CA1117692A - Methode de preparations de compositions d'oxyde de polyphenylene - Google Patents

Methode de preparations de compositions d'oxyde de polyphenylene

Info

Publication number: CA1117692A
Authority: CA; Canada
Prior art keywords: composition; weight; resin; alkenyl aromatic; impact modifier
Prior art date: 1977-12-23
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000314472A

Other languages

English (en)

Inventor

John C. Goossens

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

General Electric Co

Original Assignee

General Electric Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-12-23

Filing date

1978-10-27

Publication date

1982-02-02

1978-10-27 Application filed by General Electric Co filed Critical General Electric Co

1982-02-02 Application granted granted Critical

1982-02-02 Publication of CA1117692A publication Critical patent/CA1117692A/fr

Status Expired legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 41
238000000034 method Methods 0.000 title claims abstract description 38
239000004721 Polyphenylene oxide Substances 0.000 title claims abstract description 27
229920006380 polyphenylene oxide Polymers 0.000 title claims abstract description 24
238000002360 preparation method Methods 0.000 title claims abstract description 7
229920005989 resin Polymers 0.000 claims abstract description 30
239000011347 resin Substances 0.000 claims abstract description 30
239000000178 monomer Substances 0.000 claims abstract description 25
239000004609 Impact Modifier Substances 0.000 claims abstract description 19
238000010438 heat treatment Methods 0.000 claims abstract description 5
-1 poly(2,6-dimethyl-1,4-phenylene oxide) Polymers 0.000 claims description 20
229920001971 elastomer Polymers 0.000 claims description 16
239000005060 rubber Substances 0.000 claims description 16
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 15
125000004432 carbon atom Chemical group C* 0.000 claims description 9
239000001257 hydrogen Substances 0.000 claims description 9
229910052739 hydrogen Inorganic materials 0.000 claims description 9
229920003048 styrene butadiene rubber Polymers 0.000 claims description 8
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
125000003342 alkenyl group Chemical group 0.000 claims description 7
150000002978 peroxides Chemical class 0.000 claims description 7
XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 6
125000000217 alkyl group Chemical group 0.000 claims description 6
125000001424 substituent group Chemical group 0.000 claims description 6
229910052799 carbon Inorganic materials 0.000 claims description 5
229920002852 poly(2,6-dimethyl-1,4-phenylene oxide) polymer Polymers 0.000 claims description 5
229920001400 block copolymer Polymers 0.000 claims description 4
229920005549 butyl rubber Polymers 0.000 claims description 4
125000005843 halogen group Chemical group 0.000 claims description 4
150000002989 phenols Chemical class 0.000 claims description 4
229920002943 EPDM rubber Polymers 0.000 claims description 3
150000001875 compounds Chemical class 0.000 claims description 3
229920001577 copolymer Polymers 0.000 claims description 3
229920002857 polybutadiene Polymers 0.000 claims description 3
230000003014 reinforcing effect Effects 0.000 claims description 3
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
239000004342 Benzoyl peroxide Substances 0.000 claims description 2
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 2
239000004215 Carbon black (E152) Substances 0.000 claims description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
235000019400 benzoyl peroxide Nutrition 0.000 claims description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 2
229910052794 bromium Inorganic materials 0.000 claims description 2
125000001246 bromo group Chemical group Br* 0.000 claims description 2
239000000460 chlorine Chemical group 0.000 claims description 2
229910052801 chlorine Inorganic materials 0.000 claims description 2
125000001309 chloro group Chemical group Cl* 0.000 claims description 2
239000000945 filler Substances 0.000 claims description 2
229910052736 halogen Inorganic materials 0.000 claims description 2
150000002367 halogens Chemical class 0.000 claims description 2
229930195733 hydrocarbon Natural products 0.000 claims description 2
125000001183 hydrocarbyl group Chemical group 0.000 claims description 2
150000002431 hydrogen Chemical group 0.000 claims description 2
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical group II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 2
125000001624 naphthyl group Chemical group 0.000 claims description 2
229920001084 poly(chloroprene) Polymers 0.000 claims description 2
WRXCBRHBHGNNQA-UHFFFAOYSA-N (2,4-dichlorobenzoyl) 2,4-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1Cl WRXCBRHBHGNNQA-UHFFFAOYSA-N 0.000 claims 1
244000043261 Hevea brasiliensis Species 0.000 claims 1
239000003365 glass fiber Substances 0.000 claims 1
125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
229920003052 natural elastomer Polymers 0.000 claims 1
229920001194 natural rubber Polymers 0.000 claims 1
125000002801 octanoyl group Chemical group C(CCCCCCC)(=O)* 0.000 claims 1
229920005990 polystyrene resin Polymers 0.000 claims 1
239000012763 reinforcing filler Substances 0.000 claims 1
239000004793 Polystyrene Substances 0.000 description 18
229920002223 polystyrene Polymers 0.000 description 18
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 7
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
229920000642 polymer Polymers 0.000 description 6
229920013623 Solprene Polymers 0.000 description 5
239000003607 modifier Substances 0.000 description 5
230000000052 comparative effect Effects 0.000 description 4
239000000463 material Substances 0.000 description 4
239000007787 solid Substances 0.000 description 4
238000012719 thermal polymerization Methods 0.000 description 4
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
239000011953 free-radical catalyst Substances 0.000 description 3
229920000930 2, 6-dimethyl-1, 4-phenylene oxide Polymers 0.000 description 2
GVLZQVREHWQBJN-UHFFFAOYSA-N 3,5-dimethyl-7-oxabicyclo[2.2.1]hepta-1,3,5-triene Chemical compound CC1=C(O2)C(C)=CC2=C1 GVLZQVREHWQBJN-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
229920002633 Kraton (polymer) Polymers 0.000 description 2
238000009835 boiling Methods 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000001125 extrusion Methods 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
229940031826 phenolate Drugs 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
229920001955 polyphenylene ether Polymers 0.000 description 2
239000000843 powder Substances 0.000 description 2
238000001556 precipitation Methods 0.000 description 2
150000003254 radicals Chemical class 0.000 description 2
WAEOXIOXMKNFLQ-UHFFFAOYSA-N 1-methyl-4-prop-2-enylbenzene Chemical group CC1=CC=C(CC=C)C=C1 WAEOXIOXMKNFLQ-UHFFFAOYSA-N 0.000 description 1
IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
OMIHGPLIXGGMJB-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]hepta-1,3,5-triene Chemical group C1=CC=C2OC2=C1 OMIHGPLIXGGMJB-UHFFFAOYSA-N 0.000 description 1
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
239000005062 Polybutadiene Substances 0.000 description 1
229920000265 Polyparaphenylene Polymers 0.000 description 1
239000002174 Styrene-butadiene Substances 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
150000001721 carbon Chemical group 0.000 description 1
239000007810 chemical reaction solvent Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
239000008139 complexing agent Substances 0.000 description 1
229910001873 dinitrogen Inorganic materials 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
238000000605 extraction Methods 0.000 description 1
OVBPIULPVIDEAO-LBPRGKRZSA-N folic acid Chemical compound C=1N=C2NC(N)=NC(=O)C2=NC=1CNC1=CC=C(C(=O)N[C@@H](CCC(O)=O)C(O)=O)C=C1 OVBPIULPVIDEAO-LBPRGKRZSA-N 0.000 description 1
239000007789 gas Substances 0.000 description 1
229920000578 graft copolymer Polymers 0.000 description 1
150000002430 hydrocarbons Chemical group 0.000 description 1
239000003999 initiator Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
SRSFOMHQIATOFV-UHFFFAOYSA-N octanoyl octaneperoxoate Chemical compound CCCCCCCC(=O)OOC(=O)CCCCCCC SRSFOMHQIATOFV-UHFFFAOYSA-N 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
238000005691 oxidative coupling reaction Methods 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 description 1
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920013637 polyphenylene oxide polymer Polymers 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000010992 reflux Methods 0.000 description 1
239000011342 resin composition Substances 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000011115 styrene butadiene Substances 0.000 description 1
229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
150000003440 styrenes Chemical class 0.000 description 1
238000009834 vaporization Methods 0.000 description 1
230000008016 vaporization Effects 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)
Graft Or Block Polymers (AREA)

CA000314472A 1977-12-23 1978-10-27 Methode de preparations de compositions d'oxyde de polyphenylene Expired CA1117692A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US86367177A	1977-12-23	1977-12-23
US863,671		1977-12-23

Publications (1)

Publication Number	Publication Date
CA1117692A true CA1117692A (fr)	1982-02-02

Family

ID=25341550

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000314472A Expired CA1117692A (fr)	1977-12-23	1978-10-27	Methode de preparations de compositions d'oxyde de polyphenylene

Country Status (1)

Country	Link
CA (1)	CA1117692A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5223577A (en) *	1990-06-01	1993-06-29	Basf Aktiengesellschaft	Abs molding materials

1978
- 1978-10-27 CA CA000314472A patent/CA1117692A/fr not_active Expired

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5223577A (en) *	1990-06-01	1993-06-29	Basf Aktiengesellschaft	Abs molding materials

Legal Events

Date	Code	Title	Description
1999-02-02	MKEX	Expiry

Publication	Publication Date	Title
US4148843A (en)	1979-04-10	Compositions of capped polyphenylene oxides and alkenyl aromatic resins
US4814392A (en)	1989-03-21	Silicone-polyarylene ether block copolymers, and method for making
CA1068847A (fr)	1979-12-25	Copolymere greffe comprenant un ether de polyphenylene comportant des segments polymeriques, greffes de styrene
US4038343A (en)	1977-07-26	Resin composition containing copolyphenylene ether
US4252913A (en)	1981-02-24	Low molecular weight polyphenylene ether compositions
EP0033146A1 (fr)	1981-08-05	Compositions de polymères contenant du poly(oxyphénylène)
US3819761A (en)	1974-06-25	High impact strength thermoplastic compositions
US3976725A (en)	1976-08-24	High impact strength thermoplastic compositions
CA1063761A (fr)	1979-10-09	Extrusion en solution de produits a base d'ether polyphenylenique
CA1117692A (fr)	1982-02-02	Methode de preparations de compositions d'oxyde de polyphenylene
CA1285091C (fr)	1991-06-18	Melanges comprenant des ethers et des lactames polyphenyleniques et compositions resineuses preparees a partir de ceux-ci
JP7317213B2 (ja)	2023-07-28	熱可塑性エラストマー、組成物、及び成形体
US4189417A (en)	1980-02-19	Process for the polymerization of alkenyl aromatic monomers in the presence of polyphenylene oxides
US4564656A (en)	1986-01-14	Preparation of graft copolymers of polyphenylene ether and rubber, optionally including poly(alkenyl aromatic)
EP0243991B1 (fr)	1991-01-02	Mélange de polymère contenant un poly(éther de phénylène) et des fibres renforçantes
WO1992013035A1 (fr)	1992-08-06	Compositions d'ether polyphenylene resistant au fendillement par contrainte provoque par le milieu ambiant
JPH0237365B2 (fr)	1990-08-23
US4118348A (en)	1978-10-03	Method for preparing blends of rubber, a polyphenylene ether resin and an alkenyl aromatic addition polymer
CA1092272A (fr)	1980-12-23	Produits a base d'ether de polyphenylene comportant une charge a resistance accrue
US4536543A (en)	1985-08-20	Copolymers of polyphenylene oxides and poly(aryl ether)s
CA1084195A (fr)	1980-08-19	Produits de resines d'ether de polyphenylene, d'homopolystyrene et d'un copolymere sequence d'a-b- a.sup.1
JPH05500535A (ja)	1993-02-04	ジカルボキシレートでキャッピングされたポリフェニレンエーテルからのポリフェニレンエーテル―ポリアリ―レンスルフィド組成物
EP0271697A2 (fr)	1988-06-22	Polystyrène modifié au caoutchouc à haute résistance au choc et résines d'éther polyphénylène le contenant
CA1119743A (fr)	1982-03-09	Substances a faible p.m., type ether de polyphenylene
CA1195027A (fr)	1985-10-08	Compositions de resine de poly(oxyde de phenylene renfermant des copolymeres a sequence de siloxane

CA1117692A - Methode de preparations de compositions d'oxyde de polyphenylene - Google Patents

Info

Links

Landscapes

Applications Claiming Priority (2)

Publications (1)

Family

ID=25341550

Family Applications (1)

Country Status (1)

Cited By (1)

Cited By (1)

Similar Documents

Legal Events