CA1118165A - High strength composites and a method for forming - Google Patents

High strength composites and a method for forming

Info

Publication number: CA1118165A
Authority: CA; Canada
Prior art keywords: latex; additive; water; percent; fiber
Prior art date: 1977-08-17
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000309460A

Other languages

English (en)

French (fr)

Inventor

Dale M. Pickelman

William A. Foster

Ritchie A. Wessling

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Dow Chemical Co

Original Assignee

Dow Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-08-17

Filing date

1978-08-16

Publication date

1982-02-16

1977-08-17 Priority claimed from US05/825,320 external-priority patent/US4189345A/en

1977-08-17 Priority claimed from US05/825,323 external-priority patent/US4187142A/en

1978-08-16 Application filed by Dow Chemical Co filed Critical Dow Chemical Co

1982-02-16 Application granted granted Critical

1982-02-16 Publication of CA1118165A publication Critical patent/CA1118165A/en

Status Expired legal-status Critical Current

Links

239000002131 composite material Substances 0.000 title claims abstract description 11
238000000034 method Methods 0.000 title claims description 37
239000004816 latex Substances 0.000 claims abstract description 97
229920000126 latex Polymers 0.000 claims abstract description 97
239000000654 additive Substances 0.000 claims abstract description 60
239000002245 particle Substances 0.000 claims abstract description 44
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
125000002091 cationic group Chemical group 0.000 claims abstract description 21
239000007900 aqueous suspension Substances 0.000 claims abstract description 11
229920002401 polyacrylamide Polymers 0.000 claims abstract description 11
238000010438 heat treatment Methods 0.000 claims abstract description 8
229920006318 anionic polymer Polymers 0.000 claims abstract description 6
238000001035 drying Methods 0.000 claims abstract description 5
239000002002 slurry Substances 0.000 claims abstract description 4
239000012209 synthetic fiber Substances 0.000 claims abstract description 4
229920002994 synthetic fiber Polymers 0.000 claims abstract description 4
238000002156 mixing Methods 0.000 claims abstract description 3
239000000835 fiber Substances 0.000 claims description 36
229920001577 copolymer Polymers 0.000 claims description 29
239000000178 monomer Substances 0.000 claims description 25
229920000642 polymer Polymers 0.000 claims description 22
239000007787 solid Substances 0.000 claims description 22
230000008569 process Effects 0.000 claims description 21
238000006116 polymerization reaction Methods 0.000 claims description 16
125000000129 anionic group Chemical group 0.000 claims description 11
125000001931 aliphatic group Chemical group 0.000 claims description 6
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 5
150000001993 dienes Chemical class 0.000 claims description 5
239000006185 dispersion Substances 0.000 claims description 5
230000014759 maintenance of location Effects 0.000 claims description 5
238000012545 processing Methods 0.000 claims description 5
150000001491 aromatic compounds Chemical class 0.000 claims description 4
229910021645 metal ion Inorganic materials 0.000 claims description 4
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229920001519 homopolymer Polymers 0.000 claims description 3
229920000620 organic polymer Polymers 0.000 claims description 2
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RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 abstract description 6
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PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 22
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125000000217 alkyl group Chemical group 0.000 description 3
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240000000254 Agrostemma githago Species 0.000 description 2
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BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
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LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
150000003926 acrylamides Chemical class 0.000 description 2
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230000005540 biological transmission Effects 0.000 description 2
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
238000000502 dialysis Methods 0.000 description 2
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
238000009826 distribution Methods 0.000 description 2
WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 2
238000007720 emulsion polymerization reaction Methods 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
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AWJUIBRHMBBTKR-UHFFFAOYSA-N isoquinoline Chemical compound C1=NC=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-N 0.000 description 2
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BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
125000005537 sulfoxonium group Chemical group 0.000 description 2
RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 description 2
YWWDBCBWQNCYNR-UHFFFAOYSA-N trimethylphosphine Chemical compound CP(C)C YWWDBCBWQNCYNR-UHFFFAOYSA-N 0.000 description 2
BVURNMLGDQYNAF-SECBINFHSA-N (1r)-n,n-dimethyl-1-phenylethanamine Chemical compound CN(C)[C@H](C)C1=CC=CC=C1 BVURNMLGDQYNAF-SECBINFHSA-N 0.000 description 1
ZWKNLRXFUTWSOY-QPJJXVBHSA-N (e)-3-phenylprop-2-enenitrile Chemical compound N#C\C=C\C1=CC=CC=C1 ZWKNLRXFUTWSOY-QPJJXVBHSA-N 0.000 description 1
ZSPQVOFATJEJMT-UHFFFAOYSA-N 1,1,3,3-tetraethylthiourea Chemical compound CCN(CC)C(=S)N(CC)CC ZSPQVOFATJEJMT-UHFFFAOYSA-N 0.000 description 1
ZOASGOXWEHUTKZ-UHFFFAOYSA-N 1-(Methylthio)-propane Chemical compound CCCSC ZOASGOXWEHUTKZ-UHFFFAOYSA-N 0.000 description 1
ONQBOTKLCMXPOF-UHFFFAOYSA-N 1-ethylpyrrolidine Chemical compound CCN1CCCC1 ONQBOTKLCMXPOF-UHFFFAOYSA-N 0.000 description 1
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CISIJYCKDJSTMX-UHFFFAOYSA-N 2,2-dichloroethenylbenzene Chemical class ClC(Cl)=CC1=CC=CC=C1 CISIJYCKDJSTMX-UHFFFAOYSA-N 0.000 description 1
PRAMZQXXPOLCIY-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethanesulfonic acid Chemical compound CC(=C)C(=O)OCCS(O)(=O)=O PRAMZQXXPOLCIY-UHFFFAOYSA-N 0.000 description 1
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
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XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 1
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NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 description 1
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UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 description 1
RXJKFRMDXUJTEX-UHFFFAOYSA-N triethylphosphine Chemical compound CCP(CC)CC RXJKFRMDXUJTEX-UHFFFAOYSA-N 0.000 description 1
RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 1
YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
239000002699 waste material Substances 0.000 description 1
239000002351 wastewater Substances 0.000 description 1
229920003169 water-soluble polymer Polymers 0.000 description 1
239000001993 wax Substances 0.000 description 1
239000002023 wood Substances 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
- D21H21/52—Additives of definite length or shape
- D21H21/54—Additives of definite length or shape being spherical, e.g. microcapsules, beads
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
- D21H17/375—Poly(meth)acrylamide
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
- D21H17/42—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups anionic
- D21H17/43—Carboxyl groups or derivatives thereof

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Paper (AREA)

CA000309460A 1977-08-17 1978-08-16 High strength composites and a method for forming Expired CA1118165A (en)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US05/825,320 US4189345A (en)	1977-08-17	1977-08-17	Fibrous compositions
US05/825,323 US4187142A (en)	1977-08-17	1977-08-17	Method for forming high strength composites
US825,323		1977-08-17
US825,320		1977-08-17

Publications (1)

Publication Number	Publication Date
CA1118165A true CA1118165A (en)	1982-02-16

Family

ID=27124893

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000309460A Expired CA1118165A (en)	1977-08-17	1978-08-16	High strength composites and a method for forming

Country Status (4)

Country	Link
EP (1)	EP0000921B1 (mo)
JP (1)	JPS5455608A (mo)
CA (1)	CA1118165A (mo)
DE (1)	DE2861402D1 (mo)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5699214A (en) *	1980-01-09	1981-08-10	Hercules Inc	Organic pigment
FR2524828B1 (fr) *	1982-04-09	1986-01-10	Jeand Heurs Papeteries	Nouveaux produits pour les revetements, pour l'isolation et pour l'emballage, a base de dechets industriels et notamment de boues de papeterie et procede pour leur obtention
EP0696609B1 (en) *	1994-03-03	2002-12-04	Kawasaki Steel Corporation	Stampable glass fiber reinforced thermoplastic resin and method of producing the same

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3146157A (en) *	1962-01-08	1964-08-25	Dow Chemical Co	Paper containing a polymer mixture of polysulfonium resin and polycarboxylate resin
CA984988A (en) *	1971-12-03	1976-03-02	Orest N. Chick	Compositions of polymeric materials
JPS4928111A (mo) *	1972-07-17	1974-03-13
JPS5241364B2 (mo) *	1973-05-28	1977-10-18
JPS5182017A (ja) *	1975-01-11	1976-07-19	Teijin Ltd	Yojuboshisochi
JPS5182012A (ja) *	1975-01-14	1976-07-19	Mitsubishi Gas Chemical Co	Tokushushinoseizohoho
AU497808B2 (en) *	1975-04-21	1979-01-11	Dow Chemical Company, The	Latexes
JPS51143709A (en) *	1975-05-31	1976-12-10	Mitsubishi Gas Chemical Co	Latex modified pulp slully and production of spesific paper utilizing same

1978
- 1978-08-16 DE DE7878100676T patent/DE2861402D1/de not_active Expired
- 1978-08-16 CA CA000309460A patent/CA1118165A/en not_active Expired
- 1978-08-16 EP EP19780100676 patent/EP0000921B1/en not_active Expired
- 1978-08-17 JP JP9956678A patent/JPS5455608A/ja active Granted

Also Published As

Publication number	Publication date
JPS5455608A (en)	1979-05-02
EP0000921A1 (en)	1979-03-07
DE2861402D1 (en)	1982-01-28
EP0000921B1 (en)	1981-12-02
JPS6240480B2 (mo)	1987-08-28

Legal Events

Date	Code	Title	Description
1999-02-16	MKEX	Expiry

Publication	Publication Date	Title
US4189345A (en)	1980-02-19	Fibrous compositions
US4785030A (en)	1988-11-15	Cationic latex compositions capable of producing elastomers with hydrophilic surfaces
EP0234513A1 (en)	1987-09-02	Binder for use in a paper-making process
MXPA98000482A (en)	1998-04-01	Synthetic cationic polymers as promoters for apresting with alkenil-succin anhydride
AU6597996A (en)	1997-02-26	Synthetic cationic polymers as promoters for ASA sizing
US5989392A (en)	1999-11-23	Method of using polyammonium quaternary for controlling anionic trash and pitch deposition in pulp containing broke
US20020053413A1 (en)	2002-05-09	Method for using hydrophobically associative polymers in preparing cellulosic fiber compositions, and cellulosic fiber compositions incorporating the hydrophobically associative polymers
US4835211A (en)	1989-05-30	Cationic latex compositions capable of producing elastomers with hydrophilic surfaces
EP0418343B1 (de)	1993-05-26	Verfahren zur herstellung von papier, pappe und karton in gegenwart von n-vinylformamid-einheiten enthaltenden copolymerisaten
EP0000922B1 (en)	1982-06-23	A process for preparing a non-woven fibrous web from fibers and a latex, and the non-woven fibrous material so prepared
MX2007009615A (es)	2007-09-27	Un sistema de aditivo para uso en la fabricacion de papel y proceso para su utilizacion.
US4187142A (en)	1980-02-05	Method for forming high strength composites
US3234076A (en)	1966-02-08	Method of improving retention of fillers in paper making with acrylamidediallylamine copolymer
CN120769943A (zh)	2025-10-10	水溶性两性乳液三元共聚物、制备方法以及作为助留剂和脱水助剂的使用方法
AU2005332031A1 (en)	2006-11-30	Hydrophobic polymers and their use in preparing cellulosic fiber compositions
EP0877120B1 (en)	2000-03-22	Papermaking process
WO2000034581A1 (en)	2000-06-15	Polyampholyte coagulant in the papermaking process
CA1239256A (en)	1988-07-19	Retention aids
CA1118165A (en)	1982-02-16	High strength composites and a method for forming
EP0414496A1 (en)	1991-02-27	Method and pulp for improving paper fines and filler retention
EP4623147A1 (en)	2025-10-01	Improved retention of engineered cellulosic additives using synergistic cationic polymer combination
WO2025006743A2 (en)	2025-01-02	Use of amphoteric emulsion polymers with strength resins as retention and drainage aids
WO2025255232A1 (en)	2025-12-11	High molecular weigh gpam compositions and methods of use as strength and drainage aids
CA3219590A1 (en)	2025-06-13	Use of quick inversion cationic emulsion polymers with polyvinylamines as retention and drainage aids
HK1032250B (en)	2004-12-31	Use of polyammonium quaternary polymer for controlling anionic trash and pitch deposition and treating coated broke