CA1124253A - Polymeres inorganiques organometalliques multicouche ou amorphes - Google Patents

Polymeres inorganiques organometalliques multicouche ou amorphes

Info

Publication number: CA1124253A
Authority: CA; Canada
Prior art keywords: compound; group; metal; phosphorus; groups
Prior art date: 1979-01-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA336,417A

Other languages

English (en)

Inventor

Victor E. Parziale

Peter M. Digiacomo

Martin B. Dines

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Occidental Research Corp

Original Assignee

Occidental Research Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-01-29

Filing date

1979-09-26

Publication date

1982-05-25

1979-09-26 Application filed by Occidental Research Corp filed Critical Occidental Research Corp

1982-05-25 Application granted granted Critical

1982-05-25 Publication of CA1124253A publication Critical patent/CA1124253A/fr

Status Expired legal-status Critical Current

Links

229920000592 inorganic polymer Polymers 0.000 title abstract description 26
125000002524 organometallic group Chemical group 0.000 title abstract description 3
229910052751 metal Inorganic materials 0.000 claims abstract description 59
239000002184 metal Substances 0.000 claims abstract description 59
229910052698 phosphorus Inorganic materials 0.000 claims abstract description 34
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 31
239000011574 phosphorus Substances 0.000 claims abstract description 31
125000000962 organic group Chemical group 0.000 claims abstract description 23
229910052760 oxygen Inorganic materials 0.000 claims abstract description 17
239000001301 oxygen Substances 0.000 claims abstract description 17
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 16
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims abstract description 10
229910052785 arsenic Inorganic materials 0.000 claims abstract description 9
229910052787 antimony Inorganic materials 0.000 claims abstract description 5
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 5
150000001875 compounds Chemical class 0.000 claims description 66
-1 alknyyl Chemical group 0.000 claims description 47
239000002253 acid Substances 0.000 claims description 33
238000000034 method Methods 0.000 claims description 33
239000007787 solid Substances 0.000 claims description 31
238000006243 chemical reaction Methods 0.000 claims description 26
125000003118 aryl group Chemical group 0.000 claims description 23
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 22
125000000623 heterocyclic group Chemical group 0.000 claims description 17
229910021645 metal ion Inorganic materials 0.000 claims description 16
230000008569 process Effects 0.000 claims description 15
125000004432 carbon atom Chemical group C* 0.000 claims description 14
239000007788 liquid Substances 0.000 claims description 14
125000002723 alicyclic group Chemical group 0.000 claims description 13
239000000203 mixture Substances 0.000 claims description 12
229910052757 nitrogen Inorganic materials 0.000 claims description 12
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 11
125000005842 heteroatom Chemical group 0.000 claims description 11
125000002015 acyclic group Chemical group 0.000 claims description 10
125000000217 alkyl group Chemical group 0.000 claims description 10
150000002739 metals Chemical class 0.000 claims description 10
229910052717 sulfur Inorganic materials 0.000 claims description 10
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 9
239000002609 medium Substances 0.000 claims description 9
229910052726 zirconium Inorganic materials 0.000 claims description 9
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 7
125000003342 alkenyl group Chemical group 0.000 claims description 7
239000003054 catalyst Substances 0.000 claims description 7
125000005843 halogen group Chemical group 0.000 claims description 7
125000000018 nitroso group Chemical group N(=O)* 0.000 claims description 7
239000000126 substance Substances 0.000 claims description 7
125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims description 7
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 6
125000003545 alkoxy group Chemical group 0.000 claims description 6
125000000304 alkynyl group Chemical group 0.000 claims description 6
125000001769 aryl amino group Chemical group 0.000 claims description 6
125000005110 aryl thio group Chemical group 0.000 claims description 6
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 6
ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 6
229920006395 saturated elastomer Polymers 0.000 claims description 6
238000001179 sorption measurement Methods 0.000 claims description 6
239000011593 sulfur Substances 0.000 claims description 6
239000010936 titanium Substances 0.000 claims description 6
125000003302 alkenyloxy group Chemical group 0.000 claims description 5
125000005108 alkenylthio group Chemical group 0.000 claims description 5
125000005248 alkyl aryloxy group Chemical group 0.000 claims description 5
125000004414 alkyl thio group Chemical group 0.000 claims description 5
125000005133 alkynyloxy group Chemical group 0.000 claims description 5
229910000147 aluminium phosphate Inorganic materials 0.000 claims description 5
125000004659 aryl alkyl thio group Chemical group 0.000 claims description 5
125000002102 aryl alkyloxo group Chemical group 0.000 claims description 5
125000004181 carboxyalkyl group Chemical group 0.000 claims description 5
239000010955 niobium Substances 0.000 claims description 5
229910052763 palladium Inorganic materials 0.000 claims description 5
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 4
125000002877 alkyl aryl group Chemical group 0.000 claims description 4
125000005196 alkyl carbonyloxy group Chemical group 0.000 claims description 4
125000005109 alkynylthio group Chemical group 0.000 claims description 4
125000001691 aryl alkyl amino group Chemical group 0.000 claims description 4
125000003710 aryl alkyl group Chemical group 0.000 claims description 4
125000004104 aryloxy group Chemical group 0.000 claims description 4
150000002500 ions Chemical class 0.000 claims description 4
229910052758 niobium Inorganic materials 0.000 claims description 4
GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 4
150000002894 organic compounds Chemical class 0.000 claims description 4
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
239000000376 reactant Substances 0.000 claims description 4
125000000446 sulfanediyl group Chemical group *S* 0.000 claims description 4
229910052715 tantalum Inorganic materials 0.000 claims description 4
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 4
229910052720 vanadium Inorganic materials 0.000 claims description 4
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims description 4
125000001931 aliphatic group Chemical group 0.000 claims description 3
125000004448 alkyl carbonyl group Chemical group 0.000 claims description 3
235000010290 biphenyl Nutrition 0.000 claims description 3
239000004305 biphenyl Substances 0.000 claims description 3
125000000753 cycloalkyl group Chemical group 0.000 claims description 3
125000001624 naphthyl group Chemical group 0.000 claims description 3
125000004043 oxo group Chemical group O=* 0.000 claims description 3
125000005561 phenanthryl group Chemical group 0.000 claims description 3
150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 3
ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 claims description 2
229910052776 Thorium Inorganic materials 0.000 claims description 2
239000012736 aqueous medium Substances 0.000 claims description 2
239000000470 constituent Substances 0.000 claims description 2
239000003085 diluting agent Substances 0.000 claims description 2
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 2
239000012457 nonaqueous media Substances 0.000 claims description 2
229910052684 Cerium Inorganic materials 0.000 claims 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
229910052770 Uranium Inorganic materials 0.000 claims 1
125000005157 alkyl carboxy group Chemical group 0.000 claims 1
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims 1
230000000536 complexating effect Effects 0.000 claims 1
238000013270 controlled release Methods 0.000 claims 1
230000001276 controlling effect Effects 0.000 claims 1
125000004093 cyano group Chemical group *C#N 0.000 claims 1
125000004122 cyclic group Chemical group 0.000 claims 1
229910052735 hafnium Inorganic materials 0.000 claims 1
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims 1
125000001475 halogen functional group Chemical group 0.000 claims 1
125000002349 hydroxyamino group Chemical group [H]ON([H])[*] 0.000 claims 1
150000002484 inorganic compounds Chemical class 0.000 claims 1
229910010272 inorganic material Inorganic materials 0.000 claims 1
229910052750 molybdenum Inorganic materials 0.000 claims 1
239000011733 molybdenum Substances 0.000 claims 1
125000004434 sulfur atom Chemical group 0.000 claims 1
229910052718 tin Inorganic materials 0.000 claims 1
229910052719 titanium Inorganic materials 0.000 claims 1
DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 claims 1
239000000047 product Substances 0.000 description 30
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 28
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 27
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 22
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
229910001868 water Inorganic materials 0.000 description 19
239000000243 solution Substances 0.000 description 17
239000010410 layer Substances 0.000 description 16
LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 description 12
239000011229 interlayer Substances 0.000 description 11
229910000166 zirconium phosphate Inorganic materials 0.000 description 11
229910052799 carbon Inorganic materials 0.000 description 10
239000013078 crystal Substances 0.000 description 10
239000000463 material Substances 0.000 description 10
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
125000004429 atom Chemical group 0.000 description 8
239000007795 chemical reaction product Substances 0.000 description 8
238000009830 intercalation Methods 0.000 description 8
230000002687 intercalation Effects 0.000 description 8
125000004437 phosphorous atom Chemical group 0.000 description 8
229920000642 polymer Polymers 0.000 description 8
239000007864 aqueous solution Substances 0.000 description 7
239000007789 gas Substances 0.000 description 7
239000012071 phase Substances 0.000 description 7
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
230000000694 effects Effects 0.000 description 6
238000002474 experimental method Methods 0.000 description 6
ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 6
229940116254 phosphonic acid Drugs 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
239000002904 solvent Substances 0.000 description 6
229910019142 PO4 Inorganic materials 0.000 description 5
238000004458 analytical method Methods 0.000 description 5
239000003153 chemical reaction reagent Substances 0.000 description 5
235000021317 phosphate Nutrition 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
238000010992 reflux Methods 0.000 description 5
ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 5
JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 4
QLZHNIAADXEJJP-UHFFFAOYSA-N Phenylphosphonic acid Chemical compound OP(O)(=O)C1=CC=CC=C1 QLZHNIAADXEJJP-UHFFFAOYSA-N 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
238000004587 chromatography analysis Methods 0.000 description 4
230000008878 coupling Effects 0.000 description 4
238000010168 coupling process Methods 0.000 description 4
238000005859 coupling reaction Methods 0.000 description 4
239000008367 deionised water Substances 0.000 description 4
229910021641 deionized water Inorganic materials 0.000 description 4
238000000921 elemental analysis Methods 0.000 description 4
239000010439 graphite Substances 0.000 description 4
229910002804 graphite Inorganic materials 0.000 description 4
229910052739 hydrogen Inorganic materials 0.000 description 4
239000001257 hydrogen Substances 0.000 description 4
125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
238000011068 loading method Methods 0.000 description 4
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 4
239000000843 powder Substances 0.000 description 4
238000000634 powder X-ray diffraction Methods 0.000 description 4
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
MGUOFTDTWAAJFI-UHFFFAOYSA-J P(OCCC(=O)O)([O-])=O.[Zr+4].C(=O)(O)CCOP([O-])=O.C(=O)(O)CCOP([O-])=O.C(=O)(O)CCOP([O-])=O Chemical compound P(OCCC(=O)O)([O-])=O.[Zr+4].C(=O)(O)CCOP([O-])=O.C(=O)(O)CCOP([O-])=O.C(=O)(O)CCOP([O-])=O MGUOFTDTWAAJFI-UHFFFAOYSA-J 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
238000010521 absorption reaction Methods 0.000 description 3
238000009835 boiling Methods 0.000 description 3
150000001721 carbon Chemical group 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
238000006555 catalytic reaction Methods 0.000 description 3
238000004132 cross linking Methods 0.000 description 3
238000000354 decomposition reaction Methods 0.000 description 3
238000009826 distribution Methods 0.000 description 3
238000000605 extraction Methods 0.000 description 3
238000001914 filtration Methods 0.000 description 3
239000003456 ion exchange resin Substances 0.000 description 3
229920003303 ion-exchange polymer Polymers 0.000 description 3
238000005649 metathesis reaction Methods 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
239000010452 phosphate Substances 0.000 description 3
239000002244 precipitate Substances 0.000 description 3
239000003352 sequestering agent Substances 0.000 description 3
239000007790 solid phase Substances 0.000 description 3
241000894007 species Species 0.000 description 3
VGBPIHVLVSGJGR-UHFFFAOYSA-N thorium(4+);tetranitrate Chemical compound [Th+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VGBPIHVLVSGJGR-UHFFFAOYSA-N 0.000 description 3
238000004448 titration Methods 0.000 description 3
NLBSQHGCGGFVJW-UHFFFAOYSA-N 2-carboxyethylphosphonic acid Chemical compound OC(=O)CCP(O)(O)=O NLBSQHGCGGFVJW-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
230000010849 Ion Exchange Activity Effects 0.000 description 2
241000446313 Lamella Species 0.000 description 2
YTNVMHWNIJXNGO-UHFFFAOYSA-N OC(CCOP(O)=O)=O Chemical compound OC(CCOP(O)=O)=O YTNVMHWNIJXNGO-UHFFFAOYSA-N 0.000 description 2
XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
150000001450 anions Chemical class 0.000 description 2
150000001495 arsenic compounds Chemical class 0.000 description 2
239000002734 clay mineral Substances 0.000 description 2
239000000356 contaminant Substances 0.000 description 2
238000001816 cooling Methods 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
JKESOGMEVRTUFJ-UHFFFAOYSA-J dioxido-oxo-phenyl-$l^{5}-phosphane;titanium(4+) Chemical compound [Ti+4].[O-]P([O-])(=O)C1=CC=CC=C1.[O-]P([O-])(=O)C1=CC=CC=C1 JKESOGMEVRTUFJ-UHFFFAOYSA-J 0.000 description 2
125000000524 functional group Chemical group 0.000 description 2
239000000499 gel Substances 0.000 description 2
230000036571 hydration Effects 0.000 description 2
238000006703 hydration reaction Methods 0.000 description 2
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
238000002329 infrared spectrum Methods 0.000 description 2
230000003993 interaction Effects 0.000 description 2
239000007791 liquid phase Substances 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
150000002736 metal compounds Chemical class 0.000 description 2
239000010445 mica Substances 0.000 description 2
229910052618 mica group Inorganic materials 0.000 description 2
150000002825 nitriles Chemical class 0.000 description 2
239000003960 organic solvent Substances 0.000 description 2
150000002903 organophosphorus compounds Chemical class 0.000 description 2
125000004430 oxygen atom Chemical group O* 0.000 description 2
238000010926 purge Methods 0.000 description 2
239000000741 silica gel Substances 0.000 description 2
229910002027 silica gel Inorganic materials 0.000 description 2
239000002594 sorbent Substances 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
230000003068 static effect Effects 0.000 description 2
238000003756 stirring Methods 0.000 description 2
238000006467 substitution reaction Methods 0.000 description 2
238000002411 thermogravimetry Methods 0.000 description 2
ACHFBMLQCUMVKK-UHFFFAOYSA-N zirconium(4+) tetraphosphite Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])[O-].[O-]P([O-])[O-].[O-]P([O-])[O-].[O-]P([O-])[O-] ACHFBMLQCUMVKK-UHFFFAOYSA-N 0.000 description 2
NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical class CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 1
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
NJDPBWLDVFCXNP-UHFFFAOYSA-N 2-cyanoethyl dihydrogen phosphate Chemical class OP(O)(=O)OCCC#N NJDPBWLDVFCXNP-UHFFFAOYSA-N 0.000 description 1
LRXRAYXMPXAFNK-UHFFFAOYSA-J 3-phosphonatopropanoic acid;zirconium(4+) Chemical group [Zr+4].OC(=O)CCP([O-])([O-])=O.OC(=O)CCP([O-])([O-])=O LRXRAYXMPXAFNK-UHFFFAOYSA-J 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
DJHGAFSJWGLOIV-UHFFFAOYSA-K Arsenate3- Chemical compound [O-][As]([O-])([O-])=O DJHGAFSJWGLOIV-UHFFFAOYSA-K 0.000 description 1
DJHGAFSJWGLOIV-UHFFFAOYSA-N Arsenic acid Chemical compound O[As](O)(O)=O DJHGAFSJWGLOIV-UHFFFAOYSA-N 0.000 description 1
GOLCXWYRSKYTSP-UHFFFAOYSA-N Arsenious Acid Chemical compound O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
229910004373 HOAc Inorganic materials 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
YJWKQHSZURAYOG-UHFFFAOYSA-J O.[Zr+4].OCP([O-])([O-])=O.OCP([O-])([O-])=O Chemical compound O.[Zr+4].OCP([O-])([O-])=O.OCP([O-])([O-])=O YJWKQHSZURAYOG-UHFFFAOYSA-J 0.000 description 1
JXRZUXSYKBTIQS-UHFFFAOYSA-J P(OCCC(=O)O)([O-])=O.[Th+4].C(=O)(O)CCOP([O-])=O.C(=O)(O)CCOP([O-])=O.C(=O)(O)CCOP([O-])=O Chemical compound P(OCCC(=O)O)([O-])=O.[Th+4].C(=O)(O)CCOP([O-])=O.C(=O)(O)CCOP([O-])=O.C(=O)(O)CCOP([O-])=O JXRZUXSYKBTIQS-UHFFFAOYSA-J 0.000 description 1
238000013494 PH determination Methods 0.000 description 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
OBOXTJCIIVUZEN-UHFFFAOYSA-N [C].[O] Chemical compound [C].[O] OBOXTJCIIVUZEN-UHFFFAOYSA-N 0.000 description 1
238000000862 absorption spectrum Methods 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
229910052768 actinide Inorganic materials 0.000 description 1
239000013543 active substance Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
229920006125 amorphous polymer Polymers 0.000 description 1
238000004873 anchoring Methods 0.000 description 1
DLISVFCFLGSHAB-UHFFFAOYSA-N antimony arsenic Chemical compound [As].[Sb] DLISVFCFLGSHAB-UHFFFAOYSA-N 0.000 description 1
238000013459 approach Methods 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
150000003974 aralkylamines Chemical class 0.000 description 1
RBFQJDQYXXHULB-UHFFFAOYSA-N arsane Chemical compound [AsH3] RBFQJDQYXXHULB-UHFFFAOYSA-N 0.000 description 1
229940000489 arsenate Drugs 0.000 description 1
229940000488 arsenic acid Drugs 0.000 description 1
VJWWIRSVNSXUAC-UHFFFAOYSA-N arsinic acid Chemical compound O[AsH2]=O VJWWIRSVNSXUAC-UHFFFAOYSA-N 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
230000001588 bifunctional effect Effects 0.000 description 1
125000005998 bromoethyl group Chemical group 0.000 description 1
150000001733 carboxylic acid esters Chemical class 0.000 description 1
125000002843 carboxylic acid group Chemical group 0.000 description 1
239000000969 carrier Substances 0.000 description 1
150000001767 cationic compounds Chemical class 0.000 description 1
230000008859 change Effects 0.000 description 1
238000012512 characterization method Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 1
239000004927 clay Substances 0.000 description 1
238000010668 complexation reaction Methods 0.000 description 1
239000008139 complexing agent Substances 0.000 description 1
239000010949 copper Substances 0.000 description 1
229910001431 copper ion Inorganic materials 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007812 deficiency Effects 0.000 description 1
230000018044 dehydration Effects 0.000 description 1
238000006297 dehydration reaction Methods 0.000 description 1
238000009831 deintercalation Methods 0.000 description 1
LLQAUQDKRBLKFG-UHFFFAOYSA-N diazenyloxy(nitro)cyanamide Chemical compound N=NON([N+](=O)[O-])C#N LLQAUQDKRBLKFG-UHFFFAOYSA-N 0.000 description 1
238000004455 differential thermal analysis Methods 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
QLZHNIAADXEJJP-UHFFFAOYSA-L dioxido-oxo-phenyl-$l^{5}-phosphane Chemical compound [O-]P([O-])(=O)C1=CC=CC=C1 QLZHNIAADXEJJP-UHFFFAOYSA-L 0.000 description 1
VPCDHAPSEZNONV-UHFFFAOYSA-J dioxido-oxo-phenyl-$l^{5}-phosphane;zirconium(4+) Chemical compound [Zr+4].[O-]P([O-])(=O)C1=CC=CC=C1.[O-]P([O-])(=O)C1=CC=CC=C1 VPCDHAPSEZNONV-UHFFFAOYSA-J 0.000 description 1
GPAYUJZHTULNBE-UHFFFAOYSA-N diphenylphosphine Chemical compound C=1C=CC=CC=1PC1=CC=CC=C1 GPAYUJZHTULNBE-UHFFFAOYSA-N 0.000 description 1
230000005518 electrochemistry Effects 0.000 description 1
230000003028 elevating effect Effects 0.000 description 1
DQYBDCGIPTYXML-UHFFFAOYSA-N ethoxyethane;hydrate Chemical compound O.CCOCC DQYBDCGIPTYXML-UHFFFAOYSA-N 0.000 description 1
ZJXZSIYSNXKHEA-UHFFFAOYSA-L ethyl phosphate(2-) Chemical compound CCOP([O-])([O-])=O ZJXZSIYSNXKHEA-UHFFFAOYSA-L 0.000 description 1
125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
238000011049 filling Methods 0.000 description 1
239000003063 flame retardant Substances 0.000 description 1
238000007667 floating Methods 0.000 description 1
239000012634 fragment Substances 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
238000007210 heterogeneous catalysis Methods 0.000 description 1
238000010505 homolytic fission reaction Methods 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
239000012535 impurity Substances 0.000 description 1
230000005764 inhibitory process Effects 0.000 description 1
229910001411 inorganic cation Inorganic materials 0.000 description 1
229910003480 inorganic solid Inorganic materials 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
125000005647 linker group Chemical group 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
238000005461 lubrication Methods 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
229910001507 metal halide Inorganic materials 0.000 description 1
150000005309 metal halides Chemical class 0.000 description 1
229910052976 metal sulfide Inorganic materials 0.000 description 1
239000013081 microcrystal Substances 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
125000001064 morpholinomethyl group Chemical group [H]C([H])(*)N1C([H])([H])C([H])([H])OC([H])([H])C1([H])[H] 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
125000006501 nitrophenyl group Chemical group 0.000 description 1
231100000252 nontoxic Toxicity 0.000 description 1
230000003000 nontoxic effect Effects 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
229920000620 organic polymer Polymers 0.000 description 1
238000000643 oven drying Methods 0.000 description 1
PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
230000035515 penetration Effects 0.000 description 1
ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
150000003009 phosphonic acids Chemical class 0.000 description 1
150000003017 phosphorus Chemical class 0.000 description 1
229910000073 phosphorus hydride Inorganic materials 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000010970 precious metal Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
230000005855 radiation Effects 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000004366 reverse phase liquid chromatography Methods 0.000 description 1
230000002441 reversible effect Effects 0.000 description 1
238000005070 sampling Methods 0.000 description 1
VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical group [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
239000012265 solid product Substances 0.000 description 1
238000004611 spectroscopical analysis Methods 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
150000004763 sulfides Chemical class 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
238000012360 testing method Methods 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1
238000004809 thin layer chromatography Methods 0.000 description 1
125000003396 thiol group Chemical class [H]S* 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
230000004580 weight loss Effects 0.000 description 1
238000009736 wetting Methods 0.000 description 1
DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1
GBNDTYKAOXLLID-UHFFFAOYSA-N zirconium(4+) ion Chemical compound [Zr+4] GBNDTYKAOXLLID-UHFFFAOYSA-N 0.000 description 1

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Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

CA336,417A 1979-01-29 1979-09-26 Polymeres inorganiques organometalliques multicouche ou amorphes Expired CA1124253A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US727579A	1979-01-29	1979-01-29
US007,275		1979-01-29

Publications (1)

Publication Number	Publication Date
CA1124253A true CA1124253A (fr)	1982-05-25

Family

ID=21725215

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA336,417A Expired CA1124253A (fr)	1979-01-29	1979-09-26	Polymeres inorganiques organometalliques multicouche ou amorphes

Country Status (1)

Country	Link
CA (1)	CA1124253A (fr)

1979
- 1979-09-26 CA CA336,417A patent/CA1124253A/fr not_active Expired

Legal Events

Date	Code	Title	Description
1999-05-25	MKEX	Expiry

Publication	Publication Date	Title
US4235991A (en)	1980-11-25	Layered sulfonate end terminated organophosphorus inorganic polymers
US4298723A (en)	1981-11-03	Layered or amorphous acyclic organometallic inorganic polymers
EP0010857B1 (fr)	1982-10-20	Polymères organométalliques-inorganiques stratifiés ou amorphes et leur utilisation
CA1124252A (fr)	1982-05-25	Polymeres inorganiques organometalliques multicouche ou amorphes
US4390690A (en)	1983-06-28	Layered organophosphorous inorganic polymers containing oxygen bonded to carbon
Benš et al.	1990	Intercalation of aliphatic carboxylic acids into layered structures of vanadyl sulfate, phosphate and arsenate
US4436899A (en)	1984-03-13	Layered organophosphorus inorganic polymers
US4256872A (en)	1981-03-17	Process for preparing layered organophosphorus inorganic polymers
US4276411A (en)	1981-06-30	Layered organophosphorus inorganic polymers containing acyclic groups
Poojary et al.	1994	Synthesis and crystal structure of a new layered zirconium phosphate compound, Zr (PO4) F (OSMe2)
US4235990A (en)	1980-11-25	Layered carboxy end terminated organophosphorus inorganic polymers
US4299943A (en)	1981-11-10	Nonaqueous preparation of layered or amorphous organometallic inorganic polymers
US4267308A (en)	1981-05-12	Layered zirconium bis(benzenephosphonate) inorganic polymers
US4373079A (en)	1983-02-08	Layered or amorphous cyclic organometallic inorganic polymers
US4374242A (en)	1983-02-15	Layered organoarsenous inorganic polymers
US4962228A (en)	1990-10-09	Layered divalent metal phosphates containing pendent substituent groups and their preparation
CA1124253A (fr)	1982-05-25	Polymeres inorganiques organometalliques multicouche ou amorphes
US4487922A (en)	1984-12-11	Layered organophosphorous inorganic polymers containing cyclic groups
US4276409A (en)	1981-06-30	Layered cyano end terminated organophosphorus inorganic polymers
US4276410A (en)	1981-06-30	Layered organophosphorus inorganic polymers containing mercapto or thio groups
US5072031A (en)	1991-12-10	Layered divalent metal phosphates containing pendent substituent groups and their preparation
EP0469682B1 (fr)	1994-12-14	Composé cristallin mésoporeux d'un métal tétravalent
US4429111A (en)	1984-01-31	Layered organophosphorus inorganic polymers containing mixed functional groups
Attig et al.	1977	Crystal structures of acid hydrates and oxonium salts. XV. The triclinic trihydrate and triclinic dihydrate of 5-sulphosalicylic acid, their water structures and structural relationship
Medeiros et al.	1992	Tin (IV) phosphonates with α-layered structure: synthesis and characterization