CA1145285A - Hydrotraitement d'hydrocarbures avec un catalyseur a base d'halloysite - Google Patents

Hydrotraitement d'hydrocarbures avec un catalyseur a base d'halloysite

Info

Publication number: CA1145285A
Authority: CA; Canada
Prior art keywords: rods; catalyst; halloysite; catalytic bodies; weight percent
Prior art date: 1979-09-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000359497A

Other languages

English (en)

Inventor

Robert A. Van Nordstrand

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Chevron USA Inc

Original Assignee

Chevron Research and Technology Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-09-26

Filing date

1980-09-03

Publication date

1983-04-26

1980-09-03 Application filed by Chevron Research and Technology Co filed Critical Chevron Research and Technology Co

1983-04-26 Application granted granted Critical

1983-04-26 Publication of CA1145285A publication Critical patent/CA1145285A/fr

Status Expired legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 82
HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 title claims abstract description 55
229910052621 halloysite Inorganic materials 0.000 title claims abstract description 55
229930195733 hydrocarbon Natural products 0.000 title claims abstract description 16
150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 16
238000000034 method Methods 0.000 claims abstract description 27
239000001257 hydrogen Substances 0.000 claims abstract description 26
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 26
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 25
229910052751 metal Inorganic materials 0.000 claims description 35
239000002184 metal Substances 0.000 claims description 35
229910052809 inorganic oxide Inorganic materials 0.000 claims description 28
239000011148 porous material Substances 0.000 claims description 26
230000003197 catalytic effect Effects 0.000 claims description 21
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 14
239000000203 mixture Substances 0.000 claims description 14
239000004215 Carbon black (E152) Substances 0.000 claims description 11
229910052759 nickel Inorganic materials 0.000 claims description 7
229910052720 vanadium Inorganic materials 0.000 claims description 7
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 6
229910052750 molybdenum Inorganic materials 0.000 claims description 6
239000011733 molybdenum Substances 0.000 claims description 6
229910017052 cobalt Inorganic materials 0.000 claims description 5
239000010941 cobalt Substances 0.000 claims description 5
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 4
229910052721 tungsten Inorganic materials 0.000 claims description 4
239000010937 tungsten Substances 0.000 claims description 4
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
229910052804 chromium Inorganic materials 0.000 claims description 3
239000011651 chromium Substances 0.000 claims description 3
229910052742 iron Inorganic materials 0.000 claims description 3
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 2
239000003921 oil Substances 0.000 description 27
150000002739 metals Chemical class 0.000 description 21
239000000499 gel Substances 0.000 description 18
239000002245 particle Substances 0.000 description 14
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 12
239000002002 slurry Substances 0.000 description 12
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
239000000017 hydrogel Substances 0.000 description 9
239000000295 fuel oil Substances 0.000 description 8
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
238000006243 chemical reaction Methods 0.000 description 7
238000007493 shaping process Methods 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
239000003208 petroleum Substances 0.000 description 6
238000004517 catalytic hydrocracking Methods 0.000 description 5
239000004927 clay Substances 0.000 description 5
230000000694 effects Effects 0.000 description 5
229910052757 nitrogen Inorganic materials 0.000 description 5
239000002243 precursor Substances 0.000 description 5
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 5
239000006185 dispersion Substances 0.000 description 4
229910052500 inorganic mineral Inorganic materials 0.000 description 4
239000000463 material Substances 0.000 description 4
239000011707 mineral Substances 0.000 description 4
235000010755 mineral Nutrition 0.000 description 4
239000004113 Sepiolite Substances 0.000 description 3
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
230000002411 adverse Effects 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
238000004523 catalytic cracking Methods 0.000 description 3
238000001035 drying Methods 0.000 description 3
238000001125 extrusion Methods 0.000 description 3
238000000227 grinding Methods 0.000 description 3
239000007788 liquid Substances 0.000 description 3
239000000391 magnesium silicate Substances 0.000 description 3
239000011159 matrix material Substances 0.000 description 3
229910052624 sepiolite Inorganic materials 0.000 description 3
235000019355 sepiolite Nutrition 0.000 description 3
239000000377 silicon dioxide Substances 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000002904 solvent Substances 0.000 description 3
229910052717 sulfur Inorganic materials 0.000 description 3
239000011593 sulfur Substances 0.000 description 3
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
238000013019 agitation Methods 0.000 description 2
239000010426 asphalt Substances 0.000 description 2
238000009835 boiling Methods 0.000 description 2
238000001354 calcination Methods 0.000 description 2
239000002734 clay mineral Substances 0.000 description 2
239000000084 colloidal system Substances 0.000 description 2
238000006477 desulfuration reaction Methods 0.000 description 2
230000023556 desulfurization Effects 0.000 description 2
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
239000012065 filter cake Substances 0.000 description 2
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
238000004898 kneading Methods 0.000 description 2
235000012243 magnesium silicates Nutrition 0.000 description 2
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
238000003801 milling Methods 0.000 description 2
238000002156 mixing Methods 0.000 description 2
239000010742 number 1 fuel oil Substances 0.000 description 2
229910052625 palygorskite Inorganic materials 0.000 description 2
239000000843 powder Substances 0.000 description 2
239000000047 product Substances 0.000 description 2
239000003079 shale oil Substances 0.000 description 2
239000000243 solution Substances 0.000 description 2
229910052723 transition metal Inorganic materials 0.000 description 2
150000003624 transition metals Chemical class 0.000 description 2
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
239000005995 Aluminium silicate Substances 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
241000282326 Felis catus Species 0.000 description 1
241000208204 Linum Species 0.000 description 1
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
229910021536 Zeolite Inorganic materials 0.000 description 1
239000008186 active pharmaceutical agent Substances 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
239000011609 ammonium molybdate Substances 0.000 description 1
229940010552 ammonium molybdate Drugs 0.000 description 1
235000018660 ammonium molybdate Nutrition 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
239000007900 aqueous suspension Substances 0.000 description 1
229960000892 attapulgite Drugs 0.000 description 1
239000000440 bentonite Substances 0.000 description 1
229910000278 bentonite Inorganic materials 0.000 description 1
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000007767 bonding agent Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
229910001981 cobalt nitrate Inorganic materials 0.000 description 1
238000004939 coking Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000005336 cracking Methods 0.000 description 1
239000010779 crude oil Substances 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000002950 deficient Effects 0.000 description 1
238000007324 demetalation reaction Methods 0.000 description 1
238000003795 desorption Methods 0.000 description 1
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
235000019253 formic acid Nutrition 0.000 description 1
239000007789 gas Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
230000005764 inhibitory process Effects 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052622 kaolinite Inorganic materials 0.000 description 1
HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
235000019792 magnesium silicate Nutrition 0.000 description 1
229910052919 magnesium silicate Inorganic materials 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
238000006263 metalation reaction Methods 0.000 description 1
229910052901 montmorillonite Inorganic materials 0.000 description 1
239000005445 natural material Substances 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000001294 propane Substances 0.000 description 1
239000004576 sand Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
241000894007 species Species 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
239000004575 stone Substances 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
238000011144 upstream manufacturing Methods 0.000 description 1
238000005292 vacuum distillation Methods 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000010457 zeolite Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Chemistry (AREA)
Materials Engineering (AREA)
Oil, Petroleum & Natural Gas (AREA)
General Chemical & Material Sciences (AREA)
Dispersion Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)

CA000359497A 1979-09-26 1980-09-03 Hydrotraitement d'hydrocarbures avec un catalyseur a base d'halloysite Expired CA1145285A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US7885179A	1979-09-26	1979-09-26
US78,851		1979-09-26

Publications (1)

Publication Number	Publication Date
CA1145285A true CA1145285A (fr)	1983-04-26

Family

ID=22146587

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000359497A Expired CA1145285A (fr)	1979-09-26	1980-09-03	Hydrotraitement d'hydrocarbures avec un catalyseur a base d'halloysite

Country Status (5)

Country	Link
JP (1)	JPS5670091A (fr)
CA (1)	CA1145285A (fr)
DE (1)	DE3033963A1 (fr)
FR (1)	FR2465775B1 (fr)
GB (1)	GB2059283B (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4375406A (en) *	1981-01-21	1983-03-01	Chevron Research Company	Fibrous clay compositions containing precalcined oxides
JPS57123290A (en) *	1981-01-25	1982-07-31	Chiyoda Chem Eng & Constr Co Ltd	Method for converting heavy hydrocarbon oil into light fractions
JPH0631324B2 (ja) *	1982-07-19	1994-04-27	シエブロン・リサ−チ・コンパニ−	炭化水素供給物の品質向上法
CA1258439A (fr) *	1984-04-16	1989-08-15	Karl-Heinz W. Robschlager	Conversion catalytique des petroles lourds
US4568657A (en) *	1984-10-03	1986-02-04	Intevep, S.A.	Catalyst formed of natural clay for use in the hydrodemetallization and hydroconversion of heavy crudes and residues and method of preparation of same
EP4112164A4 (fr) *	2020-02-28	2023-08-16	JFE Mineral Company, Ltd.	Composite

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB884633A (en) *	1959-04-30	1961-12-13	Nalco Chemical Co	Silica magnesia catalysts and their use in a process for cracking hydrocarbons
US4150099A (en) *	1974-11-19	1979-04-17	Exxon Research & Engineering Co.	Synthetic halloysites

1980
- 1980-09-03 CA CA000359497A patent/CA1145285A/fr not_active Expired
- 1980-09-10 DE DE19803033963 patent/DE3033963A1/de not_active Withdrawn
- 1980-09-19 FR FR8020209A patent/FR2465775B1/fr not_active Expired
- 1980-09-23 GB GB8030646A patent/GB2059283B/en not_active Expired
- 1980-09-24 JP JP13278080A patent/JPS5670091A/ja active Pending

Also Published As

Publication number	Publication date
FR2465775A1 (fr)	1981-03-27
GB2059283B (en)	1983-09-07
JPS5670091A (en)	1981-06-11
GB2059283A (en)	1981-04-23
FR2465775B1 (fr)	1986-01-10
DE3033963A1 (de)	1981-04-09

Legal Events

Date	Code	Title	Description
2000-04-26	MKEX	Expiry

Publication	Publication Date	Title
US4446244A (en)	1984-05-01	Hydrocarbons hydroprocessing with imogolite catalyst
CA2846754C (fr)	2016-06-21	Support de catalyseur et catalyseurs prepares a partir de celui-ci
EP0283815B1 (fr)	1991-06-26	Alumine modifiée par de la silice
US4435278A (en)	1984-03-06	Hydroprocessing with a catalyst having bimodal pore distribution
KR101432315B1 (ko)	2014-08-20	계내 제조된 ｙ-파우아자사이트를 포함하는 수소화분해 촉매 및 수소화분해 방법
US4568657A (en)	1986-02-04	Catalyst formed of natural clay for use in the hydrodemetallization and hydroconversion of heavy crudes and residues and method of preparation of same
JP2547115B2 (ja)	1996-10-23	炭化水素油用水素化処理触媒組成物ならびにそれを用いる水素化処理方法
PL202786B1 (pl)	2009-07-31	Katalizator do obróbki wodorem, stosowany do konwersji ciężkich olejów węglowodorowych i jego zastosowanie
EP1567617A1 (fr)	2005-08-31	Hydrotraitement d'hydrocarbones au moyen d'un melange de catalyseurs
US5139648A (en)	1992-08-18	Hydrocarbon conversion process using pillared clay and a silica-substituted alumina
JP4369871B2 (ja)	2009-11-25	触媒の混合物を使用する重質原料のｈｐｃ法
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