CA1130778A - Reduction et reoxydation de cogel, ou catalyseur auto-reducteur - Google Patents

Reduction et reoxydation de cogel, ou catalyseur auto-reducteur

Info

Publication number: CA1130778A
Authority: CA; Canada
Prior art keywords: chromium; ambient; temperature; catalyst; titanium
Prior art date: 1977-12-05
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA387,617A

Other languages

English (en)

Inventor

Max P. Mcdaniel

Melvin B. Welch

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Phillips Petroleum Co

Original Assignee

Phillips Petroleum Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-12-05

Filing date

1981-10-08

Publication date

1982-08-31

1977-12-05 Priority claimed from US05/857,553 external-priority patent/US4151122A/en

1981-10-08 Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co

1981-10-08 Priority to CA387,617A priority Critical patent/CA1130778A/fr

1982-08-31 Application granted granted Critical

1982-08-31 Publication of CA1130778A publication Critical patent/CA1130778A/fr

Status Expired legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 98
238000010405 reoxidation reaction Methods 0.000 title claims description 30
230000009467 reduction Effects 0.000 title claims description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 77
239000000377 silicon dioxide Substances 0.000 claims abstract description 39
229910052804 chromium Inorganic materials 0.000 claims abstract description 32
239000011651 chromium Substances 0.000 claims abstract description 32
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 31
239000000203 mixture Substances 0.000 claims abstract description 22
230000001603 reducing effect Effects 0.000 claims abstract description 21
150000001845 chromium compounds Chemical class 0.000 claims abstract description 9
239000012298 atmosphere Substances 0.000 claims abstract description 8
-1 such as CO Substances 0.000 claims abstract description 8
238000000034 method Methods 0.000 claims description 44
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 37
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 35
229920000642 polymer Polymers 0.000 claims description 27
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 23
229910002091 carbon monoxide Inorganic materials 0.000 claims description 23
229910052757 nitrogen Inorganic materials 0.000 claims description 18
238000006116 polymerization reaction Methods 0.000 claims description 17
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 15
238000010438 heat treatment Methods 0.000 claims description 15
239000001301 oxygen Substances 0.000 claims description 15
229910052760 oxygen Inorganic materials 0.000 claims description 15
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 14
239000005977 Ethylene Substances 0.000 claims description 14
230000008569 process Effects 0.000 claims description 13
239000000155 melt Substances 0.000 claims description 12
239000012190 activator Substances 0.000 claims description 7
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 6
150000001336 alkenes Chemical class 0.000 claims description 6
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 6
125000004432 carbon atom Chemical group C* 0.000 claims description 3
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 1
239000000463 material Substances 0.000 abstract description 16
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 13
238000009826 distribution Methods 0.000 abstract description 12
239000001257 hydrogen Substances 0.000 abstract description 6
229910052739 hydrogen Inorganic materials 0.000 abstract description 6
238000001746 injection moulding Methods 0.000 abstract description 6
229920000098 polyolefin Polymers 0.000 abstract description 2
125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
229940105305 carbon monoxide Drugs 0.000 description 21
239000010936 titanium Substances 0.000 description 18
229910052719 titanium Inorganic materials 0.000 description 18
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 16
229960005419 nitrogen Drugs 0.000 description 16
238000011282 treatment Methods 0.000 description 15
230000004913 activation Effects 0.000 description 12
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 10
229930195733 hydrocarbon Natural products 0.000 description 7
150000002430 hydrocarbons Chemical class 0.000 description 7
239000002002 slurry Substances 0.000 description 7
239000002585 base Substances 0.000 description 6
230000000694 effects Effects 0.000 description 6
239000007789 gas Substances 0.000 description 6
239000000017 hydrogel Substances 0.000 description 6
230000003647 oxidation Effects 0.000 description 6
238000007254 oxidation reaction Methods 0.000 description 6
239000001282 iso-butane Substances 0.000 description 5
230000001590 oxidative effect Effects 0.000 description 5
229920000573 polyethylene Polymers 0.000 description 5
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
239000004215 Carbon black (E152) Substances 0.000 description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
239000004698 Polyethylene Substances 0.000 description 4
239000007864 aqueous solution Substances 0.000 description 4
230000008901 benefit Effects 0.000 description 4
229910000423 chromium oxide Inorganic materials 0.000 description 4
WYYQVWLEPYFFLP-UHFFFAOYSA-K chromium(3+);triacetate Chemical compound [Cr+3].CC([O-])=O.CC([O-])=O.CC([O-])=O WYYQVWLEPYFFLP-UHFFFAOYSA-K 0.000 description 4
238000011278 co-treatment Methods 0.000 description 4
150000002894 organic compounds Chemical class 0.000 description 4
239000000243 solution Substances 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 3
150000001298 alcohols Chemical class 0.000 description 3
229910002092 carbon dioxide Inorganic materials 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
239000003085 diluting agent Substances 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
150000003609 titanium compounds Chemical class 0.000 description 3
SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
NHYCGSASNAIGLD-UHFFFAOYSA-N Chlorine monoxide Chemical compound Cl[O] NHYCGSASNAIGLD-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
150000001735 carboxylic acids Chemical class 0.000 description 2
239000003638 chemical reducing agent Substances 0.000 description 2
229940117975 chromium trioxide Drugs 0.000 description 2
GAMDZJFZMJECOS-UHFFFAOYSA-N chromium(6+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+6] GAMDZJFZMJECOS-UHFFFAOYSA-N 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
238000001035 drying Methods 0.000 description 2
238000001125 extrusion Methods 0.000 description 2
239000001307 helium Substances 0.000 description 2
229910052734 helium Inorganic materials 0.000 description 2
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
BIZCJSDBWZTASZ-UHFFFAOYSA-N iodine pentoxide Inorganic materials O=I(=O)OI(=O)=O BIZCJSDBWZTASZ-UHFFFAOYSA-N 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 2
239000002245 particle Substances 0.000 description 2
239000011148 porous material Substances 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
229920006395 saturated elastomer Polymers 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
RZCJSVRGPHXBSM-UHFFFAOYSA-N 8-chloro-[1,3]dioxolo[4,5-g]quinazoline Chemical compound C1=C2C(Cl)=NC=NC2=CC2=C1OCO2 RZCJSVRGPHXBSM-UHFFFAOYSA-N 0.000 description 1
CYHOFESITORDDD-UHFFFAOYSA-M C(CCC)O[Cr](=O)(=O)O Chemical group C(CCC)O[Cr](=O)(=O)O CYHOFESITORDDD-UHFFFAOYSA-M 0.000 description 1
229910052770 Uranium Inorganic materials 0.000 description 1
230000003213 activating effect Effects 0.000 description 1
230000032683 aging Effects 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
229910052910 alkali metal silicate Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
238000000975 co-precipitation Methods 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
239000002131 composite material Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000013256 coordination polymer Substances 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
238000004821 distillation Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000011010 flushing procedure Methods 0.000 description 1
238000010528 free radical solution polymerization reaction Methods 0.000 description 1
238000012685 gas phase polymerization Methods 0.000 description 1
150000002366 halogen compounds Chemical class 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
239000003701 inert diluent Substances 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
238000007689 inspection Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000011707 mineral Substances 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
239000003607 modifier Substances 0.000 description 1
239000001272 nitrous oxide Substances 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 description 1
PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
239000010453 quartz Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
239000011343 solid material Substances 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
238000005406 washing Methods 0.000 description 1

Landscapes

Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

CA387,617A 1977-12-05 1981-10-08 Reduction et reoxydation de cogel, ou catalyseur auto-reducteur Expired CA1130778A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA387,617A CA1130778A (fr)	1977-12-05	1981-10-08	Reduction et reoxydation de cogel, ou catalyseur auto-reducteur

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US05/857,553 US4151122A (en)	1977-12-05	1977-12-05	Reduction and reoxidation of cogel or self-reduced catalyst
US857,553		1977-12-05
CA317,293A CA1125734A (fr)	1977-12-05	1978-12-04	Reduction et reoxydation de cogels ou de catalyseurs auto-reduits
CA387,617A CA1130778A (fr)	1977-12-05	1981-10-08	Reduction et reoxydation de cogel, ou catalyseur auto-reducteur

Publications (1)

Publication Number	Publication Date
CA1130778A true CA1130778A (fr)	1982-08-31

Family

ID=27166000

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA387,617A Expired CA1130778A (fr)	1977-12-05	1981-10-08	Reduction et reoxydation de cogel, ou catalyseur auto-reducteur

Country Status (1)

Country	Link
CA (1)	CA1130778A (fr)

1981
- 1981-10-08 CA CA387,617A patent/CA1130778A/fr not_active Expired

Legal Events

Date	Code	Title	Description
1999-08-31	MKEX	Expiry
2023-05-26	MKEX	Expiry	Effective date: 19990831

Publication	Publication Date	Title
CA1125734A (fr)	1982-06-15	Reduction et reoxydation de cogels ou de catalyseurs auto-reduits
US4182815A (en)	1980-01-08	Reduction and reoxidation of cogel or self-reduced catalyst
EP0002272B1 (fr)	1982-03-24	Catalyseur contenant du chrome, son procédé de préparation avec traitement de sulfuration, et son utilisation pour la polymérisation des oléfines
US4248735A (en)	1981-02-03	Treatment of silica
CA1166235A (fr)	1984-04-24	Catalyseur et procede de polymerisation
EP0033948B1 (fr)	1988-09-14	Procédé de fabrication d'un catalyseur, catalyseur et utilisation du catalyseur
US4460756A (en)	1984-07-17	Olefin polymerization method
US3976632A (en)	1976-08-24	Reactivation of organochromium olefin polymerization catalyst in presence of oxygen
US4397769A (en)	1983-08-09	Olefin polymerization catalyst
US4402864A (en)	1983-09-06	Catalyst support treated with titanium polymer
US4297460A (en)	1981-10-27	Treatment of silica
EP0421475B1 (fr)	1997-02-12	Procédé de polymérisation d'oléfines
US4405768A (en)	1983-09-20	Polymerization process using chromium on a support treated with titanium polymer
US3362946A (en)	1968-01-09	Method of treating supported chromium oxide catalyst and polymerization therewith
US4277587A (en)	1981-07-07	Sulfiding and reoxidation of chromium catalyst
US5093300A (en)	1992-03-03	Method for activating a chromium-containing catalyst supported on a silica-containing base
US4369295A (en)	1983-01-18	Impregnated second valence chromium compound in supported catalyst
US4325839A (en)	1982-04-20	Impregnated second valence chromium compound in supported catalyst
US4384987A (en)	1983-05-24	Supported chromium oxide polymerization catalyst
US5171801A (en)	1992-12-15	Process for olefin polymerization
CA1130778A (fr)	1982-08-31	Reduction et reoxydation de cogel, ou catalyseur auto-reducteur
US4439543A (en)	1984-03-27	Co Reduced chromyl halide on silica catalyst
US5200478A (en)	1993-04-06	Method for activating supported chromium oxide catalysts and olefin polymerization process carried out therewith
USRE31443E (en)	1983-11-15	Treatment of silica
US4503201A (en)	1985-03-05	Polymerization with CO reduced chromyl halide on silica catalyst