CA1114894A - Cellule electrochimique employant comme agent de transfert de charge un radical dithionitique de metal alcalin - Google Patents

Cellule electrochimique employant comme agent de transfert de charge un radical dithionitique de metal alcalin

Info

Publication number: CA1114894A
Authority: CA; Canada
Prior art keywords: electrolyte; dithionite; electrochemical cell; cell; solvent
Prior art date: 1976-09-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA358,124A

Other languages

English (en)

Inventor

Ralph E. Schwartz

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Maritime Commercial & Trading Corp

Original Assignee

Maritime Commercial & Trading Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-09-13

Filing date

1980-08-12

Publication date

1981-12-22

1976-09-13 Priority claimed from US05/722,548 external-priority patent/US4154902A/en

1980-08-12 Application filed by Maritime Commercial & Trading Corp filed Critical Maritime Commercial & Trading Corp

1980-08-12 Priority to CA358,124A priority Critical patent/CA1114894A/fr

1981-12-22 Application granted granted Critical

1981-12-22 Publication of CA1114894A publication Critical patent/CA1114894A/fr

Status Expired legal-status Critical Current

Links

239000002184 metal Substances 0.000 title claims abstract description 78
229910052751 metal Inorganic materials 0.000 title claims abstract description 77
238000012546 transfer Methods 0.000 title abstract description 17
239000003792 electrolyte Substances 0.000 claims abstract description 66
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims abstract description 56
GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 claims abstract description 43
239000003795 chemical substances by application Substances 0.000 claims abstract description 41
239000002904 solvent Substances 0.000 claims abstract description 31
XRZCZQUCDBWELQ-UHFFFAOYSA-L [Li+].[Li+].[O-]S(=O)S([O-])=O Chemical compound [Li+].[Li+].[O-]S(=O)S([O-])=O XRZCZQUCDBWELQ-UHFFFAOYSA-L 0.000 claims abstract description 19
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 13
229910052802 copper Inorganic materials 0.000 claims abstract description 12
239000010949 copper Substances 0.000 claims abstract description 12
239000007787 solid Substances 0.000 claims abstract description 12
238000000034 method Methods 0.000 claims abstract description 9
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 8
229910052799 carbon Inorganic materials 0.000 claims abstract description 7
150000003839 salts Chemical class 0.000 claims abstract description 6
238000004146 energy storage Methods 0.000 claims abstract description 4
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical group CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 33
239000000203 mixture Substances 0.000 claims description 27
239000007788 liquid Substances 0.000 claims description 20
239000004020 conductor Substances 0.000 claims description 15
MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical group [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 claims description 8
229910001486 lithium perchlorate Inorganic materials 0.000 claims description 8
238000007747 plating Methods 0.000 claims description 8
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 5
238000007599 discharging Methods 0.000 claims description 4
RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 3
238000011437 continuous method Methods 0.000 claims description 2
239000011255 nonaqueous electrolyte Substances 0.000 claims description 2
239000008151 electrolyte solution Substances 0.000 abstract description 10
229940021013 electrolyte solution Drugs 0.000 abstract description 10
229920006395 saturated elastomer Polymers 0.000 abstract description 6
FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 abstract description 6
238000004519 manufacturing process Methods 0.000 abstract description 3
YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 abstract description 3
238000009738 saturating Methods 0.000 abstract description 2
229910052744 lithium Inorganic materials 0.000 description 16
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 15
150000002739 metals Chemical class 0.000 description 14
230000008901 benefit Effects 0.000 description 11
239000007789 gas Substances 0.000 description 10
239000000243 solution Substances 0.000 description 10
238000006243 chemical reaction Methods 0.000 description 9
239000003960 organic solvent Substances 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
239000002253 acid Substances 0.000 description 6
-1 dithionite ions Chemical class 0.000 description 6
229910001416 lithium ion Inorganic materials 0.000 description 6
239000007864 aqueous solution Substances 0.000 description 5
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
239000000463 material Substances 0.000 description 5
239000001301 oxygen Substances 0.000 description 5
229910052760 oxygen Inorganic materials 0.000 description 5
VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 5
125000006850 spacer group Chemical group 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 4
229910052782 aluminium Inorganic materials 0.000 description 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 4
229910021645 metal ion Inorganic materials 0.000 description 4
230000037361 pathway Effects 0.000 description 4
239000012047 saturated solution Substances 0.000 description 4
239000002002 slurry Substances 0.000 description 4
229910052708 sodium Inorganic materials 0.000 description 4
239000011734 sodium Substances 0.000 description 4
238000012360 testing method Methods 0.000 description 4
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
229910007511 Li2S2O4 Inorganic materials 0.000 description 3
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
239000004743 Polypropylene Substances 0.000 description 3
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
229910052784 alkaline earth metal Inorganic materials 0.000 description 3
239000011575 calcium Substances 0.000 description 3
229910052791 calcium Inorganic materials 0.000 description 3
238000010276 construction Methods 0.000 description 3
239000011777 magnesium Substances 0.000 description 3
229910052749 magnesium Inorganic materials 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
239000011591 potassium Substances 0.000 description 3
229910052700 potassium Inorganic materials 0.000 description 3
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
239000003513 alkali Substances 0.000 description 2
150000001342 alkaline earth metals Chemical class 0.000 description 2
DKSMCEUSSQTGBK-UHFFFAOYSA-M bromite Chemical compound [O-]Br=O DKSMCEUSSQTGBK-UHFFFAOYSA-M 0.000 description 2
238000011161 development Methods 0.000 description 2
238000007706 flame test Methods 0.000 description 2
239000012530 fluid Substances 0.000 description 2
239000011261 inert gas Substances 0.000 description 2
238000005342 ion exchange Methods 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
229910000510 noble metal Inorganic materials 0.000 description 2
239000004033 plastic Substances 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
229920001155 polypropylene Polymers 0.000 description 2
238000010926 purge Methods 0.000 description 2
238000012216 screening Methods 0.000 description 2
238000007789 sealing Methods 0.000 description 2
238000000926 separation method Methods 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000000126 substance Substances 0.000 description 2
NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
CBQMKYHLDADRLN-UHFFFAOYSA-N 7-methylhypoxanthine Chemical compound N1C=NC(=O)C2=C1N=CN2C CBQMKYHLDADRLN-UHFFFAOYSA-N 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
YZCKVEUIGOORGS-UHFFFAOYSA-N Hydrogen atom Chemical group [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 description 1
229910004878 Na2S2O4 Inorganic materials 0.000 description 1
FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
GJCNZQUZWSHFHP-UHFFFAOYSA-N [Li].O=S=O Chemical compound [Li].O=S=O GJCNZQUZWSHFHP-UHFFFAOYSA-N 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
238000013459 approach Methods 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Chemical class [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
230000005587 bubbling Effects 0.000 description 1
239000003729 cation exchange resin Substances 0.000 description 1
238000004891 communication Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000004320 controlled atmosphere Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
229910021641 deionized water Inorganic materials 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
239000010931 gold Substances 0.000 description 1
229910002804 graphite Inorganic materials 0.000 description 1
239000010439 graphite Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
229910003002 lithium salt Inorganic materials 0.000 description 1
159000000002 lithium salts Chemical class 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
239000002480 mineral oil Substances 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
239000005486 organic electrolyte Substances 0.000 description 1
238000013021 overheating Methods 0.000 description 1
AHKZTVQIVOEVFO-UHFFFAOYSA-N oxide(2-) Chemical compound [O-2] AHKZTVQIVOEVFO-UHFFFAOYSA-N 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
230000002093 peripheral effect Effects 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
230000001141 propulsive effect Effects 0.000 description 1
230000002441 reversible effect Effects 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 1
229910001415 sodium ion Inorganic materials 0.000 description 1
AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
235000019345 sodium thiosulphate Nutrition 0.000 description 1
238000002211 ultraviolet spectrum Methods 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries

Landscapes

Battery Electrode And Active Subsutance (AREA)

CA358,124A 1976-09-13 1980-08-12 Cellule electrochimique employant comme agent de transfert de charge un radical dithionitique de metal alcalin Expired CA1114894A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA358,124A CA1114894A (fr)	1976-09-13	1980-08-12	Cellule electrochimique employant comme agent de transfert de charge un radical dithionitique de metal alcalin

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US05/722,548 US4154902A (en)	1976-09-13	1976-09-13	Electric battery cell, system and method
US722,548		1976-09-13
CA266,233A CA1089929A (fr)	1976-09-13	1976-11-22	Cellule electrochimique employant un radical dithionite de metal alcalin comme agent de transport de la charge
CA358,124A CA1114894A (fr)	1976-09-13	1980-08-12	Cellule electrochimique employant comme agent de transfert de charge un radical dithionitique de metal alcalin

Publications (1)

Publication Number	Publication Date
CA1114894A true CA1114894A (fr)	1981-12-22

Family

ID=27164787

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA358,124A Expired CA1114894A (fr)	1976-09-13	1980-08-12	Cellule electrochimique employant comme agent de transfert de charge un radical dithionitique de metal alcalin

Country Status (1)

Country	Link
CA (1)	CA1114894A (fr)

1980
- 1980-08-12 CA CA358,124A patent/CA1114894A/fr not_active Expired

Legal Events

Date	Code	Title	Description
1998-12-22	MKEX	Expiry

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CA1114894A (fr)	1981-12-22	Cellule electrochimique employant comme agent de transfert de charge un radical dithionitique de metal alcalin