CA1133660A - Process for the preparation of cellulose fibres from pine - Google Patents
Process for the preparation of cellulose fibres from pineInfo
- Publication number
- CA1133660A CA1133660A CA311,653A CA311653A CA1133660A CA 1133660 A CA1133660 A CA 1133660A CA 311653 A CA311653 A CA 311653A CA 1133660 A CA1133660 A CA 1133660A
- Authority
- CA
- Canada
- Prior art keywords
- weight
- peroxide
- pine
- cellulose fibres
- fibre
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 71
- 230000008569 process Effects 0.000 title claims abstract description 46
- 229920003043 Cellulose fiber Polymers 0.000 title claims abstract description 42
- 235000008331 Pinus X rigitaeda Nutrition 0.000 title claims abstract description 34
- 235000011613 Pinus brutia Nutrition 0.000 title claims abstract description 34
- 241000018646 Pinus brutia Species 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000000460 chlorine Substances 0.000 claims abstract description 25
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 25
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims abstract description 15
- 239000003513 alkali Substances 0.000 claims abstract description 13
- 238000011282 treatment Methods 0.000 claims abstract description 13
- 239000012736 aqueous medium Substances 0.000 claims abstract description 9
- 238000004061 bleaching Methods 0.000 claims abstract description 9
- 239000002609 medium Substances 0.000 claims abstract description 7
- -1 per-oxide compounds Chemical class 0.000 claims abstract description 7
- 238000004537 pulping Methods 0.000 claims abstract description 6
- 230000002378 acidificating effect Effects 0.000 claims abstract description 5
- 239000000835 fiber Substances 0.000 claims description 35
- 150000002978 peroxides Chemical class 0.000 claims description 18
- 239000001913 cellulose Substances 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical group [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 6
- 238000007670 refining Methods 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 5
- 235000010980 cellulose Nutrition 0.000 claims description 5
- 159000000003 magnesium salts Chemical class 0.000 claims description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 3
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims description 3
- 229940106135 cellulose Drugs 0.000 claims description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical class [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 2
- 150000001340 alkali metals Chemical class 0.000 claims 2
- 238000009874 alkali refining Methods 0.000 claims 2
- 239000000908 ammonium hydroxide Substances 0.000 claims 2
- 229940053326 magnesium salt Drugs 0.000 claims 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims 1
- 229910021653 sulphate ion Inorganic materials 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 10
- 229920002678 cellulose Polymers 0.000 description 10
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 9
- 239000012632 extractable Substances 0.000 description 6
- 239000000395 magnesium oxide Substances 0.000 description 5
- 235000012245 magnesium oxide Nutrition 0.000 description 5
- 239000002351 wastewater Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 238000006887 Ullmann reaction Methods 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000007844 bleaching agent Substances 0.000 description 4
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 239000004155 Chlorine dioxide Substances 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 235000010260 calcium hydrogen sulphite Nutrition 0.000 description 2
- 235000019398 chlorine dioxide Nutrition 0.000 description 2
- 238000010411 cooking Methods 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000001117 sulphuric acid Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MJZZHTJUILGXLJ-UHFFFAOYSA-N [Cu].ClCCl Chemical compound [Cu].ClCCl MJZZHTJUILGXLJ-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- LVGQIQHJMRUCRM-UHFFFAOYSA-L calcium bisulfite Chemical compound [Ca+2].OS([O-])=O.OS([O-])=O LVGQIQHJMRUCRM-UHFFFAOYSA-L 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 229910001504 inorganic chloride Inorganic materials 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 1
- 239000011654 magnesium acetate Substances 0.000 description 1
- 235000011285 magnesium acetate Nutrition 0.000 description 1
- 229940069446 magnesium acetate Drugs 0.000 description 1
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 description 1
- 229910001623 magnesium bromide Inorganic materials 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- BLQJIBCZHWBKSL-UHFFFAOYSA-L magnesium iodide Chemical compound [Mg+2].[I-].[I-] BLQJIBCZHWBKSL-UHFFFAOYSA-L 0.000 description 1
- 229910001641 magnesium iodide Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 150000004045 organic chlorine compounds Chemical class 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/08—Removal of fats, resins, pitch or waxes; Chemical or physical purification, i.e. refining, of crude cellulose by removing non-cellulosic contaminants, optionally combined with bleaching
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Cosmetics (AREA)
- Sanitary Thin Papers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2742262A DE2742262C2 (de) | 1977-09-20 | 1977-09-20 | Verfahren zur Herstellung eines mittel- bis hochviskosen Nadelholz-Sulfitzellstoffs |
| DEP2742262.4 | 1977-09-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1133660A true CA1133660A (en) | 1982-10-19 |
Family
ID=6019413
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA311,653A Expired CA1133660A (en) | 1977-09-20 | 1978-09-20 | Process for the preparation of cellulose fibres from pine |
Country Status (16)
| Country | Link |
|---|---|
| JP (1) | JPS5455606A (it) |
| AR (1) | AR218936A1 (it) |
| AT (1) | AT367812B (it) |
| BE (1) | BE870607A (it) |
| BR (1) | BR7806050A (it) |
| CA (1) | CA1133660A (it) |
| CH (1) | CH638003A5 (it) |
| DE (1) | DE2742262C2 (it) |
| ES (1) | ES472687A1 (it) |
| FI (1) | FI68273C (it) |
| FR (1) | FR2403418A1 (it) |
| GB (1) | GB2005743B (it) |
| IT (1) | IT1109111B (it) |
| NO (1) | NO153978C (it) |
| SE (1) | SE7809831L (it) |
| ZA (1) | ZA785356B (it) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2520397A1 (fr) * | 1982-01-28 | 1983-07-29 | Centre Tech Ind Papier | Procede pour le traitement de pates papetieres chimiques |
| DE4031597A1 (de) * | 1990-10-05 | 1992-04-09 | Sueddeutsche Kalkstickstoff | Verfahren zur chlorarmen bleiche und delignifizierung von zellstoff |
| SE470065C (sv) * | 1991-04-30 | 1996-01-15 | Eka Nobel Ab | Behandling av kemisk massa med en syra och därefter en magnesium- och kalciumförening vid klorfri blekning |
| US6398908B1 (en) | 1991-04-30 | 2002-06-04 | Eka Nobel Ab | Process for acid bleaching of lignocellulose-containing pulp with a magnesium compound |
| ZA955290B (en) * | 1994-07-11 | 1996-12-27 | Ingersoll Rand Co | Peroxide bleaching process for cellulosic and lignocellulosic material |
| RU2128261C1 (ru) * | 1998-05-26 | 1999-03-27 | Сыктывкарский лесной институт Санкт-Петербургской лесотехнической академии | Способ отбелки целлюлозы |
| RU2142529C1 (ru) * | 1999-05-17 | 1999-12-10 | Сыктывкарский лесной институт Санкт-Петербургской лесотехнической академии | Способ отбелки целлюлозы |
| RU2164572C1 (ru) * | 2000-03-14 | 2001-03-27 | Сыктывкарский лесной институт Санкт-Петербургской лесотехнической академии | Способ отбелки сульфатной целлюлозы |
| RU2163946C1 (ru) * | 2000-08-02 | 2001-03-10 | Институт химии Коми научного центра Уральского отделения РАН | Способ отбелки материалов или полуфабрикатов, содержащих целлюлозу |
| RU2205257C1 (ru) * | 2002-07-01 | 2003-05-27 | Сыктывкарский лесной институт Санкт-Петербургской лесотехнической академии | Способ отбелки сульфатной целлюлозы |
| RU2243304C1 (ru) * | 2004-02-04 | 2004-12-27 | Томский политехнический университет | Способ безхлорной отбелки сульфатной целлюлозы |
| DE102007036376A1 (de) * | 2007-07-31 | 2009-02-05 | Voith Patent Gmbh | Gebleichter Faserstoff |
| RU2413046C1 (ru) * | 2009-09-21 | 2011-02-27 | Эльвира Ильинична Федорова | Способ отбелки сульфатной целлюлозы |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2026068A (en) * | 1929-09-11 | 1935-12-31 | Du Pont | Process for the improvement of cellulose |
| DE753531C (de) * | 1938-11-09 | 1953-05-18 | Degussa | Verfahren zum Bleichen von Zellstoff |
-
1977
- 1977-09-20 DE DE2742262A patent/DE2742262C2/de not_active Expired
-
1978
- 1978-08-18 NO NO782820A patent/NO153978C/no unknown
- 1978-08-18 ES ES472687A patent/ES472687A1/es not_active Expired
- 1978-08-21 FR FR7824288A patent/FR2403418A1/fr active Granted
- 1978-09-15 BR BR7806050A patent/BR7806050A/pt unknown
- 1978-09-19 BE BE6046608A patent/BE870607A/xx not_active IP Right Cessation
- 1978-09-19 CH CH978978A patent/CH638003A5/de not_active IP Right Cessation
- 1978-09-19 IT IT69162/78A patent/IT1109111B/it active
- 1978-09-19 AT AT0675678A patent/AT367812B/de not_active IP Right Cessation
- 1978-09-19 SE SE7809831A patent/SE7809831L/xx unknown
- 1978-09-19 GB GB7837320A patent/GB2005743B/en not_active Expired
- 1978-09-20 FI FI782869A patent/FI68273C/fi not_active IP Right Cessation
- 1978-09-20 ZA ZA00785356A patent/ZA785356B/xx unknown
- 1978-09-20 AR AR273785A patent/AR218936A1/es active
- 1978-09-20 CA CA311,653A patent/CA1133660A/en not_active Expired
- 1978-09-20 JP JP11470478A patent/JPS5455606A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| BR7806050A (pt) | 1979-05-02 |
| FR2403418B1 (it) | 1982-07-02 |
| CH638003A5 (de) | 1983-08-31 |
| GB2005743A (en) | 1979-04-25 |
| ZA785356B (en) | 1979-09-26 |
| FR2403418A1 (fr) | 1979-04-13 |
| SE7809831L (sv) | 1979-03-21 |
| GB2005743B (en) | 1982-03-03 |
| NO782820L (no) | 1979-03-21 |
| FI68273B (fi) | 1985-04-30 |
| IT1109111B (it) | 1985-12-16 |
| DE2742262A1 (de) | 1979-03-29 |
| ES472687A1 (es) | 1979-02-16 |
| BE870607A (fr) | 1979-03-19 |
| AR218936A1 (es) | 1980-07-15 |
| IT7869162A0 (it) | 1978-09-19 |
| NO153978B (no) | 1986-03-17 |
| DE2742262C2 (de) | 1982-06-09 |
| FI782869A7 (fi) | 1979-03-21 |
| JPS5455606A (en) | 1979-05-02 |
| FI68273C (fi) | 1985-08-12 |
| ATA675678A (de) | 1981-12-15 |
| AT367812B (de) | 1982-08-10 |
| NO153978C (no) | 1986-06-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |