CA1127646A - Derives de triazine, leur fabrication, et leur emploi comme stabilisateurs des polymeres synthetiques - Google Patents

Derives de triazine, leur fabrication, et leur emploi comme stabilisateurs des polymeres synthetiques

Info

Publication number: CA1127646A
Authority: CA; Canada
Prior art keywords: formula; group; compound; hydrogen; polymer
Prior art date: 1979-08-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA358,403A

Other languages

English (en)

Inventor

Hartmut Wiezer

Gerhard Pfahler

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Hoechst AG

Original Assignee

Hoechst AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-08-16

Filing date

1980-08-15

Publication date

1982-07-13

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6078526&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA1127646(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1980-08-15 Application filed by Hoechst AG filed Critical Hoechst AG

1982-07-13 Application granted granted Critical

1982-07-13 Publication of CA1127646A publication Critical patent/CA1127646A/fr

Status Expired legal-status Critical Current

Links

239000003381 stabilizer Substances 0.000 title claims description 29
229920001059 synthetic polymer Polymers 0.000 title claims description 3
150000003918 triazines Chemical class 0.000 title abstract description 5
238000004519 manufacturing process Methods 0.000 title description 5
150000001875 compounds Chemical class 0.000 claims abstract description 36
229920000642 polymer Polymers 0.000 claims abstract description 21
150000004820 halides Chemical class 0.000 claims abstract description 9
-1 triazine compound Chemical class 0.000 claims description 42
229910052739 hydrogen Inorganic materials 0.000 claims description 22
239000001257 hydrogen Substances 0.000 claims description 22
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 15
238000006243 chemical reaction Methods 0.000 claims description 15
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 12
229920001577 copolymer Polymers 0.000 claims description 12
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 12
238000000034 method Methods 0.000 claims description 11
239000000203 mixture Substances 0.000 claims description 9
125000004432 carbon atom Chemical group C* 0.000 claims description 8
150000002431 hydrogen Chemical class 0.000 claims description 7
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 6
229910052736 halogen Inorganic materials 0.000 claims description 6
150000002367 halogens Chemical class 0.000 claims description 6
239000004793 Polystyrene Substances 0.000 claims description 5
125000006702 (C1-C18) alkyl group Chemical group 0.000 claims description 4
125000006527 (C1-C5) alkyl group Chemical group 0.000 claims description 4
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229920002223 polystyrene Polymers 0.000 claims description 2
235000013350 formula milk Nutrition 0.000 claims 17
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FKLJPTJMIBLJAV-UHFFFAOYSA-N Compound IV Chemical compound O1N=C(C)C=C1CCCCCCCOC1=CC=C(C=2OCCN=2)C=C1 FKLJPTJMIBLJAV-UHFFFAOYSA-N 0.000 claims 1
239000003054 catalyst Substances 0.000 claims 1
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239000004611 light stabiliser Substances 0.000 abstract description 3
238000013508 migration Methods 0.000 abstract description 2
230000005012 migration Effects 0.000 abstract description 2
125000003386 piperidinyl group Chemical group 0.000 abstract description 2
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JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 6
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
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MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 5
229940044603 styrene Drugs 0.000 description 5
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 4
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ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
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239000000654 additive Substances 0.000 description 3
150000001298 alcohols Chemical class 0.000 description 3
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 3
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239000004593 Epoxy Substances 0.000 description 2
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CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
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VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
230000000875 corresponding effect Effects 0.000 description 2
RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
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239000000835 fiber Substances 0.000 description 2
239000000706 filtrate Substances 0.000 description 2
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238000005580 one pot reaction Methods 0.000 description 2
229940059574 pentaerithrityl Drugs 0.000 description 2
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BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
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KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 2
150000003254 radicals Chemical class 0.000 description 2
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XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 2
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HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 1
OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
IHWDIGHWDQPQMQ-UHFFFAOYSA-N 1-octadecylsulfanyloctadecane Chemical compound CCCCCCCCCCCCCCCCCCSCCCCCCCCCCCCCCCCCC IHWDIGHWDQPQMQ-UHFFFAOYSA-N 0.000 description 1
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VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
150000002191 fatty alcohols Chemical class 0.000 description 1
239000010408 film Substances 0.000 description 1
210000004905 finger nail Anatomy 0.000 description 1
239000006260 foam Substances 0.000 description 1
238000005755 formation reaction Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 1
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
239000012433 hydrogen halide Substances 0.000 description 1
229910000039 hydrogen halide Inorganic materials 0.000 description 1
201000006747 infectious mononucleosis Diseases 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
VQTUBCCKSQIDNK-UHFFFAOYSA-N iso-butene Natural products CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
238000002955 isolation Methods 0.000 description 1
239000004922 lacquer Substances 0.000 description 1
150000002596 lactones Chemical class 0.000 description 1
239000000944 linseed oil Substances 0.000 description 1
235000021388 linseed oil Nutrition 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000000594 mannitol Substances 0.000 description 1
235000010355 mannitol Nutrition 0.000 description 1
229960001855 mannitol Drugs 0.000 description 1
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
150000007974 melamines Chemical class 0.000 description 1
229940050176 methyl chloride Drugs 0.000 description 1
238000002156 mixing Methods 0.000 description 1
QYNFXDVIHNENBG-UHFFFAOYSA-N n',n'-dimethyl-n-(2,2,6,6-tetramethylpiperidin-4-yl)propane-1,3-diamine Chemical compound CN(C)CCCNC1CC(C)(C)NC(C)(C)C1 QYNFXDVIHNENBG-UHFFFAOYSA-N 0.000 description 1
VXGNIABHMODKBU-UHFFFAOYSA-N n-(3-ethoxypropyl)-2,2,6,6-tetramethylpiperidin-4-amine Chemical compound CCOCCCNC1CC(C)(C)NC(C)(C)C1 VXGNIABHMODKBU-UHFFFAOYSA-N 0.000 description 1
WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 description 1
210000000282 nail Anatomy 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229920000620 organic polymer Polymers 0.000 description 1
235000006408 oxalic acid Nutrition 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229960003903 oxygen Drugs 0.000 description 1
125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
150000004707 phenolate Chemical class 0.000 description 1
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
150000003053 piperidines Chemical class 0.000 description 1
229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
229920002239 polyacrylonitrile Polymers 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
229920002857 polybutadiene Polymers 0.000 description 1
229920001707 polybutylene terephthalate Polymers 0.000 description 1
239000004417 polycarbonate Substances 0.000 description 1
229920000515 polycarbonate Polymers 0.000 description 1
229920000570 polyether Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
229920003226 polyurethane urea Polymers 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
239000011118 polyvinyl acetate Substances 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
239000005033 polyvinylidene chloride Substances 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
229940093956 potassium carbonate Drugs 0.000 description 1
235000011118 potassium hydroxide Nutrition 0.000 description 1
229940093932 potassium hydroxide Drugs 0.000 description 1
239000000843 powder Substances 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
238000010992 reflux Methods 0.000 description 1
239000005060 rubber Substances 0.000 description 1
YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
229960001860 salicylate Drugs 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
229940001593 sodium carbonate Drugs 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
229940083608 sodium hydroxide Drugs 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
229960002920 sorbitol Drugs 0.000 description 1
239000003549 soybean oil Substances 0.000 description 1
235000012424 soybean oil Nutrition 0.000 description 1
238000009987 spinning Methods 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
239000007858 starting material Substances 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229910052712 strontium Inorganic materials 0.000 description 1
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
239000003784 tall oil Substances 0.000 description 1
238000009864 tensile test Methods 0.000 description 1
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
229920001897 terpolymer Polymers 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
238000002411 thermogravimetry Methods 0.000 description 1
210000003813 thumb Anatomy 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 description 1
229940086542 triethylamine Drugs 0.000 description 1
229940113165 trimethylolpropane Drugs 0.000 description 1
150000003672 ureas Chemical class 0.000 description 1
238000010626 work up procedure Methods 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34926—Triazines also containing heterocyclic groups other than triazine groups
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/0622—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
- C08G73/0638—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with at least three nitrogen atoms in the ring
- C08G73/0644—Poly(1,3,5)triazines
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Compositions Of Macromolecular Compounds (AREA)
Plural Heterocyclic Compounds (AREA)
Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Anti-Oxidant Or Stabilizer Compositions (AREA)
Hydrogenated Pyridines (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

CA358,403A 1979-08-16 1980-08-15 Derives de triazine, leur fabrication, et leur emploi comme stabilisateurs des polymeres synthetiques Expired CA1127646A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DEP2933078.7		1979-08-16
DE19792933078 DE2933078A1 (de)	1979-08-16	1979-08-16	Neue triazinderivate, ihre herstellung und ihre verwendung als stabilisatoren fuer synthetische polymere

Publications (1)

Publication Number	Publication Date
CA1127646A true CA1127646A (fr)	1982-07-13

Family

ID=6078526

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA358,403A Expired CA1127646A (fr)	1979-08-16	1980-08-15	Derives de triazine, leur fabrication, et leur emploi comme stabilisateurs des polymeres synthetiques

Country Status (10)

Country	Link
US (1)	US4335242A (fr)
EP (1)	EP0024338B1 (fr)
JP (1)	JPS5630974A (fr)
AT (1)	ATE919T1 (fr)
AU (1)	AU534133B2 (fr)
BR (1)	BR8005148A (fr)
CA (1)	CA1127646A (fr)
DE (2)	DE2933078A1 (fr)
MX (1)	MX155419A (fr)
ZA (1)	ZA805019B (fr)

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DE3022896A1 (de) *	1980-06-19	1981-12-24	Hoechst Ag, 6000 Frankfurt	Polytriazinylamine, verfahren zu ihrer herstellung und ihre verwendung als stabilisatoren fuer synthetische polymere
DE3027223A1 (de) *	1980-07-18	1982-02-11	Hoechst Ag, 6000 Frankfurt	Triazinylaminotriazine, ihre herstellung und verwendung
DE3045839A1 (de) *	1980-12-05	1982-07-08	Hoechst Ag, 6000 Frankfurt	Poly-bis-triazinylamine, verfahren zu ihrer herstellung, ihre verwendung zum stabilisieren von synthetischen polymeren und die so stabilisierten polymeren
DE3111209A1 (de) *	1981-03-21	1982-09-30	Hoechst Ag, 6000 Frankfurt	Hochmolekulare piperidingruppenhaltige ester und urethane, verfahren zu ihrer herstellung, ihre verwendung als stabilisatoren fuer polymere sowie diese verbindungen enthaltende polymere
DE3113455A1 (de) *	1981-04-03	1982-10-21	Hoechst Ag, 6000 Frankfurt	Poly-bis-triazinylimide, ihre herstellung, ihre verwendung als lichtschutzmittel fuer polymere sowie die mit ihnen stabilisierten polymeren
DE3117964A1 (de) *	1981-05-07	1982-11-25	Hoechst Ag, 6000 Frankfurt	Poly-bis-triazinylaminotriazinylamine, ihre herstellung, ihre verwendung als lichtschutzmittel fuer kunststoffe und mit ihnen stabilisierte kunststoffe
EP0070386B1 (fr) *	1981-07-20	1989-01-11	American Cyanamid Company	Agents de protection contre la lumière pour polymères
DE3131684A1 (de) *	1981-08-11	1983-02-24	Hoechst Ag, 6000 Frankfurt	Polytriazinylalkohole, -ester und -urethane, ein verfahren zu ihrer herstellung und ihre verwendung als stabilisatoren
DE3138343A1 (de) *	1981-09-26	1983-04-07	Hoechst Ag, 6230 Frankfurt	Triazinyllactame, verfahren zu ihrer herstellung, ihre verwendung als stabilisatoren fuer synthetische organische polymere und die mit ihnen stabilisierten polymeren
EP0080431B1 (fr) *	1981-10-16	1986-09-24	Ciba-Geigy Ag	Mélange synergistique de polyalkylpipéridines à faible poids moléculaire et de poids moléculaire élevé
JPS5898344A (ja) *	1981-12-08	1983-06-11	Adeka Argus Chem Co Ltd	安定化された合成樹脂組成物
IT1198355B (it) *	1982-02-10	1988-12-21	Apital Prod Ind	Derivati piperidinici e loro uso come stabilizzanti per polimeri
US4492791A (en) *	1982-05-04	1985-01-08	Ciba-Geigy Corporation	Process for the preparation of polyaminotriazines
IT1160191B (it) *	1983-02-07	1987-03-04	Montedison Spa	Composizioni polimeriche autoestinguenti
GB8421555D0 (en) *	1984-08-24	1984-09-26	Ici Plc	Water-soluble dye
IT1227334B (it) *	1988-08-04	1991-04-08	Ciba Geigy Spa	Composti piperidin triazinici atti all'impiego come stabilizzanti per materiali organici.
US4889882A (en) *	1988-12-15	1989-12-26	Ici Americas Inc.	Tetramethyl piperidyl terminated triazine oligomeric esters and amides
US4981964A (en) *	1988-12-15	1991-01-01	Ici Americas Inc.	Oligomeric polyesters and polyamides containing dipiperidyl triazine groups
IT1229501B (it) *	1989-01-24	1991-09-03	Himont Italia	Procedimento per la preparazione di polimeri triazinici.
CA2066456C (fr) *	1989-09-12	2000-03-28	Robert Vincent Holland	Materiau absorbant
IT1237129B (it) *	1989-11-10	1993-05-18	Valerio Borzatta	Composti piperidin-triazinici atti all'impiego come stabilizzanti per materiali organici.
IT1237541B (it) *	1989-12-28	1993-06-08	Ciba Geigy	Composti piperidin-triazinici atti all'impiego come stabilizzanti per materiali organici
IT1246170B (it) *	1990-07-24	1994-11-16	Ciba Geigy Spa	Composizione stabilizzante per polipropilene comprendente composti triazinici contenenti gruppi piperidinici e composti metallici
IT1243374B (it) *	1990-07-27	1994-06-10	Ciba Geigy Spa	Composti piperidin-triazinici contenenti gruppi tetraidrofuranici o tetraidropiranici atti all'impiego come stabilizzanti per materiali organici
IT1243433B (it) *	1990-10-03	1994-06-10	Ciba Geigy Spa	Composti piperidin-triazinici atti all'impiego come stabilizzanti per materiali organici
US5256787A (en) *	1990-09-03	1993-10-26	Ciba-Geigy Corporation	Tri-piperdine compounds as stabilizers for organic materials
IT1254689B (it) *	1992-04-14	1995-09-28		Cooligomeri piperidin-triazinici atti all'impiego come stabilizzanti per materiali organici.
IT1263892B (it) *	1993-02-11	1996-09-05	Graziano Vignali	Composti piperidin-triazinici atti all'impiego come stabilizzanti per materiali organici
TW302377B (fr)	1993-12-24	1997-04-11	Sumitomo Chemical Co
US6046304A (en) *	1995-12-04	2000-04-04	Ciba Specialty Chemicals Corporation	Block oligomers containing 2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials
EP0782994B1 (fr) *	1995-12-04	2003-02-05	Ciba SC Holding AG	Oligomères en blocs contenant des groupes 2,2,6,6-tétraméthyle comme stabilisants pour des matériaux organiques
TW438849B (en) *	1996-04-01	2001-06-07	Ciba Sc Holding Ag	Polytriazine derivatives containing polyalkyl-piperidinyloxy or polyalkylpiperidinylamino groups
DE69719004T2 (de)	1996-12-24	2003-07-24	Ciba Speciality Chemicals Holding Inc., Basel	Triazinverbindungen die 2,2,6,6-Tetramethyl-4-piperidingruppen enthalten als Stabilisatoren für organische Materialen
TW428008B (en)	1997-05-27	2001-04-01	Ciba Sc Holding Ag	Block oligomers containing 1-hydrocarbyloxy-2,2,6,6-tetramethy1-4-piperidyl groups as stabilizers for organic materials
JP4332817B2 (ja)	1997-05-27	2009-09-16	チバスペシャルティケミカルズホールディングインコーポレーテッド	有機材料のための安定剤としての１−ヒドロカルビルオキシ−２，２，６，６−テトラメチル−４−ピペリジル基を含むブロックオリゴマー
CN1094938C (zh)	1997-05-27	2002-11-27	西巴特殊化学品控股有限公司	作为有机材料稳定剂的含有1－烃氧基－2,2,6,6－四甲基－4－哌啶基的嵌段低聚物
TW491872B (en) *	1997-05-27	2002-06-21	Ciba Sc Holding Ag	Block oligomers containing l-hydrocarbyloxy-2,2,6,6-tetramethyl-4- piperidyl groups as stabilizers for lower polyolefin
TW509683B (en) *	1997-05-27	2002-11-11	Ciba Sc Holding Ag	Triazine derivatives containing 2,2,6,6-tetramethyl-4-piperidyl groups
TW589341B (en)	1997-05-27	2004-06-01	Ciba Sc Holding Ag	Block oligomers containing 1-hydrocarbyloxy-2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials
IT1292040B1 (it) *	1997-05-30	1999-01-25	Ciba Spec Chem Spa	Processo per la preparazione di prodotti politriazinici contenenti gruppi 2,2,6,6-tetrametil-4-piperidile
EP2130854B1 (fr)	2008-05-09	2016-10-19	MCA Technologies GMBH	Composés de type polytriazinyl en tant que substances ignifuges et stabilisants à la lumière
CN108714113B (zh) *	2018-06-02	2021-08-17	浙江莱凡化妆品有限公司	一种印花甲油及其制备工艺和使用方法

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GB1393551A (en) *	1972-04-21	1975-05-07	Ciba Geigy Ag	Piperidine derivatives
IT1052501B (it) *	1975-12-04	1981-07-20	Chimosa Chimica Organica Spa	Composti politriazinici utilizzabili per la stabilizzazione di polimeri sintetici e procedimento per la loro preparazione
IT1060458B (it) *	1975-12-18	1982-08-20	Chimosa Chimica Organica Spa	Composti piperidil triazinici adatti per la stabilizzazione di polimeri sintetici e procedimento per la loro preparazione
US4161592A (en) *	1976-07-08	1979-07-17	Ciba-Geigy Corporation	Piperidinyl-s-triazines
IT1123083B (it) *	1976-11-26	1986-04-30	Chimosa Chimica Organica Spa	Derivati piperidinici della 1,3,5 triazina quali stabilizzanti per polimeri sintetici che li comprendono e procedimento per la loro preparazione
DE2862264D1 (en) *	1977-12-30	1983-07-07	Ciba Geigy Ag	New polyalkylpiperidine derivatives of s-triazines, their use in the stabilisation of plastics and plastics stabilized in this way

1979
- 1979-08-16 DE DE19792933078 patent/DE2933078A1/de not_active Withdrawn
1980
- 1980-08-09 DE DE8080104717T patent/DE3060342D1/de not_active Expired
- 1980-08-09 AT AT80104717T patent/ATE919T1/de not_active IP Right Cessation
- 1980-08-09 EP EP80104717A patent/EP0024338B1/fr not_active Expired
- 1980-08-13 US US06/177,861 patent/US4335242A/en not_active Expired - Lifetime
- 1980-08-14 JP JP11113780A patent/JPS5630974A/ja active Granted
- 1980-08-14 AU AU61449/80A patent/AU534133B2/en not_active Ceased
- 1980-08-15 ZA ZA00805019A patent/ZA805019B/xx unknown
- 1980-08-15 MX MX183577A patent/MX155419A/es unknown
- 1980-08-15 BR BR8005148A patent/BR8005148A/pt unknown
- 1980-08-15 CA CA358,403A patent/CA1127646A/fr not_active Expired

Also Published As

Publication number	Publication date
JPS6360752B2 (fr)	1988-11-25
DE3060342D1 (en)	1982-06-09
ZA805019B (en)	1981-09-30
JPS5630974A (en)	1981-03-28
DE2933078A1 (de)	1981-03-26
MX155419A (es)	1988-03-01
US4335242A (en)	1982-06-15
EP0024338A1 (fr)	1981-03-04
AU534133B2 (en)	1984-01-05
AU6144980A (en)	1981-02-19
EP0024338B1 (fr)	1982-04-28
ATE919T1 (de)	1982-05-15
BR8005148A (pt)	1981-02-24

Legal Events

Date	Code	Title	Description
1999-07-13	MKEX	Expiry

Publication	Publication Date	Title
CA1127646A (fr)	1982-07-13	Derives de triazine, leur fabrication, et leur emploi comme stabilisateurs des polymeres synthetiques
US4340534A (en)	1982-07-20	Ethers based on polyalkyl-1-oxadiazaspirodecanes
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JPS6341394B2 (fr)	1988-08-17
JPH0223580B2 (fr)	1990-05-24
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