CA1143002A - Electrolyte organique pour piles au lithium rechargeables - Google Patents
Electrolyte organique pour piles au lithium rechargeablesInfo
- Publication number
- CA1143002A CA1143002A CA000354948A CA354948A CA1143002A CA 1143002 A CA1143002 A CA 1143002A CA 000354948 A CA000354948 A CA 000354948A CA 354948 A CA354948 A CA 354948A CA 1143002 A CA1143002 A CA 1143002A
- Authority
- CA
- Canada
- Prior art keywords
- lithium
- electrolyte
- sulfolane
- rechargeable cell
- cell
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 40
- 239000005486 organic electrolyte Substances 0.000 title abstract description 4
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 claims abstract description 18
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000006184 cosolvent Substances 0.000 claims abstract description 13
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 claims abstract description 12
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 claims abstract description 11
- 229910001486 lithium perchlorate Inorganic materials 0.000 claims abstract description 11
- 239000007788 liquid Substances 0.000 claims abstract description 8
- -1 lithium tetrafluoroborate Chemical compound 0.000 claims abstract description 7
- 239000003792 electrolyte Substances 0.000 claims description 22
- 239000002904 solvent Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 7
- 239000011877 solvent mixture Substances 0.000 claims description 7
- CFJRPNFOLVDFMJ-UHFFFAOYSA-N titanium disulfide Chemical group S=[Ti]=S CFJRPNFOLVDFMJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000011255 nonaqueous electrolyte Substances 0.000 claims description 4
- GRVDJDISBSALJP-UHFFFAOYSA-N methyloxidanyl Chemical compound [O]C GRVDJDISBSALJP-UHFFFAOYSA-N 0.000 claims 1
- 239000008151 electrolyte solution Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000007747 plating Methods 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 229910013462 LiC104 Inorganic materials 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 230000001464 adherent effect Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- APVPOHHVBBYQAV-UHFFFAOYSA-N n-(4-aminophenyl)sulfonyloctadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NS(=O)(=O)C1=CC=C(N)C=C1 APVPOHHVBBYQAV-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 101100536354 Drosophila melanogaster tant gene Proteins 0.000 description 1
- 241000760358 Enodes Species 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 229910003092 TiS2 Inorganic materials 0.000 description 1
- ZYDVNTYVDVZMKF-UHFFFAOYSA-N [Cl].[Ag] Chemical compound [Cl].[Ag] ZYDVNTYVDVZMKF-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006182 cathode active material Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- QLOAVXSYZAJECW-UHFFFAOYSA-N methane;molecular fluorine Chemical compound C.FF QLOAVXSYZAJECW-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- MBDNRNMVTZADMQ-UHFFFAOYSA-N sulfolene Chemical compound O=S1(=O)CC=CC1 MBDNRNMVTZADMQ-UHFFFAOYSA-N 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US5272679A | 1979-06-28 | 1979-06-28 | |
| US052,726 | 1979-06-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1143002A true CA1143002A (fr) | 1983-03-15 |
Family
ID=21979518
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000354948A Expired CA1143002A (fr) | 1979-06-28 | 1980-06-26 | Electrolyte organique pour piles au lithium rechargeables |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS567362A (fr) |
| CA (1) | CA1143002A (fr) |
| CH (1) | CH644473A5 (fr) |
| DE (1) | DE3024151C2 (fr) |
| FR (1) | FR2460550A1 (fr) |
| GB (1) | GB2054948B (fr) |
| IT (1) | IT1131555B (fr) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5887778A (ja) * | 1981-11-20 | 1983-05-25 | Nippon Telegr & Teleph Corp <Ntt> | リチウム二次電池用非水電解液 |
| JPS5951465A (ja) * | 1982-08-16 | 1984-03-24 | アライド・コ−ポレ−シヨン | 改良した電解質を有する共役ポリマ−電池 |
| US4482613A (en) * | 1983-02-16 | 1984-11-13 | Duracell Inc. | Cell with safe venting electrolyte |
| JPH0636370B2 (ja) * | 1984-01-24 | 1994-05-11 | 日本電信電話株式会社 | リチウム二次電池用電解液 |
| US5219684A (en) * | 1990-05-16 | 1993-06-15 | Her Majesty The Queen In Right Of Canada, As Represented By The Province Of British Columbia | Electrochemical cells containing a safety electrolyte solvent |
| US6166899A (en) * | 1997-12-18 | 2000-12-26 | Nippon Chemi-Con Corporation | Electrolyte for electrolytic capacitor and electrolytic capacitor having the same |
| JP2002075446A (ja) * | 2000-08-02 | 2002-03-15 | Samsung Sdi Co Ltd | リチウム−硫黄電池 |
| PL1815546T3 (pl) * | 2004-12-02 | 2013-03-29 | Oxis Energy Ltd | Elektrolit do akumulatorów litowo-siarkowych i akumulatory litowo-siarkowe jego używające |
| US20080076029A1 (en) * | 2006-07-27 | 2008-03-27 | Bowden William L | Battery |
| US7648798B2 (en) | 2006-07-27 | 2010-01-19 | The Gillette Company | Battery with electrolyte containing aluminum salt |
| US20080026296A1 (en) * | 2006-07-27 | 2008-01-31 | Bowden William L | Battery |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3907597A (en) * | 1974-09-27 | 1975-09-23 | Union Carbide Corp | Nonaqueous cell having an electrolyte containing sulfolane or an alkyl-substituted derivative thereof |
| US3953235A (en) * | 1974-12-23 | 1976-04-27 | Union Carbide Corporation | Nonaqueous cell having an electrolyte containing crotonitrile |
| US4009052A (en) * | 1975-02-24 | 1977-02-22 | Exxon Research And Engineering Company | Chalcogenide battery |
-
1980
- 1980-06-26 CA CA000354948A patent/CA1143002A/fr not_active Expired
- 1980-06-27 DE DE3024151A patent/DE3024151C2/de not_active Expired
- 1980-06-27 CH CH498580A patent/CH644473A5/fr not_active IP Right Cessation
- 1980-06-27 FR FR8014386A patent/FR2460550A1/fr active Granted
- 1980-06-27 GB GB8021055A patent/GB2054948B/en not_active Expired
- 1980-06-27 JP JP8768280A patent/JPS567362A/ja active Pending
- 1980-06-30 IT IT23148/80A patent/IT1131555B/it active
Also Published As
| Publication number | Publication date |
|---|---|
| DE3024151A1 (de) | 1981-01-08 |
| DE3024151C2 (de) | 1983-12-01 |
| IT8023148A0 (it) | 1980-06-30 |
| CH644473A5 (fr) | 1984-07-31 |
| FR2460550A1 (fr) | 1981-01-23 |
| GB2054948B (en) | 1983-05-11 |
| JPS567362A (en) | 1981-01-26 |
| IT1131555B (it) | 1986-06-25 |
| FR2460550B1 (fr) | 1984-10-12 |
| GB2054948A (en) | 1981-02-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |