CA1125083A - Compositions de visualisation a base de complexe de cobalt(iii) contenant un dialdehyde aromatique, comme agent precurseur reducteur, et de la triazine s, comme agent oxydant - Google Patents

Compositions de visualisation a base de complexe de cobalt(iii) contenant un dialdehyde aromatique, comme agent precurseur reducteur, et de la triazine s, comme agent oxydant

Info

Publication number: CA1125083A
Authority: CA; Canada
Prior art keywords: iii; cobalt; composition; oxidizing agent; triazine
Prior art date: 1979-10-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA345,835A

Other languages

English (en)

Inventor

Thap Dominh

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Eastman Kodak Co

Original Assignee

Eastman Kodak Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-10-22

Filing date

1980-02-18

Publication date

1982-06-08

1980-02-18 Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co

1982-06-08 Application granted granted Critical

1982-06-08 Publication of CA1125083A publication Critical patent/CA1125083A/fr

Status Expired legal-status Critical Current

Links

JAWGVVJVYSANRY-UHFFFAOYSA-N cobalt(3+) Chemical compound [Co+3] JAWGVVJVYSANRY-UHFFFAOYSA-N 0.000 title claims abstract description 45
239000000203 mixture Substances 0.000 title claims abstract description 36
239000007800 oxidant agent Substances 0.000 title claims abstract description 23
239000003638 chemical reducing agent Substances 0.000 title claims abstract description 18
125000003118 aryl group Chemical group 0.000 title claims abstract description 16
ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 title claims abstract description 13
238000003384 imaging method Methods 0.000 title claims abstract description 10
JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 title claims description 7
239000002243 precursor Substances 0.000 title description 12
150000001412 amines Chemical class 0.000 claims abstract description 19
239000003446 ligand Substances 0.000 claims abstract description 15
239000003795 chemical substances by application Substances 0.000 claims description 13
ZWLUXSQADUDCSB-UHFFFAOYSA-N phthalaldehyde Chemical group O=CC1=CC=CC=C1C=O ZWLUXSQADUDCSB-UHFFFAOYSA-N 0.000 claims description 9
125000004429 atom Chemical group 0.000 claims description 7
150000001875 compounds Chemical class 0.000 claims description 7
230000005855 radiation Effects 0.000 claims description 6
229910052736 halogen Inorganic materials 0.000 claims description 5
238000000034 method Methods 0.000 claims description 5
230000003213 activating effect Effects 0.000 claims description 3
238000010438 heat treatment Methods 0.000 claims description 3
GOTIJEQQGSMAIN-UHFFFAOYSA-N 2-methyl-4,6-bis(tribromomethyl)-1,3,5-triazine Chemical group CC1=NC(C(Br)(Br)Br)=NC(C(Br)(Br)Br)=N1 GOTIJEQQGSMAIN-UHFFFAOYSA-N 0.000 claims 2
125000005843 halogen group Chemical group 0.000 claims 2
-1 cobalt com-plexes Chemical class 0.000 description 19
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 17
229910017052 cobalt Inorganic materials 0.000 description 16
239000010941 cobalt Substances 0.000 description 16
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
239000011230 binding agent Substances 0.000 description 8
238000009740 moulding (composite fabrication) Methods 0.000 description 8
239000011248 coating agent Substances 0.000 description 7
238000000576 coating method Methods 0.000 description 7
AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 6
BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 6
239000000463 material Substances 0.000 description 6
150000004053 quinones Chemical class 0.000 description 6
238000006722 reduction reaction Methods 0.000 description 6
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 5
229910021529 ammonia Inorganic materials 0.000 description 5
150000001450 anions Chemical class 0.000 description 5
VZVHUBYZGAUXLX-UHFFFAOYSA-N azane;azanide;cobalt(3+) Chemical compound N.N.N.[NH2-].[NH2-].[NH2-].[Co+3] VZVHUBYZGAUXLX-UHFFFAOYSA-N 0.000 description 5
229920000642 polymer Polymers 0.000 description 5
125000001424 substituent group Chemical group 0.000 description 5
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
230000007935 neutral effect Effects 0.000 description 4
VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 4
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 4
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
150000001768 cations Chemical class 0.000 description 3
GXWORUBZHJHIGI-UHFFFAOYSA-K cobalt(3+);triperchlorate Chemical compound [Co+3].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O GXWORUBZHJHIGI-UHFFFAOYSA-K 0.000 description 3
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
JGUQDUKBUKFFRO-CIIODKQPSA-N dimethylglyoxime Chemical compound O/N=C(/C)\C(\C)=N\O JGUQDUKBUKFFRO-CIIODKQPSA-N 0.000 description 3
230000000694 effects Effects 0.000 description 3
150000002367 halogens Chemical class 0.000 description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
239000000047 product Substances 0.000 description 3
239000002904 solvent Substances 0.000 description 3
QVQOGNOOAMQKCE-ZTYVOHGWSA-N (2s)-n-[(2s)-1-[(2-amino-2-oxoethyl)amino]-5-(diaminomethylideneamino)-1-oxopentan-2-yl]-1-[(10r,13s,16s,19s,22s)-13-(2-amino-2-oxoethyl)-16-(3-amino-3-oxopropyl)-19-benzyl-22-[(4-methoxyphenyl)methyl]-12,15,18,21,24-pentaoxo-7,8-dithia-11,14,17,20,23-pen Chemical compound C1=CC(OC)=CC=C1C[C@H]1C(=O)N[C@@H](CC=2C=CC=CC=2)C(=O)N[C@@H](CCC(N)=O)C(=O)N[C@@H](CC(N)=O)C(=O)N[C@H](C(=O)N2[C@@H](CCC2)C(=O)N[C@@H](CCCN=C(N)N)C(=O)NCC(N)=O)CSSC2(CCCCC2)CC(=O)N1 QVQOGNOOAMQKCE-ZTYVOHGWSA-N 0.000 description 2
108700005160 1-(1-mercaptocyclohexaneacetic acid)-2-(O- methyl-L-tyrosine)-8-L-arginine- vasopressin Proteins 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 2
DTQVDTLACAAQTR-UHFFFAOYSA-M Trifluoroacetate Chemical compound [O-]C(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-M 0.000 description 2
125000003342 alkenyl group Chemical group 0.000 description 2
125000003545 alkoxy group Chemical group 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
QSQUFRGBXGXOHF-UHFFFAOYSA-N cobalt(iii) nitrate Chemical compound [Co].O[N+]([O-])=O.O[N+]([O-])=O.O[N+]([O-])=O QSQUFRGBXGXOHF-UHFFFAOYSA-N 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
230000007246 mechanism Effects 0.000 description 2
229940054441 o-phthalaldehyde Drugs 0.000 description 2
YZERDTREOUSUHF-UHFFFAOYSA-N pentafluorobenzoic acid Chemical compound OC(=O)C1=C(F)C(F)=C(F)C(F)=C1F YZERDTREOUSUHF-UHFFFAOYSA-N 0.000 description 2
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
229910052709 silver Inorganic materials 0.000 description 2
239000004332 silver Substances 0.000 description 2
125000003107 substituted aryl group Chemical group 0.000 description 2
ROWMQJJMCWDJDT-UHFFFAOYSA-N tribromomethane Chemical compound Br[C](Br)Br ROWMQJJMCWDJDT-UHFFFAOYSA-N 0.000 description 2
XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 2
GVTLFGJNTIRUEG-ZHACJKMWSA-N (e)-n-(3-methoxyphenyl)-3-phenylprop-2-enamide Chemical compound COC1=CC=CC(NC(=O)\C=C\C=2C=CC=CC=2)=C1 GVTLFGJNTIRUEG-ZHACJKMWSA-N 0.000 description 1
QDNPCYCBQFHNJC-UHFFFAOYSA-N 1,1'-biphenyl-3,4-diol Chemical compound C1=C(O)C(O)=CC=C1C1=CC=CC=C1 QDNPCYCBQFHNJC-UHFFFAOYSA-N 0.000 description 1
150000004055 1,2-benzoquinones Chemical class 0.000 description 1
150000004057 1,4-benzoquinones Chemical class 0.000 description 1
JAAIPIWKKXCNOC-UHFFFAOYSA-N 1h-tetrazol-1-ium-5-thiolate Chemical class SC1=NN=NN1 JAAIPIWKKXCNOC-UHFFFAOYSA-N 0.000 description 1
XETLOFNELZCXMX-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-(4-hexoxyphenyl)-2-hydroxy-2-phenylacetate;hydrochloride Chemical compound Cl.C1=CC(OCCCCCC)=CC=C1C(O)(C(=O)OCCN(CC)CC)C1=CC=CC=C1 XETLOFNELZCXMX-UHFFFAOYSA-N 0.000 description 1
QKRFTDNUEHPOJG-UHFFFAOYSA-N 2-chloro-3-propan-2-yloxynaphthalene-1,4-dione Chemical compound C1=CC=C2C(=O)C(OC(C)C)=C(Cl)C(=O)C2=C1 QKRFTDNUEHPOJG-UHFFFAOYSA-N 0.000 description 1
FNRMMDCDHWCQTH-UHFFFAOYSA-N 2-chloropyridine;3-chloropyridine;4-chloropyridine Chemical compound ClC1=CC=NC=C1.ClC1=CC=CN=C1.ClC1=CC=CC=N1 FNRMMDCDHWCQTH-UHFFFAOYSA-N 0.000 description 1
BNCADMBVWNPPIZ-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical compound COCN(COC)C1=NC(N(COC)COC)=NC(N(COC)COC)=N1 BNCADMBVWNPPIZ-UHFFFAOYSA-N 0.000 description 1
FLGUVXZLKJMWCN-UHFFFAOYSA-N 2-propan-2-yloxyanthracene-1,4-dione Chemical compound C1=CC=C2C=C(C(C(OC(C)C)=CC3=O)=O)C3=CC2=C1 FLGUVXZLKJMWCN-UHFFFAOYSA-N 0.000 description 1
UPLMJIUMVHVVAB-UHFFFAOYSA-N 2-propan-2-yloxynaphthalene-1,4-dione Chemical compound C1=CC=C2C(=O)C(OC(C)C)=CC(=O)C2=C1 UPLMJIUMVHVVAB-UHFFFAOYSA-N 0.000 description 1
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
108010010803 Gelatin Proteins 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
239000002841 Lewis acid Substances 0.000 description 1
AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 1
229920001744 Polyaldehyde Polymers 0.000 description 1
LCTONWCANYUPML-UHFFFAOYSA-M Pyruvate Chemical compound CC(=O)C([O-])=O LCTONWCANYUPML-UHFFFAOYSA-M 0.000 description 1
239000007983 Tris buffer Substances 0.000 description 1
CUNHLNUZHNUYKR-UHFFFAOYSA-H [Co+3].[Co+3].NCCN.NCCN.NCCN.[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F Chemical compound [Co+3].[Co+3].NCCN.NCCN.NCCN.[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F CUNHLNUZHNUYKR-UHFFFAOYSA-H 0.000 description 1
150000001242 acetic acid derivatives Chemical class 0.000 description 1
239000012190 activator Substances 0.000 description 1
125000005041 acyloxyalkyl group Chemical group 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
125000004183 alkoxy alkyl group Chemical group 0.000 description 1
125000004448 alkyl carbonyl group Chemical group 0.000 description 1
125000005599 alkyl carboxylate group Chemical group 0.000 description 1
150000001413 amino acids Chemical class 0.000 description 1
125000004103 aminoalkyl group Chemical group 0.000 description 1
125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 1
230000003321 amplification Effects 0.000 description 1
125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
150000004056 anthraquinones Chemical class 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
125000005160 aryl oxy alkyl group Chemical group 0.000 description 1
125000004104 aryloxy group Chemical group 0.000 description 1
150000001540 azides Chemical class 0.000 description 1
239000002585 base Substances 0.000 description 1
125000001164 benzothiazolyl group Chemical group S1C(=NC2=C1C=CC=C2)* 0.000 description 1
239000007844 bleaching agent Substances 0.000 description 1
230000031709 bromination Effects 0.000 description 1
238000005893 bromination reaction Methods 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
230000001680 brushing effect Effects 0.000 description 1
235000013877 carbamide Nutrition 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
125000005587 carbonate group Chemical group 0.000 description 1
ABDBNWQRPYOPDF-UHFFFAOYSA-N carbonofluoridic acid Chemical compound OC(F)=O ABDBNWQRPYOPDF-UHFFFAOYSA-N 0.000 description 1
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
125000005518 carboxamido group Chemical group 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
229920002678 cellulose Chemical class 0.000 description 1
239000001913 cellulose Chemical class 0.000 description 1
230000005591 charge neutralization Effects 0.000 description 1
239000013522 chelant Substances 0.000 description 1
229910052729 chemical element Inorganic materials 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
238000005660 chlorination reaction Methods 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
239000008199 coating composition Substances 0.000 description 1
SPBNESDHQFJNNO-UHFFFAOYSA-K cobalt(3+);2,2,2-trifluoroacetate Chemical compound [Co+3].[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F SPBNESDHQFJNNO-UHFFFAOYSA-K 0.000 description 1
UEOPTWSPXHQVKF-UHFFFAOYSA-K cobalt(3+);2,2-dichloroacetate Chemical compound [Co+3].[O-]C(=O)C(Cl)Cl.[O-]C(=O)C(Cl)Cl.[O-]C(=O)C(Cl)Cl UEOPTWSPXHQVKF-UHFFFAOYSA-K 0.000 description 1
NMBDAQCKNYPFCW-UHFFFAOYSA-K cobalt(3+);2-pyridin-2-ylpyridine;triperchlorate Chemical compound [Co+3].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.N1=CC=CC=C1C1=CC=CC=N1.N1=CC=CC=C1C1=CC=CC=N1.N1=CC=CC=C1C1=CC=CC=N1 NMBDAQCKNYPFCW-UHFFFAOYSA-K 0.000 description 1
RNFWKDPQYKOMHP-UHFFFAOYSA-K cobalt(3+);carbonate;perchlorate Chemical compound [Co+3].[O-]C([O-])=O.[O-]Cl(=O)(=O)=O RNFWKDPQYKOMHP-UHFFFAOYSA-K 0.000 description 1
JHBWUDJPQWKJHP-UHFFFAOYSA-N cobalt(3+);ethane-1,2-diamine Chemical compound [Co+3].NCCN.NCCN.NCCN JHBWUDJPQWKJHP-UHFFFAOYSA-N 0.000 description 1
229940000425 combination drug Drugs 0.000 description 1
XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000007812 deficiency Effects 0.000 description 1
125000003963 dichloro group Chemical group Cl* 0.000 description 1
125000006575 electron-withdrawing group Chemical group 0.000 description 1
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
229920000159 gelatin Polymers 0.000 description 1
239000008273 gelatin Substances 0.000 description 1
235000019322 gelatine Nutrition 0.000 description 1
235000011852 gelatine desserts Nutrition 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
125000005842 heteroatom Chemical group 0.000 description 1
125000000623 heterocyclic group Chemical group 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
230000005764 inhibitory process Effects 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
150000007517 lewis acids Chemical class 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
239000000178 monomer Substances 0.000 description 1
150000004780 naphthols Chemical class 0.000 description 1
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
238000003199 nucleic acid amplification method Methods 0.000 description 1
SCOAVUHOIJMIBW-UHFFFAOYSA-N phenanthrene-1,2-dione Chemical class C1=CC=C2C(C=CC(C3=O)=O)=C3C=CC2=C1 SCOAVUHOIJMIBW-UHFFFAOYSA-N 0.000 description 1
ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical group [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical group [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920003214 poly(methacrylonitrile) Polymers 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920000139 polyethylene terephthalate Polymers 0.000 description 1
239000005020 polyethylene terephthalate Substances 0.000 description 1
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
238000007639 printing Methods 0.000 description 1
125000004076 pyridyl group Chemical group 0.000 description 1
125000002112 pyrrolidino group Chemical group [*]N1C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
125000002943 quinolinyl group Chemical group N1=C(C=CC2=CC=CC=C12)* 0.000 description 1
239000000376 reactant Substances 0.000 description 1
125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
239000000243 solution Substances 0.000 description 1
KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
229940124530 sulfonamide Drugs 0.000 description 1
150000003456 sulfonamides Chemical class 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
150000007944 thiolates Chemical class 0.000 description 1
150000003918 triazines Chemical class 0.000 description 1
150000003852 triazoles Chemical class 0.000 description 1
ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 description 1
150000003672 ureas Chemical class 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/67—Compositions containing cobalt salts or cobalt compounds as photosensitive substances

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Physics & Mathematics (AREA)
General Physics & Mathematics (AREA)
Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)

CA345,835A 1979-10-22 1980-02-18 Compositions de visualisation a base de complexe de cobalt(iii) contenant un dialdehyde aromatique, comme agent precurseur reducteur, et de la triazine s, comme agent oxydant Expired CA1125083A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US8719079A	1979-10-22	1979-10-22
US87,190		1979-10-22

Publications (1)

Publication Number	Publication Date
CA1125083A true CA1125083A (fr)	1982-06-08

Family

ID=22203624

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA345,835A Expired CA1125083A (fr)	1979-10-22	1980-02-18	Compositions de visualisation a base de complexe de cobalt(iii) contenant un dialdehyde aromatique, comme agent precurseur reducteur, et de la triazine s, comme agent oxydant

Country Status (5)

Country	Link
JP (1)	JPS5672436A (fr)
CA (1)	CA1125083A (fr)
DE (1)	DE3039279C2 (fr)
FR (1)	FR2468148B1 (fr)
GB (1)	GB2062272B (fr)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1116915A (fr) *	1977-12-28	1982-01-26	Anthony Adin	Inhibition de la formation d'images au moyen de complexes de cobalt (iii)

1980
- 1980-02-18 CA CA345,835A patent/CA1125083A/fr not_active Expired
- 1980-10-17 DE DE19803039279 patent/DE3039279C2/de not_active Expired
- 1980-10-20 FR FR8022367A patent/FR2468148B1/fr not_active Expired
- 1980-10-20 JP JP14676480A patent/JPS5672436A/ja active Pending
- 1980-10-21 GB GB8033918A patent/GB2062272B/en not_active Expired

Also Published As

Publication number	Publication date
DE3039279C2 (de)	1984-01-12
DE3039279A1 (de)	1981-04-30
GB2062272A (en)	1981-05-20
FR2468148A1 (fr)	1981-04-30
FR2468148B1 (fr)	1986-02-14
GB2062272B (en)	1983-07-20
JPS5672436A (en)	1981-06-16

Legal Events

Date	Code	Title	Description
1999-06-08	MKEX	Expiry

Publication	Publication Date	Title
US5153104A (en)	1992-10-06	Thermally developable light-sensitive layers containing photobleachable sensitizers
US4247625A (en)	1981-01-27	Imaging processes, elements and compositions featuring dye-retaining binders for reaction products of cobalt complexes and aromatic dialdehyde
US4196002A (en)	1980-04-01	Photothermographic element containing heat sensitive dye materials
US4138265A (en)	1979-02-06	Antifoggants in certain photographic and photothermographic materials that include silver salts of 3-amino-1,2,4-mercaptotriazole
US4201590A (en)	1980-05-06	Heat sensitive reactive products of hexaarylbiimidazole and antihalation dyes
US4201588A (en)	1980-05-06	Radiation sensitive co(III)complex photoreduction element with image recording layer
US4273860A (en)	1981-06-16	Inhibition of image formation utilizing cobalt(III) complexes
CA1116915A (fr)	1982-01-26	Inhibition de la formation d'images au moyen de complexes de cobalt (iii)
CA1125083A (fr)	1982-06-08	Compositions de visualisation a base de complexe de cobalt(iii) contenant un dialdehyde aromatique, comme agent precurseur reducteur, et de la triazine s, comme agent oxydant
US4318977A (en)	1982-03-09	Cobalt (III) complex imaging compositions having improved photographic properties
US4294912A (en)	1981-10-13	Thermally responsive cobalt(III) complex imaging compositions having lowered activation temperatures
CA1139148A (fr)	1983-01-11	Composes de visualisation a complexe de cobalt (iii) comprenant un precurseur d'agent reducteur et un antivoile organique
US3856531A (en)	1974-12-24	Photographic compositions and processes
US4308341A (en)	1981-12-29	Non-silver imaging compositions having improved speeds and processing temperatures
US3764335A (en)	1973-10-09	Image forming compositions including an azide and transition metal complexes of triorganophosphines
US4410623A (en)	1983-10-18	Phthalaldehyde adduct and imaging compositions, elements and methods incorporating same
US4130426A (en)	1978-12-19	Heat developable light-sensitive diazotype materials and process of use
CA1116917A (fr)	1982-01-26	Materiel photothermographique a pouvoir de couverture et contenant un agent de formation de germes a base d'hydrazine-thiouree
US3113865A (en)	1963-12-10	Heat developable diazo sulfones
US3767409A (en)	1973-10-23	Photographic triorganophosphine-azide dye forming composition and article
US4288531A (en)	1981-09-08	Imaging elements
US4195998A (en)	1980-04-01	CO(III) Complex containing radiation sensitive element with diazo recording layer
EP0029837B1 (fr)	1984-04-25	Stabilisateurs photothermographiques
GB1584851A (en)	1981-02-18	Photographic imaging element
CA1144412A (fr)	1983-04-12	Element qui renferme une couche de colorant a base de o-dialdehyde aromatique, une composition de visualisation photosensible, et une couche surimposee de polymere