CA1122780A - Silice amorphe, produits connexes et leur preparation - Google Patents

Silice amorphe, produits connexes et leur preparation

Info

Publication number: CA1122780A
Authority: CA; Canada
Prior art keywords: particles; opsil; amorphous silica; crystals; calcium carbonate
Prior art date: 1975-03-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA358,851A

Other languages

English (en)

Inventor

Toru Takikawa

Akira Takahashi

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Osaka Packing Seizosho KK

Original Assignee

Osaka Packing Seizosho KK

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-03-25

Filing date

1980-08-22

Publication date

1982-05-04

1975-03-25 Priority claimed from JP50036298A external-priority patent/JPS51125699A/ja

1975-03-25 Priority claimed from JP3629975A external-priority patent/JPS528023A/ja

1975-03-25 Priority claimed from JP3630075A external-priority patent/JPS528024A/ja

1976-03-24 Priority claimed from CA248,633A external-priority patent/CA1097030A/fr

1980-08-22 Application filed by Osaka Packing Seizosho KK filed Critical Osaka Packing Seizosho KK

1980-08-22 Priority to CA358,851A priority Critical patent/CA1122780A/fr

1982-05-04 Application granted granted Critical

1982-05-04 Publication of CA1122780A publication Critical patent/CA1122780A/fr

Status Expired legal-status Critical Current

Links

VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 274
238000000034 method Methods 0.000 title claims description 22
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 219
239000002245 particle Substances 0.000 claims abstract description 172
229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 111
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 101
239000011164 primary particle Substances 0.000 claims abstract description 84
239000011246 composite particle Substances 0.000 claims abstract description 43
239000010419 fine particle Substances 0.000 claims abstract description 20
239000013078 crystal Substances 0.000 claims description 150
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 78
239000002131 composite material Substances 0.000 claims description 75
229910052918 calcium silicate Inorganic materials 0.000 claims description 60
239000000378 calcium silicate Substances 0.000 claims description 59
OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims description 58
229910002092 carbon dioxide Inorganic materials 0.000 claims description 39
239000001569 carbon dioxide Substances 0.000 claims description 38
239000007789 gas Substances 0.000 abstract description 39
239000002253 acid Substances 0.000 abstract description 20
238000001179 sorption measurement Methods 0.000 abstract description 11
229960003563 calcium carbonate Drugs 0.000 description 104
235000010216 calcium carbonate Nutrition 0.000 description 100
239000011163 secondary particle Substances 0.000 description 88
ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 62
239000002002 slurry Substances 0.000 description 59
235000012241 calcium silicate Nutrition 0.000 description 58
239000000377 silicon dioxide Substances 0.000 description 55
UGGQKDBXXFIWJD-UHFFFAOYSA-N calcium;dihydroxy(oxo)silane;hydrate Chemical compound O.[Ca].O[Si](O)=O UGGQKDBXXFIWJD-UHFFFAOYSA-N 0.000 description 40
238000002441 X-ray diffraction Methods 0.000 description 33
239000000463 material Substances 0.000 description 33
239000007858 starting material Substances 0.000 description 33
235000012239 silicon dioxide Nutrition 0.000 description 32
239000000292 calcium oxide Substances 0.000 description 31
235000012255 calcium oxide Nutrition 0.000 description 31
229910052681 coesite Inorganic materials 0.000 description 30
229910052906 cristobalite Inorganic materials 0.000 description 30
229910052682 stishovite Inorganic materials 0.000 description 30
229910052905 tridymite Inorganic materials 0.000 description 30
238000006243 chemical reaction Methods 0.000 description 25
MKTRXTLKNXLULX-UHFFFAOYSA-P pentacalcium;dioxido(oxo)silane;hydron;tetrahydrate Chemical compound [H+].[H+].O.O.O.O.[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O MKTRXTLKNXLULX-UHFFFAOYSA-P 0.000 description 25
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 24
238000004458 analytical method Methods 0.000 description 24
239000001110 calcium chloride Substances 0.000 description 24
229910001628 calcium chloride Inorganic materials 0.000 description 24
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 22
239000000047 product Substances 0.000 description 22
239000007787 solid Substances 0.000 description 20
239000011148 porous material Substances 0.000 description 19
229910002027 silica gel Inorganic materials 0.000 description 18
239000000741 silica gel Substances 0.000 description 18
238000003756 stirring Methods 0.000 description 16
238000001035 drying Methods 0.000 description 14
238000000635 electron micrograph Methods 0.000 description 14
239000000203 mixture Substances 0.000 description 14
239000003921 oil Substances 0.000 description 14
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 13
229960005069 calcium Drugs 0.000 description 13
229910052791 calcium Inorganic materials 0.000 description 13
239000011575 calcium Substances 0.000 description 13
238000007493 shaping process Methods 0.000 description 13
239000000243 solution Substances 0.000 description 13
238000005452 bending Methods 0.000 description 12
230000006835 compression Effects 0.000 description 11
238000007906 compression Methods 0.000 description 11
239000000835 fiber Substances 0.000 description 11
238000010438 heat treatment Methods 0.000 description 11
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 10
230000005484 gravity Effects 0.000 description 10
235000008733 Citrus aurantifolia Nutrition 0.000 description 9
235000011941 Tilia x europaea Nutrition 0.000 description 9
239000004571 lime Substances 0.000 description 9
238000001878 scanning electron micrograph Methods 0.000 description 9
239000010456 wollastonite Substances 0.000 description 9
229910052882 wollastonite Inorganic materials 0.000 description 9
238000001027 hydrothermal synthesis Methods 0.000 description 8
239000000843 powder Substances 0.000 description 8
239000000654 additive Substances 0.000 description 7
239000003054 catalyst Substances 0.000 description 7
239000006185 dispersion Substances 0.000 description 7
238000007654 immersion Methods 0.000 description 7
239000000126 substance Substances 0.000 description 7
239000003795 chemical substances by application Substances 0.000 description 6
-1 dehydrant Substances 0.000 description 6
230000018044 dehydration Effects 0.000 description 6
238000006297 dehydration reaction Methods 0.000 description 6
239000000945 filler Substances 0.000 description 6
229920006395 saturated elastomer Polymers 0.000 description 6
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 5
238000009826 distribution Methods 0.000 description 5
238000004519 manufacturing process Methods 0.000 description 5
238000001000 micrograph Methods 0.000 description 5
229920000049 Carbon (fiber) Polymers 0.000 description 4
239000003463 adsorbent Substances 0.000 description 4
239000011230 binding agent Substances 0.000 description 4
239000004917 carbon fiber Substances 0.000 description 4
239000004568 cement Substances 0.000 description 4
239000004927 clay Substances 0.000 description 4
239000003086 colorant Substances 0.000 description 4
239000000470 constituent Substances 0.000 description 4
239000000499 gel Substances 0.000 description 4
239000011521 glass Substances 0.000 description 4
239000003365 glass fiber Substances 0.000 description 4
229960000443 hydrochloric acid Drugs 0.000 description 4
235000011167 hydrochloric acid Nutrition 0.000 description 4
239000012212 insulator Substances 0.000 description 4
230000000704 physical effect Effects 0.000 description 4
239000012779 reinforcing material Substances 0.000 description 4
239000004576 sand Substances 0.000 description 4
229910001220 stainless steel Inorganic materials 0.000 description 4
239000010935 stainless steel Substances 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
238000010306 acid treatment Methods 0.000 description 3
230000000996 additive effect Effects 0.000 description 3
159000000007 calcium salts Chemical class 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
238000002425 crystallisation Methods 0.000 description 3
230000008025 crystallization Effects 0.000 description 3
239000011490 mineral wool Substances 0.000 description 3
229920002994 synthetic fiber Polymers 0.000 description 3
239000012209 synthetic fiber Substances 0.000 description 3
238000005406 washing Methods 0.000 description 3
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical group CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
241000820057 Ithone Species 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
239000010425 asbestos Substances 0.000 description 2
238000009924 canning Methods 0.000 description 2
239000008119 colloidal silica Substances 0.000 description 2
230000008602 contraction Effects 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
239000002781 deodorant agent Substances 0.000 description 2
239000002274 desiccant Substances 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000001914 filtration Methods 0.000 description 2
239000011810 insulating material Substances 0.000 description 2
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 2
239000010453 quartz Substances 0.000 description 2
230000003014 reinforcing effect Effects 0.000 description 2
229910052895 riebeckite Inorganic materials 0.000 description 2
239000008279 sol Substances 0.000 description 2
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
239000005909 Kieselgur Substances 0.000 description 1
241000353097 Molva molva Species 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
238000005299 abrasion Methods 0.000 description 1
239000002250 absorbent Substances 0.000 description 1
230000002745 absorbent Effects 0.000 description 1
230000004913 activation Effects 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
239000003905 agrochemical Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
238000009835 boiling Methods 0.000 description 1
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
239000000920 calcium hydroxide Substances 0.000 description 1
235000011116 calcium hydroxide Nutrition 0.000 description 1
229910001861 calcium hydroxide Inorganic materials 0.000 description 1
239000000969 carrier Substances 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
239000004567 concrete Substances 0.000 description 1
239000002537 cosmetic Substances 0.000 description 1
238000010586 diagram Methods 0.000 description 1
BCAARMUWIRURQS-UHFFFAOYSA-N dicalcium;oxocalcium;silicate Chemical compound [Ca+2].[Ca+2].[Ca]=O.[O-][Si]([O-])([O-])[O-] BCAARMUWIRURQS-UHFFFAOYSA-N 0.000 description 1
LPTQBQUNGHOZHM-UHFFFAOYSA-N dicalcium;silicate;hydrate Chemical compound O.[Ca+2].[Ca+2].[O-][Si]([O-])([O-])[O-] LPTQBQUNGHOZHM-UHFFFAOYSA-N 0.000 description 1
239000003814 drug Substances 0.000 description 1
239000000428 dust Substances 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
239000004744 fabric Substances 0.000 description 1
239000010881 fly ash Substances 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
XQSFXFQDJCDXDT-UHFFFAOYSA-N hydroxysilicon Chemical compound [Si]O XQSFXFQDJCDXDT-UHFFFAOYSA-N 0.000 description 1
229910052909 inorganic silicate Inorganic materials 0.000 description 1
239000013067 intermediate product Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
230000001678 irradiating effect Effects 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
229910001562 pearlite Inorganic materials 0.000 description 1
239000000546 pharmaceutical excipient Substances 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
239000011819 refractory material Substances 0.000 description 1
239000012744 reinforcing agent Substances 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
239000011435 rock Substances 0.000 description 1
229910052814 silicon oxide Inorganic materials 0.000 description 1
230000002226 simultaneous effect Effects 0.000 description 1
239000002893 slag Substances 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
241000894007 species Species 0.000 description 1
235000019976 tricalcium silicate Nutrition 0.000 description 1
229910021534 tricalcium silicate Inorganic materials 0.000 description 1

Landscapes

Silicates, Zeolites, And Molecular Sieves (AREA)
Silicon Compounds (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)

CA358,851A 1975-03-25 1980-08-22 Silice amorphe, produits connexes et leur preparation Expired CA1122780A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA358,851A CA1122780A (fr)	1975-03-25	1980-08-22	Silice amorphe, produits connexes et leur preparation

Applications Claiming Priority (8)

Application Number	Priority Date	Filing Date	Title
JP36299		1975-03-25
JP36298		1975-03-25
JP50036298A JPS51125699A (en)	1975-03-25	1975-03-25	The production of moldable high purity and porous silica gel secondary particles
JP3629975A JPS528023A (en)	1975-03-25	1975-03-25	Method of manufacturing high purity porous silica gel mouldings
JP3630075A JPS528024A (en)	1975-03-25	1975-03-25	Manufacturing of porous silica gel plastics
JP36300		1975-03-25
CA248,633A CA1097030A (fr)	1975-03-25	1976-03-24	Traduction non-disponible
CA358,851A CA1122780A (fr)	1975-03-25	1980-08-22	Silice amorphe, produits connexes et leur preparation

Publications (1)

Publication Number	Publication Date
CA1122780A true CA1122780A (fr)	1982-05-04

Family

ID=27508061

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA358,851A Expired CA1122780A (fr)	1975-03-25	1980-08-22	Silice amorphe, produits connexes et leur preparation

Country Status (1)

Country	Link
CA (1)	CA1122780A (fr)

1980
- 1980-08-22 CA CA358,851A patent/CA1122780A/fr not_active Expired

Legal Events

Date	Code	Title	Description
1999-05-04	MKEX	Expiry

Publication	Publication Date	Title
CA1097030A (fr)	1981-03-10	Traduction non-disponible
US4676929A (en)	1987-06-30	Gels, gel products and methods
US4777206A (en)	1988-10-11	Article of manufacture composed of gel
Franus	2012	Characterization of X-type Zeolite Prepared from Coal Fly Ash.
KR930009350B1 (ko)	1993-09-28	실리카 성형체 및 그 제조방법
YANG	1960	The system magnesia‐silica‐water below 300 C.: I, Low‐temperature phases from 100 to 300 C. and their properties
CA1122779A (fr)	1982-05-04	Silice amorphe, produits connexes et leur preparation
CA1122780A (fr)	1982-05-04	Silice amorphe, produits connexes et leur preparation
JPS6158436B2 (fr)	1986-12-11
US4952388A (en)	1990-08-28	Method of treating phyllosilicates
JP3341278B2 (ja)	2002-11-05	メソポア材料及びその製造方法
CA1122778A (fr)	1982-05-04	Silice amorphe, produits connexes et leur preparation
CA1123172A (fr)	1982-05-11	Silice amorphe, produits connexes et leur preparation
JPS5849654A (ja)	1983-03-23	珪酸カルシウムを主成分とする断熱成型体
US4826628A (en)	1989-05-02	Vapor/thermal method of delaminating and stabilizing a phyllosilate and product
JPH021527B2 (fr)	1990-01-11
GB2047297A (en)	1980-11-26	Mineral-fibre boards
JPS6035318B2 (ja)	1985-08-14	シリカ−炭酸カルシウム複合成形体
JPH0116783B2 (fr)	1989-03-27
KR800001043B1 (ko)	1980-09-29	신규의 무정형 실리카의 제조 방법
US4836954A (en)	1989-06-06	Fluorinated phyllosilicate and method
KR800001101B1 (ko)	1980-10-08	신규의 무정형 실리카의 복합재료
JPS6341849B2 (fr)	1988-08-19
JPS6341850B2 (fr)	1988-08-19
Şen	2025	Synthesis of zeolite LTA from kaolin and its model CBC and WAC performance: Optimized by central composite design