CA1139362A - Pile a cathode de trioxyde de soufre soluble - Google Patents

Pile a cathode de trioxyde de soufre soluble

Info

Publication number: CA1139362A
Authority: CA; Canada
Prior art keywords: electrochemical cell; cell according; primary electrochemical; sulfur trioxide; electrolyte salt
Prior art date: 1978-12-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000341180A

Other languages

English (en)

Inventor

Richard Gary, Sr.

Carl R. Schlaikjer

Robert J. Staniewicz

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Verizon Laboratories Inc

Original Assignee

GTE Laboratories Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-12-20

Filing date

1979-12-04

Publication date

1983-01-11

1979-12-04 Application filed by GTE Laboratories Inc filed Critical GTE Laboratories Inc

1983-01-11 Application granted granted Critical

1983-01-11 Publication of CA1139362A publication Critical patent/CA1139362A/fr

Status Expired legal-status Critical Current

Links

AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 title claims abstract description 88
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims abstract description 80
150000003839 salts Chemical class 0.000 claims abstract description 44
239000003792 electrolyte Substances 0.000 claims abstract description 39
239000006184 cosolvent Substances 0.000 claims abstract description 21
229910052744 lithium Inorganic materials 0.000 claims abstract description 21
239000008151 electrolyte solution Substances 0.000 claims abstract description 13
239000010405 anode material Substances 0.000 claims abstract description 10
239000011877 solvent mixture Substances 0.000 claims abstract description 7
239000006182 cathode active material Substances 0.000 claims abstract description 5
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 18
229910052751 metal Inorganic materials 0.000 claims description 12
239000002184 metal Substances 0.000 claims description 12
239000000463 material Substances 0.000 claims description 11
239000000243 solution Substances 0.000 claims description 11
150000001450 anions Chemical class 0.000 claims description 10
229910001540 lithium hexafluoroarsenate(V) Inorganic materials 0.000 claims description 10
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
229910052708 sodium Inorganic materials 0.000 claims description 8
239000011734 sodium Substances 0.000 claims description 8
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 5
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
229910052788 barium Inorganic materials 0.000 claims description 5
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 5
229910052792 caesium Inorganic materials 0.000 claims description 5
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 5
229910052791 calcium Inorganic materials 0.000 claims description 5
239000011575 calcium Substances 0.000 claims description 5
229910052749 magnesium Inorganic materials 0.000 claims description 5
239000011777 magnesium Substances 0.000 claims description 5
229910052700 potassium Inorganic materials 0.000 claims description 5
239000011591 potassium Substances 0.000 claims description 5
229910052712 strontium Inorganic materials 0.000 claims description 5
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 5
239000006229 carbon black Substances 0.000 claims description 4
229910052731 fluorine Inorganic materials 0.000 claims description 4
229910052701 rubidium Inorganic materials 0.000 claims description 4
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 4
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
239000011230 binding agent Substances 0.000 claims description 3
229910052796 boron Inorganic materials 0.000 claims description 3
239000000460 chlorine Substances 0.000 claims description 3
229910052801 chlorine Inorganic materials 0.000 claims description 3
229910002804 graphite Inorganic materials 0.000 claims description 3
239000010439 graphite Substances 0.000 claims description 3
150000002500 ions Chemical class 0.000 claims description 3
229910052794 bromium Inorganic materials 0.000 claims description 2
150000001768 cations Chemical class 0.000 claims description 2
UQSQSQZYBQSBJZ-UHFFFAOYSA-M fluorosulfate group Chemical group S(=O)(=O)([O-])F UQSQSQZYBQSBJZ-UHFFFAOYSA-M 0.000 claims description 2
229910052739 hydrogen Inorganic materials 0.000 claims description 2
229910052740 iodine Inorganic materials 0.000 claims description 2
230000003334 potential effect Effects 0.000 abstract 1
239000002904 solvent Substances 0.000 description 18
239000007788 liquid Substances 0.000 description 11
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
229940021013 electrolyte solution Drugs 0.000 description 10
239000000126 substance Substances 0.000 description 10
239000000203 mixture Substances 0.000 description 8
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 6
YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical group ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 description 6
239000010406 cathode material Substances 0.000 description 5
229910052759 nickel Inorganic materials 0.000 description 5
238000002360 preparation method Methods 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 3
239000004020 conductor Substances 0.000 description 3
238000005868 electrolysis reaction Methods 0.000 description 3
239000011521 glass Substances 0.000 description 3
230000009467 reduction Effects 0.000 description 3
-1 ru~idium Chemical compound 0.000 description 3
238000003860 storage Methods 0.000 description 3
229910017048 AsF6 Inorganic materials 0.000 description 2
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical group [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
238000004090 dissolution Methods 0.000 description 2
239000011737 fluorine Chemical group 0.000 description 2
230000006870 function Effects 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
230000003993 interaction Effects 0.000 description 2
PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
239000007800 oxidant agent Substances 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
230000002441 reversible effect Effects 0.000 description 2
239000007787 solid Substances 0.000 description 2
150000005311 thiohalides Chemical class 0.000 description 2
FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 2
229910052718 tin Inorganic materials 0.000 description 2
229910052719 titanium Inorganic materials 0.000 description 2
239000010936 titanium Substances 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
239000002841 Lewis acid Substances 0.000 description 1
229910001290 LiPF6 Inorganic materials 0.000 description 1
229910015255 MoF6 Inorganic materials 0.000 description 1
101100396546 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) tif-6 gene Proteins 0.000 description 1
229910000990 Ni alloy Inorganic materials 0.000 description 1
229910006068 SO3F Inorganic materials 0.000 description 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
229910004516 TaF6 Inorganic materials 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
229910052787 antimony Inorganic materials 0.000 description 1
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
229910052785 arsenic Inorganic materials 0.000 description 1
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
229910052790 beryllium Inorganic materials 0.000 description 1
ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229910052793 cadmium Inorganic materials 0.000 description 1
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
229940000425 combination drug Drugs 0.000 description 1
239000000470 constituent Substances 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
230000002950 deficient Effects 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000008014 freezing Effects 0.000 description 1
238000007710 freezing Methods 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
229910052735 hafnium Inorganic materials 0.000 description 1
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
229910052738 indium Inorganic materials 0.000 description 1
APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
150000002484 inorganic compounds Chemical class 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
150000007517 lewis acids Chemical class 0.000 description 1
229910001547 lithium hexafluoroantimonate(V) Inorganic materials 0.000 description 1
229910001496 lithium tetrafluoroborate Inorganic materials 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000000034 method Methods 0.000 description 1
RLCOZMCCEKDUPY-UHFFFAOYSA-H molybdenum hexafluoride Chemical compound F[Mo](F)(F)(F)(F)F RLCOZMCCEKDUPY-UHFFFAOYSA-H 0.000 description 1
239000000178 monomer Substances 0.000 description 1
229910052758 niobium Inorganic materials 0.000 description 1
239000010955 niobium Substances 0.000 description 1
GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
238000002161 passivation Methods 0.000 description 1
230000010287 polarization Effects 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
230000036647 reaction Effects 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
229910052706 scandium Inorganic materials 0.000 description 1
SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
230000007928 solubilization Effects 0.000 description 1
238000005063 solubilization Methods 0.000 description 1
238000007614 solvation Methods 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
229960005349 sulfur Drugs 0.000 description 1
235000001508 sulfur Nutrition 0.000 description 1
230000002459 sustained effect Effects 0.000 description 1
229910052715 tantalum Inorganic materials 0.000 description 1
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
229910052716 thallium Inorganic materials 0.000 description 1
BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
230000001988 toxicity Effects 0.000 description 1
231100000419 toxicity Toxicity 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
229910052727 yttrium Inorganic materials 0.000 description 1
VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte

Landscapes

Engineering & Computer Science (AREA)
Manufacturing & Machinery (AREA)
Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
General Chemical & Material Sciences (AREA)
Secondary Cells (AREA)
Primary Cells (AREA)
Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

CA000341180A 1978-12-20 1979-12-04 Pile a cathode de trioxyde de soufre soluble Expired CA1139362A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US97157378A	1978-12-20	1978-12-20
US971,573		1978-12-20

Publications (1)

Publication Number	Publication Date
CA1139362A true CA1139362A (fr)	1983-01-11

Family

ID=25518560

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000341180A Expired CA1139362A (fr)	1978-12-20	1979-12-04	Pile a cathode de trioxyde de soufre soluble

Country Status (5)

Country	Link
CA (1)	CA1139362A (fr)
DE (1)	DE2951169A1 (fr)
DK (1)	DK541379A (fr)
FR (1)	FR2445033A1 (fr)
GB (1)	GB2038078B (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4513067A (en) *	1983-06-30	1985-04-23	Duracell Inc.	Inorganic non-aqueous cell
FR2574223B1 (fr) *	1984-12-03	1987-05-07	Accumulateurs Fixes	Generateur electrochimique dont la matiere active negative est a base d'un metal alcalin ou alcalinoterreux
EP0186200A3 (fr) *	1984-12-27	1988-03-23	Eveready Battery Company, Inc.	Pile non aqueuse à solution cathode-électrolyte contenant un additif au bore
DK155560C (da) *	1985-06-17	1989-09-18	Hellesens As	Elektrisk batteri

1979
- 1979-12-04 CA CA000341180A patent/CA1139362A/fr not_active Expired
- 1979-12-18 DK DK541379A patent/DK541379A/da not_active Application Discontinuation
- 1979-12-19 GB GB7943791A patent/GB2038078B/en not_active Expired
- 1979-12-19 DE DE19792951169 patent/DE2951169A1/de not_active Withdrawn
- 1979-12-20 FR FR7931235A patent/FR2445033A1/fr active Granted

Also Published As

Publication number	Publication date
DK541379A (da)	1980-06-21
GB2038078B (en)	1983-02-09
DE2951169A1 (de)	1980-07-10
FR2445033A1 (fr)	1980-07-18
FR2445033B3 (fr)	1981-12-11
GB2038078A (en)	1980-07-16

Legal Events

Date	Code	Title	Description
2000-01-11	MKEX	Expiry

Publication	Publication Date	Title
US4463072A (en)	1984-07-31	Secondary batteries containing room-temperature molten 1,2,3-trialkylimidazolium halide non-aqueous electrolyte
US4020240A (en)	1977-04-26	Electrochemical cell with clovoborate salt in electrolyte and method of operation and composition of matter
US3907597A (en)	1975-09-23	Nonaqueous cell having an electrolyte containing sulfolane or an alkyl-substituted derivative thereof
US4857423A (en)	1989-08-15	Overcharge protection of secondary, non-aqueous batteries
US6033343A (en)	2000-03-07	Iron-based storage battery
US4331743A (en)	1982-05-25	Method for increasing recycling life of non-aqueous cells
JP2949180B2 (ja)	1999-09-13	リチウム二次電池用負極
JPH0527953B2 (fr)	1993-04-22
US4869977A (en)	1989-09-26	Electrolyte additive for lithium-sulfur dioxide electrochemical cell
US3681144A (en)	1972-08-01	Lithium-metal selenide organic electrolyte cell
IE44370B1 (en)	1981-11-04	Nonqwueous cell
JPH01206571A (ja)	1989-08-18	非水二次電池の過充電保護
KR920009805B1 (ko)	1992-10-22	라튬 이차전지
US3508966A (en)	1970-04-28	Electrochemical cell with non-aqueous electrolyte
AU593980B2 (en)	1990-02-22	Electrolyte for lithium-sulfur dioxide electrochemical cell
CA1151725A (fr)	1983-08-09	Collecteurs cathodiques pour pile non aqueuse avec agent de catalyse fait d'oxyde metallique
CA1139362A (fr)	1983-01-11	Pile a cathode de trioxyde de soufre soluble
US3681143A (en)	1972-08-01	Lithium-metal vanadate organic electrolyte cell
US3953235A (en)	1976-04-27	Nonaqueous cell having an electrolyte containing crotonitrile
US3951685A (en)	1976-04-20	Nonaqueous cell utilizing a 3Me2Ox-based electrolyte
US12494509B2 (en)	2025-12-09	Non-aqueous ammonia electrolytes for lithium anode based primary and reserve batteries
CA1139364A (fr)	1983-01-11	Pile a cathode de trioxyde de soufre soluble
US3985577A (en)	1976-10-12	Lithium/fluorographite primary cell with improved electrolyte
Maxfield et al.	1989	Alloy/conducting-polymer composite electrodes: electrolytes, cathodes, and morphology
US3711334A (en)	1973-01-16	Lithium-metal molybdate organic electrolyte cell