1972-09-11	1974-06-11	Polaroid Corp	Novel photographic products and processes
US4056394A (en) *	1976-04-14	1977-11-01	Eastman Kodak Company	Timing layer for color transfer film units comprising copolymer with activation energy to penetration greater than 18 kcal/mole

1978
- 1978-10-05 CA CA312,741A patent/CA1112929A/fr not_active Expired
- 1978-11-02 DE DE19782847637 patent/DE2847637A1/de not_active Withdrawn
- 1978-11-03 FR FR7831100A patent/FR2408162A1/fr active Granted
- 1978-11-03 GB GB7843126A patent/GB2007862B/en not_active Expired
- 1978-11-04 JP JP13517678A patent/JPS5931695B2/ja not_active Expired

Also Published As

Publication number	Publication date
DE2847637A1 (de)	1979-05-10
GB2007862A (en)	1979-05-23
GB2007862B (en)	1982-03-03
FR2408162A1 (fr)	1979-06-01
JPS5931695B2 (ja)	1984-08-03
JPS5474744A (en)	1979-06-15
FR2408162B1 (fr)	1982-06-25

Legal Events

Date	Code	Title	Description
1998-11-24	MKEX	Expiry

Publication	Publication Date	Title
US4450224A (en)	1984-05-22	Polymeric mordants
US4201578A (en)	1980-05-06	Blocked competing developers for color transfer
US4061496A (en)	1977-12-06	Combination of two timing layers for photographic products
JPS602654B2 (ja)	1985-01-23	写真組体
US4056394A (en)	1977-11-01	Timing layer for color transfer film units comprising copolymer with activation energy to penetration greater than 18 kcal/mole
US4009030A (en)	1977-02-22	Timing layer for color transfer assemblages comprising a mixture of cellulose acetate and maleic anhydride copolymer
US4229516A (en)	1980-10-21	Photographic material with temporary barrier layer comprising a mixture of vinylidene chloride terpolymer and polymeric carboxy-ester-lactone and photographic transfer process therefor
US4131469A (en)	1978-12-26	Photographic element with polymeric ammonium mordant
US4256827A (en)	1981-03-17	Photographic element for color diffusion transfer process having a novel neutralizing system
US4356250A (en)	1982-10-26	Use of zinc salts to increase dye stability
CA1112929A (fr)	1981-11-24	Utilisation d'esters d'hydroquinone comme revelateurs competitifs bloques pour les assemblages de transfert de couleur
US4190447A (en)	1980-02-26	Cover sheets for integral imaging receiver elements
US4267262A (en)	1981-05-12	Color diffusion transfer photographic elements comprising a neutralizing system timing layer
US4029849A (en)	1977-06-14	Cover sheets with timing layer comprising cellulose acetate and copolymer of maleic anhydride
CA1087899A (fr)	1980-10-21	Elements de transfert d'image photographique comportant des couches neutralisantes formees de materiaux en particules
US4317892A (en)	1982-03-02	Barrier layer between reactants in photographic products comprising a mixture of vinylidene chloride terpolymer and polymeric carboxy-ester-lactone
CA1116455A (fr)	1982-01-19	Couches a effet temporisateur pour produits photographiques
US4296195A (en)	1981-10-20	Two-sheet diffusion transfer assemblages and photographic elements
US4030920A (en)	1977-06-21	Processing compositions containing glycols for color transfer processes comprising direct positive silver halide developement
US4374919A (en)	1983-02-22	Diffusion transfer color photographic element with U.V. absorbing agent adjacent protective layer
US4415647A (en)	1983-11-15	Polymeric vehicle for dye image-receiving layer containing a poly(vinylimidazole) mordant
US4606992A (en)	1986-08-19	Reflecting layer for image transfer prints
US4358524A (en)	1982-11-09	Polymeric vehicle for metallizable dye image-receiving layer
US4389479A (en)	1983-06-21	Neutralizing layer for color transfer assemblages
US4353973A (en)	1982-10-12	Use of oxalic acid or an acid salt thereof in color transfer assemblages