CA1115876A - Produit a base d'olefine convenant pour l'enduction de la fibre de verre, et stable en stockage - Google Patents

Produit a base d'olefine convenant pour l'enduction de la fibre de verre, et stable en stockage

Info

Publication number: CA1115876A
Authority: CA; Canada
Prior art keywords: maleonated; coupling agent; polymers; weight; polymer
Prior art date: 1978-08-14
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA314,189A

Other languages

English (en)

Inventor

Chester S. Temple

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

PPG Industries Inc

Original Assignee

PPG Industries Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-08-14

Filing date

1978-10-25

Publication date

1982-01-05

1978-10-25 Application filed by PPG Industries Inc filed Critical PPG Industries Inc

1982-01-05 Application granted granted Critical

1982-01-05 Publication of CA1115876A publication Critical patent/CA1115876A/fr

Status Expired legal-status Critical Current

Links

229920000098 polyolefin Polymers 0.000 title claims abstract description 38
238000003860 storage Methods 0.000 title description 10
239000011152 fibreglass Substances 0.000 title description 2
238000004513 sizing Methods 0.000 claims abstract description 68
229920000642 polymer Polymers 0.000 claims abstract description 62
239000003365 glass fiber Substances 0.000 claims abstract description 55
239000004743 Polypropylene Substances 0.000 claims abstract description 40
239000000835 fiber Substances 0.000 claims abstract description 40
239000007822 coupling agent Substances 0.000 claims abstract description 34
238000000034 method Methods 0.000 claims abstract description 30
239000003381 stabilizer Substances 0.000 claims abstract description 26
239000000314 lubricant Substances 0.000 claims abstract description 25
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 21
238000004132 cross linking Methods 0.000 claims abstract description 19
-1 polypropylene Polymers 0.000 claims description 47
239000000203 mixture Substances 0.000 claims description 38
229920001155 polypropylene Polymers 0.000 claims description 37
239000011521 glass Substances 0.000 claims description 30
239000000839 emulsion Substances 0.000 claims description 19
229940117958 vinyl acetate Drugs 0.000 claims description 18
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 14
229920001519 homopolymer Polymers 0.000 claims description 13
239000004593 Epoxy Substances 0.000 claims description 12
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 12
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 11
239000002253 acid Substances 0.000 claims description 10
229920001577 copolymer Polymers 0.000 claims description 10
229920006037 cross link polymer Polymers 0.000 claims description 10
229920000728 polyester Polymers 0.000 claims description 10
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
150000008064 anhydrides Chemical class 0.000 claims description 6
239000002131 composite material Substances 0.000 claims description 6
239000004814 polyurethane Substances 0.000 claims description 6
229910000077 silane Inorganic materials 0.000 claims description 6
229920002635 polyurethane Polymers 0.000 claims description 4
KNDQHSIWLOJIGP-UMRXKNAASA-N (3ar,4s,7r,7as)-rel-3a,4,7,7a-tetrahydro-4,7-methanoisobenzofuran-1,3-dione Chemical compound O=C1OC(=O)[C@@H]2[C@H]1[C@]1([H])C=C[C@@]2([H])C1 KNDQHSIWLOJIGP-UMRXKNAASA-N 0.000 claims description 3
239000004698 Polyethylene Substances 0.000 claims description 3
229920000573 polyethylene Polymers 0.000 claims description 3
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 2
229920000058 polyacrylate Polymers 0.000 claims 8
229920006243 acrylic copolymer Polymers 0.000 claims 4
150000001732 carboxylic acid derivatives Chemical class 0.000 claims 4
FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical group [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims 4
150000004756 silanes Chemical class 0.000 claims 4
239000007788 liquid Substances 0.000 claims 1
238000003825 pressing Methods 0.000 claims 1
230000015572 biosynthetic process Effects 0.000 abstract description 6
230000002787 reinforcement Effects 0.000 abstract description 4
239000007787 solid Substances 0.000 description 17
239000000463 material Substances 0.000 description 16
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
238000001035 drying Methods 0.000 description 7
230000008569 process Effects 0.000 description 7
230000008878 coupling Effects 0.000 description 4
238000010168 coupling process Methods 0.000 description 4
238000005859 coupling reaction Methods 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
230000003014 reinforcing effect Effects 0.000 description 4
WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 3
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
230000008901 benefit Effects 0.000 description 3
230000015556 catabolic process Effects 0.000 description 3
239000011248 coating agent Substances 0.000 description 3
238000000576 coating method Methods 0.000 description 3
238000006731 degradation reaction Methods 0.000 description 3
125000003700 epoxy group Chemical group 0.000 description 3
239000004615 ingredient Substances 0.000 description 3
239000011976 maleic acid Substances 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
150000002978 peroxides Chemical class 0.000 description 3
125000004001 thioalkyl group Chemical group 0.000 description 3
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
239000006087 Silane Coupling Agent Substances 0.000 description 2
229920002472 Starch Polymers 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
239000008365 aqueous carrier Substances 0.000 description 2
229910052804 chromium Inorganic materials 0.000 description 2
239000011651 chromium Substances 0.000 description 2
239000008367 deionised water Substances 0.000 description 2
229910021641 deionized water Inorganic materials 0.000 description 2
230000001419 dependent effect Effects 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
230000007062 hydrolysis Effects 0.000 description 2
238000006460 hydrolysis reaction Methods 0.000 description 2
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
239000011159 matrix material Substances 0.000 description 2
238000000465 moulding Methods 0.000 description 2
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
229920000647 polyepoxide Polymers 0.000 description 2
229920005672 polyolefin resin Polymers 0.000 description 2
235000019698 starch Nutrition 0.000 description 2
239000008107 starch Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
239000004094 surface-active agent Substances 0.000 description 2
LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 2
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
229920002554 vinyl polymer Polymers 0.000 description 2
STGNLGBPLOVYMA-TZKOHIRVSA-N (z)-but-2-enedioic acid Chemical group OC(=O)\C=C/C(O)=O.OC(=O)\C=C/C(O)=O STGNLGBPLOVYMA-TZKOHIRVSA-N 0.000 description 1
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
AYKYXWQEBUNJCN-UHFFFAOYSA-N 3-methylfuran-2,5-dione Chemical compound CC1=CC(=O)OC1=O AYKYXWQEBUNJCN-UHFFFAOYSA-N 0.000 description 1
OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical class CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
229920006397 acrylic thermoplastic Polymers 0.000 description 1
230000009471 action Effects 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
125000004103 aminoalkyl group Chemical group 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
230000002238 attenuated effect Effects 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
239000013043 chemical agent Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
DBULDCSVZCUQIR-UHFFFAOYSA-N chromium(3+);trisulfide Chemical compound [S-2].[S-2].[S-2].[Cr+3].[Cr+3] DBULDCSVZCUQIR-UHFFFAOYSA-N 0.000 description 1
YECBRSTWAYLPIM-UHFFFAOYSA-N chromium;hydrochloride Chemical compound Cl.[Cr] YECBRSTWAYLPIM-UHFFFAOYSA-N 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
230000001808 coupling effect Effects 0.000 description 1
LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
229920001887 crystalline plastic Polymers 0.000 description 1
238000005520 cutting process Methods 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
238000010981 drying operation Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
125000005670 ethenylalkyl group Chemical group 0.000 description 1
239000001530 fumaric acid Substances 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
230000006872 improvement Effects 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
LDHQCZJRKDOVOX-IHWYPQMZSA-N isocrotonic acid Chemical compound C\C=C/C(O)=O LDHQCZJRKDOVOX-IHWYPQMZSA-N 0.000 description 1
239000011133 lead Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
125000005395 methacrylic acid group Chemical group 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
239000011707 mineral Substances 0.000 description 1
239000003607 modifier Substances 0.000 description 1
239000000178 monomer Substances 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000000088 plastic resin Substances 0.000 description 1
229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
239000002952 polymeric resin Substances 0.000 description 1
230000002028 premature Effects 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000000926 separation method Methods 0.000 description 1
125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 1
239000005361 soda-lime glass Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 1
TXDNPSYEJHXKMK-UHFFFAOYSA-N sulfanylsilane Chemical class S[SiH3] TXDNPSYEJHXKMK-UHFFFAOYSA-N 0.000 description 1
229920003002 synthetic resin Polymers 0.000 description 1
ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
- C08J5/08—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Materials Engineering (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
General Chemical & Material Sciences (AREA)
Polymers & Plastics (AREA)
Textile Engineering (AREA)
Life Sciences & Earth Sciences (AREA)
Medicinal Chemistry (AREA)
Geochemistry & Mineralogy (AREA)
General Life Sciences & Earth Sciences (AREA)
Manufacturing & Machinery (AREA)
Dispersion Chemistry (AREA)
Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Reinforced Plastic Materials (AREA)
Surface Treatment Of Glass Fibres Or Filaments (AREA)
Compositions Of Macromolecular Compounds (AREA)

CA314,189A 1978-08-14 1978-10-25 Produit a base d'olefine convenant pour l'enduction de la fibre de verre, et stable en stockage Expired CA1115876A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US93323778A	1978-08-14	1978-08-14
US933,237		1978-08-14

Publications (1)

Publication Number	Publication Date
CA1115876A true CA1115876A (fr)	1982-01-05

Family

ID=25463601

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA314,189A Expired CA1115876A (fr)	1978-08-14	1978-10-25	Produit a base d'olefine convenant pour l'enduction de la fibre de verre, et stable en stockage

Country Status (9)

Country	Link
JP (1)	JPS5527889A (fr)
BE (1)	BE872343A (fr)
CA (1)	CA1115876A (fr)
CH (1)	CH642034A5 (fr)
DE (1)	DE2853755C2 (fr)
FR (1)	FR2433604A1 (fr)
GB (1)	GB2030611B (fr)
IT (1)	IT1192742B (fr)
NL (1)	NL178411C (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4648706A (en) *	1984-10-17	1987-03-10	Casio Computer Company, Ltd.	Image reproduction apparatus
US4687318A (en) *	1984-12-25	1987-08-18	Casio Computer Co, Ltd.	Copying apparatus
US4733271A (en) *	1985-04-30	1988-03-22	Casio Computer Co., Ltd.	Image reproduction apparatus with detector for detecting position of moveable copier unit
WO2009055403A2 (fr) *	2007-10-26	2009-04-30	3M Innovative Properties Company	Composition aqueuse de liant ou de colle

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB908191A (en) *	1960-05-04	1962-10-17	Owens Corning Fiberglass Corp	Processes and compositions for coating glass fibres
FR1267996A (fr) *	1959-07-07	1961-07-28	Pittsburgh Plate Glass Co	Solution d'apprêt pour fibres de verre
US3143405A (en) *	1960-11-03	1964-08-04	Owens Corning Fiberglass Corp	Method of producing polyamide coated glass fibers
US3418094A (en) *	1964-12-29	1968-12-24	Union Carbide Corp	Anti-static agents for glass fiber materials
US3429760A (en) *	1965-02-23	1969-02-25	Smith Corp A O	Method of making glass reinforced resin articles
US3444120A (en) *	1966-03-14	1969-05-13	Owens Corning Fiberglass Corp	Glass fabric having improved yarn slippage and hand
US3615979A (en) *	1968-07-01	1971-10-26	Owens Corning Fiberglass Corp	Process of making sheet molding compound and materials thereof
CA937830A (en) *	1970-10-15	1973-12-04	Owens-Corning Fiberglas Corporation	Moldable glass fiber-reinforced resin composite
JPS5319714B2 (fr) *	1973-06-27	1978-06-22
DE2426654C3 (de) *	1974-06-01	1978-10-05	Bayer Ag, 5090 Leverkusen	Wäßrige Schlichte und Verfahren zur Beschichtung von Glasfasern
JPS512550A (ja) *	1974-06-28	1976-01-10	Akira Nadaguchi	Fusekisochi
US4039716A (en) *	1974-09-20	1977-08-02	Owens-Corning Fiberglas Corporation	Resin coated glass fibers and method of producing same through use of an aqueous silane-containing sizing composition whereby hydrolysis and polymerization of the silane is inhibited
JPS5145714A (ja) *	1974-10-18	1976-04-19	Hitachi Ltd	Hatsudenkikudoyogendokino shutsuryokuseigenseigyosochi
US3997306A (en) *	1975-03-31	1976-12-14	Ppg Industries, Inc.	Glass fiber sizing composition for the reinforcement of resin matrices and method of using same
JPS51149993A (en) *	1975-06-19	1976-12-23	Fuji Fibre Glass Co Ltd	Sizing component of glass fibre
JPS5233237A (en) *	1975-09-09	1977-03-14	Mitsubishi Electric Corp	Elevator control system
JPS5248233A (en) *	1975-10-16	1977-04-16	Okura Seisakushiyo Yuugen	Mortar feeder

1978
- 1978-10-25 CA CA314,189A patent/CA1115876A/fr not_active Expired
- 1978-10-31 NL NLAANVRAGE7810824,A patent/NL178411C/xx not_active IP Right Cessation
- 1978-11-08 GB GB7843705A patent/GB2030611B/en not_active Expired
- 1978-11-24 JP JP14523978A patent/JPS5527889A/ja active Granted
- 1978-11-28 BE BE191991A patent/BE872343A/fr not_active IP Right Cessation
- 1978-12-08 FR FR7834638A patent/FR2433604A1/fr not_active Withdrawn
- 1978-12-13 DE DE2853755A patent/DE2853755C2/de not_active Expired
- 1978-12-19 CH CH1290378A patent/CH642034A5/fr not_active IP Right Cessation
1979
- 1979-06-21 IT IT23770/79A patent/IT1192742B/it active

Also Published As

Publication number	Publication date
FR2433604A1 (fr)	1980-03-14
JPS5527889A (en)	1980-02-28
IT7923770A0 (it)	1979-06-21
NL7810824A (nl)	1980-02-18
BE872343A (fr)	1979-05-28
JPS5738538B2 (fr)	1982-08-16
NL178411B (nl)	1985-10-16
DE2853755C2 (de)	1984-12-20
DE2853755A1 (de)	1980-02-21
GB2030611B (en)	1983-03-02
NL178411C (nl)	1986-03-17
CH642034A5 (fr)	1984-03-30
GB2030611A (en)	1980-04-10
IT1192742B (it)	1988-05-04

Legal Events

Date	Code	Title	Description
1999-01-05	MKEX	Expiry

Publication	Publication Date	Title
US4358501A (en)	1982-11-09	Storage stable polyolefin compatible size for fiber glass strands
US4248935A (en)	1981-02-03	Storage stable polyolefin compatible non-crosslinking size for fiber glass strands
US4457970A (en)	1984-07-03	Glass fiber reinforced thermoplastics
US4455343A (en)	1984-06-19	Aqueous treating composition for glass fiber strands used to produce mats for thermoplastics
EP0750594B1 (fr)	1999-05-19	Encollage de fibres de verre, fibres de verre encollees et articles de renforcement de polyolefines
US4240944A (en)	1980-12-23	Emulsion composition and method for use in treating glass fibers
US4283322A (en)	1981-08-11	Emulsion composition and method for use in treating glass fibers
US5648169A (en)	1997-07-15	Glass fiber size and mat
KR100342115B1 (ko)	2002-11-23	유기 매트릭스 보강용 유리섬유
US3849148A (en)	1974-11-19	Method of treating glass fibers to improve adhesion to polyolefins
US2801189A (en)	1957-07-30	Glass fiber article and process of plural coated fiber and process of preparation
US4413085A (en)	1983-11-01	Storage stable polyolefin compatible non-crosslinking size for fiber glass strands
KR20080081268A (ko)	2008-09-09	섬유 사이즈, 사이즈된 보강재 및 사이즈된 보강재에 의해보강된 물품
US4808478A (en)	1989-02-28	Chemically treated glass fibers for reinforcing thermosetting polymers
US4369264A (en)	1983-01-18	Aqueous treating composition for glass fiber strands used to produce mats for thermoplastic polymers
US3661628A (en)	1972-05-09	Inorganic oxide substrate coated with water dispersible ethylene and acrylic-methacrylic copolymer salts with siloxane
US4263082A (en)	1981-04-21	Storage stable polyolefin compatible non-crosslinking size for fiber glass strands
US4581392A (en)	1986-04-08	Hot melt glass fiber coating
EP0511235B1 (fr)	1995-07-19	Composition polymere
US6379794B1 (en)	2002-04-30	Acrylic impregnant for fibers
JP2004530805A (ja)	2004-10-07	サイジング処理されたガラスストランド、サイジング組成物及び前記ストランドを含んでなる複合体
CA1115876A (fr)	1982-01-05	Produit a base d'olefine convenant pour l'enduction de la fibre de verre, et stable en stockage
US4547533A (en)	1985-10-15	Glass-fiber-reinforced ABS-molding compositions
US5141802A (en)	1992-08-25	Chemically treated shapes, fillers and reinforcement for polymer matrices
EP0353493B1 (fr)	1993-03-10	Objets, charges ou renforcements pour matrices polymères traités chimiquement