CA1136319A - Compositions de resine polyphenylenoxyde renfermant des resines aromatiques alkenylees modifiees au polysiloxane - Google Patents

Compositions de resine polyphenylenoxyde renfermant des resines aromatiques alkenylees modifiees au polysiloxane

Info

Publication number: CA1136319A
Authority: CA; Canada
Prior art keywords: composition; polysiloxane; alkenyl aromatic; group; groups
Prior art date: 1980-02-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000346158A

Other languages

English (en)

Inventor

Glenn D. Cooper

William R. Haaf

Howard A. Vaughn, Jr.

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

General Electric Co

Original Assignee

General Electric Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-02-21

Filing date

1980-02-21

Publication date

1982-11-23

1980-02-21 Application filed by General Electric Co filed Critical General Electric Co

1980-02-21 Priority to CA000346158A priority Critical patent/CA1136319A/fr

1982-11-23 Application granted granted Critical

1982-11-23 Publication of CA1136319A publication Critical patent/CA1136319A/fr

Status Expired legal-status Critical Current

Links

239000011347 resin Substances 0.000 title claims abstract description 54
229920005989 resin Polymers 0.000 title claims abstract description 54
229920001955 polyphenylene ether Polymers 0.000 title claims abstract description 25
125000003118 aryl group Chemical group 0.000 title claims description 9
125000003342 alkenyl group Polymers 0.000 title description 6
239000011342 resin composition Substances 0.000 title description 4
239000000203 mixture Substances 0.000 claims abstract description 82
-1 polysiloxane Polymers 0.000 claims abstract description 67
229920001296 polysiloxane Polymers 0.000 claims abstract description 33
239000003063 flame retardant Substances 0.000 claims abstract description 20
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 19
239000002245 particle Substances 0.000 claims abstract description 19
238000000465 moulding Methods 0.000 claims description 21
125000004432 carbon atom Chemical group C* 0.000 claims description 19
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 17
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 17
239000000654 additive Substances 0.000 claims description 15
150000001875 compounds Chemical class 0.000 claims description 12
239000000178 monomer Substances 0.000 claims description 12
230000000996 additive effect Effects 0.000 claims description 11
239000012763 reinforcing filler Substances 0.000 claims description 11
XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical group C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 8
125000005843 halogen group Chemical group 0.000 claims description 7
229910052698 phosphorus Inorganic materials 0.000 claims description 7
239000011574 phosphorus Substances 0.000 claims description 7
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 6
229910052799 carbon Inorganic materials 0.000 claims description 6
229910052739 hydrogen Inorganic materials 0.000 claims description 6
239000001257 hydrogen Substances 0.000 claims description 6
150000002894 organic compounds Chemical class 0.000 claims description 6
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 6
238000009757 thermoplastic moulding Methods 0.000 claims description 6
229910019142 PO4 Inorganic materials 0.000 claims description 5
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 5
235000021317 phosphate Nutrition 0.000 claims description 5
230000000379 polymerizing effect Effects 0.000 claims description 5
229910000410 antimony oxide Inorganic materials 0.000 claims description 4
239000003365 glass fiber Substances 0.000 claims description 4
150000002430 hydrocarbons Chemical group 0.000 claims description 4
VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 4
230000003014 reinforcing effect Effects 0.000 claims description 4
150000001463 antimony compounds Chemical class 0.000 claims description 3
150000001555 benzenes Chemical class 0.000 claims description 3
125000000068 chlorophenyl group Chemical group 0.000 claims description 3
229910052736 halogen Inorganic materials 0.000 claims description 3
150000002367 halogens Chemical group 0.000 claims description 3
229930195733 hydrocarbon Natural products 0.000 claims description 3
229910052760 oxygen Inorganic materials 0.000 claims description 3
239000001301 oxygen Substances 0.000 claims description 3
150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 3
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
229920002554 vinyl polymer Polymers 0.000 claims description 3
125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 claims description 2
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 2
239000004215 Carbon black (E152) Substances 0.000 claims description 2
YMOONIIMQBGTDU-VOTSOKGWSA-N [(e)-2-bromoethenyl]benzene Chemical compound Br\C=C\C1=CC=CC=C1 YMOONIIMQBGTDU-VOTSOKGWSA-N 0.000 claims description 2
125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 claims description 2
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 claims description 2
229920006395 saturated elastomer Polymers 0.000 claims description 2
125000001424 substituent group Chemical group 0.000 claims description 2
125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 claims description 2
229930195735 unsaturated hydrocarbon Natural products 0.000 claims 5
125000000547 substituted alkyl group Chemical group 0.000 claims 4
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
229910052794 bromium Inorganic materials 0.000 claims 1
125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims 1
239000011521 glass Substances 0.000 description 28
239000004793 Polystyrene Substances 0.000 description 12
229920001577 copolymer Polymers 0.000 description 10
229920002223 polystyrene Polymers 0.000 description 10
229910052770 Uranium Inorganic materials 0.000 description 9
229920000642 polymer Polymers 0.000 description 9
239000000945 filler Substances 0.000 description 8
238000000034 method Methods 0.000 description 8
230000002787 reinforcement Effects 0.000 description 7
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
239000000835 fiber Substances 0.000 description 6
125000000217 alkyl group Chemical group 0.000 description 5
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
239000005083 Zinc sulfide Substances 0.000 description 4
229910052782 aluminium Inorganic materials 0.000 description 4
238000007664 blowing Methods 0.000 description 4
KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical compound [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 4
238000002156 mixing Methods 0.000 description 4
229910052984 zinc sulfide Inorganic materials 0.000 description 4
DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
229920001971 elastomer Polymers 0.000 description 3
229920000578 graft copolymer Polymers 0.000 description 3
150000002431 hydrogen Chemical group 0.000 description 3
239000004615 ingredient Substances 0.000 description 3
230000001590 oxidative effect Effects 0.000 description 3
239000000047 product Substances 0.000 description 3
239000005060 rubber Substances 0.000 description 3
239000000243 solution Substances 0.000 description 3
150000003440 styrenes Chemical class 0.000 description 3
229920001169 thermoplastic Polymers 0.000 description 3
239000004416 thermosoftening plastic Substances 0.000 description 3
QQBLOZGVRHAYGT-UHFFFAOYSA-N tris-decyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OCCCCCCCCCC QQBLOZGVRHAYGT-UHFFFAOYSA-N 0.000 description 3
239000011787 zinc oxide Substances 0.000 description 3
PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
229920002943 EPDM rubber Polymers 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
239000006057 Non-nutritive feed additive Substances 0.000 description 2
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
239000004698 Polyethylene Substances 0.000 description 2
229920000265 Polyparaphenylene Polymers 0.000 description 2
229920000147 Styrene maleic anhydride Polymers 0.000 description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
239000010425 asbestos Substances 0.000 description 2
239000005388 borosilicate glass Substances 0.000 description 2
229910052918 calcium silicate Inorganic materials 0.000 description 2
239000000378 calcium silicate Substances 0.000 description 2
OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
238000013329 compounding Methods 0.000 description 2
YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 2
USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 2
CAYGQBVSOZLICD-UHFFFAOYSA-N hexabromobenzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1Br CAYGQBVSOZLICD-UHFFFAOYSA-N 0.000 description 2
239000003999 initiator Substances 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
239000011159 matrix material Substances 0.000 description 2
239000012764 mineral filler Substances 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
229910052755 nonmetal Inorganic materials 0.000 description 2
150000002843 nonmetals Chemical class 0.000 description 2
239000008188 pellet Substances 0.000 description 2
229940031826 phenolate Drugs 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
239000010452 phosphate Substances 0.000 description 2
239000000049 pigment Substances 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
239000004033 plastic Substances 0.000 description 2
229920000573 polyethylene Polymers 0.000 description 2
229910052895 riebeckite Inorganic materials 0.000 description 2
150000004760 silicates Chemical class 0.000 description 2
NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
238000004513 sizing Methods 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
239000004408 titanium dioxide Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
AQPHBYQUCKHJLT-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-(2,3,4,5,6-pentabromophenyl)benzene Chemical group BrC1=C(Br)C(Br)=C(Br)C(Br)=C1C1=C(Br)C(Br)=C(Br)C(Br)=C1Br AQPHBYQUCKHJLT-UHFFFAOYSA-N 0.000 description 1
NDRKXFLZSRHAJE-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-(2,3,4-tribromophenyl)benzene Chemical group BrC1=C(Br)C(Br)=CC=C1C1=C(Br)C(Br)=C(Br)C(Br)=C1Br NDRKXFLZSRHAJE-UHFFFAOYSA-N 0.000 description 1
DJHWAIPYZDRNMH-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-(2-bromophenyl)benzene Chemical group BrC1=CC=CC=C1C1=C(Br)C(Br)=C(Br)C(Br)=C1Br DJHWAIPYZDRNMH-UHFFFAOYSA-N 0.000 description 1
QRFALSDGOMLVIR-UHFFFAOYSA-N 1,2,3,4-tetrabromobenzene Chemical compound BrC1=CC=C(Br)C(Br)=C1Br QRFALSDGOMLVIR-UHFFFAOYSA-N 0.000 description 1
FPYGQQPAMXFHJF-UHFFFAOYSA-N 1-bromo-2-(4-bromophenyl)benzene Chemical group C1=CC(Br)=CC=C1C1=CC=CC=C1Br FPYGQQPAMXFHJF-UHFFFAOYSA-N 0.000 description 1
JAYCNKDKIKZTAF-UHFFFAOYSA-N 1-chloro-2-(2-chlorophenyl)benzene Chemical group ClC1=CC=CC=C1C1=CC=CC=C1Cl JAYCNKDKIKZTAF-UHFFFAOYSA-N 0.000 description 1
WAEOXIOXMKNFLQ-UHFFFAOYSA-N 1-methyl-4-prop-2-enylbenzene Chemical group CC1=CC=C(CC=C)C=C1 WAEOXIOXMKNFLQ-UHFFFAOYSA-N 0.000 description 1
IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
UFNIBRDIUNVOMX-UHFFFAOYSA-N 2,4'-dichlorobiphenyl Chemical group C1=CC(Cl)=CC=C1C1=CC=CC=C1Cl UFNIBRDIUNVOMX-UHFFFAOYSA-N 0.000 description 1
GVJRTUUUJYMTNQ-UHFFFAOYSA-N 2-(2,5-dioxofuran-3-yl)acetic acid Chemical compound OC(=O)CC1=CC(=O)OC1=O GVJRTUUUJYMTNQ-UHFFFAOYSA-N 0.000 description 1
125000004974 2-butenyl group Chemical group C(C=CC)* 0.000 description 1
SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
AYKYXWQEBUNJCN-UHFFFAOYSA-N 3-methylfuran-2,5-dione Chemical compound CC1=CC(=O)OC1=O AYKYXWQEBUNJCN-UHFFFAOYSA-N 0.000 description 1
OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 1
OMIHGPLIXGGMJB-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]hepta-1,3,5-triene Chemical compound C1=CC=C2OC2=C1 OMIHGPLIXGGMJB-UHFFFAOYSA-N 0.000 description 1
239000004606 Fillers/Extenders Substances 0.000 description 1
108010010803 Gelatin Proteins 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
229920002472 Starch Polymers 0.000 description 1
239000002174 Styrene-butadiene Substances 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
125000003277 amino group Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000011324 bead Substances 0.000 description 1
235000010290 biphenyl Nutrition 0.000 description 1
150000004074 biphenyls Chemical class 0.000 description 1
229920001400 block copolymer Polymers 0.000 description 1
125000001246 bromo group Chemical group Br* 0.000 description 1
MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 1
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
229940000425 combination drug Drugs 0.000 description 1
239000008139 complexing agent Substances 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
125000004093 cyano group Chemical group *C#N 0.000 description 1
WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 1
LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
238000007580 dry-mixing Methods 0.000 description 1
229920003247 engineering thermoplastic Polymers 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
235000013305 food Nutrition 0.000 description 1
238000013467 fragmentation Methods 0.000 description 1
238000006062 fragmentation reaction Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
239000000499 gel Substances 0.000 description 1
239000008273 gelatin Substances 0.000 description 1
229920000159 gelatin Polymers 0.000 description 1
235000019322 gelatine Nutrition 0.000 description 1
235000011852 gelatine desserts Nutrition 0.000 description 1
150000002366 halogen compounds Chemical class 0.000 description 1
CKAPSXZOOQJIBF-UHFFFAOYSA-N hexachlorobenzene Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl CKAPSXZOOQJIBF-UHFFFAOYSA-N 0.000 description 1
229920006158 high molecular weight polymer Polymers 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
125000001183 hydrocarbyl group Chemical group 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
239000011872 intimate mixture Substances 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
239000000463 material Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
125000005394 methallyl group Chemical group 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
239000012778 molding material Substances 0.000 description 1
230000002794 monomerizing effect Effects 0.000 description 1
125000001624 naphthyl group Chemical group 0.000 description 1
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
238000000399 optical microscopy Methods 0.000 description 1
125000005375 organosiloxane group Chemical group 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
238000005691 oxidative coupling reaction Methods 0.000 description 1
MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920001596 poly (chlorostyrenes) Polymers 0.000 description 1
229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
229920002379 silicone rubber Polymers 0.000 description 1
239000004945 silicone rubber Substances 0.000 description 1
229910001923 silver oxide Inorganic materials 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000008107 starch Substances 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000011115 styrene butadiene Substances 0.000 description 1
229920003048 styrene butadiene rubber Polymers 0.000 description 1
229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
229920003047 styrene-styrene-butadiene-styrene Polymers 0.000 description 1
230000008961 swelling Effects 0.000 description 1
SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
238000004627 transmission electron microscopy Methods 0.000 description 1

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Compositions Of Macromolecular Compounds (AREA)

CA000346158A 1980-02-21 1980-02-21 Compositions de resine polyphenylenoxyde renfermant des resines aromatiques alkenylees modifiees au polysiloxane Expired CA1136319A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000346158A CA1136319A (fr)	1980-02-21	1980-02-21	Compositions de resine polyphenylenoxyde renfermant des resines aromatiques alkenylees modifiees au polysiloxane

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000346158A CA1136319A (fr)	1980-02-21	1980-02-21	Compositions de resine polyphenylenoxyde renfermant des resines aromatiques alkenylees modifiees au polysiloxane

Publications (1)

Publication Number	Publication Date
CA1136319A true CA1136319A (fr)	1982-11-23

Family

ID=4116295

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000346158A Expired CA1136319A (fr)	1980-02-21	1980-02-21	Compositions de resine polyphenylenoxyde renfermant des resines aromatiques alkenylees modifiees au polysiloxane

Country Status (1)

Country	Link
CA (1)	CA1136319A (fr)

1980
- 1980-02-21 CA CA000346158A patent/CA1136319A/fr not_active Expired

Legal Events

Date	Code	Title	Description
1999-11-23	MKEX	Expiry

Publication	Publication Date	Title
US4226761A (en)	1980-10-07	Polyphenylene ether resin compositions containing polysiloxane-modified alkenyl aromatic resins
CA1043926A (fr)	1978-12-05	Melanges d'une resine d'ether de polyphenylene et de resines aromatiques d'alkenyls
US4101504A (en)	1978-07-18	High impact compositions of a polyphenylene ether resin and alkenyl aromatic resins modified with EPDM rubber
CA1070884A (fr)	1980-01-29	Melange de resine de polyphenylene-ether, resines aromatiques de type alkenyle modifiees par du caoutchouc epdm et polymeres greffes a forte teneur en caoutchouc
US3960808A (en)	1976-06-01	Polyphenylene ether composition
US5071911A (en)	1991-12-10	Thermoplastic resin composition and process for producing the same
US4101503A (en)	1978-07-18	Compositions of a polyphenylene ether resin and high molecular weight alkenyl aromatic resins modified with EPDM rubber
US4172826A (en)	1979-10-30	Polyphenylene ether resin compositions containing EPDM rubber-modified alkenyl aromatic resins and hydrogenated elastomeric block copolymers
US4102850A (en)	1978-07-25	High impact polyphenylene ether resin compositions containing mineral oil
US4101505A (en)	1978-07-18	Compositions of a polyphenylene ether resin and EPDM rubber-modified alkenyl aromatic resins having specified gel content
US4139574A (en)	1979-02-13	Impact resistant polyphenylene ether resin compositions containing EPDM rubber-modified alkenyl aromatic resins and hydrogenated radial teleblock copolymers
US3974235A (en)	1976-08-10	Blends of a polyphenylene ether resin, alkenyl aromatic resins modified with EPDM rubber and flame retardant
US4196116A (en)	1980-04-01	Impact resistant polyphenylene ether compositions containing EPDM rubber-modified alkenyl aromatic resins and hydrogenated diblock copolymers
US4152316A (en)	1979-05-01	Compositions of a polyphenylene ether resin and alkenyl aromatic resins modified with epdm rubber
US3959211A (en)	1976-05-25	Blends of a polyphenylene ether resin and alkenyl aromatic resins modified with EPDM rubber
US4020124A (en)	1977-04-26	Blends of a polyphenylene ether resin, alkenyl aromatic resins modified with EPDM rubber and graft polymerized high rubber content polymers
CA1119742A (fr)	1982-03-09	Substances resistant aux chocs, a base de resine d'ether de polyphenylene, contenant des copolymeres hydrogenes a structure radiale
CA1094250A (fr)	1981-01-20	Substances moussante a base d'oxyde de polyphenylene
US4224209A (en)	1980-09-23	Polyphenylene ether resin compositions containing poly(alkylene oxides) and phosphate plasticizer
US4127558A (en)	1978-11-28	Compositions of a polyphenylene ether resin and alkenyl aromatic resins modified with EPDM rubber containing propylene
CA1087791A (fr)	1980-10-14	Produits a base de resine d'ether de polyphenylene resistant aux chocs et contenant des copolymeres radiaux, telesequences
US4228046A (en)	1980-10-14	Thermoplastic molding compositions of rubber modified copolymers of a vinyl aromatic compound and an α,β-unsaturated cyclic anhydride
EP0071773A2 (fr)	1983-02-16	Articles moulés à résistance améliorée au choc et compositions pour ceux-ci
US4143095A (en)	1979-03-06	Polyphenylene ether resin compositions containing a hydrogenated elastomeric block copolymer
CA1129137A (fr)	1982-08-03	Melanges de resines de polyphenylene-ether, contenant du polypentenamer