CA1116831A - Procede polyvalent pour la production de dioxyde de chlore - Google Patents

Procede polyvalent pour la production de dioxyde de chlore

Info

Publication number: CA1116831A
Authority: CA; Canada
Prior art keywords: alkali metal; chlorine dioxide; acid; chlorine; ions
Prior art date: 1978-12-15
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000340989A

Other languages

English (en)

Inventor

Harold Dev. Partridge

Peter Lai

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Occidental Chemical Corp

Original Assignee

Hooker Chemicals and Plastics Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-12-15

Filing date

1979-11-30

Publication date

1982-01-26

1978-12-15 Priority claimed from US05/970,023 external-priority patent/US4223072A/en

1979-11-30 Application filed by Hooker Chemicals and Plastics Corp filed Critical Hooker Chemicals and Plastics Corp

1982-01-26 Application granted granted Critical

1982-01-26 Publication of CA1116831A publication Critical patent/CA1116831A/fr

Status Expired legal-status Critical Current

Links

OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims abstract description 113
239000004155 Chlorine dioxide Substances 0.000 title claims abstract description 56
235000019398 chlorine dioxide Nutrition 0.000 title claims abstract description 56
238000000034 method Methods 0.000 title claims abstract description 41
230000008569 process Effects 0.000 title claims abstract description 39
-1 silver ions Chemical class 0.000 claims abstract description 51
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 46
239000002253 acid Substances 0.000 claims abstract description 45
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 44
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 24
239000000460 chlorine Substances 0.000 claims abstract description 24
229910052801 chlorine Inorganic materials 0.000 claims abstract description 23
229910001514 alkali metal chloride Inorganic materials 0.000 claims abstract description 17
229910052936 alkali metal sulfate Inorganic materials 0.000 claims abstract description 15
239000003054 catalyst Substances 0.000 claims abstract description 15
238000004519 manufacturing process Methods 0.000 claims abstract description 15
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 14
GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims abstract description 12
239000006227 byproduct Substances 0.000 claims abstract description 9
229910001437 manganese ion Inorganic materials 0.000 claims abstract description 6
229910052785 arsenic Inorganic materials 0.000 claims abstract description 5
229910052709 silver Inorganic materials 0.000 claims abstract description 5
239000004332 silver Substances 0.000 claims abstract description 5
238000006243 chemical reaction Methods 0.000 claims description 66
229910052783 alkali metal Inorganic materials 0.000 claims description 31
XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Inorganic materials [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 30
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 22
235000011167 hydrochloric acid Nutrition 0.000 claims description 20
229960000443 hydrochloric acid Drugs 0.000 claims description 20
239000011780 sodium chloride Substances 0.000 claims description 11
229910052938 sodium sulfate Inorganic materials 0.000 claims description 10
235000011152 sodium sulphate Nutrition 0.000 claims description 10
239000000047 product Substances 0.000 claims description 7
239000000376 reactant Substances 0.000 claims description 7
229920006395 saturated elastomer Polymers 0.000 claims description 7
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 5
229910052753 mercury Inorganic materials 0.000 claims description 5
150000007513 acids Chemical class 0.000 claims description 4
229910052763 palladium Inorganic materials 0.000 claims description 4
KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
238000005649 metathesis reaction Methods 0.000 claims description 3
235000010755 mineral Nutrition 0.000 claims description 3
239000011707 mineral Substances 0.000 claims description 3
230000004048 modification Effects 0.000 claims description 3
238000012986 modification Methods 0.000 claims description 3
230000003197 catalytic effect Effects 0.000 claims 1
239000012047 saturated solution Substances 0.000 abstract description 4
235000019647 acidic taste Nutrition 0.000 abstract 2
229940099041 chlorine dioxide Drugs 0.000 description 46
239000000243 solution Substances 0.000 description 41
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
235000017168 chlorine Nutrition 0.000 description 20
229940060038 chlorine Drugs 0.000 description 20
BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 8
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 8
229960003010 sodium sulfate Drugs 0.000 description 8
239000000203 mixture Substances 0.000 description 7
239000002002 slurry Substances 0.000 description 7
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
239000013078 crystal Substances 0.000 description 5
239000007788 liquid Substances 0.000 description 5
150000003839 salts Chemical class 0.000 description 5
FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 4
239000007864 aqueous solution Substances 0.000 description 4
239000007789 gas Substances 0.000 description 4
229910000041 hydrogen chloride Inorganic materials 0.000 description 4
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 4
WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 3
238000004061 bleaching Methods 0.000 description 3
239000003153 chemical reaction reagent Substances 0.000 description 3
238000000926 separation method Methods 0.000 description 3
229910000342 sodium bisulfate Inorganic materials 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
230000008901 benefit Effects 0.000 description 2
238000009835 boiling Methods 0.000 description 2
238000011161 development Methods 0.000 description 2
230000018109 developmental process Effects 0.000 description 2
MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000011261 inert gas Substances 0.000 description 2
230000007246 mechanism Effects 0.000 description 2
KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 2
238000004076 pulp bleaching Methods 0.000 description 2
238000000746 purification Methods 0.000 description 2
SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
JZUFKLXOESDKRF-UHFFFAOYSA-N Chlorothiazide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC2=C1NCNS2(=O)=O JZUFKLXOESDKRF-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
241000288049 Perdix perdix Species 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
YUHVVTLNLCJEOB-UHFFFAOYSA-N [Cl].O=Cl=O Chemical compound [Cl].O=Cl=O YUHVVTLNLCJEOB-UHFFFAOYSA-N 0.000 description 1
ZQOMKIOQTCAGCM-UHFFFAOYSA-L [Na+].[Na+].OS(O)(=O)=O.[O-]S([O-])(=O)=O Chemical compound [Na+].[Na+].OS(O)(=O)=O.[O-]S([O-])(=O)=O ZQOMKIOQTCAGCM-UHFFFAOYSA-L 0.000 description 1
DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 1
230000002730 additional effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001447 alkali salts Chemical class 0.000 description 1
HAYXDMNJJFVXCI-UHFFFAOYSA-N arsenic(5+) Chemical compound [As+5] HAYXDMNJJFVXCI-UHFFFAOYSA-N 0.000 description 1
YALMXYPQBUJUME-UHFFFAOYSA-L calcium chlorate Chemical compound [Ca+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O YALMXYPQBUJUME-UHFFFAOYSA-L 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000003841 chloride salts Chemical class 0.000 description 1
229910001902 chlorine oxide Inorganic materials 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
229940077449 dichromate ion Drugs 0.000 description 1
SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
239000002360 explosive Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000008246 gaseous mixture Substances 0.000 description 1
GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
239000002440 industrial waste Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000002655 kraft paper Substances 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000000123 paper Substances 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
238000011112 process operation Methods 0.000 description 1
238000010956 selective crystallization Methods 0.000 description 1
229910001961 silver nitrate Inorganic materials 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
SRWFBFUYENBCGF-UHFFFAOYSA-M sodium;chloride;hydrochloride Chemical compound [Na+].Cl.[Cl-] SRWFBFUYENBCGF-UHFFFAOYSA-M 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
238000010408 sweeping Methods 0.000 description 1
239000004753 textile Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1

Landscapes

Inorganic Compounds Of Heavy Metals (AREA)

CA000340989A 1978-12-15 1979-11-30 Procede polyvalent pour la production de dioxyde de chlore Expired CA1116831A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US05/970,023 US4223072A (en)	1977-12-23	1978-12-15	Flexible coating resins from siloxane resins having a very low degree of organic substitution
US970,023		1978-12-18

Publications (1)

Publication Number	Publication Date
CA1116831A true CA1116831A (fr)	1982-01-26

Family

ID=25516321

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000340989A Expired CA1116831A (fr)	1978-12-15	1979-11-30	Procede polyvalent pour la production de dioxyde de chlore

Country Status (1)

Country	Link
CA (1)	CA1116831A (fr)

1979
- 1979-11-30 CA CA000340989A patent/CA1116831A/fr not_active Expired

Legal Events

Date	Code	Title	Description
1999-01-26	MKEX	Expiry

Publication	Publication Date	Title
US3563702A (en)	1971-02-16	Production of chlorine dioxide
US4473540A (en)	1984-09-25	High efficiency chlorine dioxide process
CA2028550C (fr)	1998-10-27	Methode de production de dioxyde de chlore
CA2097525C (fr)	2000-05-02	Un procede de production en continu de dioxyde de chlore
US3864456A (en)	1975-02-04	Manufacture of chlorine dioxide, chlorine and anhydrous sodium sulphate
CA2028549C (fr)	1998-10-27	Methode de production de dioxyde de chlore
US3810969A (en)	1974-05-14	Process for the production of chlorine dioxide
CA1079931A (fr)	1980-06-24	Production elevee de chlore par le procede solvay
EP0513167A4 (en)	1993-01-13	Process for the production of highly pure concentrated solutions of potassium hypochlorite
US4396592A (en)	1983-08-02	Plural zone process for the preparation of chlorine dioxide
EP0646095B1 (fr)	1997-01-08	Procede de production de dioxyde de chlore
CA2178043C (fr)	1998-12-22	Methode pour l'obtention de dioxyde de chlore
US4137296A (en)	1979-01-30	Production of chlorine dioxide
US4145401A (en)	1979-03-20	High efficiency chlorine dioxide production at low acidity with methanol addition
US4206193A (en)	1980-06-03	Versatile process for generating chlorine dioxide
US3933987A (en)	1976-01-20	Simultaneous production of chlorine dioxide and a salt of a strong acid
CA1105877A (fr)	1981-07-28	Procede d'obtention de dioxyde de chlore
US5593653A (en)	1997-01-14	Metathesis of acidic by-product of chlorine dioxide generating process
CA1116831A (fr)	1982-01-26	Procede polyvalent pour la production de dioxyde de chlore
EP0131378B1 (fr)	1989-05-10	Procédé de production de dioxyde de chlore
JPH02293301A (ja)	1990-12-04	二酸化塩素の製造方法
CA2023452A1 (fr)	1991-09-06	Procede de production du dioxyde de chlore
US4178356A (en)	1979-12-11	Process for manufacturing chlorine dioxide
FI69292C (fi)	1986-01-10	Foerfarande foer framstaellning av klordioxid
CA1049950A (fr)	1979-03-06	Synthese integree de dioxyde de chlore