CA1124436A - Materiaux de separation pour systemes secondaires de piles alcalines et methode pour mesurer analytiquement l'efficacite de ces materiaux - Google Patents

Materiaux de separation pour systemes secondaires de piles alcalines et methode pour mesurer analytiquement l'efficacite de ces materiaux

Info

Publication number: CA1124436A
Authority: CA; Canada
Prior art keywords: separator; zinc; separator material; electrolyte; polymer component
Prior art date: 1977-09-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA312,229A

Other languages

English (en)

Inventor

James J. Bolstad

Giuseppe D. Bucci

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

GNB Inc

Original Assignee

Gould Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-09-30

Filing date

1978-09-27

Publication date

1982-05-25

1978-09-26 Priority claimed from US05/945,978 external-priority patent/US4221123A/en

1978-09-27 Application filed by Gould Inc filed Critical Gould Inc

1982-05-25 Application granted granted Critical

1982-05-25 Publication of CA1124436A publication Critical patent/CA1124436A/fr

Status Expired legal-status Critical Current

Links

239000000463 material Substances 0.000 title claims abstract description 125
238000000034 method Methods 0.000 title description 9
239000003792 electrolyte Substances 0.000 claims abstract description 31
229920000642 polymer Polymers 0.000 claims abstract description 27
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 76
229910052725 zinc Inorganic materials 0.000 claims description 76
239000011701 zinc Substances 0.000 claims description 76
230000035515 penetration Effects 0.000 claims description 28
239000011148 porous material Substances 0.000 claims description 28
241000894007 species Species 0.000 claims description 22
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 18
QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 claims description 13
-1 polyethylene Polymers 0.000 claims description 13
229920006242 ethylene acrylic acid copolymer Polymers 0.000 claims description 12
230000004888 barrier function Effects 0.000 claims description 9
229910052759 nickel Inorganic materials 0.000 claims description 9
229920001577 copolymer Polymers 0.000 claims description 7
239000004698 Polyethylene Substances 0.000 claims description 5
239000004743 Polypropylene Substances 0.000 claims description 5
229920000573 polyethylene Polymers 0.000 claims description 5
229920001155 polypropylene Polymers 0.000 claims description 5
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
229910052799 carbon Inorganic materials 0.000 claims description 4
239000004793 Polystyrene Substances 0.000 claims description 3
229920002223 polystyrene Polymers 0.000 claims description 3
150000001298 alcohols Chemical class 0.000 claims 2
150000001412 amines Chemical class 0.000 claims 2
150000001735 carboxylic acids Chemical class 0.000 claims 2
125000002560 nitrile group Chemical group 0.000 claims 2
150000003460 sulfonic acids Chemical class 0.000 claims 2
101000583218 Drosophila melanogaster Protein krasavietz Proteins 0.000 abstract 1
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 43
210000004027 cell Anatomy 0.000 description 33
238000012360 testing method Methods 0.000 description 27
238000009792 diffusion process Methods 0.000 description 19
238000004458 analytical method Methods 0.000 description 11
229920006226 ethylene-acrylic acid Polymers 0.000 description 9
239000000243 solution Substances 0.000 description 9
230000032258 transport Effects 0.000 description 9
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
210000001787 dendrite Anatomy 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
238000010521 absorption reaction Methods 0.000 description 5
238000002144 chemical decomposition reaction Methods 0.000 description 5
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
239000005977 Ethylene Substances 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
230000008859 change Effects 0.000 description 4
230000007423 decrease Effects 0.000 description 4
230000008021 deposition Effects 0.000 description 4
230000000694 effects Effects 0.000 description 4
238000010438 heat treatment Methods 0.000 description 4
239000000523 sample Substances 0.000 description 4
239000000126 substance Substances 0.000 description 4
230000008901 benefit Effects 0.000 description 3
230000015556 catabolic process Effects 0.000 description 3
230000007547 defect Effects 0.000 description 3
238000006731 degradation reaction Methods 0.000 description 3
238000009826 distribution Methods 0.000 description 3
239000000839 emulsion Substances 0.000 description 3
239000011521 glass Substances 0.000 description 3
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
238000003908 quality control method Methods 0.000 description 3
238000004626 scanning electron microscopy Methods 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
238000004566 IR spectroscopy Methods 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
230000003321 amplification Effects 0.000 description 2
238000005266 casting Methods 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
239000008151 electrolyte solution Substances 0.000 description 2
229940021013 electrolyte solution Drugs 0.000 description 2
239000007789 gas Substances 0.000 description 2
238000002173 high-resolution transmission electron microscopy Methods 0.000 description 2
230000007062 hydrolysis Effects 0.000 description 2
238000006460 hydrolysis reaction Methods 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
238000005259 measurement Methods 0.000 description 2
239000000203 mixture Substances 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
238000003199 nucleic acid amplification method Methods 0.000 description 2
239000002861 polymer material Substances 0.000 description 2
XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical group [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 2
238000001556 precipitation Methods 0.000 description 2
230000000717 retained effect Effects 0.000 description 2
238000001228 spectrum Methods 0.000 description 2
238000012795 verification Methods 0.000 description 2
229920002126 Acrylic acid copolymer Polymers 0.000 description 1
238000012935 Averaging Methods 0.000 description 1
229910014033 C-OH Inorganic materials 0.000 description 1
229910014570 C—OH Inorganic materials 0.000 description 1
239000004677 Nylon Substances 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
ZCDNRPPFBQDQHR-SSYATKPKSA-N Syrosingopine Chemical compound C1=C(OC)C(OC(=O)OCC)=C(OC)C=C1C(=O)O[C@H]1[C@H](OC)[C@@H](C(=O)OC)[C@H]2C[C@@H]3C(NC=4C5=CC=C(OC)C=4)=C5CCN3C[C@H]2C1 ZCDNRPPFBQDQHR-SSYATKPKSA-N 0.000 description 1
230000002745 absorbent Effects 0.000 description 1
239000002250 absorbent Substances 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
238000011888 autopsy Methods 0.000 description 1
235000013405 beer Nutrition 0.000 description 1
NSAODVHAXBZWGW-UHFFFAOYSA-N cadmium silver Chemical compound [Ag].[Cd] NSAODVHAXBZWGW-UHFFFAOYSA-N 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
230000001186 cumulative effect Effects 0.000 description 1
230000001351 cycling effect Effects 0.000 description 1
230000006378 damage Effects 0.000 description 1
230000000593 degrading effect Effects 0.000 description 1
238000006704 dehydrohalogenation reaction Methods 0.000 description 1
238000011161 development Methods 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
239000002001 electrolyte material Substances 0.000 description 1
238000005530 etching Methods 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000004744 fabric Substances 0.000 description 1
238000007654 immersion Methods 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
230000005764 inhibitory process Effects 0.000 description 1
239000010954 inorganic particle Substances 0.000 description 1
239000012212 insulator Substances 0.000 description 1
230000037427 ion transport Effects 0.000 description 1
230000001788 irregular Effects 0.000 description 1
230000002427 irreversible effect Effects 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000001000 micrograph Methods 0.000 description 1
239000000178 monomer Substances 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
229920001778 nylon Polymers 0.000 description 1
239000011368 organic material Substances 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
230000036961 partial effect Effects 0.000 description 1
239000002245 particle Substances 0.000 description 1
229940086255 perform Drugs 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
238000010248 power generation Methods 0.000 description 1
230000002028 premature Effects 0.000 description 1
230000008569 process Effects 0.000 description 1
230000005855 radiation Effects 0.000 description 1
238000011536 re-plating Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000001878 scanning electron micrograph Methods 0.000 description 1
BSWGGJHLVUUXTL-UHFFFAOYSA-N silver zinc Chemical compound [Zn].[Ag] BSWGGJHLVUUXTL-UHFFFAOYSA-N 0.000 description 1
238000002791 soaking Methods 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
230000003595 spectral effect Effects 0.000 description 1
230000007847 structural defect Effects 0.000 description 1
239000000758 substrate Substances 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1

Classifications

- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/411—Organic material
- H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/411—Organic material
- H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
- H01M50/417—Polyolefins
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0002—Aqueous electrolytes
- H01M2300/0014—Alkaline electrolytes
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
General Chemical & Material Sciences (AREA)
Cell Separators (AREA)
Secondary Cells (AREA)

CA312,229A 1977-09-30 1978-09-27 Materiaux de separation pour systemes secondaires de piles alcalines et methode pour mesurer analytiquement l'efficacite de ces materiaux Expired CA1124436A (fr)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US83835177A	1977-09-30	1977-09-30
US838,351		1977-09-30
US05/945,978 US4221123A (en)	1978-09-26	1978-09-26	Separator materials for secondary alkaline battery systems and method of analytically determining the suitability of such materials
US945,978		1978-09-26

Publications (1)

Publication Number	Publication Date
CA1124436A true CA1124436A (fr)	1982-05-25

Family

ID=27126019

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA312,229A Expired CA1124436A (fr)	1977-09-30	1978-09-27	Materiaux de separation pour systemes secondaires de piles alcalines et methode pour mesurer analytiquement l'efficacite de ces materiaux

Country Status (3)

Country	Link
CA (1)	CA1124436A (fr)
FR (1)	FR2404926A1 (fr)
GB (1)	GB2005290A (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1177534A (fr) *	1980-11-26	1984-11-06	John E. Bennett	Accumulateur au lithium et a l'ammoniate de soufre
CN117790915B (zh) *	2023-12-27	2024-09-17	天科新能源有限责任公司	一种钠离子电池正负极电解质隔膜层叠控制系统

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1470131A (fr) *	1965-02-26	1967-02-17	Radiation Applic Inc	Séparateur pour piles alcalines
US3585081A (en) *	1968-09-16	1971-06-15	Alfred Harris Mirman	Battery separator
US3684580A (en) *	1970-08-19	1972-08-15	Michael J Lysaght	Battery separator materials
JPS4854446A (fr) *	1971-11-12	1973-07-31
GB1451892A (en) *	1972-09-25	1976-10-06	Secr Defence	Separators for electrolytic cells
US3925332A (en) *	1974-06-18	1975-12-09	Asahi Dow Ltd	Hydrophilic membrane and process for the preparation thereof
JPS52101436A (en) *	1976-02-20	1977-08-25	Hitachi Maxell	Zinc alkali secondary battery
JPS52112740A (en) *	1976-03-17	1977-09-21	Hitachi Maxell	Zinc alkali secondary battery
JPS5524658A (en) *	1978-08-11	1980-02-21	Seiko Instr & Electronics Ltd	Inspecting circuit for electronic watch

1978
- 1978-09-27 CA CA312,229A patent/CA1124436A/fr not_active Expired
- 1978-09-29 FR FR7827961A patent/FR2404926A1/fr not_active Withdrawn
- 1978-09-29 GB GB7838782A patent/GB2005290A/en not_active Withdrawn

Also Published As

Publication number	Publication date
GB2005290A (en)	1979-04-19
FR2404926A1 (fr)	1979-04-27

Legal Events

Date	Code	Title	Description
1999-05-25	MKEX	Expiry

Publication	Publication Date	Title
KR100286147B1 (ko)	2001-04-16	전지용 격리판 및 전지
Yu et al.	1999	Determination of the lithium ion diffusion coefficient in graphite
US5589295A (en)	1996-12-31	Thin film polymeric gel electrolytes
Mastragostino et al.	1983	Polymeric salt as bromine complexing agent in a Zn-Br2 model battery
JPH08507407A (ja)	1996-08-06	ハイブリッド重合体電解質を用いた再充電可能リチウム挿入電池
Zhu et al.	1998	Effects of ionomer films on secondary alkaline zinc electrodes
BRPI0617556A2 (pt)	2011-07-26	bateria e bateria de lÍtio
Ribes et al.	1996	Correlation between cycling efficiency and surface morphology of electrodeposited lithium. Effect of fluorinated surface active additives
Hamlen et al.	1969	Anodes for refuelable magnesium‐air batteries
US4221123A (en)	1980-09-09	Separator materials for secondary alkaline battery systems and method of analytically determining the suitability of such materials
US5376478A (en)	1994-12-27	Lithium secondary battery of vanadium pentoxide and polyphosphazene
CA1124436A (fr)	1982-05-25	Materiaux de separation pour systemes secondaires de piles alcalines et methode pour mesurer analytiquement l'efficacite de ces materiaux
US3485673A (en)	1969-12-23	Nickel-zinc battery system having an aqueous electrolyte consisting of potassium hydroxide and potassium carbonate
US4287272A (en)	1981-09-01	Cell separator and cell
CN114976488B (zh)	2024-06-04	隔膜及其制备方法、锂离子电池
Ciszewski et al.	2007	Usefulness of microporous hydrophobic polypropylene membranes after plasma-induced graft polymerization of acrylic acid for high-power nickel–cadmium batteries
US20020182499A1 (en)	2002-12-05	Battery separator with copper-containing inorganic salt
US4544616A (en)	1985-10-01	Secondary battery containing zinc electrode with modified separator and method
CA2117100A1 (fr)	1994-10-14	Methode pour fabriquer une pellicule separatrice polymerique electrolytiquement conductrice pour accumulateur, et pellicule ainsi obtenue
US7029792B2 (en)	2006-04-18	Recombinant separator
JP2003288945A (ja)	2003-10-10	ガルヴァーニ電池の製造方法
JPH10275608A (ja)	1998-10-13	アルカリ亜鉛蓄電池用セパレータ及びアルカリ亜鉛蓄電池
Nishiura et al.	1998	Application of alkylene oxide gel polymer electrolytes to lithium rechargeable batteries
JP4152454B2 (ja)	2008-09-17	アルカリ亜鉛電池用セパレータ
JP6589439B2 (ja)	2019-10-16	アルカリ蓄電池