CA1113540A - Additif pour cellule electrochimique a anode de lithium et a cathode de chlorure de thionyl - Google Patents

Additif pour cellule electrochimique a anode de lithium et a cathode de chlorure de thionyl

Info

Publication number: CA1113540A
Authority: CA; Canada
Prior art keywords: current collector; anode; electrochemical cell; copper; lithium
Prior art date: 1977-08-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA310,153A

Other languages

English (en)

Inventor

Louis R. Giattino

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Individual

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-08-29

Filing date

1978-08-28

Publication date

1981-12-01

1978-08-28 Application filed by Individual filed Critical Individual

1981-12-01 Application granted granted Critical

1981-12-01 Publication of CA1113540A publication Critical patent/CA1113540A/fr

Status Expired legal-status Critical Current

Links

FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 title claims abstract description 38
229910052744 lithium Inorganic materials 0.000 title claims abstract description 23
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 22
239000000654 additive Substances 0.000 title claims abstract description 10
230000000996 additive effect Effects 0.000 title claims abstract description 10
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 21
229910052802 copper Inorganic materials 0.000 claims abstract description 21
239000010949 copper Substances 0.000 claims abstract description 21
239000003792 electrolyte Substances 0.000 claims abstract description 15
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
239000008151 electrolyte solution Substances 0.000 claims description 10
XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 claims description 10
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 8
229910052791 calcium Inorganic materials 0.000 claims description 8
239000011575 calcium Substances 0.000 claims description 8
229910052799 carbon Inorganic materials 0.000 claims description 7
YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 claims description 5
239000002245 particle Substances 0.000 claims 1
239000002904 solvent Substances 0.000 abstract description 7
238000006243 chemical reaction Methods 0.000 description 13
239000007788 liquid Substances 0.000 description 11
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 10
150000003839 salts Chemical class 0.000 description 10
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 6
239000002841 Lewis acid Substances 0.000 description 5
150000007517 lewis acids Chemical class 0.000 description 5
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
239000000243 solution Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 2
239000006230 acetylene black Substances 0.000 description 2
239000002253 acid Substances 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
239000006182 cathode active material Substances 0.000 description 2
239000010406 cathode material Substances 0.000 description 2
OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 2
229940037395 electrolytes Drugs 0.000 description 2
PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 2
239000000463 material Substances 0.000 description 2
IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 2
JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
239000007787 solid Substances 0.000 description 2
125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 description 2
229910015900 BF3 Inorganic materials 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
229910000733 Li alloy Inorganic materials 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
239000000370 acceptor Substances 0.000 description 1
230000002730 additional effect Effects 0.000 description 1
239000010405 anode material Substances 0.000 description 1
229910052787 antimony Inorganic materials 0.000 description 1
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
ILAHWRKJUDSMFH-UHFFFAOYSA-N boron tribromide Chemical compound BrB(Br)Br ILAHWRKJUDSMFH-UHFFFAOYSA-N 0.000 description 1
WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
238000010276 construction Methods 0.000 description 1
BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 description 1
230000007812 deficiency Effects 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000002001 electrolyte material Substances 0.000 description 1
229910002804 graphite Inorganic materials 0.000 description 1
239000010439 graphite Substances 0.000 description 1
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
GLNWILHOFOBOFD-UHFFFAOYSA-N lithium sulfide Chemical compound [Li+].[Li+].[S-2] GLNWILHOFOBOFD-UHFFFAOYSA-N 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
OTCVAHKKMMUFAY-UHFFFAOYSA-N oxosilver Chemical compound [Ag]=O OTCVAHKKMMUFAY-UHFFFAOYSA-N 0.000 description 1
239000008188 pellet Substances 0.000 description 1
239000011148 porous material Substances 0.000 description 1
235000011164 potassium chloride Nutrition 0.000 description 1
239000001103 potassium chloride Substances 0.000 description 1
235000003270 potassium fluoride Nutrition 0.000 description 1
239000011698 potassium fluoride Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
229910001923 silver oxide Inorganic materials 0.000 description 1
NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Substances [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
235000013024 sodium fluoride Nutrition 0.000 description 1
239000011775 sodium fluoride Substances 0.000 description 1
CMXPERZAMAQXSF-UHFFFAOYSA-M sodium;1,4-bis(2-ethylhexoxy)-1,4-dioxobutane-2-sulfonate;1,8-dihydroxyanthracene-9,10-dione Chemical compound [Na+].O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=CC=C2O.CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC CMXPERZAMAQXSF-UHFFFAOYSA-M 0.000 description 1
FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 description 1
DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1

Classifications

- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/668—Composites of electroconductive material and synthetic resins
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/663—Selection of materials containing carbon or carbonaceous materials as conductive part, e.g. graphite, carbon fibres
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
General Chemical & Material Sciences (AREA)
Materials Engineering (AREA)
Composite Materials (AREA)
Manufacturing & Machinery (AREA)
Primary Cells (AREA)
Battery Electrode And Active Subsutance (AREA)

CA310,153A 1977-08-29 1978-08-28 Additif pour cellule electrochimique a anode de lithium et a cathode de chlorure de thionyl Expired CA1113540A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US82849377A	1977-08-29	1977-08-29
US828,493		1977-08-29

Publications (1)

Publication Number	Publication Date
CA1113540A true CA1113540A (fr)	1981-12-01

Family

ID=25251967

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA310,153A Expired CA1113540A (fr)	1977-08-29	1978-08-28	Additif pour cellule electrochimique a anode de lithium et a cathode de chlorure de thionyl

Country Status (5)

Country	Link
CA (1)	CA1113540A (fr)
DE (1)	DE2837511C2 (fr)
FR (1)	FR2402307A1 (fr)
GB (2)	GB2083684B (fr)
IL (1)	IL55428A0 (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4264687A (en) *	1979-09-24	1981-04-28	Duracell International Inc.	Fluid depolarized cell
US4272593A (en) *	1980-04-25	1981-06-09	Gte Laboratories Incorporated	Electrochemical cell with improved cathode current collector
IL60238A (en) *	1980-06-05	1983-07-31	Tadiran Israel Elect Ind Ltd	Cathode and electric cell containing same
US4619874A (en) *	1982-05-06	1986-10-28	Medtronic, Inc.	Electrochemical cells with end-of-life indicator
DE3318981A1 (de) *	1983-05-25	1984-11-29	Duracell International Inc., Tarrytown, N.Y.	Nichtwaessrige elektrochemische zelle
IL77786A (en) *	1986-02-04	1990-02-09	Univ Ramot	Electrochemical cell
FR3059472B1 (fr) *	2016-11-28	2019-05-17	Commissariat A L'energie Atomique Et Aux Energies Alternatives	Pile a cathode liquide specifique
FR3071966B1 (fr) *	2017-09-29	2019-11-08	Commissariat A L'energie Atomique Et Aux Energies Alternatives	Pile a cathode liquide hybride
FR3071967B1 (fr) *	2017-09-29	2021-04-16	Commissariat Energie Atomique	Pile a cathode liquide a architecture specifique

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
BE793372A (fr) *	1971-12-27	1973-06-27	Union Carbide Corp	Pile electro-chimique non aqueuse
US3922174A (en) *	1973-01-22	1975-11-25	Gte Laboratories Inc	Electrochemical cell
US3907593A (en) *	1974-05-17	1975-09-23	Gte Laboratories Inc	Electrochemical cells

1978
- 1978-08-24 IL IL7855428A patent/IL55428A0/xx not_active IP Right Cessation
- 1978-08-25 GB GB8035266A patent/GB2083684B/en not_active Expired
- 1978-08-25 GB GB7834613A patent/GB2003651B/en not_active Expired
- 1978-08-28 CA CA310,153A patent/CA1113540A/fr not_active Expired
- 1978-08-28 DE DE2837511A patent/DE2837511C2/de not_active Expired
- 1978-08-28 FR FR7824825A patent/FR2402307A1/fr active Granted

Also Published As

Publication number	Publication date
GB2083684B (en)	1983-02-02
DE2837511A1 (de)	1979-03-08
GB2083684A (en)	1982-03-24
FR2402307A1 (fr)	1979-03-30
IL55428A0 (en)	1978-10-31
FR2402307B1 (fr)	1983-09-09
GB2003651B (en)	1982-09-02
GB2003651A (en)	1979-03-14
DE2837511C2 (de)	1986-10-23

Legal Events

Date	Code	Title	Description
1998-12-01	MKEX	Expiry

Publication	Publication Date	Title
US4049887A (en)	1977-09-20	Electrochemical cells with cathode-active materials of layered compounds
US3922174A (en)	1975-11-25	Electrochemical cell
US4436796A (en)	1984-03-13	All-solid electrodes with mixed conductor matrix
US3960594A (en)	1976-06-01	Primary or secondary electrochemical cell
US5035963A (en)	1991-07-30	High temperature rechargeable molten salt battery
US3891457A (en)	1975-06-24	Electrochemical cell
US4167608A (en)	1979-09-11	Additive for lithium anode, thionyl chloride active cathode electrochemical cell
US4246327A (en)	1981-01-20	High energy-density battery system
JP2001520447A (ja)	2001-10-30	液体電解質リチウム−硫黄電池
US4722877A (en)	1988-02-02	Long cycle life solid-state solid polymer electrolyte cells
US4869977A (en)	1989-09-26	Electrolyte additive for lithium-sulfur dioxide electrochemical cell
GB2043988A (en)	1980-10-08	Nonaqueous electrochemical cell
CA1113540A (fr)	1981-12-01	Additif pour cellule electrochimique a anode de lithium et a cathode de chlorure de thionyl
US4262065A (en)	1981-04-14	Additive for lithium batteries
US4751157A (en)	1988-06-14	Cathode material for use in lithium electrochemical cell and lithium electrochemical cell including said cathode material
US5213914A (en)	1993-05-25	Non-aqueous, rechargeable electrochemical cell
US4752541A (en)	1988-06-21	Electrolyte for lithium-sulfur dioxide electrochemical cell
JPH04500286A (ja)	1992-01-16	リチウム２次系に対する正電流集電子
US4400453A (en)	1983-08-23	Non-aqueous electrochemical cell
CA1258107A (fr)	1989-08-01	Pile secondaire au lithium
GB2056752A (en)	1981-03-18	Electrochemical cell having electrolyte comprising halogens and interhalogens
IE46357B1 (en)	1983-05-18	Non-aqueous lead oxide electric cell
Uchiyama et al.	1987	Solvent effects on rechargeable lithium cells
US4384028A (en)	1983-05-17	Liquid cathode electrochemical cell additives
US4508796A (en)	1985-04-02	Chromium (V) compounds as cathode material in electrochemical power sources