CA1121293A - Hydrotraitement ou hydrofractionnement catalytique des hydrocarbures - Google Patents

Hydrotraitement ou hydrofractionnement catalytique des hydrocarbures

Info

Publication number: CA1121293A
Authority: CA; Canada
Prior art keywords: catalyst; process according; range; coke; hydrocarbon
Prior art date: 1979-11-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000340641A

Other languages

English (en)

Inventor

Jaroslav F. Kriz

James F. Kelly

Marten Ternan

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Canada Minister of Energy Mines and Resources

Original Assignee

Canada Minister of Energy Mines and Resources

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-11-26

Filing date

1979-11-26

Publication date

1982-04-06

1979-11-26 Application filed by Canada Minister of Energy Mines and Resources filed Critical Canada Minister of Energy Mines and Resources

1979-11-26 Priority to CA000340641A priority Critical patent/CA1121293A/fr

1982-04-06 Application granted granted Critical

1982-04-06 Publication of CA1121293A publication Critical patent/CA1121293A/fr

Status Expired legal-status Critical Current

Links

229930195733 hydrocarbon Natural products 0.000 title claims abstract description 26
150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 26
239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 25
238000004517 catalytic hydrocracking Methods 0.000 title claims abstract description 15
239000003921 oil Substances 0.000 title description 10
230000003197 catalytic effect Effects 0.000 title description 6
239000003054 catalyst Substances 0.000 claims abstract description 115
238000000034 method Methods 0.000 claims abstract description 39
230000008569 process Effects 0.000 claims abstract description 33
239000001257 hydrogen Substances 0.000 claims abstract description 24
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 24
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 23
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 14
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 14
229910052744 lithium Inorganic materials 0.000 claims abstract description 14
230000003247 decreasing effect Effects 0.000 claims abstract description 13
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 12
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 11
229910052700 potassium Inorganic materials 0.000 claims abstract description 11
239000011591 potassium Substances 0.000 claims abstract description 11
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 10
229910052708 sodium Inorganic materials 0.000 claims abstract description 10
239000011734 sodium Substances 0.000 claims abstract description 10
230000008021 deposition Effects 0.000 claims abstract description 8
239000000377 silicon dioxide Substances 0.000 claims abstract description 6
229910021472 group 8 element Inorganic materials 0.000 claims abstract description 4
239000003575 carbonaceous material Substances 0.000 claims abstract description 3
239000000463 material Substances 0.000 claims description 21
239000011148 porous material Substances 0.000 claims description 21
239000010779 crude oil Substances 0.000 claims description 17
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 15
239000007788 liquid Substances 0.000 claims description 13
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 12
238000009835 boiling Methods 0.000 claims description 12
229910052750 molybdenum Inorganic materials 0.000 claims description 12
239000011733 molybdenum Substances 0.000 claims description 10
229910052759 nickel Inorganic materials 0.000 claims description 7
239000010426 asphalt Substances 0.000 claims description 6
239000010941 cobalt Substances 0.000 claims description 4
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
229910017052 cobalt Inorganic materials 0.000 claims description 3
230000006872 improvement Effects 0.000 claims description 3
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
229910052721 tungsten Inorganic materials 0.000 claims description 3
239000010937 tungsten Substances 0.000 claims description 3
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
229910052792 caesium Inorganic materials 0.000 claims description 2
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 2
229910052804 chromium Inorganic materials 0.000 claims description 2
239000011651 chromium Substances 0.000 claims description 2
229910052730 francium Inorganic materials 0.000 claims description 2
KLMCZVJOEAUDNE-UHFFFAOYSA-N francium atom Chemical compound [Fr] KLMCZVJOEAUDNE-UHFFFAOYSA-N 0.000 claims description 2
239000003208 petroleum Substances 0.000 claims description 2
229910052701 rubidium Inorganic materials 0.000 claims description 2
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 2
239000000571 coke Substances 0.000 description 41
238000006243 chemical reaction Methods 0.000 description 28
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 11
239000005864 Sulphur Substances 0.000 description 11
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
239000000047 product Substances 0.000 description 10
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
239000012263 liquid product Substances 0.000 description 9
229910052757 nitrogen Inorganic materials 0.000 description 9
239000001301 oxygen Substances 0.000 description 9
229910052760 oxygen Inorganic materials 0.000 description 9
229910052799 carbon Inorganic materials 0.000 description 8
229910052751 metal Inorganic materials 0.000 description 7
239000002184 metal Substances 0.000 description 7
239000011295 pitch Substances 0.000 description 6
150000001875 compounds Chemical class 0.000 description 5
230000007423 decrease Effects 0.000 description 5
238000011156 evaluation Methods 0.000 description 5
238000002474 experimental method Methods 0.000 description 5
239000007789 gas Substances 0.000 description 5
150000002739 metals Chemical class 0.000 description 5
239000000203 mixture Substances 0.000 description 5
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
239000002253 acid Substances 0.000 description 4
229910052784 alkaline earth metal Inorganic materials 0.000 description 4
150000001342 alkaline earth metals Chemical class 0.000 description 4
238000004939 coking Methods 0.000 description 4
239000000446 fuel Substances 0.000 description 4
229910021476 group 6 element Inorganic materials 0.000 description 4
XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 4
229910052808 lithium carbonate Inorganic materials 0.000 description 4
239000000843 powder Substances 0.000 description 4
238000000926 separation method Methods 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 3
229910052783 alkali metal Inorganic materials 0.000 description 3
150000001340 alkali metals Chemical class 0.000 description 3
239000006227 byproduct Substances 0.000 description 3
230000008859 change Effects 0.000 description 3
230000009849 deactivation Effects 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000002245 particle Substances 0.000 description 3
239000002243 precursor Substances 0.000 description 3
239000007787 solid Substances 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
239000002585 base Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
229910000428 cobalt oxide Inorganic materials 0.000 description 2
238000009792 diffusion process Methods 0.000 description 2
238000002309 gasification Methods 0.000 description 2
230000005484 gravity Effects 0.000 description 2
FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
150000002605 large molecules Chemical class 0.000 description 2
229920002521 macromolecule Polymers 0.000 description 2
239000000376 reactant Substances 0.000 description 2
238000000629 steam reforming Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
238000012360 testing method Methods 0.000 description 2
229910052720 vanadium Inorganic materials 0.000 description 2
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
239000013585 weight reducing agent Substances 0.000 description 2
239000010457 zeolite Substances 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
239000007848 Bronsted acid Substances 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
239000002841 Lewis acid Substances 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000000370 acceptor Substances 0.000 description 1
238000003916 acid precipitation Methods 0.000 description 1
239000012190 activator Substances 0.000 description 1
150000001341 alkaline earth metal compounds Chemical class 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
238000013459 approach Methods 0.000 description 1
230000008901 benefit Effects 0.000 description 1
239000007806 chemical reaction intermediate Substances 0.000 description 1
238000000975 co-precipitation Methods 0.000 description 1
239000003245 coal Substances 0.000 description 1
UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
229910001429 cobalt ion Inorganic materials 0.000 description 1
229910001981 cobalt nitrate Inorganic materials 0.000 description 1
XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 1
IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
230000007812 deficiency Effects 0.000 description 1
238000004821 distillation Methods 0.000 description 1
238000000921 elemental analysis Methods 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000005194 fractionation Methods 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
239000013628 high molecular weight specie Substances 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
239000000852 hydrogen donor Substances 0.000 description 1
238000005984 hydrogenation reaction Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
239000003350 kerosene Substances 0.000 description 1
150000007517 lewis acids Chemical class 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
-1 molybdate ions Chemical class 0.000 description 1
150000004682 monohydrates Chemical class 0.000 description 1
238000003947 neutron activation analysis Methods 0.000 description 1
229910000480 nickel oxide Inorganic materials 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
239000008188 pellet Substances 0.000 description 1
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
239000002994 raw material Substances 0.000 description 1
238000007670 refining Methods 0.000 description 1
238000002407 reforming Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000005201 scrubbing Methods 0.000 description 1
239000003079 shale oil Substances 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
239000011949 solid catalyst Substances 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)

CA000340641A 1979-11-26 1979-11-26 Hydrotraitement ou hydrofractionnement catalytique des hydrocarbures Expired CA1121293A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000340641A CA1121293A (fr)	1979-11-26	1979-11-26	Hydrotraitement ou hydrofractionnement catalytique des hydrocarbures

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000340641A CA1121293A (fr)	1979-11-26	1979-11-26	Hydrotraitement ou hydrofractionnement catalytique des hydrocarbures

Publications (1)

Publication Number	Publication Date
CA1121293A true CA1121293A (fr)	1982-04-06

Family

ID=4115692

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000340641A Expired CA1121293A (fr)	1979-11-26	1979-11-26	Hydrotraitement ou hydrofractionnement catalytique des hydrocarbures

Country Status (1)

Country	Link
CA (1)	CA1121293A (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0673678A1 (fr) *	1992-03-30	1995-09-27	Texaco Development Corporation	Catalyseur d'hydrocraquage de charges lourdes hydrocarburées
US7402547B2 (en)	2003-12-19	2008-07-22	Shell Oil Company	Systems and methods of producing a crude product
US7534342B2 (en)	2003-12-19	2009-05-19	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
US7678264B2 (en)	2005-04-11	2010-03-16	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
US7745369B2 (en)	2003-12-19	2010-06-29	Shell Oil Company	Method and catalyst for producing a crude product with minimal hydrogen uptake
US7749374B2 (en)	2006-10-06	2010-07-06	Shell Oil Company	Methods for producing a crude product
US7918992B2 (en)	2005-04-11	2011-04-05	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
US8450538B2 (en)	2008-04-10	2013-05-28	Shell Oil Company	Hydrocarbon composition

1979
- 1979-11-26 CA CA000340641A patent/CA1121293A/fr not_active Expired

Cited By (41)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0673678A1 (fr) *	1992-03-30	1995-09-27	Texaco Development Corporation	Catalyseur d'hydrocraquage de charges lourdes hydrocarburées
US7828958B2 (en)	2003-12-19	2010-11-09	Shell Oil Company	Systems and methods of producing a crude product
US8070936B2 (en)	2003-12-19	2011-12-06	Shell Oil Company	Systems and methods of producing a crude product
US7416653B2 (en)	2003-12-19	2008-08-26	Shell Oil Company	Systems and methods of producing a crude product
US7534342B2 (en)	2003-12-19	2009-05-19	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
US7588681B2 (en)	2003-12-19	2009-09-15	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
US7591941B2 (en)	2003-12-19	2009-09-22	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
US7615196B2 (en)	2003-12-19	2009-11-10	Shell Oil Company	Systems for producing a crude product
US7625481B2 (en)	2003-12-19	2009-12-01	Shell Oil Company	Systems and methods of producing a crude product
US7628908B2 (en)	2003-12-19	2009-12-08	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
US7648625B2 (en)	2003-12-19	2010-01-19	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
US7674370B2 (en)	2003-12-19	2010-03-09	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
US8663453B2 (en)	2003-12-19	2014-03-04	Shell Oil Company	Crude product composition
US7736490B2 (en)	2003-12-19	2010-06-15	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
US7745369B2 (en)	2003-12-19	2010-06-29	Shell Oil Company	Method and catalyst for producing a crude product with minimal hydrogen uptake
US7402547B2 (en)	2003-12-19	2008-07-22	Shell Oil Company	Systems and methods of producing a crude product
US7763160B2 (en)	2003-12-19	2010-07-27	Shell Oil Company	Systems and methods of producing a crude product
US7780844B2 (en)	2003-12-19	2010-08-24	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
US7807046B2 (en)	2003-12-19	2010-10-05	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
US7413646B2 (en)	2003-12-19	2008-08-19	Shell Oil Company	Systems and methods of producing a crude product
US8613851B2 (en)	2003-12-19	2013-12-24	Shell Oil Company	Crude product composition
US8025794B2 (en)	2003-12-19	2011-09-27	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
US7854833B2 (en)	2003-12-19	2010-12-21	Shell Oil Company	Systems and methods of producing a crude product
US7879223B2 (en)	2003-12-19	2011-02-01	Shell Oil Company	Systems and methods of producing a crude product
US8608938B2 (en)	2003-12-19	2013-12-17	Shell Oil Company	Crude product composition
US7959797B2 (en)	2003-12-19	2011-06-14	Shell Oil Company	Systems and methods of producing a crude product
US7837863B2 (en)	2003-12-19	2010-11-23	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
US8025791B2 (en)	2003-12-19	2011-09-27	Shell Oil Company	Systems and methods of producing a crude product
US8070937B2 (en)	2003-12-19	2011-12-06	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
US7811445B2 (en)	2003-12-19	2010-10-12	Shell Oil Company	Systems and methods of producing a crude product
US8163166B2 (en)	2003-12-19	2012-04-24	Shell Oil Company	Systems and methods of producing a crude product
US8241489B2 (en)	2003-12-19	2012-08-14	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
US8268164B2 (en)	2003-12-19	2012-09-18	Shell Oil Company	Systems and methods of producing a crude product
US8394254B2 (en)	2003-12-19	2013-03-12	Shell Oil Company	Crude product composition
US8506794B2 (en)	2003-12-19	2013-08-13	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
US8475651B2 (en)	2003-12-19	2013-07-02	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
US8481450B2 (en)	2005-04-11	2013-07-09	Shell Oil Company	Catalysts for producing a crude product
US7918992B2 (en)	2005-04-11	2011-04-05	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
US7678264B2 (en)	2005-04-11	2010-03-16	Shell Oil Company	Systems, methods, and catalysts for producing a crude product
US7749374B2 (en)	2006-10-06	2010-07-06	Shell Oil Company	Methods for producing a crude product
US8450538B2 (en)	2008-04-10	2013-05-28	Shell Oil Company	Hydrocarbon composition

Legal Events

Date	Code	Title	Description
1999-04-06	MKEX	Expiry

Publication	Publication Date	Title
US5624547A (en)	1997-04-29	Process for pretreatment of hydrocarbon oil prior to hydrocracking and fluid catalytic cracking
US4051021A (en)	1977-09-27	Hydrodesulfurization of hydrocarbon feed utilizing a silica stabilized alumina composite catalyst
US3887455A (en)	1975-06-03	Ebullating bed process for hydrotreatment of heavy crudes and residua
CA2228889C (fr)	2007-11-13	Procede d'hydroconversion au moyen d'un catalyseur a repartition de dimensions de pores specifique, sans ajout de silice
RU2443472C2 (ru)	2012-02-27	Высокостабильный катализатор гидрообессеривания тяжелых углеводородов и способы его получения и применения
US3114701A (en)	1963-12-17	Catalytic hydrodenitrification process
CA1094004A (fr)	1981-01-20	Procede d'hydrocracking catalyse d'huiles lourdes
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