CA1129132A - Systemes de revetement a base de copolymere epoxy-acrylique aqueux, thermodurcissable et sechant a l'air - Google Patents

Systemes de revetement a base de copolymere epoxy-acrylique aqueux, thermodurcissable et sechant a l'air

Info

Publication number: CA1129132A
Authority: CA; Canada
Prior art keywords: copolymer; organic solvent; monoethylenic; monomer; tertiary amine
Prior art date: 1979-01-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA343,118A

Other languages

English (en)

Inventor

Kazys Sekmakas

Raj Shah

John D. Derossi

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

DeSoto Inc

Original Assignee

DeSoto Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-01-08

Filing date

1980-01-04

Publication date

1982-08-03

1979-01-08 Priority claimed from US06/001,749 external-priority patent/US4217261A/en

1980-01-04 Application filed by DeSoto Inc filed Critical DeSoto Inc

1982-08-03 Application granted granted Critical

1982-08-03 Publication of CA1129132A publication Critical patent/CA1129132A/fr

Status Expired legal-status Critical Current

Links

238000000576 coating method Methods 0.000 title claims abstract description 15
229920001187 thermosetting polymer Polymers 0.000 title claims abstract description 14
239000011248 coating agent Substances 0.000 title claims abstract description 13
238000007605 air drying Methods 0.000 title claims abstract description 7
229920006243 acrylic copolymer Polymers 0.000 title claims description 6
239000000178 monomer Substances 0.000 claims abstract description 47
229920001577 copolymer Polymers 0.000 claims abstract description 38
229920000647 polyepoxide Polymers 0.000 claims abstract description 30
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
239000003960 organic solvent Substances 0.000 claims abstract description 25
150000003512 tertiary amines Chemical class 0.000 claims abstract description 18
239000000243 solution Substances 0.000 claims description 20
239000004593 Epoxy Substances 0.000 claims description 17
239000000203 mixture Substances 0.000 claims description 15
239000004094 surface-active agent Substances 0.000 claims description 12
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 11
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 8
150000001735 carboxylic acids Chemical class 0.000 claims description 8
239000002904 solvent Substances 0.000 claims description 8
239000002253 acid Substances 0.000 claims description 7
150000001408 amides Chemical class 0.000 claims description 7
238000000034 method Methods 0.000 claims description 7
125000001302 tertiary amino group Chemical group 0.000 claims description 7
230000001476 alcoholic effect Effects 0.000 claims description 5
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 5
239000008199 coating composition Substances 0.000 claims description 5
150000002148 esters Chemical class 0.000 claims description 5
150000007513 acids Chemical class 0.000 claims description 4
GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 4
150000002118 epoxides Chemical class 0.000 claims description 3
125000003700 epoxy group Chemical group 0.000 claims description 3
229930185605 Bisphenol Natural products 0.000 claims description 2
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
238000002156 mixing Methods 0.000 claims description 2
125000004433 nitrogen atom Chemical group N* 0.000 claims 2
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 1
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 claims 1
230000001804 emulsifying effect Effects 0.000 claims 1
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims 1
239000000306 component Substances 0.000 description 23
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
238000006243 chemical reaction Methods 0.000 description 8
239000003822 epoxy resin Substances 0.000 description 8
239000003054 catalyst Substances 0.000 description 7
229940063557 methacrylate Drugs 0.000 description 7
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
239000000839 emulsion Substances 0.000 description 6
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 4
POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 4
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
-1 di-methyl aminoethyl Chemical group 0.000 description 3
239000003973 paint Substances 0.000 description 3
ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 2
229940093475 2-ethoxyethanol Drugs 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
JVTAAEKCZFNVCJ-UHFFFAOYSA-N Lactic Acid Natural products CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
238000013019 agitation Methods 0.000 description 2
229920000180 alkyd Polymers 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
125000000129 anionic group Chemical group 0.000 description 2
230000003115 biocidal effect Effects 0.000 description 2
239000003139 biocide Substances 0.000 description 2
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
238000005336 cracking Methods 0.000 description 2
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
235000019256 formaldehyde Nutrition 0.000 description 2
229960004279 formaldehyde Drugs 0.000 description 2
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
231100001261 hazardous Toxicity 0.000 description 2
ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
239000004816 latex Substances 0.000 description 2
229920000126 latex Polymers 0.000 description 2
239000007788 liquid Substances 0.000 description 2
230000014759 maintenance of location Effects 0.000 description 2
239000000463 material Substances 0.000 description 2
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
239000007787 solid Substances 0.000 description 2
230000003381 solubilizing effect Effects 0.000 description 2
239000000126 substance Substances 0.000 description 2
OORRCVPWRPVJEK-UHFFFAOYSA-N 2-oxidanylethanoic acid Chemical compound OCC(O)=O.OCC(O)=O OORRCVPWRPVJEK-UHFFFAOYSA-N 0.000 description 1
OTKLRHWBZHQJOP-UHFFFAOYSA-N 3-aminopropyl prop-2-enoate Chemical compound NCCCOC(=O)C=C OTKLRHWBZHQJOP-UHFFFAOYSA-N 0.000 description 1
VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
239000002841 Lewis acid Substances 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
241001024304 Mino Species 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
MZVQCMJNVPIDEA-UHFFFAOYSA-N [CH2]CN(CC)CC Chemical group [CH2]CN(CC)CC MZVQCMJNVPIDEA-UHFFFAOYSA-N 0.000 description 1
UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
238000005299 abrasion Methods 0.000 description 1
239000000443 aerosol Substances 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
IXWIAFSBWGYQOE-UHFFFAOYSA-M aluminum;magnesium;oxygen(2-);silicon(4+);hydroxide;tetrahydrate Chemical compound O.O.O.O.[OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Mg+2].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] IXWIAFSBWGYQOE-UHFFFAOYSA-M 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
230000001680 brushing effect Effects 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
229920003118 cationic copolymer Polymers 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
238000001246 colloidal dispersion Methods 0.000 description 1
230000002860 competitive effect Effects 0.000 description 1
239000013530 defoamer Substances 0.000 description 1
239000012975 dibutyltin dilaurate Substances 0.000 description 1
125000006264 diethylaminomethyl group Chemical group [H]C([H])([H])C([H])([H])N(C([H])([H])*)C([H])([H])C([H])([H])[H] 0.000 description 1
238000004945 emulsification Methods 0.000 description 1
235000019253 formic acid Nutrition 0.000 description 1
235000013350 formula milk Nutrition 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
229960004592 isopropanol Drugs 0.000 description 1
239000004310 lactic acid Substances 0.000 description 1
235000014655 lactic acid Nutrition 0.000 description 1
231100001231 less toxic Toxicity 0.000 description 1
150000007517 lewis acids Chemical class 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
238000010422 painting Methods 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
235000019260 propionic acid Nutrition 0.000 description 1
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
230000036647 reaction Effects 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000010992 reflux Methods 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
239000000758 substrate Substances 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D157/00—Coating compositions based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D157/04—Copolymers in which only the monomer in minority is defined

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Paints Or Removers (AREA)
Compositions Of Macromolecular Compounds (AREA)
Epoxy Resins (AREA)

CA343,118A 1979-01-08 1980-01-04 Systemes de revetement a base de copolymere epoxy-acrylique aqueux, thermodurcissable et sechant a l'air Expired CA1129132A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US06/001,749 US4217261A (en)	1976-12-20	1979-01-08	Air drying thermosetting aqueous epoxy-acrylic copolymer coating systems
US001,749		1979-01-08

Publications (1)

Publication Number	Publication Date
CA1129132A true CA1129132A (fr)	1982-08-03

Family

ID=21697660

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA343,118A Expired CA1129132A (fr)	1979-01-08	1980-01-04	Systemes de revetement a base de copolymere epoxy-acrylique aqueux, thermodurcissable et sechant a l'air

Country Status (5)

Country	Link
JP (1)	JPS5592729A (fr)
CA (1)	CA1129132A (fr)
DE (1)	DE2948965A1 (fr)
FR (1)	FR2445851A1 (fr)
GB (1)	GB2039912A (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2516089B1 (fr) *	1981-11-09	1987-03-20	Sandoz Sa	Compositions durcissables, utilisables pour le finissage du cuir et des matieres textiles
JPS6026061A (ja) *	1983-07-25	1985-02-08	Fuji Photo Film Co Ltd	金属製フイルムパトロ−ネ用塗料

1979
- 1979-12-05 DE DE19792948965 patent/DE2948965A1/de not_active Withdrawn
- 1979-12-26 JP JP17023079A patent/JPS5592729A/ja active Pending
1980
- 1980-01-04 CA CA343,118A patent/CA1129132A/fr not_active Expired
- 1980-01-04 FR FR8000135A patent/FR2445851A1/fr not_active Withdrawn
- 1980-01-08 GB GB8000564A patent/GB2039912A/en not_active Withdrawn

Also Published As

Publication number	Publication date
DE2948965A1 (de)	1980-07-17
FR2445851A1 (fr)	1980-08-01
JPS5592729A (en)	1980-07-14
GB2039912A (en)	1980-08-20

Legal Events

Date	Code	Title	Description
1999-08-03	MKEX	Expiry

Publication	Publication Date	Title
EP0048128B2 (fr)	1987-12-02	Compositions de revêtement
US4151143A (en)	1979-04-24	Surfactant-free polymer emulsion coating composition and method for preparing same
KR970001719B1 (ko)	1997-02-14	하이드록시 성분, 무수물 성분 및 오늄 화합물을 함유한 주위온도 경화 조성물
CA2124235C (fr)	1999-01-19	Composition de revetement aqueux
TW416976B (en)	2001-01-01	Process for producing multilayer coatings
US4244850A (en)	1981-01-13	Air curable latex
EP0980408A1 (fr)	2000-02-23	Compositions de revetement a base aqueuse pour recipients metalliques
JPS5825388B2 (ja)	1983-05-27	マツタンニカルボキシルキオモツカキヨウザイオフクムフンタイトソウソセイブツ
EP0414752B1 (fr)	1993-08-04	Composition de revetement a base d'eau
JPH06248229A (ja)	1994-09-06	コーティング媒体及び耐酸性コーティングの製造のためのその使用
JPH0692562B2 (ja)	1994-11-16	ポリエポキシドと，α−オレフィンおよびオレフィン性不飽和モノ酸無水物の共重合体とを含有する高固形分塗料組成物
JPH08501124A (ja)	1996-02-06	自動車用再仕上げプライマーサーフェイサー
JPS6287288A (ja)	1987-04-21	基材にコンポジツトフイルムを提供する方法
US4133790A (en)	1979-01-09	Air drying thermosetting aqueous epoxy-acrylic copolymer coating systems
EP0183463B1 (fr)	1990-04-11	Revêtement d'entretien durcissant à basse température
US4906726A (en)	1990-03-06	Water-based coating compositions containing hydroxides and oxides of calcium, strontium and barium
US4049607A (en)	1977-09-20	Heat convertible coating compositions
CA1129132A (fr)	1982-08-03	Systemes de revetement a base de copolymere epoxy-acrylique aqueux, thermodurcissable et sechant a l'air
US3136733A (en)	1964-06-09	Highway marking composition
US4104230A (en)	1978-08-01	Two-package polymeric compositions
US4217261A (en)	1980-08-12	Air drying thermosetting aqueous epoxy-acrylic copolymer coating systems
CA1301988C (fr)	1992-05-26	Procede de preparation de composition de peinture aqueuse
JPH0621275B2 (ja)	1994-03-23	熱硬化性被覆組成物
JPH0673335A (ja)	1994-03-15	水性被覆組成物および支持体を被覆するためのその使用
HU212245B (en)	1996-04-29	Coating composition and process for producing its binding component