CA1146921A - Procede de conversion d'hydrocarbures - Google Patents

Procede de conversion d'hydrocarbures

Info

Publication number: CA1146921A
Authority: CA; Canada
Prior art keywords: catalyst; zeolite; alkali metal; zsm; contacting
Prior art date: 1979-12-14
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000359783A

Other languages

English (en)

Inventor

David S. Shihabi

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mobil Oil AS

Original Assignee

Mobil Oil AS

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-12-14

Filing date

1980-09-03

Publication date

1983-05-24

1980-09-03 Application filed by Mobil Oil AS filed Critical Mobil Oil AS

1983-05-24 Application granted granted Critical

1983-05-24 Publication of CA1146921A publication Critical patent/CA1146921A/fr

Status Expired legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 42
230000008569 process Effects 0.000 title claims abstract description 32
229930195733 hydrocarbon Natural products 0.000 title claims abstract description 29
150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 29
239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 17
238000006243 chemical reaction Methods 0.000 title description 43
239000003054 catalyst Substances 0.000 claims abstract description 105
239000010457 zeolite Substances 0.000 claims abstract description 101
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 66
229910021536 Zeolite Inorganic materials 0.000 claims abstract description 64
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 47
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims abstract description 35
230000000694 effects Effects 0.000 claims abstract description 31
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 28
238000005336 cracking Methods 0.000 claims abstract description 24
239000000377 silicon dioxide Substances 0.000 claims abstract description 23
238000009835 boiling Methods 0.000 claims abstract description 11
238000010025 steaming Methods 0.000 claims abstract description 11
239000012263 liquid product Substances 0.000 claims abstract description 5
229910052783 alkali metal Inorganic materials 0.000 claims description 27
239000001257 hydrogen Substances 0.000 claims description 27
229910052739 hydrogen Inorganic materials 0.000 claims description 27
239000011734 sodium Substances 0.000 claims description 27
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 26
229910052708 sodium Inorganic materials 0.000 claims description 25
150000001340 alkali metals Chemical class 0.000 claims description 24
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 22
239000000203 mixture Substances 0.000 claims description 22
239000003921 oil Substances 0.000 claims description 22
229910052751 metal Inorganic materials 0.000 claims description 17
239000002184 metal Substances 0.000 claims description 17
239000010779 crude oil Substances 0.000 claims description 14
238000005342 ion exchange Methods 0.000 claims description 10
-1 alkali metal cation Chemical class 0.000 claims description 9
238000005984 hydrogenation reaction Methods 0.000 claims description 8
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 6
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 5
229910052744 lithium Inorganic materials 0.000 claims description 5
239000011159 matrix material Substances 0.000 claims description 5
238000002360 preparation method Methods 0.000 claims description 4
239000002243 precursor Substances 0.000 claims 4
PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims 1
238000002441 X-ray diffraction Methods 0.000 claims 1
239000002253 acid Substances 0.000 abstract description 16
239000000047 product Substances 0.000 description 22
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
239000013078 crystal Substances 0.000 description 16
239000000243 solution Substances 0.000 description 16
239000007789 gas Substances 0.000 description 15
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 12
238000004517 catalytic hydrocracking Methods 0.000 description 12
239000007788 liquid Substances 0.000 description 12
229910052717 sulfur Inorganic materials 0.000 description 12
239000011593 sulfur Substances 0.000 description 12
235000019647 acidic taste Nutrition 0.000 description 11
239000002585 base Substances 0.000 description 11
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 9
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
125000004435 hydrogen atom Chemical group [H]* 0.000 description 8
238000012360 testing method Methods 0.000 description 8
230000003197 catalytic effect Effects 0.000 description 7
125000002091 cationic group Chemical group 0.000 description 7
238000001354 calcination Methods 0.000 description 6
150000001768 cations Chemical class 0.000 description 6
150000002431 hydrogen Chemical class 0.000 description 6
150000002500 ions Chemical class 0.000 description 6
238000004519 manufacturing process Methods 0.000 description 6
229910052757 nitrogen Inorganic materials 0.000 description 6
150000002892 organic cations Chemical class 0.000 description 6
239000003208 petroleum Substances 0.000 description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 5
239000003513 alkali Substances 0.000 description 5
239000011230 binding agent Substances 0.000 description 5
239000000463 material Substances 0.000 description 5
150000002739 metals Chemical class 0.000 description 5
239000011148 porous material Substances 0.000 description 5
239000009671 shengli Substances 0.000 description 5
239000001993 wax Substances 0.000 description 5
PFEOZHBOMNWTJB-UHFFFAOYSA-N 3-methylpentane Chemical compound CCC(C)CC PFEOZHBOMNWTJB-UHFFFAOYSA-N 0.000 description 4
230000002378 acidificating effect Effects 0.000 description 4
229910052784 alkaline earth metal Inorganic materials 0.000 description 4
230000008901 benefit Effects 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Chemical compound [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 4
229910052799 carbon Inorganic materials 0.000 description 4
238000004523 catalytic cracking Methods 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
238000007324 demetalation reaction Methods 0.000 description 4
239000000446 fuel Substances 0.000 description 4
239000007791 liquid phase Substances 0.000 description 4
238000012545 processing Methods 0.000 description 4
239000011780 sodium chloride Substances 0.000 description 4
230000032683 aging Effects 0.000 description 3
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 3
150000003863 ammonium salts Chemical class 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
125000000129 anionic group Chemical group 0.000 description 3
229910052792 caesium Inorganic materials 0.000 description 3
239000007795 chemical reaction product Substances 0.000 description 3
239000000295 fuel oil Substances 0.000 description 3
239000003502 gasoline Substances 0.000 description 3
230000005484 gravity Effects 0.000 description 3
239000001307 helium Substances 0.000 description 3
229910052734 helium Inorganic materials 0.000 description 3
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 3
238000007689 inspection Methods 0.000 description 3
238000009434 installation Methods 0.000 description 3
238000011282 treatment Methods 0.000 description 3
PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
230000004913 activation Effects 0.000 description 2
239000008186 active pharmaceutical agent Substances 0.000 description 2
238000013019 agitation Methods 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 2
AIYUHDOJVYHVIT-UHFFFAOYSA-M caesium chloride Chemical compound [Cl-].[Cs+] AIYUHDOJVYHVIT-UHFFFAOYSA-M 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
238000006555 catalytic reaction Methods 0.000 description 2
230000008859 change Effects 0.000 description 2
229910001603 clinoptilolite Inorganic materials 0.000 description 2
229910052681 coesite Inorganic materials 0.000 description 2
239000000571 coke Substances 0.000 description 2
239000002131 composite material Substances 0.000 description 2
239000000356 contaminant Substances 0.000 description 2
239000012084 conversion product Substances 0.000 description 2
238000001816 cooling Methods 0.000 description 2
229910052906 cristobalite Inorganic materials 0.000 description 2
230000009849 deactivation Effects 0.000 description 2
238000010586 diagram Methods 0.000 description 2
229910052675 erionite Inorganic materials 0.000 description 2
239000012013 faujasite Substances 0.000 description 2
229910001657 ferrierite group Inorganic materials 0.000 description 2
229910052677 heulandite Inorganic materials 0.000 description 2
230000002209 hydrophobic effect Effects 0.000 description 2
230000006698 induction Effects 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
238000006317 isomerization reaction Methods 0.000 description 2
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
238000002156 mixing Methods 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
229910052680 mordenite Inorganic materials 0.000 description 2
125000004430 oxygen atom Chemical group O* 0.000 description 2
229910052763 palladium Inorganic materials 0.000 description 2
239000002245 particle Substances 0.000 description 2
230000000737 periodic effect Effects 0.000 description 2
239000012071 phase Substances 0.000 description 2
230000036619 pore blockages Effects 0.000 description 2
239000003079 shale oil Substances 0.000 description 2
229910052710 silicon Inorganic materials 0.000 description 2
239000010703 silicon Substances 0.000 description 2
235000012239 silicon dioxide Nutrition 0.000 description 2
VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
238000003756 stirring Methods 0.000 description 2
229910052682 stishovite Inorganic materials 0.000 description 2
229910052905 tridymite Inorganic materials 0.000 description 2
239000012808 vapor phase Substances 0.000 description 2
OCKGFTQIICXDQW-ZEQRLZLVSA-N 5-[(1r)-1-hydroxy-2-[4-[(2r)-2-hydroxy-2-(4-methyl-1-oxo-3h-2-benzofuran-5-yl)ethyl]piperazin-1-yl]ethyl]-4-methyl-3h-2-benzofuran-1-one Chemical compound C1=C2C(=O)OCC2=C(C)C([C@@H](O)CN2CCN(CC2)C[C@H](O)C2=CC=C3C(=O)OCC3=C2C)=C1 OCKGFTQIICXDQW-ZEQRLZLVSA-N 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
235000018734 Sambucus australis Nutrition 0.000 description 1
244000180577 Sambucus australis Species 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
229910001413 alkali metal ion Inorganic materials 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
239000011959 amorphous silica alumina Substances 0.000 description 1
238000013459 approach Methods 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
229910001423 beryllium ion Inorganic materials 0.000 description 1
230000005540 biological transmission Effects 0.000 description 1
238000010504 bond cleavage reaction Methods 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 description 1
238000004364 calculation method Methods 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
229910052676 chabazite Inorganic materials 0.000 description 1
WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000013329 compounding Methods 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000007906 compression Methods 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
230000001186 cumulative effect Effects 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
239000002283 diesel fuel Substances 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
239000010771 distillate fuel oil Substances 0.000 description 1
238000004821 distillation Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
238000000921 elemental analysis Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
229910001683 gmelinite Inorganic materials 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
230000002427 irreversible effect Effects 0.000 description 1
229910001711 laumontite Inorganic materials 0.000 description 1
239000010687 lubricating oil Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000011707 mineral Substances 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
239000010743 number 2 fuel oil Substances 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
239000008188 pellet Substances 0.000 description 1
239000001294 propane Substances 0.000 description 1
VMXUWOKSQNHOCA-UKTHLTGXSA-N ranitidine Chemical compound [O-][N+](=O)\C=C(/NC)NCCSCC1=CC=C(CN(C)C)O1 VMXUWOKSQNHOCA-UKTHLTGXSA-N 0.000 description 1
229910052761 rare earth metal Inorganic materials 0.000 description 1
150000002910 rare earth metals Chemical class 0.000 description 1
238000011084 recovery Methods 0.000 description 1
230000009467 reduction Effects 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
238000011160 research Methods 0.000 description 1
239000004576 sand Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
230000007017 scission Effects 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
235000010344 sodium nitrate Nutrition 0.000 description 1
239000011949 solid catalyst Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
241000894007 species Species 0.000 description 1
229910052678 stilbite Inorganic materials 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
230000002459 sustained effect Effects 0.000 description 1
238000010998 test method Methods 0.000 description 1
238000004227 thermal cracking Methods 0.000 description 1
230000009466 transformation Effects 0.000 description 1
238000000844 transformation Methods 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
239000011800 void material Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/36—Steaming
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles

Landscapes

Chemical & Material Sciences (AREA)
Crystallography & Structural Chemistry (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Materials Engineering (AREA)
General Chemical & Material Sciences (AREA)
Inorganic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)

CA000359783A 1979-12-14 1980-09-03 Procede de conversion d'hydrocarbures Expired CA1146921A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US06/103,793 US4284529A (en)	1979-12-14	1979-12-14	Hydrocarbon conversion catalyst
US103,793		1979-12-14

Publications (1)

Publication Number	Publication Date
CA1146921A true CA1146921A (fr)	1983-05-24

Family

ID=22297061

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000359783A Expired CA1146921A (fr)	1979-12-14	1980-09-03	Procede de conversion d'hydrocarbures

Country Status (9)

Country	Link
US (1)	US4284529A (fr)
EP (1)	EP0030784B1 (fr)
JP (1)	JPS5686989A (fr)
AU (1)	AU532593B2 (fr)
BR (1)	BR8005618A (fr)
CA (1)	CA1146921A (fr)
DE (1)	DE3066991D1 (fr)
PH (1)	PH16477A (fr)
ZA (1)	ZA805230B (fr)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4396538A (en) *	1979-09-04	1983-08-02	Mobil Oil Corporation	Hydrotreating/hydrocracking catalyst
US4428862A (en) *	1980-07-28	1984-01-31	Union Oil Company Of California	Catalyst for simultaneous hydrotreating and hydrodewaxing of hydrocarbons
US4441991A (en) *	1981-04-21	1984-04-10	Mobil Oil Corporation	Catalytic dewaxing of oils containing ammonia over highly siliceous porous crystalline materials of the zeolite ZSM-5 type
US4600497A (en) *	1981-05-08	1986-07-15	Union Oil Company Of California	Process for treating waxy shale oils
US4790927A (en) *	1981-05-26	1988-12-13	Union Oil Company Of California	Process for simultaneous hydrotreating and hydrodewaxing of hydrocarbons
US4877762A (en) *	1981-05-26	1989-10-31	Union Oil Company Of California	Catalyst for simultaneous hydrotreating and hydrodewaxing of hydrocarbons
US4481104A (en) *	1981-10-26	1984-11-06	Mobil Oil Corporation	Use of low acidity high silica to alumina ratio large pore zeolites for distillate production in catalytic cracking
US4402866A (en) *	1981-12-16	1983-09-06	Mobil Oil Corporation	Aging resistance shape selective catalyst with enhanced activity
US4784747A (en) *	1982-03-22	1988-11-15	Mobil Oil Corporation	Catalysts over steam activated zeolite catalyst
US4559314A (en) *	1982-03-22	1985-12-17	Mobil Oil Corporation	Zeolite activation
US4430200A (en)	1982-08-09	1984-02-07	Mobil Oil Corporation	Hydrocarbon conversion process
US4428826A (en)	1982-08-19	1984-01-31	Mobil Oil Corporation	Dewaxing and upgrading of raw shale oils
US4665248A (en) *	1983-02-14	1987-05-12	Mobil Oil Corporation	Zeolite modification and its use in conversion of alcohols and ethers to hydrocarbons
US4788377A (en) *	1983-04-22	1988-11-29	Mobil Oil Corporation	Process for manufacturing olefins
US4642404A (en) *	1984-01-23	1987-02-10	Mobil Oil Corporation	Conversion of olefins and paraffins to higher hydrocarbons
US4626609A (en) *	1984-01-23	1986-12-02	Mobil Oil Corporation	Aromatic compound conversion
US4621161A (en) *	1984-01-23	1986-11-04	Mobil Oil Corporation	Oxygenate conversion over activated zeolite catalyst
US4842714A (en) *	1984-11-27	1989-06-27	Uop	Catalytic cracking process using silicoaluminophosphate molecular sieves
US4870192A (en) *	1985-08-12	1989-09-26	Mobil Oil Corporation	Production of lactones and omega-hydroxycarboxylic acids
US4808296A (en) *	1985-10-18	1989-02-28	Mobil Oil Corporation	Process for dewaxing hydrocarbon feedstock
US4668377A (en) *	1985-10-21	1987-05-26	Mobil Oil Corporation	Catalytic process for dewaxing
US4894142A (en) *	1987-03-24	1990-01-16	Uop	Hydrocracking process employing low acidity Y zeolite
US4814543A (en) *	1987-12-28	1989-03-21	Mobil Oil Corporation	Nitrogen resistant paraffin hydroisomerization catalysts
US4877581A (en) *	1988-09-01	1989-10-31	Mobil Oil Corporation	Catalyst for dewaxing hydrocarbon feedstock
US5147526A (en) *	1991-10-01	1992-09-15	Amoco Corporation	Distillate hydrogenation
TW252053B (fr) *	1991-11-01	1995-07-21	Shell Internat Res Schappej Bv
US5955642A (en) *	1996-10-30	1999-09-21	Fina Technology, Inc.	Gas phase alkylation-liquid transalkylation process
EP0920911A1 (fr) *	1997-12-05	1999-06-09	Fina Research S.A.	Production de catalyseurs pour la conversion d'oléfines
EP0921177A1 (fr) *	1997-12-05	1999-06-09	Fina Research S.A.	Production d'oléfines
US6093671A (en) *	1998-07-30	2000-07-25	Phillips Petroleum Company	Carbided hydrocarbon conversion catalyst composition and processes therefor and therewith
US6057485A (en) *	1998-11-17	2000-05-02	Fina Technology, Inc.	Gas phase alkylation with split load of catalyst
EP1061117A1 (fr) *	1999-06-16	2000-12-20	Fina Research S.A.	Production d'oléfines
US6294077B1 (en) *	2000-02-02	2001-09-25	Mobil Oil Corporation	Production of high viscosity lubricating oil stock with improved ZSM-5 catalyst
US8366909B2 (en) *	2009-02-26	2013-02-05	Chevron U.S.A. Inc.	Reforming process at low pressure
CN103194259A (zh) *	2013-04-10	2013-07-10	王�锋	柴油非临氢降凝工艺方法
KR102671191B1 (ko) *	2022-03-04	2024-05-30	주식회사 삼안	공사용 터널 내 담수를 이용한 지하 유류 비축기지용 원유 출하펌프 냉각시스템

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1127335A (fr) *	1954-07-10	1956-12-13	Kalle & Co Ag	Aspe transportant des produits à enrouler autour de lui dans la direction de son axe lors de l'enroulement
BE608029A (fr) *	1957-02-05	1900-01-01
FR1312246A (fr) *	1961-12-21	1962-12-14	Socony Mobil Oil Co	Préparation de compositions catalytiques à base d'aluminosilicate
BE642448A (fr) *	1963-03-12	1964-07-13
USRE28341E (en) *	1964-05-01	1975-02-18		Marshall dann
US3257310A (en) *	1964-07-02	1966-06-21	Socony Mobil Oil Co Inc	Steam activated catalyst
US3702886A (en) *	1969-10-10	1972-11-14	Mobil Oil Corp	Crystalline zeolite zsm-5 and method of preparing the same
USRE28398E (en) *	1969-10-10	1975-04-22		Marshall dann
US3709979A (en) *	1970-04-23	1973-01-09	Mobil Oil Corp	Crystalline zeolite zsm-11
US3832449A (en) *	1971-03-18	1974-08-27	Mobil Oil Corp	Crystalline zeolite zsm{14 12
US3897327A (en) *	1971-10-20	1975-07-29	Union Oil Co	Hydrocracking process with stabilized y-zeolite catalysts
US3968024A (en) *	1973-07-06	1976-07-06	Mobil Oil Corporation	Catalytic hydrodewaxing
US3894104A (en) *	1973-08-09	1975-07-08	Mobil Oil Corp	Aromatization of hetero-atom substituted hydrocarbons
US4016245A (en) *	1973-09-04	1977-04-05	Mobil Oil Corporation	Crystalline zeolite and method of preparing same
US3899544A (en) *	1974-03-28	1975-08-12	Mobil Oil Corp	Conversion of alcohols and ethers to hydrocarbons
US4046859A (en) *	1974-11-29	1977-09-06	Mobil Oil Corporation	Crystalline zeolite and method of preparing same
FR2323664A1 (fr) *	1975-09-10	1977-04-08	Erap	Procede de deshydrocyclisation d'hydrocarbures aliphatiques
US4128592A (en) *	1977-11-23	1978-12-05	Mobil Oil Corporation	Selective production of para dialkyl benzene
GB2027742B (en) *	1978-08-09	1982-11-03	Mobil Oil Corp	Catalysts for hydrodewaxing oils

1979
- 1979-12-14 US US06/103,793 patent/US4284529A/en not_active Expired - Lifetime
1980
- 1980-08-25 ZA ZA00805230A patent/ZA805230B/xx unknown
- 1980-08-27 AU AU61796/80A patent/AU532593B2/en not_active Ceased
- 1980-09-03 BR BR8005618A patent/BR8005618A/pt unknown
- 1980-09-03 DE DE8080303069T patent/DE3066991D1/de not_active Expired
- 1980-09-03 CA CA000359783A patent/CA1146921A/fr not_active Expired
- 1980-09-03 EP EP80303069A patent/EP0030784B1/fr not_active Expired
- 1980-09-04 JP JP12180880A patent/JPS5686989A/ja active Granted
- 1980-09-04 PH PH24538A patent/PH16477A/en unknown

Also Published As

Publication number	Publication date
DE3066991D1 (en)	1984-04-19
BR8005618A (pt)	1981-06-16
JPS6337834B2 (fr)	1988-07-27
AU532593B2 (en)	1983-10-06
EP0030784B1 (fr)	1984-03-14
JPS5686989A (en)	1981-07-15
US4284529A (en)	1981-08-18
AU6179680A (en)	1981-06-18
ZA805230B (en)	1982-04-28
EP0030784A1 (fr)	1981-06-24
PH16477A (en)	1983-10-25

Legal Events

Date	Code	Title	Description
2000-05-24	MKEX	Expiry

Publication	Publication Date	Title
CA1146921A (fr)	1983-05-24	Procede de conversion d'hydrocarbures
CA1156589A (fr)	1983-11-08	Hydrofractionnement catalytique
EP0024948B1 (fr)	1984-03-28	Procédé pour convertir un hydrocarbure à point d'ébullition élevé et catalyseur pour ce procédé
CA1189470A (fr)	1985-06-25	Methode pour ameliorer l'activite catalytique
DE68905478T2 (de)	1993-06-24	Verfahren zur herstellung eines zeolith-beta-kohlenwasserstoffumwandlungskatalysators.
US4402866A (en)	1983-09-06	Aging resistance shape selective catalyst with enhanced activity
US4416765A (en)	1983-11-22	Catalytic cracking
US4724066A (en)	1988-02-09	Composites of microporous aluminum phosphates and zeolites and conversions over these catalysts
US5554274A (en)	1996-09-10	Manufacture of improved catalyst
US5689024A (en)	1997-11-18	Use of crystalline SUZ-9
CA1285236C (fr)	1991-06-25	Procede de production d'un hydrocarbure ayant une teneur reduite en paraffines normales
CA1156586A (fr)	1983-11-08	Huiles lourdes a bas point d'ecoulement
US4315814A (en)	1982-02-16	Hydrocarbon conversion process
US4521297A (en)	1985-06-04	Catalytic conversion of shale oil
US4954243A (en)	1990-09-04	Catalytic cracking with framework aluminum extracted zeolite
US4711710A (en)	1987-12-08	Process for making improved lubricating oils from heavy feedstock
US4683052A (en)	1987-07-28	Method for non-oxidative hydrogen reactivation of zeolite dewaxing catalysts
US4448673A (en)	1984-05-15	Aging resistance shape selective catalyst with enhanced activity
US4521298A (en)	1985-06-04	Promotion of cracking catalyst octane yield performance
US4263126A (en)	1981-04-21	Preparation and use of reactive dispersions
GB1601655A (en)	1981-11-04	Catalytic dewaxing with a hydrogen form zeolite l catalyst
US4396538A (en)	1983-08-02	Hydrotreating/hydrocracking catalyst
US4428826A (en)	1984-01-31	Dewaxing and upgrading of raw shale oils
US5300215A (en)	1994-04-05	Catalytic cracking with a catalyst comprising a boron phosphate matrix
AU694354B2 (en)	1998-07-16	Catalytic conversion with mcm-58