CA1134093A - Neoprenes et melanges de neoprenes a teneur de resine - Google Patents

Neoprenes et melanges de neoprenes a teneur de resine

Info

Publication number: CA1134093A
Authority: CA; Canada
Prior art keywords: neoprene; elastomer; weight; composition; proportion
Prior art date: 1978-02-06
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA320,979A

Other languages

English (en)

Inventor

Mark C. Chen

Douglas J. Kelly

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

EIDP Inc

Original Assignee

EI Du Pont de Nemours and Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-02-06

Filing date

1979-02-05

Publication date

1982-10-19

1979-02-05 Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co

1982-10-19 Application granted granted Critical

1982-10-19 Publication of CA1134093A publication Critical patent/CA1134093A/fr

Status Expired legal-status Critical Current

Links

229920001084 poly(chloroprene) Polymers 0.000 title claims abstract description 40
239000000203 mixture Substances 0.000 title claims abstract description 35
229920005989 resin Polymers 0.000 title abstract description 19
239000011347 resin Substances 0.000 title abstract description 19
229920001971 elastomer Polymers 0.000 claims abstract description 27
229920000642 polymer Polymers 0.000 claims abstract description 25
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 12
239000013032 Hydrocarbon resin Substances 0.000 claims abstract description 9
150000001993 dienes Chemical class 0.000 claims abstract description 9
125000003118 aryl group Chemical group 0.000 claims abstract description 6
239000003208 petroleum Substances 0.000 claims abstract description 5
239000000806 elastomer Substances 0.000 claims description 20
238000000034 method Methods 0.000 claims description 16
229910052717 sulfur Inorganic materials 0.000 claims description 13
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 12
YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 claims description 12
239000011593 sulfur Substances 0.000 claims description 12
229920001577 copolymer Polymers 0.000 claims description 10
229920006270 hydrocarbon resin Polymers 0.000 claims description 8
238000004073 vulcanization Methods 0.000 claims description 7
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
229910052799 carbon Inorganic materials 0.000 claims description 5
229920003048 styrene butadiene rubber Polymers 0.000 claims description 5
229920002959 polymer blend Polymers 0.000 claims description 4
LIFLRQVHKGGNSG-UHFFFAOYSA-N 2,3-dichlorobuta-1,3-diene Chemical compound ClC(=C)C(Cl)=C LIFLRQVHKGGNSG-UHFFFAOYSA-N 0.000 claims description 3
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 3
238000005481 NMR spectroscopy Methods 0.000 claims description 3
239000005062 Polybutadiene Substances 0.000 claims description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
229920001519 homopolymer Polymers 0.000 claims description 3
229910052739 hydrogen Inorganic materials 0.000 claims description 3
239000001257 hydrogen Substances 0.000 claims description 3
229910052740 iodine Inorganic materials 0.000 claims description 3
239000011630 iodine Substances 0.000 claims description 3
150000002894 organic compounds Chemical class 0.000 claims description 3
229910052760 oxygen Inorganic materials 0.000 claims description 3
239000001301 oxygen Substances 0.000 claims description 3
229920002857 polybutadiene Polymers 0.000 claims description 3
229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 3
150000002431 hydrogen Chemical class 0.000 claims description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
239000005060 rubber Substances 0.000 abstract description 10
238000010186 staining Methods 0.000 abstract description 7
230000008901 benefit Effects 0.000 abstract 1
230000006866 deterioration Effects 0.000 abstract 1
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 12
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 12
238000005336 cracking Methods 0.000 description 9
229960005349 sulfur Drugs 0.000 description 8
235000001508 sulfur Nutrition 0.000 description 8
235000021355 Stearic acid Nutrition 0.000 description 6
239000000395 magnesium oxide Substances 0.000 description 6
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 6
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 6
239000008117 stearic acid Substances 0.000 description 6
239000011787 zinc oxide Substances 0.000 description 6
230000003068 static effect Effects 0.000 description 4
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 3
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
ZEEBGORNQSEQBE-UHFFFAOYSA-N [2-(3-phenylphenoxy)-6-(trifluoromethyl)pyridin-4-yl]methanamine Chemical compound C1(=CC(=CC=C1)OC1=NC(=CC(=C1)CN)C(F)(F)F)C1=CC=CC=C1 ZEEBGORNQSEQBE-UHFFFAOYSA-N 0.000 description 3
239000000126 substance Substances 0.000 description 3
OPNUROKCUBTKLF-UHFFFAOYSA-N 1,2-bis(2-methylphenyl)guanidine Chemical compound CC1=CC=CC=C1N\C(N)=N\C1=CC=CC=C1C OPNUROKCUBTKLF-UHFFFAOYSA-N 0.000 description 2
CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 2
SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
239000002174 Styrene-butadiene Substances 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
230000000694 effects Effects 0.000 description 2
-1 styrene Chemical class 0.000 description 2
IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical class C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
BUZICZZQJDLXJN-UHFFFAOYSA-N 3-azaniumyl-4-hydroxybutanoate Chemical compound OCC(N)CC(O)=O BUZICZZQJDLXJN-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
SUYHGHZDQZCCCK-UHFFFAOYSA-N C1(=C(C=CC=C1)NC(NC1=C(C=CC=C1)C)=N)C.[S] Chemical compound C1(=C(C=CC=C1)NC(NC1=C(C=CC=C1)C)=N)C.[S] SUYHGHZDQZCCCK-UHFFFAOYSA-N 0.000 description 1
NJIVFJXLMDTJCA-UHFFFAOYSA-N C1(=CC=C(C=C1)N)N.[S] Chemical compound C1(=CC=C(C=C1)N)N.[S] NJIVFJXLMDTJCA-UHFFFAOYSA-N 0.000 description 1
244000043261 Hevea brasiliensis Species 0.000 description 1
YZCKVEUIGOORGS-UHFFFAOYSA-N Hydrogen atom Chemical compound [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 description 1
239000004594 Masterbatch (MB) Substances 0.000 description 1
239000006244 Medium Thermal Substances 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
KFFQABQEJATQAT-UHFFFAOYSA-N N,N'-dibutylthiourea Chemical compound CCCCNC(=S)NCCCC KFFQABQEJATQAT-UHFFFAOYSA-N 0.000 description 1
FLVIGYVXZHLUHP-UHFFFAOYSA-N N,N'-diethylthiourea Chemical compound CCNC(=S)NCC FLVIGYVXZHLUHP-UHFFFAOYSA-N 0.000 description 1
239000004264 Petrolatum Substances 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
238000005299 abrasion Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 1
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
239000006229 carbon black Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
229940125898 compound 5 Drugs 0.000 description 1
238000013329 compounding Methods 0.000 description 1
230000002939 deleterious effect Effects 0.000 description 1
AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000000921 elemental analysis Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
230000005484 gravity Effects 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
238000002955 isolation Methods 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
229920000126 latex Polymers 0.000 description 1
239000004816 latex Substances 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
125000005395 methacrylic acid group Chemical class 0.000 description 1
XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
239000000178 monomer Substances 0.000 description 1
229920003052 natural elastomer Polymers 0.000 description 1
229920001194 natural rubber Polymers 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
MVAOEXBRERPGIT-UHFFFAOYSA-N octamine Chemical compound N.N.N.N.N.N.N.N MVAOEXBRERPGIT-UHFFFAOYSA-N 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
229940066842 petrolatum Drugs 0.000 description 1
235000019271 petrolatum Nutrition 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
239000012744 reinforcing agent Substances 0.000 description 1
239000012763 reinforcing filler Substances 0.000 description 1
238000007127 saponification reaction Methods 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000011115 styrene butadiene Substances 0.000 description 1
KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
WCLDITPGPXSPGV-UHFFFAOYSA-N tricamba Chemical compound COC1=C(Cl)C=C(Cl)C(Cl)=C1C(O)=O WCLDITPGPXSPGV-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L11/00—Compositions of homopolymers or copolymers of chloroprene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)

CA320,979A 1978-02-06 1979-02-05 Neoprenes et melanges de neoprenes a teneur de resine Expired CA1134093A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US87549278A	1978-02-06	1978-02-06
US875,492		1978-02-06

Publications (1)

Publication Number	Publication Date
CA1134093A true CA1134093A (fr)	1982-10-19

Family

ID=25365906

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA320,979A Expired CA1134093A (fr)	1978-02-06	1979-02-05	Neoprenes et melanges de neoprenes a teneur de resine

Country Status (5)

Country	Link
JP (1)	JPS54113642A (fr)
CA (1)	CA1134093A (fr)
DE (1)	DE2904070A1 (fr)
FR (1)	FR2416245A1 (fr)
GB (1)	GB2013693A (fr)

1979
- 1979-02-03 DE DE19792904070 patent/DE2904070A1/de not_active Withdrawn
- 1979-02-05 FR FR7902870A patent/FR2416245A1/fr not_active Withdrawn
- 1979-02-05 CA CA320,979A patent/CA1134093A/fr not_active Expired
- 1979-02-05 JP JP1151779A patent/JPS54113642A/ja active Pending
- 1979-02-05 GB GB7903942A patent/GB2013693A/en not_active Withdrawn

Also Published As

Publication number	Publication date
JPS54113642A (en)	1979-09-05
FR2416245A1 (fr)	1979-08-31
GB2013693A (en)	1979-08-15
DE2904070A1 (de)	1979-08-09

Legal Events

Date	Code	Title	Description
1999-10-19	MKEX	Expiry

Publication	Publication Date	Title
CA1080875A (fr)	1980-07-01	MELANGES DE TRANS-1,4 POLYMERES ET DE POLY (.epsilon.-CAPROLACTONE)
US4191671A (en)	1980-03-04	Abrasion resistant rubber compositions
US3451458A (en)	1969-06-24	Silica filled synthetic rubber compositions and tire treads
US7594528B2 (en)	2009-09-29	Tire with sidewall comprised of emulsion styrene/butadiene rubber, cis 1,4-polyisoprene rubber and cis 1,4-polybutadiene rubber
KR20110025202A (ko)	2011-03-09	실리카가 충전된 탄성중합체 배합물
JPH0717208A (ja)	1995-01-20	ゴムとコードの積層品およびそれらの構成部材を有するタイヤ
JP7690397B2 (ja)	2025-06-10	硬化性液体ゴムベース組成物用ポリエン
CA2257002C (fr)	2011-03-15	Composants pour pneus renfermant des polyolefines fonctionnalisees
US7279518B2 (en)	2007-10-09	Filled elastomeric butyl compounds
CA1159985A (fr)	1984-01-03	Pneumatiques
US3852225A (en)	1974-12-03	Polymer composition having high flow property
US4166083A (en)	1979-08-28	Rubber composition and process for preparation thereof
US4075159A (en)	1978-02-21	Rubber compositions with benzoic acid compounds
JP2002234310A (ja)	2002-08-20	選択された低分子量ポリエステル可塑剤を含有するゴム組成物のトレッドを有するタイヤ
US3687881A (en)	1972-08-29	Zinc-containing polymer compositions
CA1134093A (fr)	1982-10-19	Neoprenes et melanges de neoprenes a teneur de resine
US7015265B2 (en)	2006-03-21	Filled elastomeric butyl compounds with improved scorch safety
US3635862A (en)	1972-01-18	Stabilized polymer compositions
US20250115747A1 (en)	2025-04-10	Rubber composition with superior grip and improved hysteresis composition
US4386181A (en)	1983-05-31	Heat-aging-resistant rubber composition
US6405775B1 (en)	2002-06-18	Tire with tread of rubber composition containing selective low molecular weight polyester plasticizer
KR20020076063A (ko)	2002-10-09	분산성이 향상된 실리카로 보강된 타이어용 ｓｂｒ고무조성물
US5362785A (en)	1994-11-08	Rubber composition suitable for automobile tires and its production
JPS61238501A (ja)	1986-10-23	耐久性の改善された空気入りタイヤ
KR100505735B1 (ko)	2005-08-03	타이어 트레드 고무 조성물