CA1130986A - Methode d'epuration de gaz - Google Patents

Methode d'epuration de gaz

Info

Publication number: CA1130986A
Authority: CA; Canada
Prior art keywords: hydrogen; compound; metal; formula; disulphonamide
Prior art date: 1978-07-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA361,292A

Other languages

English (en)

Inventor

Donald R. Randell

Emyr Phillips

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF Schweiz AG

Original Assignee

Ciba Geigy Investments Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-07-21

Filing date

1980-09-30

Publication date

1982-09-07

1979-07-19 Priority claimed from CA000332127A external-priority patent/CA1140924A/fr

1980-09-30 Application filed by Ciba Geigy Investments Ltd filed Critical Ciba Geigy Investments Ltd

1980-09-30 Priority to CA361,292A priority Critical patent/CA1130986A/fr

1982-09-07 Application granted granted Critical

1982-09-07 Publication of CA1130986A publication Critical patent/CA1130986A/fr

Status Expired legal-status Critical Current

Links

238000000746 purification Methods 0.000 title abstract description 3
150000001875 compounds Chemical class 0.000 claims abstract description 32
239000000243 solution Substances 0.000 claims abstract description 23
239000007789 gas Substances 0.000 claims abstract description 21
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 18
239000001301 oxygen Substances 0.000 claims abstract description 18
229910052760 oxygen Inorganic materials 0.000 claims abstract description 18
239000001257 hydrogen Substances 0.000 claims abstract description 17
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 17
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims abstract description 15
229910052751 metal Inorganic materials 0.000 claims abstract description 11
239000002184 metal Substances 0.000 claims abstract description 11
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 10
239000005864 Sulphur Substances 0.000 claims abstract description 9
239000012670 alkaline solution Substances 0.000 claims abstract description 9
150000001768 cations Chemical group 0.000 claims abstract description 7
239000003352 sequestering agent Substances 0.000 claims abstract description 7
239000002738 chelating agent Substances 0.000 claims abstract description 5
150000002736 metal compounds Chemical class 0.000 claims abstract description 4
125000000217 alkyl group Chemical group 0.000 claims abstract description 3
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 3
239000000463 material Substances 0.000 claims abstract description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract 9
238000000034 method Methods 0.000 claims description 18
239000000203 mixture Substances 0.000 claims description 12
229910052757 nitrogen Inorganic materials 0.000 claims description 12
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 7
229910052700 potassium Inorganic materials 0.000 claims description 7
239000011591 potassium Substances 0.000 claims description 7
239000011734 sodium Substances 0.000 claims description 7
229910052708 sodium Inorganic materials 0.000 claims description 7
XTSPUZLHSITOOU-UHFFFAOYSA-N 9,10-dioxoanthracene-1-sulfonamide Chemical class O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2S(=O)(=O)N XTSPUZLHSITOOU-UHFFFAOYSA-N 0.000 claims description 6
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 6
-1 N,N'- disulphomethylanthraquinone-2,6-disulphonamide N,N'-disulphomethylanthraquinone-2,7-disulphonamide N,N'-disulphomethylanthraquinone-1,5-disulphonamide Chemical compound 0.000 claims description 6
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
238000010521 absorption reaction Methods 0.000 claims description 3
229910021529 ammonia Inorganic materials 0.000 claims description 3
229930195733 hydrocarbon Natural products 0.000 claims description 3
150000002430 hydrocarbons Chemical class 0.000 claims description 3
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims description 3
229910052720 vanadium Inorganic materials 0.000 claims description 3
150000003682 vanadium compounds Chemical class 0.000 claims description 3
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
239000005977 Ethylene Substances 0.000 claims description 2
150000003863 ammonium salts Chemical class 0.000 claims description 2
239000007788 liquid Substances 0.000 claims description 2
125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims description 2
ADSDHMANTIJUDA-UHFFFAOYSA-N [2-ethyl-9,10-dioxo-6-(sulfosulfamoyl)-1h-anthracen-2-yl]sulfonylsulfamic acid Chemical compound O=C1C2=CC(S(=O)(=O)NS(O)(=O)=O)=CC=C2C(=O)C2=C1C=CC(CC)(S(=O)(=O)NS(O)(=O)=O)C2 ADSDHMANTIJUDA-UHFFFAOYSA-N 0.000 claims 1
PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 abstract description 5
150000004056 anthraquinones Chemical class 0.000 abstract description 4
FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 abstract 1
229940124530 sulfonamide Drugs 0.000 abstract 1
239000003054 catalyst Substances 0.000 description 11
238000012360 testing method Methods 0.000 description 8
238000007254 oxidation reaction Methods 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
239000002253 acid Substances 0.000 description 6
VDQVEACBQKUUSU-UHFFFAOYSA-M disodium;sulfanide Chemical compound [Na+].[Na+].[SH-] VDQVEACBQKUUSU-UHFFFAOYSA-M 0.000 description 5
150000002431 hydrogen Chemical class 0.000 description 5
229910052979 sodium sulfide Inorganic materials 0.000 description 5
150000002500 ions Chemical class 0.000 description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
229910052783 alkali metal Inorganic materials 0.000 description 3
150000001340 alkali metals Chemical class 0.000 description 3
238000005259 measurement Methods 0.000 description 3
230000003647 oxidation Effects 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
238000010586 diagram Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
RARSTEWPMJQKKO-UHFFFAOYSA-N 2-[[6-(carboxymethylsulfamoyl)-9,10-dioxoanthracen-2-yl]sulfonylamino]acetic acid Chemical compound OC(=O)CNS(=O)(=O)C1=CC=C2C(=O)C3=CC(S(=O)(=O)NCC(=O)O)=CC=C3C(=O)C2=C1 RARSTEWPMJQKKO-UHFFFAOYSA-N 0.000 description 1
WMKGEXCLQBXLHZ-UHFFFAOYSA-N 2-[carboxymethyl-(9,10-dioxo-7-sulfamoylanthracen-2-yl)sulfonylamino]acetic acid Chemical compound C(=O)(O)CN(S(=O)(=O)C1=CC=2C(C3=CC(=CC=C3C(C2C=C1)=O)S(=O)(=O)N)=O)CC(=O)O WMKGEXCLQBXLHZ-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
229940126062 Compound A Drugs 0.000 description 1
QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
KALIJUWJEJSPSG-UHFFFAOYSA-N [[9,10-dioxo-5-(sulfomethylsulfamoyl)anthracen-1-yl]sulfonylamino]methanesulfonic acid Chemical class O=C1C=2C(S(=O)(=O)NCS(=O)(=O)O)=CC=CC=2C(=O)C2=C1C=CC=C2S(=O)(=O)NCS(O)(=O)=O KALIJUWJEJSPSG-UHFFFAOYSA-N 0.000 description 1
VEYSRMNMONRAAF-UHFFFAOYSA-N [[9,10-dioxo-6-(sulfomethylsulfamoyl)anthracen-2-yl]sulfonylamino]methanesulfonic acid Chemical class OS(=O)(=O)CNS(=O)(=O)C1=CC=C2C(=O)C3=CC(S(=O)(=O)NCS(=O)(=O)O)=CC=C3C(=O)C2=C1 VEYSRMNMONRAAF-UHFFFAOYSA-N 0.000 description 1
LGWUBVACJKAMDA-UHFFFAOYSA-N [[9,10-dioxo-6-(sulfomethylsulfamoyl)anthracen-2-yl]sulfonylamino]methanesulfonic acid;sodium Chemical compound [Na].[Na].OS(=O)(=O)CNS(=O)(=O)C1=CC=C2C(=O)C3=CC(S(=O)(=O)NCS(=O)(=O)O)=CC=C3C(=O)C2=C1 LGWUBVACJKAMDA-UHFFFAOYSA-N 0.000 description 1
LDVKESHMXMSJKG-UHFFFAOYSA-N [[9,10-dioxo-7-(sulfomethylsulfamoyl)anthracen-2-yl]sulfonylamino]methanesulfonic acid Chemical class C1=C(S(=O)(=O)NCS(O)(=O)=O)C=C2C(=O)C3=CC(S(=O)(=O)NCS(=O)(=O)O)=CC=C3C(=O)C2=C1 LDVKESHMXMSJKG-UHFFFAOYSA-N 0.000 description 1
238000005273 aeration Methods 0.000 description 1
238000013019 agitation Methods 0.000 description 1
125000005210 alkyl ammonium group Chemical group 0.000 description 1
125000002947 alkylene group Chemical group 0.000 description 1
238000007664 blowing Methods 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229940075397 calomel Drugs 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
JNGZXGGOCLZBFB-IVCQMTBJSA-N compound E Chemical compound N([C@@H](C)C(=O)N[C@@H]1C(N(C)C2=CC=CC=C2C(C=2C=CC=CC=2)=N1)=O)C(=O)CC1=CC(F)=CC(F)=C1 JNGZXGGOCLZBFB-IVCQMTBJSA-N 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000011161 development Methods 0.000 description 1
ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical compound Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 1
239000012535 impurity Substances 0.000 description 1
150000008040 ionic compounds Chemical class 0.000 description 1
238000009533 lab test Methods 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphonic acid group Chemical group P(O)(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
238000006479 redox reaction Methods 0.000 description 1
238000010405 reoxidation reaction Methods 0.000 description 1
239000000523 sample Substances 0.000 description 1
238000004088 simulation Methods 0.000 description 1
UPDATVKGFTVGQJ-UHFFFAOYSA-N sodium;azane Chemical compound N.[Na+] UPDATVKGFTVGQJ-UHFFFAOYSA-N 0.000 description 1
239000012085 test solution Substances 0.000 description 1
238000012546 transfer Methods 0.000 description 1
IHIXIJGXTJIKRB-UHFFFAOYSA-N trisodium vanadate Chemical compound [Na+].[Na+].[Na+].[O-][V]([O-])([O-])=O IHIXIJGXTJIKRB-UHFFFAOYSA-N 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Landscapes

Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

CA361,292A 1978-07-21 1980-09-30 Methode d'epuration de gaz Expired CA1130986A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA361,292A CA1130986A (fr)	1978-07-21	1980-09-30	Methode d'epuration de gaz

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
GB30844/78		1978-07-21
GB7830844		1978-07-21
CA000332127A CA1140924A (fr)	1978-07-21	1979-07-19	Methode d'epuration de gaz
CA361,292A CA1130986A (fr)	1978-07-21	1980-09-30	Methode d'epuration de gaz

Publications (1)

Publication Number	Publication Date
CA1130986A true CA1130986A (fr)	1982-09-07

Family

ID=27166334

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA361,292A Expired CA1130986A (fr)	1978-07-21	1980-09-30	Methode d'epuration de gaz

Country Status (1)

Country	Link
CA (1)	CA1130986A (fr)

1980
- 1980-09-30 CA CA361,292A patent/CA1130986A/fr not_active Expired

Legal Events

Date	Code	Title	Description
1999-09-07	MKEX	Expiry

Publication	Publication Date	Title
Felsenfeld et al.	1959	Specific reactions of hydrogen peroxide with the active site of hemocyanin. The formation of “methemocyanin”
US4251493A (en)	1981-02-17	Gas purification process
Fuzzi	1978	Study of iron (III) catalysed sulphur dioxide oxidation in aqueous solution over a wide range of pH
US4049776A (en)	1977-09-20	Method of removing hydrogen sulfide from gases and liquids
CA1130986A (fr)	1982-09-07	Methode d'epuration de gaz
US4637926A (en)	1987-01-20	Method of removing hydrogen sulphide from gases
Harrison et al.	1982	Aqueous phase oxidation of sulfites by ozone in the presence of iron and manganese
GB2029386A (en)	1980-03-19	Removal of H2S from gases and liquid hydrocarbons
Rao et al.	1990	Thallimetric oxidations—V: titrimetric and spectrophotometric determination of hydrogen peroxide
Rizkalla et al.	1982	The kinetics of decomposition of hydrogen peroxide in the presence of ethylenediaminetetraacetatoiron (III) complex
Tomiyasu et al.	1992	Spectrophotometric determination of trace amounts of iodide by its catalytic effect on the chlorpromazine-hydrogen peroxide reaction
Duff et al.	1972	The use of triethanolamine in a buffer for the determination of fluoride in calcium and transition metal orthophosphates, using a fluoride-selective el
Banks et al.	1954	Reaction of iron (II) with 1, 2-cyclohexanedionedioxime in acid solution
Murti et al.	1977	Extractive spectrophotometric determination of mercury with thiobenzoylacetone; Analysis of waste water.
Jones et al.	1959	Hydrogen peroxide+ water mixtures. Part 5.—Stabilization against the iron perchlorate catalyzed decomposition of hydrogen peroxide
Hamza et al.	1990	Detection, quantitative collection and semiquantitative determination of bismuth (III) and zinc (II) in aqueous media using polyurethane foam treated with dithizone
Ono et al.	1979	Polysoap as a new titrant for the determination of sodium dodecylbenzenesulfonate by colloid titration.
GB1533384A (en)	1978-11-22	Treatment of effluents
Khan et al.	1986	Ruthenium (III) and ruthenium (III)-aminopolycarboxylic acid chelate-catalyzed oxidation of ascorbic acid by molecular oxygen
Sanchez-Pedreǹo et al.	1988	Kinetic determination of Hg (II) in different materials, based on its inhibitory effect on a catalysed process
SU1430352A1 (ru)	1988-10-15	Способ обескислороживани воды
Lai et al.	1967	Polarography of uranyl-nitrilotriacetate complex
Gilmour et al.	1953	Electrode reactions of isolated chloroplast fragments
SU1151884A1 (ru)	1985-04-23	Способ определени роданидов
SU823275A1 (ru)	1981-04-23	Способ определени перекисиВОдОРОдА