CA1123530A - Emulsion au silicone pour la production d'un elastomere, et methodes de preparation connexes - Google Patents

Emulsion au silicone pour la production d'un elastomere, et methodes de preparation connexes

Info

Publication number: CA1123530A
Authority: CA; Canada
Prior art keywords: emulsion; weight; colloidal silica; parts; silicone emulsion
Prior art date: 1979-06-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA330,246A

Other languages

English (en)

Inventor

John C. Saam

Christine M. Schmidt

Robert D. Johnson

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Dow Silicones Corp

Original Assignee

Dow Corning Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-06-21

Filing date

1979-06-21

Publication date

1982-05-11

1979-06-21 Application filed by Dow Corning Corp filed Critical Dow Corning Corp

1979-06-21 Priority to CA330,246A priority Critical patent/CA1123530A/fr

1981-08-06 Priority to CA383,360A priority patent/CA1130487A/fr

1982-05-11 Application granted granted Critical

1982-05-11 Publication of CA1123530A publication Critical patent/CA1123530A/fr

Status Expired legal-status Critical Current

Links

239000000839 emulsion Substances 0.000 title claims abstract description 230
229920001296 polysiloxane Polymers 0.000 title claims abstract description 109
238000000034 method Methods 0.000 title claims description 28
238000002360 preparation method Methods 0.000 title description 11
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 79
239000008119 colloidal silica Substances 0.000 claims abstract description 60
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 47
150000001412 amines Chemical class 0.000 claims abstract description 19
-1 polydimethylsiloxane Polymers 0.000 claims description 26
239000012071 phase Substances 0.000 claims description 18
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 17
235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 16
239000002562 thickening agent Substances 0.000 claims description 16
239000000945 filler Substances 0.000 claims description 15
239000004205 dimethyl polysiloxane Substances 0.000 claims description 14
FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 claims description 12
KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 12
229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 12
229910001415 sodium ion Inorganic materials 0.000 claims description 12
239000006185 dispersion Substances 0.000 claims description 11
125000000129 anionic group Chemical group 0.000 claims description 10
230000001804 emulsifying effect Effects 0.000 claims description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
239000003945 anionic surfactant Substances 0.000 claims description 6
150000003606 tin compounds Chemical class 0.000 claims description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
239000002518 antifoaming agent Substances 0.000 claims description 5
239000008346 aqueous phase Substances 0.000 claims description 5
229910052799 carbon Inorganic materials 0.000 claims description 5
239000001257 hydrogen Substances 0.000 claims description 5
229910052739 hydrogen Inorganic materials 0.000 claims description 5
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
239000002245 particle Substances 0.000 claims description 4
229910052708 sodium Inorganic materials 0.000 claims description 4
239000011734 sodium Substances 0.000 claims description 4
238000007720 emulsion polymerization reaction Methods 0.000 claims description 3
239000000203 mixture Substances 0.000 claims description 3
229910052757 nitrogen Inorganic materials 0.000 claims description 3
125000004122 cyclic group Chemical group 0.000 claims description 2
125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 claims description 2
125000004433 nitrogen atom Chemical group N* 0.000 claims 2
125000004430 oxygen atom Chemical group O* 0.000 claims 2
238000003860 storage Methods 0.000 abstract description 42
238000000576 coating method Methods 0.000 abstract description 20
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 18
239000011248 coating agent Substances 0.000 abstract description 12
239000000463 material Substances 0.000 abstract description 6
239000000047 product Substances 0.000 description 37
YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 20
229920000642 polymer Polymers 0.000 description 20
239000004615 ingredient Substances 0.000 description 17
238000002156 mixing Methods 0.000 description 14
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 12
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 10
239000002253 acid Substances 0.000 description 9
239000003995 emulsifying agent Substances 0.000 description 9
239000004816 latex Substances 0.000 description 9
229920000126 latex Polymers 0.000 description 9
239000000377 silicon dioxide Substances 0.000 description 9
239000003054 catalyst Substances 0.000 description 8
239000003973 paint Substances 0.000 description 8
239000003795 chemical substances by application Substances 0.000 description 7
229920001971 elastomer Polymers 0.000 description 7
239000000806 elastomer Substances 0.000 description 7
229920000058 polyacrylate Polymers 0.000 description 7
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
239000002585 base Substances 0.000 description 6
150000008044 alkali metal hydroxides Chemical class 0.000 description 5
239000007859 condensation product Substances 0.000 description 5
HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 5
230000000694 effects Effects 0.000 description 5
241000894007 species Species 0.000 description 5
239000004408 titanium dioxide Substances 0.000 description 5
NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 4
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 4
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 4
150000007513 acids Chemical class 0.000 description 4
HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 4
239000003517 fume Substances 0.000 description 4
239000003456 ion exchange resin Substances 0.000 description 4
229920003303 ion-exchange polymer Polymers 0.000 description 4
238000012216 screening Methods 0.000 description 4
235000019333 sodium laurylsulphate Nutrition 0.000 description 4
239000000758 substrate Substances 0.000 description 4
150000003460 sulfonic acids Chemical class 0.000 description 4
239000004094 surface-active agent Substances 0.000 description 4
WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
XQBCVRSTVUHIGH-UHFFFAOYSA-L [dodecanoyloxy(dioctyl)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCCCCCC)(CCCCCCCC)OC(=O)CCCCCCCCCCC XQBCVRSTVUHIGH-UHFFFAOYSA-L 0.000 description 3
239000003377 acid catalyst Substances 0.000 description 3
230000032683 aging Effects 0.000 description 3
229910052783 alkali metal Inorganic materials 0.000 description 3
125000002091 cationic group Chemical group 0.000 description 3
150000002500 ions Chemical class 0.000 description 3
230000007935 neutral effect Effects 0.000 description 3
230000000704 physical effect Effects 0.000 description 3
239000011253 protective coating Substances 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
235000012239 silicon dioxide Nutrition 0.000 description 3
159000000000 sodium salts Chemical class 0.000 description 3
238000003892 spreading Methods 0.000 description 3
BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 2
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 2
241000134426 Ceratopogonidae Species 0.000 description 2
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
229920005830 Polyurethane Foam Polymers 0.000 description 2
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
150000007514 bases Chemical class 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
239000006229 carbon black Substances 0.000 description 2
235000019241 carbon black Nutrition 0.000 description 2
229910052681 coesite Inorganic materials 0.000 description 2
239000003086 colorant Substances 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
229910052906 cristobalite Inorganic materials 0.000 description 2
239000003431 cross linking reagent Substances 0.000 description 2
235000014113 dietary fatty acids Nutrition 0.000 description 2
239000002270 dispersing agent Substances 0.000 description 2
239000000194 fatty acid Substances 0.000 description 2
229930195729 fatty acid Natural products 0.000 description 2
150000004665 fatty acids Chemical class 0.000 description 2
239000011521 glass Substances 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
229910052500 inorganic mineral Inorganic materials 0.000 description 2
230000007774 longterm Effects 0.000 description 2
230000014759 maintenance of location Effects 0.000 description 2
239000002609 medium Substances 0.000 description 2
239000011707 mineral Substances 0.000 description 2
PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 2
125000005375 organosiloxane group Chemical group 0.000 description 2
239000000049 pigment Substances 0.000 description 2
239000011496 polyurethane foam Substances 0.000 description 2
230000005855 radiation Effects 0.000 description 2
238000000926 separation method Methods 0.000 description 2
239000000243 solution Substances 0.000 description 2
229910052682 stishovite Inorganic materials 0.000 description 2
239000000725 suspension Substances 0.000 description 2
229910052905 tridymite Inorganic materials 0.000 description 2
229960004418 trolamine Drugs 0.000 description 2
CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
NNAVBEAARXTLEG-UHFFFAOYSA-N 2-(10-methylundecyl)phenol Chemical class CC(C)CCCCCCCCCC1=CC=CC=C1O NNAVBEAARXTLEG-UHFFFAOYSA-N 0.000 description 1
MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 description 1
WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
LIFHMKCDDVTICL-UHFFFAOYSA-N 6-(chloromethyl)phenanthridine Chemical compound C1=CC=C2C(CCl)=NC3=CC=CC=C3C2=C1 LIFHMKCDDVTICL-UHFFFAOYSA-N 0.000 description 1
NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 description 1
229920002319 Poly(methyl acrylate) Polymers 0.000 description 1
239000004147 Sorbitan trioleate Substances 0.000 description 1
PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 1
DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
229910001413 alkali metal ion Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
150000001447 alkali salts Chemical class 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 1
229940063953 ammonium lauryl sulfate Drugs 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
238000010539 anionic addition polymerization reaction Methods 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
150000008107 benzenesulfonic acids Chemical class 0.000 description 1
229920001400 block copolymer Polymers 0.000 description 1
239000007853 buffer solution Substances 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Inorganic materials [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
238000005345 coagulation Methods 0.000 description 1
230000015271 coagulation Effects 0.000 description 1
239000008199 coating composition Substances 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
239000012975 dibutyltin dilaurate Substances 0.000 description 1
SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 1
229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
238000004945 emulsification Methods 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000005227 gel permeation chromatography Methods 0.000 description 1
125000005908 glyceryl ester group Chemical group 0.000 description 1
230000005484 gravity Effects 0.000 description 1
230000009931 harmful effect Effects 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
150000002466 imines Chemical class 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
239000013627 low molecular weight specie Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 1
239000010445 mica Substances 0.000 description 1
229910052618 mica group Inorganic materials 0.000 description 1
UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
150000002790 naphthalenes Chemical class 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
125000005474 octanoate group Chemical group 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
230000019612 pigmentation Effects 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000010453 quartz Substances 0.000 description 1
230000008707 rearrangement Effects 0.000 description 1
229910052701 rubidium Inorganic materials 0.000 description 1
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
229930182490 saponin Natural products 0.000 description 1
150000007949 saponins Chemical class 0.000 description 1
235000017709 saponins Nutrition 0.000 description 1
150000003335 secondary amines Chemical class 0.000 description 1
229920005573 silicon-containing polymer Polymers 0.000 description 1
229920002379 silicone rubber Polymers 0.000 description 1
235000019337 sorbitan trioleate Nutrition 0.000 description 1
229960000391 sorbitan trioleate Drugs 0.000 description 1
IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
239000004753 textile Substances 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
238000009736 wetting Methods 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)
Paints Or Removers (AREA)

CA330,246A 1979-06-21 1979-06-21 Emulsion au silicone pour la production d'un elastomere, et methodes de preparation connexes Expired CA1123530A (fr)

Priority Applications (2)

Application Number	Priority Date	Filing Date	Title
CA330,246A CA1123530A (fr)	1979-06-21	1979-06-21	Emulsion au silicone pour la production d'un elastomere, et methodes de preparation connexes
CA383,360A CA1130487A (fr)	1979-06-21	1981-08-06	Emulsion au silicone donnant un elastomere, et methode de preparation connexe

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA330,246A CA1123530A (fr)	1979-06-21	1979-06-21	Emulsion au silicone pour la production d'un elastomere, et methodes de preparation connexes

Publications (1)

Publication Number	Publication Date
CA1123530A true CA1123530A (fr)	1982-05-11

Family

ID=4114512

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA330,246A Expired CA1123530A (fr)	1979-06-21	1979-06-21	Emulsion au silicone pour la production d'un elastomere, et methodes de preparation connexes

Country Status (1)

Country	Link
CA (1)	CA1123530A (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN110475928A (zh) *	2017-03-31	2019-11-19	信越化学工业株式会社	粘固有有机硅的纤维及其制造方法
US11214920B2 (en)	2017-03-31	2022-01-04	Shin-Etsu Chemical Co., Ltd.	Fiber treatment agent for electron beam fixing

1979
- 1979-06-21 CA CA330,246A patent/CA1123530A/fr not_active Expired

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN110475928A (zh) *	2017-03-31	2019-11-19	信越化学工业株式会社	粘固有有机硅的纤维及其制造方法
US11214920B2 (en)	2017-03-31	2022-01-04	Shin-Etsu Chemical Co., Ltd.	Fiber treatment agent for electron beam fixing

Legal Events

Date	Code	Title	Description
1999-05-11	MKEX	Expiry

Publication	Publication Date	Title
US4221688A (en)	1980-09-09	Silicone emulsion which provides an elastomeric product and methods for preparation
EP0166396B1 (fr)	1990-08-08	Emulsions de polydiorganosiloxanes réticulés
CA1160379A (fr)	1984-01-10	Emulsion au silicone donnant un produit elastomerique, et methodes de preparation connexes
US2568384A (en)	1951-09-18	Stable solution
US3975294A (en)	1976-08-17	Surface active composition
US3360491A (en)	1967-12-26	Method of polymerizing siloxanes and silcarbanes in emulsion
US4052331A (en)	1977-10-04	Surface active composition
US4618645A (en)	1986-10-21	Method of producing aqueous latex of crosslinked polydiorganosiloxane
JPS6254824B2 (fr)	1987-11-17
CA1276352C (fr)	1990-11-13	Latex de polydiorganosiloxane
US11180656B2 (en)	2021-11-23	Silicone emulsion composition capable of being formed into coating film, and coating film
AU628225B2 (en)	1992-09-10	Aqueous dispersions of organopolysiloxanes
CA1276353C (fr)	1990-11-13	Emulsions de latex de polydiorganosiloxane arme
EP0029291B1 (fr)	1983-01-26	Procédé de préparation d'une émulsion au silicone préréticulée
EP0828794B1 (fr)	2000-01-19	Dispersions aqueuses d'organopolysiloxanes
JP3854670B2 (ja)	2006-12-06	シリコーン組成物
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EP1120434B1 (fr)	2003-06-18	Emulsions contenant des polymères silicone
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CA1123530A (fr)	1982-05-11	Emulsion au silicone pour la production d'un elastomere, et methodes de preparation connexes
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CA1123530A - Emulsion au silicone pour la production d'un elastomere, et methodes de preparation connexes - Google Patents

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