CA1131306A - Additif a base de tetrafluoroborate pour piles au lithium a debit eleve - Google Patents

Additif a base de tetrafluoroborate pour piles au lithium a debit eleve

Info

Publication number: CA1131306A
Authority: CA; Canada
Prior art keywords: electrolyte; lithium; cell; dissolved; methylformate
Prior art date: 1978-09-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA335,955A

Other languages

English (en)

Inventor

Nehemiah Margalit

Philip E. Krouse

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

ESB International Corp

Original Assignee

ESB International Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-09-25

Filing date

1979-09-19

Publication date

1982-09-07

1979-09-19 Application filed by ESB International Corp filed Critical ESB International Corp

1982-09-07 Application granted granted Critical

1982-09-07 Publication of CA1131306A publication Critical patent/CA1131306A/fr

Status Expired legal-status Critical Current

Links

-1 Tetrafluoroborate Chemical compound 0.000 title claims abstract description 23
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 22
229910052744 lithium Inorganic materials 0.000 title claims abstract description 22
239000000654 additive Substances 0.000 title claims abstract description 13
230000000996 additive effect Effects 0.000 title claims abstract description 9
239000000203 mixture Substances 0.000 claims abstract description 7
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 6
239000011734 sodium Substances 0.000 claims abstract description 6
229910052708 sodium Inorganic materials 0.000 claims abstract description 6
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 5
239000011591 potassium Substances 0.000 claims abstract description 5
229910052700 potassium Inorganic materials 0.000 claims abstract description 5
239000003792 electrolyte Substances 0.000 claims description 27
TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical group COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 claims description 20
239000002904 solvent Substances 0.000 claims description 10
YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims description 4
150000003839 salts Chemical class 0.000 claims description 4
XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims description 3
WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 claims description 2
239000011255 nonaqueous electrolyte Substances 0.000 claims description 2
MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 claims 1
229910001486 lithium perchlorate Inorganic materials 0.000 claims 1
MCVFFRWZNYZUIJ-UHFFFAOYSA-M lithium;trifluoromethanesulfonate Chemical compound [Li+].[O-]S(=O)(=O)C(F)(F)F MCVFFRWZNYZUIJ-UHFFFAOYSA-M 0.000 claims 1
229910001495 sodium tetrafluoroborate Inorganic materials 0.000 claims 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 3
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract description 3
229910052782 aluminium Inorganic materials 0.000 abstract description 3
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 3
229910052788 barium Inorganic materials 0.000 abstract description 3
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract description 3
229910052790 beryllium Inorganic materials 0.000 abstract description 3
ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 abstract description 3
229910052792 caesium Inorganic materials 0.000 abstract description 3
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 abstract description 3
229910052791 calcium Inorganic materials 0.000 abstract description 3
239000011575 calcium Substances 0.000 abstract description 3
229910052749 magnesium Inorganic materials 0.000 abstract description 3
239000011777 magnesium Substances 0.000 abstract description 3
229910052701 rubidium Inorganic materials 0.000 abstract description 3
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 abstract description 3
210000004027 cell Anatomy 0.000 description 15
238000006243 chemical reaction Methods 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 5
238000005755 formation reaction Methods 0.000 description 5
229910001496 lithium tetrafluoroborate Inorganic materials 0.000 description 4
238000006731 degradation reaction Methods 0.000 description 3
239000000047 product Substances 0.000 description 3
230000000087 stabilizing effect Effects 0.000 description 3
239000000126 substance Substances 0.000 description 3
239000011345 viscous material Substances 0.000 description 3
210000003850 cellular structure Anatomy 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
239000011521 glass Substances 0.000 description 2
238000007086 side reaction Methods 0.000 description 2
239000000243 solution Substances 0.000 description 2
229910020261 KBF4 Inorganic materials 0.000 description 1
229910020808 NaBF Inorganic materials 0.000 description 1
239000000443 aerosol Substances 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
239000010406 cathode material Substances 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000008021 deposition Effects 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000008151 electrolyte solution Substances 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000012535 impurity Substances 0.000 description 1
238000007689 inspection Methods 0.000 description 1
230000003993 interaction Effects 0.000 description 1
229910001540 lithium hexafluoroarsenate(V) Inorganic materials 0.000 description 1
229910003002 lithium salt Inorganic materials 0.000 description 1
159000000002 lithium salts Chemical class 0.000 description 1
230000007774 longterm Effects 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
238000000034 method Methods 0.000 description 1
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
229920002379 silicone rubber Polymers 0.000 description 1
239000004945 silicone rubber Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical class OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
230000000007 visual effect Effects 0.000 description 1

Classifications

- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries

Landscapes

Engineering & Computer Science (AREA)
Manufacturing & Machinery (AREA)
Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
General Chemical & Material Sciences (AREA)
Primary Cells (AREA)
Secondary Cells (AREA)

CA335,955A 1978-09-25 1979-09-19 Additif a base de tetrafluoroborate pour piles au lithium a debit eleve Expired CA1131306A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US94542578A	1978-09-25	1978-09-25
US945,425		1978-09-25

Publications (1)

Publication Number	Publication Date
CA1131306A true CA1131306A (fr)	1982-09-07

Family

ID=25483067

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA335,955A Expired CA1131306A (fr)	1978-09-25	1979-09-19	Additif a base de tetrafluoroborate pour piles au lithium a debit eleve

Country Status (4)

Country	Link
JP (1)	JPS5546298A (fr)
CA (1)	CA1131306A (fr)
DE (1)	DE2938461A1 (fr)
DK (1)	DK398079A (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4279972A (en) *	1979-08-27	1981-07-21	Duracell International Inc.	Non-aqueous electrolyte cell
JPS5996667A (ja) *	1982-11-25	1984-06-04	Nippon Telegr & Teleph Corp <Ntt>	リチウム電池用電解液

1979
- 1979-09-19 CA CA335,955A patent/CA1131306A/fr not_active Expired
- 1979-09-22 DE DE19792938461 patent/DE2938461A1/de not_active Withdrawn
- 1979-09-24 DK DK398079A patent/DK398079A/da unknown
- 1979-09-25 JP JP12309579A patent/JPS5546298A/ja active Pending

Also Published As

Publication number	Publication date
DK398079A (da)	1980-03-26
JPS5546298A (en)	1980-03-31
DE2938461A1 (de)	1980-04-03

Legal Events

Date	Code	Title	Description
1999-09-07	MKEX	Expiry
2022-09-10	MKEX	Expiry	Effective date: 19990907

Publication	Publication Date	Title
US3947289A (en)	1976-03-30	Mixed solvents for high and low temperature organic electrolyte batteries
US3907597A (en)	1975-09-23	Nonaqueous cell having an electrolyte containing sulfolane or an alkyl-substituted derivative thereof
US4139680A (en)	1979-02-13	Method for preventing dendritic growth in secondary cells
US3993501A (en)	1976-11-23	Nonaqueous electrochemical cell
US3423242A (en)	1969-01-21	Electric current-producing cell with anhydrous organic liquid electrolyte
US4160070A (en)	1979-07-03	Additive for high drain rate lithium cells
US4056663A (en)	1977-11-01	Performance in an organic electrolyte
US4218523A (en)	1980-08-19	Nonaqueous electrochemical cell
SU524541A3 (ru)	1976-08-05	Химический источник тока
US3493433A (en)	1970-02-03	Electrodeposition of alkali metals from nonaqueous solvents
EP0111214A2 (fr)	1984-06-20	Cellule non-aqueuse et méthode de traitement d'une anode active métallique d'une telle cellule
IE50677B1 (en)	1986-06-11	Non-aqueous li/mno2 cell
US3279952A (en)	1966-10-18	Electric current-producing cell having acetic anhydride electrolyte solvent
US4177329A (en)	1979-12-04	Electrolyte salts for non aqueous electrochemical cells
US4012564A (en)	1977-03-15	Electrochemical cells having an electrolytic solution comprising a covalent inorganic oxyhalide solvent
US4444855A (en)	1984-04-24	Non-aqueous electrochemical cell
US4037025A (en)	1977-07-19	Halogen fueled organic electrolyte fuel cell
US4195122A (en)	1980-03-25	Additive for high drain rate lithium cells
US4216279A (en)	1980-08-05	Manganese dioxide fluoride-containing cathodes for solid electrolyte cells
US4277545A (en)	1981-07-07	Nonaqueous cell
CA1131306A (fr)	1982-09-07	Additif a base de tetrafluoroborate pour piles au lithium a debit eleve
US4400453A (en)	1983-08-23	Non-aqueous electrochemical cell
Jasinski	1970	A summary of patents on organic electrolyte batteries
CA1043866A (fr)	1978-12-05	Cellule non aqueuse avec electrolyte a crotonitrile
US3887397A (en)	1975-06-03	Highly conductive stable electrolyte for lithium batteries