CA1128121A - Additif a base de cadmium pour piles a l'oxyde d'argent bivalent - Google Patents

Additif a base de cadmium pour piles a l'oxyde d'argent bivalent

Info

Publication number: CA1128121A
Authority: CA; Canada
Prior art keywords: silver oxide; positive electrode; oxide; cell; cadmium
Prior art date: 1978-03-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA322,622A

Other languages

English (en)

Inventor

Robert F. Scarr

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Union Carbide Corp

Original Assignee

Union Carbide Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-03-30

Filing date

1979-02-28

Publication date

1982-07-20

1979-02-28 Application filed by Union Carbide Corp filed Critical Union Carbide Corp

1981-10-02 Priority to CA000387245A priority Critical patent/CA1142221A/fr

1981-10-02 Priority to CA000387244A priority patent/CA1142220A/fr

1982-07-20 Application granted granted Critical

1982-07-20 Publication of CA1128121A publication Critical patent/CA1128121A/fr

Status Expired legal-status Critical Current

Links

NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 title claims abstract description 114
229910001923 silver oxide Inorganic materials 0.000 title claims abstract description 66
239000000654 additive Substances 0.000 title abstract description 9
230000000996 additive effect Effects 0.000 title abstract description 6
150000001875 compounds Chemical class 0.000 title description 2
239000003792 electrolyte Substances 0.000 claims abstract description 41
OTCVAHKKMMUFAY-UHFFFAOYSA-N oxosilver Chemical compound [Ag]=O OTCVAHKKMMUFAY-UHFFFAOYSA-N 0.000 claims abstract description 18
CXKCTMHTOKXKQT-UHFFFAOYSA-N cadmium oxide Inorganic materials [Cd]=O CXKCTMHTOKXKQT-UHFFFAOYSA-N 0.000 claims abstract description 16
CFEAAQFZALKQPA-UHFFFAOYSA-N cadmium(2+);oxygen(2-) Chemical compound [O-2].[Cd+2] CFEAAQFZALKQPA-UHFFFAOYSA-N 0.000 claims abstract description 16
-1 cadmium oxide Chemical class 0.000 claims abstract description 12
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 22
239000000463 material Substances 0.000 claims description 12
229910052725 zinc Inorganic materials 0.000 claims description 12
239000011701 zinc Substances 0.000 claims description 12
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 11
239000011787 zinc oxide Substances 0.000 claims description 11
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 10
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 4
229910052793 cadmium Inorganic materials 0.000 claims description 3
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 3
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 2
239000008116 calcium stearate Substances 0.000 claims description 2
235000013539 calcium stearate Nutrition 0.000 claims description 2
UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 claims description 2
229910052738 indium Inorganic materials 0.000 claims description 2
APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 2
RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 claims description 2
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 2
229940065285 cadmium compound Drugs 0.000 abstract description 20
150000001662 cadmium compounds Chemical class 0.000 abstract description 20
239000000126 substance Substances 0.000 abstract description 4
239000001257 hydrogen Substances 0.000 description 4
229910052739 hydrogen Inorganic materials 0.000 description 4
239000000203 mixture Substances 0.000 description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
239000007789 gas Substances 0.000 description 3
239000008188 pellet Substances 0.000 description 3
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
235000010210 aluminium Nutrition 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
238000000975 co-precipitation Methods 0.000 description 2
239000000470 constituent Substances 0.000 description 2
229910052737 gold Inorganic materials 0.000 description 2
239000010931 gold Substances 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000007774 positive electrode material Substances 0.000 description 2
CPRMKOQKXYSDML-UHFFFAOYSA-M rubidium hydroxide Chemical compound [OH-].[Rb+] CPRMKOQKXYSDML-UHFFFAOYSA-M 0.000 description 2
229910052709 silver Inorganic materials 0.000 description 2
239000004332 silver Substances 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
230000002195 synergetic effect Effects 0.000 description 2
MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
229910000611 Zinc aluminium Inorganic materials 0.000 description 1
KZNMRPQBBZBTSW-UHFFFAOYSA-N [Au]=O Chemical compound [Au]=O KZNMRPQBBZBTSW-UHFFFAOYSA-N 0.000 description 1
230000002745 absorbent Effects 0.000 description 1
239000002250 absorbent Substances 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
150000004645 aluminates Chemical class 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Inorganic materials [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 1
239000006182 cathode active material Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000002131 composite material Substances 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
229910001882 dioxygen Inorganic materials 0.000 description 1
230000009977 dual effect Effects 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
229910001922 gold oxide Inorganic materials 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
PMHURSZHKKJGBM-UHFFFAOYSA-N isoxaben Chemical compound O1N=C(C(C)(CC)CC)C=C1NC(=O)C1=C(OC)C=CC=C1OC PMHURSZHKKJGBM-UHFFFAOYSA-N 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
238000000034 method Methods 0.000 description 1
238000000465 moulding Methods 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
229960003903 oxygen Drugs 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000011148 porous material Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
UUCCCPNEFXQJEL-UHFFFAOYSA-L strontium dihydroxide Chemical compound [OH-].[OH-].[Sr+2] UUCCCPNEFXQJEL-UHFFFAOYSA-L 0.000 description 1
229910001866 strontium hydroxide Inorganic materials 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/04—Cells with aqueous electrolyte
- H01M6/06—Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/54—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of silver

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
General Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Manufacturing & Machinery (AREA)
Inorganic Chemistry (AREA)
Battery Electrode And Active Subsutance (AREA)
Primary Cells (AREA)

CA322,622A 1978-03-30 1979-02-28 Additif a base de cadmium pour piles a l'oxyde d'argent bivalent Expired CA1128121A (fr)

Priority Applications (2)

Application Number	Priority Date	Filing Date	Title
CA000387245A CA1142221A (fr)	1979-02-28	1981-10-02	Additif a base de compose cadmifere pour des cellules utilisant de l'oxyde d'argent divalent
CA000387244A CA1142220A (fr)	1979-02-28	1981-10-02	Additif a base de compose cadmifere pour des cellules utilisant de l'oxyde d'argent divalent

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US89182478A	1978-03-30	1978-03-30
US891,824		1978-03-30

Publications (1)

Publication Number	Publication Date
CA1128121A true CA1128121A (fr)	1982-07-20

Family

ID=25398882

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA322,622A Expired CA1128121A (fr)	1978-03-30	1979-02-28	Additif a base de cadmium pour piles a l'oxyde d'argent bivalent

Country Status (11)

Country	Link
JP (1)	JPS54132733A (fr)
AU (1)	AU531064B2 (fr)
BE (1)	BE875189A (fr)
CA (1)	CA1128121A (fr)
CH (1)	CH633913A5 (fr)
DE (1)	DE2912496C2 (fr)
DK (1)	DK129279A (fr)
FR (1)	FR2421475A1 (fr)
GB (1)	GB2019078B (fr)
HK (1)	HK37783A (fr)
NL (1)	NL7902460A (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB2079522B (en) *	1980-06-23	1983-08-03	Sumitomo Metal Mining Co	Silver oxide cell
JPS57107565A (en) *	1980-12-25	1982-07-05	Sumitomo Metal Mining Co Ltd	Silver peroxide battery
JPS57118371A (en) *	1981-01-16	1982-07-23	Sumitomo Metal Mining Co Ltd	Silver peroxide cell
JPS57136772A (en) *	1981-02-09	1982-08-23	Seiko Instr & Electronics Ltd	Silver oxide cell
JPS5894761A (ja) *	1981-12-01	1983-06-06	Seiko Instr & Electronics Ltd	過酸化銀電池
DE3714654A1 (de) *	1987-05-02	1988-11-10	Varta Batterie	Bei hoher temperatur entladbares galvanisches primaerelement mit alkalischem elektrolyten

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2714624A (en) *	1954-03-10	1955-08-02	Costa Arquimedes Sayas	Storage batteries
US2829189A (en) *	1956-08-24	1958-04-01	Burgess Battery Co	Alkaline dry cell
DE1205597B (de) *	1959-10-22	1965-11-25	Witte & Sutor Kondensatoren U	Verfahren zur Herstellung eines gasdicht verschlossenen Akkumulators mit Silberelektrode
NL265075A (fr) *	1960-05-24
GB1065059A (en) *	1962-12-17	1967-04-12	Electric Storage Battery Co	Improvements relating to storage battery electrodes
JPS5250615B2 (fr) *	1974-06-08	1977-12-26
US4009056A (en) *	1976-03-15	1977-02-22	Esb Incorporated	Primary alkaline cell having a stable divalent silver oxide depolarizer mix
IL50348A (en) *	1976-08-24	1979-01-31	Ate Of Israel Represented By M	Inorganic additives for zinc-alkaline secondary batteries
US4078127A (en) *	1977-04-21	1978-03-07	Esb Incorporated	Additive for an alkaline battery employing divalent silver oxide positive active material
GB2003455B (en) *	1977-08-19	1982-02-24	Matsushita Electric Industrial Co Ltd	Divalent silver oxide for use in primary cells and manufacturing method thereof
US4146685A (en) *	1978-03-28	1979-03-27	Union Carbide Corporation	Molded metal oxide electrodes containing an ethylene acrylic acid additive

1979
- 1979-02-28 CA CA322,622A patent/CA1128121A/fr not_active Expired
- 1979-03-29 NL NL7902460A patent/NL7902460A/xx not_active Application Discontinuation
- 1979-03-29 AU AU45579/79A patent/AU531064B2/en not_active Ceased
- 1979-03-29 GB GB7910980A patent/GB2019078B/en not_active Expired
- 1979-03-29 DK DK129279A patent/DK129279A/da not_active IP Right Cessation
- 1979-03-29 FR FR7907905A patent/FR2421475A1/fr active Granted
- 1979-03-29 BE BE0/194296A patent/BE875189A/fr not_active IP Right Cessation
- 1979-03-29 DE DE19792912496 patent/DE2912496C2/de not_active Expired
- 1979-03-29 CH CH294079A patent/CH633913A5/fr not_active IP Right Cessation
- 1979-03-29 JP JP3766079A patent/JPS54132733A/ja active Pending
1983
- 1983-09-29 HK HK37783A patent/HK37783A/xx unknown

Also Published As

Publication number	Publication date
GB2019078B (en)	1982-08-25
NL7902460A (nl)	1979-10-02
DK129279A (da)	1979-10-01
GB2019078A (en)	1979-10-24
CH633913A5 (fr)	1982-12-31
FR2421475A1 (fr)	1979-10-26
HK37783A (en)	1983-10-07
DE2912496A1 (de)	1979-10-04
JPS54132733A (en)	1979-10-16
FR2421475B1 (fr)	1984-04-13
AU4557979A (en)	1979-10-04
BE875189A (fr)	1979-10-01
AU531064B2 (en)	1983-08-11
DE2912496C2 (de)	1982-04-01

Legal Events

Date	Code	Title	Description
1999-07-20	MKEX	Expiry

Publication	Publication Date	Title
US5342712A (en)	1994-08-30	Additives for primary electrochemical cells having manganese dioxide cathodes
EP0474382B1 (fr)	1998-05-27	Piles électrochimiques substantiellement exemptes de mercure
GB2028565A (en)	1980-03-05	Alkaline primary cells
JP4049811B2 (ja)	2008-02-20	一次電気化学電池
US5532085A (en)	1996-07-02	Additives for alkaline electrochemical cells having manganese dioxide cathodes
EP1988590A1 (fr)	2008-11-05	Pile alcaline
KR940704067A (ko)	1994-12-12	바륨 첨가물을 가진 이산화망간-아연 전지용 음극(cathodes for zinc manganese dioxide cells having baring additives)
US5308374A (en)	1994-05-03	Method of manufacturing zinc-alkaline batteries
US4167609A (en)	1979-09-11	Zinc oxide additive for divalent silver oxide electrodes
CA1127707A (fr)	1982-07-13	Additif a base d'aluminium pour piles a electrodes en oxyde d'argent bivalent
US3017448A (en)	1962-01-16	Electric battery
SE445277B (sv)	1986-06-09	Formpressad metalloxidelektrod, sett for framstellning derav samt anvendning i en cell
US4250234A (en)	1981-02-10	Divalent silver oxide cell
CA1142221A (fr)	1983-03-01	Additif a base de compose cadmifere pour des cellules utilisant de l'oxyde d'argent divalent
CA1142220A (fr)	1983-03-01	Additif a base de compose cadmifere pour des cellules utilisant de l'oxyde d'argent divalent
CA1133578A (fr)	1982-10-12	Additif d'aluminium pour piles a electrodes en oxyde d'argent divalent
EP4160758A1 (fr)	2023-04-05	Pile bouton alcaline
US3281280A (en)	1966-10-25	Corrosion inhibitors
KR20040108640A (ko)	2004-12-24	알칼리 전지용 전해액 및 상기 전해액을 사용한 알칼리 전지
JPH0454347B2 (fr)	1992-08-31
JPH0418671B2 (fr)	1992-03-27
JPH0136673B2 (fr)	1989-08-01
JPS56165274A (en)	1981-12-18	Primary battery
JPH10214618A (ja)	1998-08-11	アルカリ電池
JPS6324299B2 (fr)	1988-05-20