CA1136600A - Substances a base d'acide carboxylique aromatique et de peroxyde, s'ecoulant librement, seches et sans danger - Google Patents

Substances a base d'acide carboxylique aromatique et de peroxyde, s'ecoulant librement, seches et sans danger

Info

Publication number: CA1136600A
Authority: CA; Canada
Prior art keywords: peroxide; solid; benzoic acid; weight; composition
Prior art date: 1979-08-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000355772A

Other languages

English (en)

Inventor

Solomon C. Westbrook

Jose Sanchez

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Arkema Inc

Original Assignee

Pennwalt Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-08-13

Filing date

1980-07-09

Publication date

1982-11-30

1980-07-09 Application filed by Pennwalt Corp filed Critical Pennwalt Corp

1981-10-05 Priority to US06/308,220 priority Critical patent/US4387044A/en

1982-11-30 Application granted granted Critical

1982-11-30 Publication of CA1136600A publication Critical patent/CA1136600A/fr

Status Expired legal-status Critical Current

Links

WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 title claims abstract description 184
239000000203 mixture Substances 0.000 title claims abstract description 159
150000002978 peroxides Chemical class 0.000 title claims abstract description 85
239000005711 Benzoic acid Substances 0.000 claims abstract description 86
235000010233 benzoic acid Nutrition 0.000 claims abstract description 86
239000007787 solid Substances 0.000 claims abstract description 69
239000000178 monomer Substances 0.000 claims abstract description 28
-1 diacyl peroxide Chemical class 0.000 claims abstract description 22
229920006337 unsaturated polyester resin Polymers 0.000 claims abstract description 16
239000012933 diacyl peroxide Substances 0.000 claims abstract description 5
JHQVCQDWGSXTFE-UHFFFAOYSA-N 2-(2-prop-2-enoxycarbonyloxyethoxy)ethyl prop-2-enyl carbonate Chemical compound C=CCOC(=O)OCCOCCOC(=O)OCC=C JHQVCQDWGSXTFE-UHFFFAOYSA-N 0.000 claims abstract description 4
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 92
235000019400 benzoyl peroxide Nutrition 0.000 claims description 92
238000000034 method Methods 0.000 claims description 23
238000002844 melting Methods 0.000 claims description 16
230000008018 melting Effects 0.000 claims description 16
239000002480 mineral oil Substances 0.000 claims description 16
235000010446 mineral oil Nutrition 0.000 claims description 15
150000001451 organic peroxides Chemical class 0.000 claims description 15
239000000428 dust Substances 0.000 claims description 13
150000001558 benzoic acid derivatives Chemical class 0.000 claims description 11
125000000217 alkyl group Chemical group 0.000 claims description 9
ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 claims description 8
LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 claims description 8
238000004132 cross linking Methods 0.000 claims description 7
YMOIBQNMVPBEEZ-UHFFFAOYSA-N 2-phenoxyethoxycarbonyloxy 2-phenoxyethyl carbonate Chemical compound C=1C=CC=CC=1OCCOC(=O)OOC(=O)OCCOC1=CC=CC=C1 YMOIBQNMVPBEEZ-UHFFFAOYSA-N 0.000 claims description 5
230000000977 initiatory effect Effects 0.000 claims description 5
125000005634 peroxydicarbonate group Chemical group 0.000 claims description 5
230000000379 polymerizing effect Effects 0.000 claims description 5
XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 4
IAWYWVVBKGWUEP-UHFFFAOYSA-N benzyl phenylmethoxycarbonyloxy carbonate Chemical compound C=1C=CC=CC=1COC(=O)OOC(=O)OCC1=CC=CC=C1 IAWYWVVBKGWUEP-UHFFFAOYSA-N 0.000 claims description 4
NLBJAOHLJABDAU-UHFFFAOYSA-N (3-methylbenzoyl) 3-methylbenzenecarboperoxoate Chemical compound CC1=CC=CC(C(=O)OOC(=O)C=2C=C(C)C=CC=2)=C1 NLBJAOHLJABDAU-UHFFFAOYSA-N 0.000 claims description 3
NOBYOEQUFMGXBP-UHFFFAOYSA-N (4-tert-butylcyclohexyl) (4-tert-butylcyclohexyl)oxycarbonyloxy carbonate Chemical compound C1CC(C(C)(C)C)CCC1OC(=O)OOC(=O)OC1CCC(C(C)(C)C)CC1 NOBYOEQUFMGXBP-UHFFFAOYSA-N 0.000 claims description 3
JGBAASVQPMTVHO-UHFFFAOYSA-N 2,5-dihydroperoxy-2,5-dimethylhexane Chemical compound OOC(C)(C)CCC(C)(C)OO JGBAASVQPMTVHO-UHFFFAOYSA-N 0.000 claims description 3
125000001424 substituent group Chemical group 0.000 claims 1
238000009472 formulation Methods 0.000 abstract description 35
238000006116 polymerization reaction Methods 0.000 abstract description 10
239000003999 initiator Substances 0.000 abstract description 8
BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 abstract description 4
230000003111 delayed effect Effects 0.000 abstract description 4
238000002156 mixing Methods 0.000 abstract description 2
239000000155 melt Substances 0.000 abstract 2
125000001118 alkylidene group Chemical group 0.000 abstract 1
150000001559 benzoic acids Chemical class 0.000 abstract 1
229960004365 benzoic acid Drugs 0.000 description 73
VOWAEIGWURALJQ-UHFFFAOYSA-N Dicyclohexyl phthalate Chemical compound C=1C=CC=C(C(=O)OC2CCCCC2)C=1C(=O)OC1CCCCC1 VOWAEIGWURALJQ-UHFFFAOYSA-N 0.000 description 41
239000000945 filler Substances 0.000 description 26
239000000047 product Substances 0.000 description 18
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
239000002253 acid Substances 0.000 description 16
229920005989 resin Polymers 0.000 description 14
239000011347 resin Substances 0.000 description 14
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 12
238000003556 assay Methods 0.000 description 12
238000012360 testing method Methods 0.000 description 12
239000011342 resin composition Substances 0.000 description 11
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
229940038597 peroxide anti-acne preparations for topical use Drugs 0.000 description 9
238000002360 preparation method Methods 0.000 description 9
239000002002 slurry Substances 0.000 description 9
239000000243 solution Substances 0.000 description 9
239000004094 surface-active agent Substances 0.000 description 9
229920001567 vinyl ester resin Polymers 0.000 description 9
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 7
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
238000001914 filtration Methods 0.000 description 6
239000007788 liquid Substances 0.000 description 6
229920006305 unsaturated polyester Polymers 0.000 description 6
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 6
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical group C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 description 5
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 5
239000000725 suspension Substances 0.000 description 5
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
150000007513 acids Chemical class 0.000 description 4
125000003118 aryl group Chemical group 0.000 description 4
231100001261 hazardous Toxicity 0.000 description 4
239000012766 organic filler Substances 0.000 description 4
125000000864 peroxy group Chemical group O(O*)* 0.000 description 4
229920000728 polyester Polymers 0.000 description 4
239000008247 solid mixture Substances 0.000 description 4
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 3
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
229920000180 alkyd Polymers 0.000 description 3
150000008064 anhydrides Chemical class 0.000 description 3
150000004649 carbonic acid derivatives Chemical class 0.000 description 3
150000001735 carboxylic acids Chemical class 0.000 description 3
230000001627 detrimental effect Effects 0.000 description 3
239000000839 emulsion Substances 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
239000002360 explosive Substances 0.000 description 3
239000011521 glass Substances 0.000 description 3
239000000463 material Substances 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
229920000642 polymer Polymers 0.000 description 3
239000000126 substance Substances 0.000 description 3
238000010557 suspension polymerization reaction Methods 0.000 description 3
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
UBRWPVTUQDJKCC-UHFFFAOYSA-N 1,3-bis(2-tert-butylperoxypropan-2-yl)benzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC(C(C)(C)OOC(C)(C)C)=C1 UBRWPVTUQDJKCC-UHFFFAOYSA-N 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 2
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
239000004604 Blowing Agent Substances 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
239000004641 Diallyl-phthalate Substances 0.000 description 2
BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 2
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
239000004698 Polyethylene Substances 0.000 description 2
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
239000003963 antioxidant agent Substances 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
229960002255 azelaic acid Drugs 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 2
JKJWYKGYGWOAHT-UHFFFAOYSA-N bis(prop-2-enyl) carbonate Chemical compound C=CCOC(=O)OCC=C JKJWYKGYGWOAHT-UHFFFAOYSA-N 0.000 description 2
FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 2
239000006229 carbon black Substances 0.000 description 2
235000019241 carbon black Nutrition 0.000 description 2
150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
238000005266 casting Methods 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
239000007859 condensation product Substances 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
230000007797 corrosion Effects 0.000 description 2
238000005260 corrosion Methods 0.000 description 2
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
239000000975 dye Substances 0.000 description 2
FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 2
239000013022 formulation composition Substances 0.000 description 2
235000011087 fumaric acid Nutrition 0.000 description 2
239000007789 gas Substances 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
239000012760 heat stabilizer Substances 0.000 description 2
PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 2
229910052500 inorganic mineral Inorganic materials 0.000 description 2
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
239000004611 light stabiliser Substances 0.000 description 2
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000011707 mineral Substances 0.000 description 2
BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
239000004014 plasticizer Substances 0.000 description 2
229920001225 polyester resin Polymers 0.000 description 2
239000004645 polyester resin Substances 0.000 description 2
239000000843 powder Substances 0.000 description 2
HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 2
229920006395 saturated elastomer Polymers 0.000 description 2
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
231100000489 sensitizer Toxicity 0.000 description 2
238000003756 stirring Methods 0.000 description 2
238000003860 storage Methods 0.000 description 2
KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
150000005846 sugar alcohols Polymers 0.000 description 2
229910052717 sulfur Inorganic materials 0.000 description 2
239000011593 sulfur Substances 0.000 description 2
ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 description 2
229920002554 vinyl polymer Polymers 0.000 description 2
239000011787 zinc oxide Substances 0.000 description 2
WRXCBRHBHGNNQA-UHFFFAOYSA-N (2,4-dichlorobenzoyl) 2,4-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1Cl WRXCBRHBHGNNQA-UHFFFAOYSA-N 0.000 description 1
ITSILTVXGLRLHL-UHFFFAOYSA-N (2-benzylbenzoyl) 2-benzylbenzenecarboperoxoate Chemical compound C=1C=CC=C(CC=2C=CC=CC=2)C=1C(=O)OOC(=O)C1=CC=CC=C1CC1=CC=CC=C1 ITSILTVXGLRLHL-UHFFFAOYSA-N 0.000 description 1
UAHNNBOKPMGCOS-UHFFFAOYSA-N (2-chloroacetyl) 2-chloroethaneperoxoate Chemical compound ClCC(=O)OOC(=O)CCl UAHNNBOKPMGCOS-UHFFFAOYSA-N 0.000 description 1
WOTCBNVQQFUGLX-UHFFFAOYSA-N (2-methoxybenzoyl) 2-methoxybenzenecarboperoxoate Chemical compound COC1=CC=CC=C1C(=O)OOC(=O)C1=CC=CC=C1OC WOTCBNVQQFUGLX-UHFFFAOYSA-N 0.000 description 1
ZICNIEOYWVIEQJ-UHFFFAOYSA-N (2-methylbenzoyl) 2-methylbenzenecarboperoxoate Chemical compound CC1=CC=CC=C1C(=O)OOC(=O)C1=CC=CC=C1C ZICNIEOYWVIEQJ-UHFFFAOYSA-N 0.000 description 1
XBDOGXHLESIJJK-UHFFFAOYSA-N (3-chlorobenzoyl) 3-chlorobenzenecarboperoxoate Chemical compound ClC1=CC=CC(C(=O)OOC(=O)C=2C=C(Cl)C=CC=2)=C1 XBDOGXHLESIJJK-UHFFFAOYSA-N 0.000 description 1
OXYKVVLTXXXVRT-UHFFFAOYSA-N (4-chlorobenzoyl) 4-chlorobenzenecarboperoxoate Chemical compound C1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1 OXYKVVLTXXXVRT-UHFFFAOYSA-N 0.000 description 1
TYKGVIDLNFGKOJ-UHFFFAOYSA-N (4-fluorobenzoyl) 4-fluorobenzenecarboperoxoate Chemical compound C1=CC(F)=CC=C1C(=O)OOC(=O)C1=CC=C(F)C=C1 TYKGVIDLNFGKOJ-UHFFFAOYSA-N 0.000 description 1
XVOUMQNXTGKGMA-OWOJBTEDSA-N (E)-glutaconic acid Chemical compound OC(=O)C\C=C\C(O)=O XVOUMQNXTGKGMA-OWOJBTEDSA-N 0.000 description 1
ORTVZLZNOYNASJ-UPHRSURJSA-N (z)-but-2-ene-1,4-diol Chemical compound OC\C=C/CO ORTVZLZNOYNASJ-UPHRSURJSA-N 0.000 description 1
ILFYLFICPMIXSN-UHFFFAOYSA-N 1,3,5-tris(2-hydroperoxypropan-2-yl)benzene Chemical compound OOC(C)(C)C1=CC(C(C)(C)OO)=CC(C(C)(C)OO)=C1 ILFYLFICPMIXSN-UHFFFAOYSA-N 0.000 description 1
REGMWDPZVFOJLY-UHFFFAOYSA-N 1,4-bis(2-hydroperoxypropan-2-yl)benzene Chemical compound OOC(C)(C)C1=CC=C(C(C)(C)OO)C=C1 REGMWDPZVFOJLY-UHFFFAOYSA-N 0.000 description 1
ZPOUDMYDJJMHOO-UHFFFAOYSA-N 1-(1-hydroxycyclohexyl)peroxycyclohexan-1-ol Chemical compound C1CCCCC1(O)OOC1(O)CCCCC1 ZPOUDMYDJJMHOO-UHFFFAOYSA-N 0.000 description 1
SLBOQBILGNEPEB-UHFFFAOYSA-N 1-chloroprop-2-enylbenzene Chemical compound C=CC(Cl)C1=CC=CC=C1 SLBOQBILGNEPEB-UHFFFAOYSA-N 0.000 description 1
DGSNTUCORHZCPV-UHFFFAOYSA-N 1-hydroperoxy-1-(1-hydroperoxycyclohexyl)peroxycyclohexane Chemical compound C1CCCCC1(OO)OOC1(OO)CCCCC1 DGSNTUCORHZCPV-UHFFFAOYSA-N 0.000 description 1
BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
BKYWPNROPGQIFZ-UHFFFAOYSA-N 2,4-dimethylbenzoic acid Chemical compound CC1=CC=C(C(O)=O)C(C)=C1 BKYWPNROPGQIFZ-UHFFFAOYSA-N 0.000 description 1
HVYSCTOUDBGKSR-UHFFFAOYSA-N 2,7-dihydroperoxy-2,7-dimethylocta-3,5-diyne Chemical compound OOC(C)(C)C#CC#CC(C)(C)OO HVYSCTOUDBGKSR-UHFFFAOYSA-N 0.000 description 1
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
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ODQWDBNAMVRLSR-UHFFFAOYSA-N 3,5-dimethyldioxolane-3,5-diol Chemical compound CC1(O)CC(C)(O)OO1 ODQWDBNAMVRLSR-UHFFFAOYSA-N 0.000 description 1
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KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 description 1
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LYJHVEDILOKZCG-UHFFFAOYSA-N Allyl benzoate Chemical compound C=CCOC(=O)C1=CC=CC=C1 LYJHVEDILOKZCG-UHFFFAOYSA-N 0.000 description 1
ZDZVKPXKLLLOOA-UHFFFAOYSA-N Allylmalonic acid Chemical compound OC(=O)C(C(O)=O)CC=C ZDZVKPXKLLLOOA-UHFFFAOYSA-N 0.000 description 1
235000013162 Cocos nucifera Nutrition 0.000 description 1
244000060011 Cocos nucifera Species 0.000 description 1
229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
229920002943 EPDM rubber Polymers 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
229930195725 Mannitol Natural products 0.000 description 1
229920003091 Methocel™ Polymers 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
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239000004721 Polyphenylene oxide Substances 0.000 description 1
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XSHJLFOMGJTADT-UHFFFAOYSA-N [4-methyl-2-(4-methyl-2-phenylpentan-2-yl)peroxypentan-2-yl]benzene Chemical compound C=1C=CC=CC=1C(C)(CC(C)C)OOC(C)(CC(C)C)C1=CC=CC=C1 XSHJLFOMGJTADT-UHFFFAOYSA-N 0.000 description 1
238000003916 acid precipitation Methods 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000001361 adipic acid Substances 0.000 description 1
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125000001931 aliphatic group Chemical group 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001447 alkali salts Chemical class 0.000 description 1
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XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
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239000002585 base Substances 0.000 description 1
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238000005119 centrifugation Methods 0.000 description 1
HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 description 1
YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
229940018557 citraconic acid Drugs 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000000498 cooling water Substances 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
IFDVQVHZEKPUSC-UHFFFAOYSA-N cyclohex-3-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCC=CC1C(O)=O IFDVQVHZEKPUSC-UHFFFAOYSA-N 0.000 description 1
BLCKNMAZFRMCJJ-UHFFFAOYSA-N cyclohexyl cyclohexyloxycarbonyloxy carbonate Chemical compound C1CCCCC1OC(=O)OOC(=O)OC1CCCCC1 BLCKNMAZFRMCJJ-UHFFFAOYSA-N 0.000 description 1
ZJGVBDHBTIOVRP-UHFFFAOYSA-N dibenzoyl hexanediperoxoate Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)CCCCC(=O)OOC(=O)C1=CC=CC=C1 ZJGVBDHBTIOVRP-UHFFFAOYSA-N 0.000 description 1
JBSLOWBPDRZSMB-BQYQJAHWSA-N dibutyl (e)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C\C(=O)OCCCC JBSLOWBPDRZSMB-BQYQJAHWSA-N 0.000 description 1
229960002380 dibutyl phthalate Drugs 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
YHOHCZWPIKTKAZ-UHFFFAOYSA-N dihexyl butanedioate;sodium Chemical compound [Na].CCCCCCOC(=O)CCC(=O)OCCCCCC YHOHCZWPIKTKAZ-UHFFFAOYSA-N 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
QZYRMODBFHTNHF-UHFFFAOYSA-N ditert-butyl benzene-1,2-dicarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1C(=O)OOC(C)(C)C QZYRMODBFHTNHF-UHFFFAOYSA-N 0.000 description 1
VGUWHIIVOSLWAM-UHFFFAOYSA-N ditert-butyl butanediperoxoate Chemical compound CC(C)(C)OOC(=O)CCC(=O)OOC(C)(C)C VGUWHIIVOSLWAM-UHFFFAOYSA-N 0.000 description 1
YFQXEEXTCUCORR-UHFFFAOYSA-N ditert-butyl hexanediperoxoate Chemical compound CC(C)(C)OOC(=O)CCCCC(=O)OOC(C)(C)C YFQXEEXTCUCORR-UHFFFAOYSA-N 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000010410 dusting Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
125000003700 epoxy group Chemical group 0.000 description 1
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GLVVKKSPKXTQRB-UHFFFAOYSA-N ethenyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC=C GLVVKKSPKXTQRB-UHFFFAOYSA-N 0.000 description 1
UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
BGSFCOHRQUBESL-UHFFFAOYSA-N ethyl prop-2-enyl carbonate Chemical compound CCOC(=O)OCC=C BGSFCOHRQUBESL-UHFFFAOYSA-N 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
239000011953 free-radical catalyst Substances 0.000 description 1
239000001530 fumaric acid Substances 0.000 description 1
150000002238 fumaric acids Chemical class 0.000 description 1
238000001879 gelation Methods 0.000 description 1
239000003365 glass fiber Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical group 0.000 description 1
238000013038 hand mixing Methods 0.000 description 1
IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
QMXBAGNATMRETP-UHFFFAOYSA-N hexadecanoyl hexadecaneperoxoate Chemical compound CCCCCCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCCCCCC QMXBAGNATMRETP-UHFFFAOYSA-N 0.000 description 1
QWVBGCWRHHXMRM-UHFFFAOYSA-N hexadecoxycarbonyloxy hexadecyl carbonate Chemical compound CCCCCCCCCCCCCCCCOC(=O)OOC(=O)OCCCCCCCCCCCCCCCC QWVBGCWRHHXMRM-UHFFFAOYSA-N 0.000 description 1
HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
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239000000594 mannitol Substances 0.000 description 1
235000010355 mannitol Nutrition 0.000 description 1
HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
229910052914 metal silicate Inorganic materials 0.000 description 1
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
MTJBMPVTGWFCIZ-UHFFFAOYSA-N methyl 2-(2-methoxycarbonylbenzoyl)peroxycarbonylbenzoate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OOC(=O)C1=CC=CC=C1C(=O)OC MTJBMPVTGWFCIZ-UHFFFAOYSA-N 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
HPKCQFGYSFRQDZ-UHFFFAOYSA-N octadecanoyl benzenecarboperoxoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OOC(=O)C1=CC=CC=C1 HPKCQFGYSFRQDZ-UHFFFAOYSA-N 0.000 description 1
239000003921 oil Substances 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 description 1
UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
229920000570 polyether Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
239000003505 polymerization initiator Substances 0.000 description 1
229920005862 polyol Polymers 0.000 description 1
150000003077 polyols Chemical class 0.000 description 1
229920000166 polytrimethylene carbonate Polymers 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
230000002028 premature Effects 0.000 description 1
BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 1
239000002990 reinforced plastic Substances 0.000 description 1
239000005336 safety glass Substances 0.000 description 1
230000035945 sensitivity Effects 0.000 description 1
230000035939 shock Effects 0.000 description 1
229920002379 silicone rubber Polymers 0.000 description 1
WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
239000004299 sodium benzoate Substances 0.000 description 1
235000010234 sodium benzoate Nutrition 0.000 description 1
BTJYKXPSPBJJDQ-UHFFFAOYSA-M sodium;1,4-bis(4-methylpentan-2-yloxy)-1,4-dioxobutane-2-sulfonate Chemical compound [Na+].CC(C)CC(C)OC(=O)CC(S([O-])(=O)=O)C(=O)OC(C)CC(C)C BTJYKXPSPBJJDQ-UHFFFAOYSA-M 0.000 description 1
239000002904 solvent Substances 0.000 description 1
235000015096 spirit Nutrition 0.000 description 1
238000013112 stability test Methods 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
229920003048 styrene butadiene rubber Polymers 0.000 description 1
235000010983 sucrose acetate isobutyrate Nutrition 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
229920003051 synthetic elastomer Polymers 0.000 description 1
239000005061 synthetic rubber Substances 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 1
TUXIOAHIBIEZAG-UHFFFAOYSA-N tridecoxycarbonyloxy tridecyl carbonate Chemical compound CCCCCCCCCCCCCOC(=O)OOC(=O)OCCCCCCCCCCCCC TUXIOAHIBIEZAG-UHFFFAOYSA-N 0.000 description 1
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
239000003021 water soluble solvent Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
- C08G63/54—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation the acids or hydroxy compounds containing carbocyclic rings
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Compositions Of Macromolecular Compounds (AREA)
Polymerization Catalysts (AREA)
Macromonomer-Based Addition Polymer (AREA)

CA000355772A 1979-08-13 1980-07-09 Substances a base d'acide carboxylique aromatique et de peroxyde, s'ecoulant librement, seches et sans danger Expired CA1136600A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
US06/308,220 US4387044A (en)	1979-08-13	1981-10-05	Safe, dry, free-flowing solid peroxide/unsubstituted or alkyl substituted benzoic acid compositions

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US6615079A	1979-08-13	1979-08-13
US066,150		1979-08-13

Publications (1)

Publication Number	Publication Date
CA1136600A true CA1136600A (fr)	1982-11-30

Family

ID=22067565

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000355772A Expired CA1136600A (fr)	1979-08-13	1980-07-09	Substances a base d'acide carboxylique aromatique et de peroxyde, s'ecoulant librement, seches et sans danger

Country Status (4)

Country	Link
JP (1)	JPS5636502A (fr)
BR (1)	BR8005067A (fr)
CA (1)	CA1136600A (fr)
DE (1)	DE3030658A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US10875982B2 (en)	2015-11-23	2020-12-29	United Initiators Gmbh	BCHPC having a reduced burning rate

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH078898B2 (ja) *	1987-05-28	1995-02-01	帝人株式会社	成形用熱硬化性エポキシ樹脂組成物

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2453070A (en) *	1944-08-23	1948-11-02	Buffalo Electrochemical Compan	Organic peroxide composition
US2453071A (en) *	1945-01-27	1948-11-02	Buffalo Electro Chem Co	Desensitization of solid organic peroxides
DE1048028B (de) *	1956-09-05	1958-12-31	Elektrochem Werke Muenchen Ag	Polymerisationskatalysator in Loesung zur Herstellung von Polymerisaten und Mischpolymerisaten aus ungesaettigten, organischen Verbindungen
NL132378C (fr) *	1966-06-23
DE1922171C3 (de) *	1969-04-30	1979-03-01	Peroxid-Chemie Gmbh, 8021 Hoellriegelskreuth	Verfahren zur Herstellung einer Peroxidpaste

1980
- 1980-07-09 CA CA000355772A patent/CA1136600A/fr not_active Expired
- 1980-08-12 JP JP10991380A patent/JPS5636502A/ja active Pending
- 1980-08-12 BR BR8005067A patent/BR8005067A/pt unknown
- 1980-08-13 DE DE19803030658 patent/DE3030658A1/de not_active Ceased

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US10875982B2 (en)	2015-11-23	2020-12-29	United Initiators Gmbh	BCHPC having a reduced burning rate

Also Published As

Publication number	Publication date
BR8005067A (pt)	1981-05-12
JPS5636502A (en)	1981-04-09
DE3030658A1 (de)	1981-03-26

Legal Events

Date	Code	Title	Description
1999-11-30	MKEX	Expiry

Publication	Publication Date	Title
US4387044A (en)	1983-06-07	Safe, dry, free-flowing solid peroxide/unsubstituted or alkyl substituted benzoic acid compositions
US5051531A (en)	1991-09-24	Antioxidant-peroxides
US4097408A (en)	1978-06-27	Diperoxyester mixture prepared by reacting dihydroperoxides and carbonyls
BRPI0611398B1 (pt)	2017-03-07	solução aceleradora, processo para cura de poliéster insaturado ou uma resina de acrilato, processo de polimerização redox e uso da solução aceleradora
US5541151A (en)	1996-07-30	Stabilized dialkyl peroxydicarbonate compositions and their uses
EP0377633B1 (fr)	1995-05-17	Initiateurs a radicaux exempts de peroxyde, contenant des groupes photostabilisants amines retardes
US4042773A (en)	1977-08-16	Peroxide free radical initiators containing ultraviolet light stabilizing groups
CA1136600A (fr)	1982-11-30	Substances a base d'acide carboxylique aromatique et de peroxyde, s'ecoulant librement, seches et sans danger
US3821273A (en)	1974-06-28	Novel dialkyl peroxydicarbonates
US20040260111A1 (en)	2004-12-23	Ketone peroxide derivatives, their preparation and use
US3763275A (en)	1973-10-02	Curing processes employing beta-substituted diperoxyketals
US4055714A (en)	1977-10-25	Azo free radical initiators containing ultraviolet light stabilizing groups
CA1085416A (fr)	1980-09-09	Diperoxydes non symetriques et modes d'emploi pour la polymerisation de monomeres insatures
TWI242548B (en)	2005-11-01	Stabilized organic peroxide compositions
US6764977B2 (en)	2004-07-20	Safe, free-flowing solid peroxide compositions
AU751095B2 (en)	2002-08-08	Peroxides, their preparation process and use
US3857828A (en)	1974-12-31	Di(2-phenoxyethyl) peroxydicarbonate
US3832336A (en)	1974-08-27	Curing and polymerizing processes employing beta-substituted diperoxyketals
US4137252A (en)	1979-01-30	Dicyclododecyl peroxydicarbonate
US5420173A (en)	1995-05-30	Multi-component ethylenically unsaturate peroxyesters
US4045463A (en)	1977-08-30	Peroxyesters of sorbic acid
JP2576572B2 (ja)	1997-01-29	不飽和単量体の重合開始剤および不飽和ポリエステル樹脂組成物の硬化剤
US4302569A (en)	1981-11-24	2-Chloro-2-alkyl substituted peroxyesters
US4486580A (en)	1984-12-04	Process for using t-alkyl peroxy-2-alkyl-2-arylacetates as free-radical initiators and curing catalysts
US4285877A (en)	1981-08-25	Di(2-methyl-2-phenyl propyl) peroxy dicarbonate and other novel (2-alkyl-2-phenyl) substituted peroxy dicarbonates

CA1136600A - Substances a base d'acide carboxylique aromatique et de peroxyde, s'ecoulant librement, seches et sans danger - Google Patents

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