CA1114986A - Substances durcissables contenant des resines epoxydes, des acetals de polyvinyles et un sel -onium d'aromatique - Google Patents

Substances durcissables contenant des resines epoxydes, des acetals de polyvinyles et un sel -onium d'aromatique

Info

Publication number: CA1114986A
Authority: CA; Canada
Prior art keywords: accordance; curable composition; onium salt; aromatic; whole number
Prior art date: 1976-10-14
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA287,740A

Other languages

English (en)

Inventor

James V. Crivello

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

General Electric Co

Original Assignee

General Electric Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-10-14

Filing date

1977-09-29

Publication date

1981-12-22

1977-09-29 Application filed by General Electric Co filed Critical General Electric Co

1981-12-22 Application granted granted Critical

1981-12-22 Publication of CA1114986A publication Critical patent/CA1114986A/fr

Status Expired legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 45
150000003839 salts Chemical class 0.000 title claims abstract description 27
125000003118 aryl group Chemical group 0.000 title claims abstract description 18
239000003822 epoxy resin Substances 0.000 title claims abstract description 13
229920000647 polyepoxide Polymers 0.000 title claims abstract description 13
229920002554 vinyl polymer Polymers 0.000 title claims abstract description 7
DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 title claims abstract description 5
125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 title claims 3
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 title description 3
239000000758 substrate Substances 0.000 claims abstract description 9
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 24
-1 aromatic iodonium salt Chemical class 0.000 claims description 24
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 16
ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 claims description 6
125000000217 alkyl group Chemical group 0.000 claims description 6
229910052739 hydrogen Inorganic materials 0.000 claims description 5
239000001257 hydrogen Substances 0.000 claims description 5
229910052752 metalloid Inorganic materials 0.000 claims description 5
150000002738 metalloids Chemical class 0.000 claims description 5
VUBUXALTYMBEQO-UHFFFAOYSA-N 2,2,3,3,3-pentafluoro-1-phenylpropan-1-one Chemical group FC(F)(F)C(F)(F)C(=O)C1=CC=CC=C1 VUBUXALTYMBEQO-UHFFFAOYSA-N 0.000 claims description 4
239000002184 metal Substances 0.000 claims description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
229910052787 antimony Inorganic materials 0.000 claims description 3
229910052785 arsenic Inorganic materials 0.000 claims description 3
239000007795 chemical reaction product Substances 0.000 claims description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
229910052751 metal Inorganic materials 0.000 claims description 3
229920003986 novolac Polymers 0.000 claims description 3
239000003960 organic solvent Substances 0.000 claims description 3
229910052698 phosphorus Inorganic materials 0.000 claims description 3
229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
229910052711 selenium Inorganic materials 0.000 claims description 3
125000000547 substituted alkyl group Chemical group 0.000 claims description 3
HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 claims description 3
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
125000000753 cycloalkyl group Chemical group 0.000 claims description 2
229910052736 halogen Inorganic materials 0.000 claims description 2
125000005843 halogen group Chemical group 0.000 claims description 2
125000000623 heterocyclic group Chemical group 0.000 claims description 2
229910052757 nitrogen Inorganic materials 0.000 claims description 2
229910052717 sulfur Inorganic materials 0.000 claims description 2
229940068984 polyvinyl alcohol Drugs 0.000 claims 2
235000019422 polyvinyl alcohol Nutrition 0.000 claims 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 5
229910052802 copper Inorganic materials 0.000 abstract description 5
239000010949 copper Substances 0.000 abstract description 5
229920002120 photoresistant polymer Polymers 0.000 abstract description 5
239000011354 acetal resin Substances 0.000 abstract 1
229920006324 polyoxymethylene Polymers 0.000 abstract 1
150000003254 radicals Chemical class 0.000 description 10
239000000975 dye Substances 0.000 description 9
239000011521 glass Substances 0.000 description 9
238000000034 method Methods 0.000 description 7
229940073584 methylene chloride Drugs 0.000 description 7
239000004593 Epoxy Substances 0.000 description 6
229920005989 resin Polymers 0.000 description 6
239000011347 resin Substances 0.000 description 6
229920000642 polymer Polymers 0.000 description 5
229920003319 Araldite® Polymers 0.000 description 4
239000002131 composite material Substances 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
239000000123 paper Substances 0.000 description 4
229920000139 polyethylene terephthalate Polymers 0.000 description 4
239000005020 polyethylene terephthalate Substances 0.000 description 4
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
150000001241 acetals Chemical class 0.000 description 3
125000002091 cationic group Chemical group 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 2
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
DPKHZNPWBDQZCN-UHFFFAOYSA-N acridine orange free base Chemical compound C1=CC(N(C)C)=CC2=NC3=CC(N(C)C)=CC=C3C=C21 DPKHZNPWBDQZCN-UHFFFAOYSA-N 0.000 description 2
BGLGAKMTYHWWKW-UHFFFAOYSA-N acridine yellow Chemical compound [H+].[Cl-].CC1=C(N)C=C2N=C(C=C(C(C)=C3)N)C3=CC2=C1 BGLGAKMTYHWWKW-UHFFFAOYSA-N 0.000 description 2
239000000981 basic dye Substances 0.000 description 2
DZBUGLKDJFMEHC-UHFFFAOYSA-N benzoquinolinylidene Natural products C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 description 2
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
239000011248 coating agent Substances 0.000 description 2
238000000576 coating method Methods 0.000 description 2
239000003085 diluting agent Substances 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
125000000524 functional group Chemical group 0.000 description 2
239000000463 material Substances 0.000 description 2
229910052753 mercury Inorganic materials 0.000 description 2
RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 2
239000000049 pigment Substances 0.000 description 2
230000005855 radiation Effects 0.000 description 2
239000011669 selenium Substances 0.000 description 2
NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
239000002904 solvent Substances 0.000 description 2
JADVWWSKYZXRGX-UHFFFAOYSA-M thioflavine T Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C1=[N+](C)C2=CC=C(C)C=C2S1 JADVWWSKYZXRGX-UHFFFAOYSA-M 0.000 description 2
ZWAJLVLEBYIOTI-OLQVQODUSA-N (1s,6r)-7-oxabicyclo[4.1.0]heptane Chemical compound C1CCC[C@@H]2O[C@@H]21 ZWAJLVLEBYIOTI-OLQVQODUSA-N 0.000 description 1
STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
KFKRXESVMDBTNQ-UHFFFAOYSA-N 3-[18-(2-carboxylatoethyl)-8,13-bis(1-hydroxyethyl)-3,7,12,17-tetramethyl-22,23-dihydroporphyrin-21,24-diium-2-yl]propanoate Chemical compound N1C2=C(C)C(C(C)O)=C1C=C(N1)C(C)=C(C(O)C)C1=CC(C(C)=C1CCC(O)=O)=NC1=CC(C(CCC(O)=O)=C1C)=NC1=C2 KFKRXESVMDBTNQ-UHFFFAOYSA-N 0.000 description 1
QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 description 1
OECTYKWYRCHAKR-UHFFFAOYSA-N 4-vinylcyclohexene dioxide Chemical compound C1OC1C1CC2OC2CC1 OECTYKWYRCHAKR-UHFFFAOYSA-N 0.000 description 1
RBHIUNHSNSQJNG-UHFFFAOYSA-N 6-methyl-3-(2-methyloxiran-2-yl)-7-oxabicyclo[4.1.0]heptane Chemical compound C1CC2(C)OC2CC1C1(C)CO1 RBHIUNHSNSQJNG-UHFFFAOYSA-N 0.000 description 1
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
229910017048 AsF6 Inorganic materials 0.000 description 1
229920002799 BoPET Polymers 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
239000001856 Ethyl cellulose Substances 0.000 description 1
239000004606 Fillers/Extenders Substances 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
239000005041 Mylar™ Substances 0.000 description 1
229910052779 Neodymium Inorganic materials 0.000 description 1
229910052781 Neptunium Inorganic materials 0.000 description 1
FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 description 1
206010034962 Photopsia Diseases 0.000 description 1
229910052777 Praseodymium Inorganic materials 0.000 description 1
239000004614 Process Aid Substances 0.000 description 1
BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 description 1
229910052776 Thorium Inorganic materials 0.000 description 1
239000002253 acid Substances 0.000 description 1
229910052768 actinide Inorganic materials 0.000 description 1
150000001255 actinides Chemical class 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
229910001413 alkali metal ion Inorganic materials 0.000 description 1
229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
VUEDNLCYHKSELL-UHFFFAOYSA-N arsonium Chemical compound [AsH4+] VUEDNLCYHKSELL-UHFFFAOYSA-N 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
YYGQJKUBOMYTGS-UHFFFAOYSA-N bis[4-(diethylamino)phenyl]methanone;bis[4-(dimethylamino)phenyl]methanone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(N(C)C)C=C1.C1=CC(N(CC)CC)=CC=C1C(=O)C1=CC=C(N(CC)CC)C=C1 YYGQJKUBOMYTGS-UHFFFAOYSA-N 0.000 description 1
YRPWLKVCRKAUAO-UHFFFAOYSA-N bismuthonium Chemical class [BiH4+] YRPWLKVCRKAUAO-UHFFFAOYSA-N 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
229910052793 cadmium Inorganic materials 0.000 description 1
229910052792 caesium Inorganic materials 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
125000000068 chlorophenyl group Chemical group 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
229940000425 combination drug Drugs 0.000 description 1
239000004020 conductor Substances 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
OZLBDYMWFAHSOQ-UHFFFAOYSA-N diphenyliodanium Chemical class C=1C=CC=CC=1[I+]C1=CC=CC=C1 OZLBDYMWFAHSOQ-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
125000003700 epoxy group Chemical group 0.000 description 1
229920001249 ethyl cellulose Polymers 0.000 description 1
235000019325 ethyl cellulose Nutrition 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
239000004744 fabric Substances 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000010408 film Substances 0.000 description 1
230000004907 flux Effects 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
238000013007 heat curing Methods 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
229910052738 indium Inorganic materials 0.000 description 1
239000011256 inorganic filler Substances 0.000 description 1
229910003475 inorganic filler Inorganic materials 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
229910052747 lanthanoid Inorganic materials 0.000 description 1
150000002602 lanthanoids Chemical class 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
238000005649 metathesis reaction Methods 0.000 description 1
230000000051 modifying effect Effects 0.000 description 1
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
125000006501 nitrophenyl group Chemical group 0.000 description 1
239000004843 novolac epoxy resin Substances 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
239000005297 pyrex Substances 0.000 description 1
125000004076 pyridyl group Chemical group 0.000 description 1
239000010453 quartz Substances 0.000 description 1
229910052761 rare earth metal Inorganic materials 0.000 description 1
239000005060 rubber Substances 0.000 description 1
229910052706 scandium Inorganic materials 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
229940100890 silver compound Drugs 0.000 description 1
150000003379 silver compounds Chemical class 0.000 description 1
229910001923 silver oxide Inorganic materials 0.000 description 1
229910001494 silver tetrafluoroborate Inorganic materials 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
150000003498 tellurium compounds Chemical class 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
150000003573 thiols Chemical class 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
229910001428 transition metal ion Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
229920006163 vinyl copolymer Polymers 0.000 description 1
239000002023 wood Substances 0.000 description 1
229910052724 xenon Inorganic materials 0.000 description 1
FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Landscapes

Epoxy Resins (AREA)

CA287,740A 1976-10-14 1977-09-29 Substances durcissables contenant des resines epoxydes, des acetals de polyvinyles et un sel -onium d'aromatique Expired CA1114986A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US73242176A	1976-10-14	1976-10-14
US732,421		1976-10-14

Publications (1)

Publication Number	Publication Date
CA1114986A true CA1114986A (fr)	1981-12-22

Family

ID=24943458

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA287,740A Expired CA1114986A (fr)	1976-10-14	1977-09-29	Substances durcissables contenant des resines epoxydes, des acetals de polyvinyles et un sel -onium d'aromatique

Country Status (1)

Country	Link
CA (1)	CA1114986A (fr)

1977
- 1977-09-29 CA CA287,740A patent/CA1114986A/fr not_active Expired

Legal Events

Date	Code	Title	Description
1998-12-22	MKEX	Expiry

Publication	Publication Date	Title
US4193799A (en)	1980-03-18	Method of making printing plates and printed circuit
US4081276A (en)	1978-03-28	Photographic method
US4058400A (en)	1977-11-15	Cationically polymerizable compositions containing group VIa onium salts
US4161405A (en)	1979-07-17	Method of cationally polymerizing oxirane free materials with group VIa onium salts
US4069056A (en)	1978-01-17	Photopolymerizable composition containing group Va aromatic onium salts
US4442197A (en)	1984-04-10	Photocurable compositions
US4156035A (en)	1979-05-22	Photocurable epoxy-acrylate compositions
US4933377A (en)	1990-06-12	Novel sulfonium salts and the use thereof as photoinitiators
US4069054A (en)	1978-01-17	Photopolymerizable composition containing a sensitized aromatic sulfonium compound and a cationacally polymerizable monomer
US4318766A (en)	1982-03-09	Process of using photocopolymerizable compositions based on epoxy and hydroxyl-containing organic materials
US4231951A (en)	1980-11-04	Complex salt photoinitiator
DE69024786T2 (de)	1996-08-29	Neue oniumsalze und deren verwendung als photoinitiatoren
CA1306568C (fr)	1992-08-18	Resine photosensible negative a base de polyphenols et de composes vinyliquesou d'ethers vinyliques
GB1565671A (en)	1980-04-23	Photocopolymerizable compositions based on epoxy and hydroxyl-containing organic materials
US4593052A (en)	1986-06-03	Polymerizable compositions containing diphenyliodosyl salts
US4537854A (en)	1985-08-27	Photoresist compositions and method
US4054635A (en)	1977-10-18	Copolymer of glycidyl methacrylate and allyl glycidyl ether
CA1164710A (fr)	1984-04-03	Compositions photosensibles phototropes contenant un agent colorant a base de fluoranne
US4054455A (en)	1977-10-18	Article having a layer containing a copolymer of glycidyl methacrylate and allyl glycidyl ether
CA1331926C (fr)	1994-09-13	Composes de resine photosensible
EP0313221A2 (fr)	1989-04-26	Photostencil pour l'impression sérigraphique
US4220707A (en)	1980-09-02	Epoxy resin composition for image formation
DE2730725C2 (fr)	1990-08-16
US4113497A (en)	1978-09-12	Compositions with organohalogen compound and diazonium salts as photoinitiators of epoxy compounds in photo-polymerization
CA1114986A (fr)	1981-12-22	Substances durcissables contenant des resines epoxydes, des acetals de polyvinyles et un sel -onium d'aromatique