CA1148008A - Elements photosensibles a couche d'halogenure d'argent renfermant des particules inertes et une matiere colorante captrice d'images - Google Patents

Elements photosensibles a couche d'halogenure d'argent renfermant des particules inertes et une matiere colorante captrice d'images

Info

Publication number: CA1148008A
Authority: CA; Canada
Prior art keywords: silver halide; layer; photosensitive; gelatin; film unit
Prior art date: 1979-06-27
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000330673A

Other languages

English (en)

Inventor

Peter O. Kliem

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Polaroid Corp

Original Assignee

Polaroid Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-06-27

Filing date

1979-06-27

Publication date

1983-06-14

1979-06-27 Application filed by Polaroid Corp filed Critical Polaroid Corp

1979-06-27 Priority to CA000330673A priority Critical patent/CA1148008A/fr

1983-06-14 Application granted granted Critical

1983-06-14 Publication of CA1148008A publication Critical patent/CA1148008A/fr

Status Expired legal-status Critical Current

Links

239000004332 silver Substances 0.000 title claims abstract description 233
229910052709 silver Inorganic materials 0.000 title claims abstract description 233
-1 silver halide Chemical class 0.000 title claims abstract description 207
239000002245 particle Substances 0.000 title claims abstract description 111
239000000463 material Substances 0.000 title claims abstract description 32
108010010803 Gelatin Proteins 0.000 claims abstract description 108
229920000159 gelatin Polymers 0.000 claims abstract description 108
239000008273 gelatin Substances 0.000 claims abstract description 108
235000019322 gelatine Nutrition 0.000 claims abstract description 108
235000011852 gelatine desserts Nutrition 0.000 claims abstract description 108
229920000126 latex Polymers 0.000 claims abstract description 32
238000012546 transfer Methods 0.000 claims abstract description 31
239000004816 latex Substances 0.000 claims abstract description 29
238000012545 processing Methods 0.000 claims abstract description 25
238000009792 diffusion process Methods 0.000 claims abstract description 18
239000003513 alkali Substances 0.000 claims abstract description 16
239000000203 mixture Substances 0.000 claims abstract description 16
230000008961 swelling Effects 0.000 claims abstract description 14
230000005855 radiation Effects 0.000 claims abstract description 8
239000000975 dye Substances 0.000 claims description 68
239000000839 emulsion Substances 0.000 claims description 54
229920000642 polymer Polymers 0.000 claims description 36
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 14
238000000149 argon plasma sintering Methods 0.000 claims description 13
230000006870 function Effects 0.000 claims description 10
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 9
229920001577 copolymer Polymers 0.000 claims description 8
229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 8
239000004926 polymethyl methacrylate Substances 0.000 claims description 8
AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 claims description 7
239000001043 yellow dye Substances 0.000 claims description 7
239000004793 Polystyrene Substances 0.000 claims description 5
238000000926 separation method Methods 0.000 claims description 5
229920002223 polystyrene Polymers 0.000 claims description 4
238000009740 moulding (composite fabrication) Methods 0.000 claims 13
239000002131 composite material Substances 0.000 claims 1
239000010410 layer Substances 0.000 description 135
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 14
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
229940102838 methylmethacrylate Drugs 0.000 description 8
229920001519 homopolymer Polymers 0.000 description 7
DWYHDSLIWMUSOO-UHFFFAOYSA-N 2-phenyl-1h-benzimidazole Chemical compound C1=CC=CC=C1C1=NC2=CC=CC=C2N1 DWYHDSLIWMUSOO-UHFFFAOYSA-N 0.000 description 6
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
230000008901 benefit Effects 0.000 description 6
239000000178 monomer Substances 0.000 description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
238000011161 development Methods 0.000 description 5
239000006185 dispersion Substances 0.000 description 5
239000011229 interlayer Substances 0.000 description 5
238000000034 method Methods 0.000 description 5
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
239000002585 base Substances 0.000 description 4
229920002401 polyacrylamide Polymers 0.000 description 4
230000008569 process Effects 0.000 description 4
239000000047 product Substances 0.000 description 4
230000002829 reductive effect Effects 0.000 description 4
ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 4
239000000243 solution Substances 0.000 description 4
229920006029 tetra-polymer Polymers 0.000 description 4
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
PCSMJKASWLYICJ-UHFFFAOYSA-N Succinic aldehyde Chemical compound O=CCCC=O PCSMJKASWLYICJ-UHFFFAOYSA-N 0.000 description 3
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 3
229920002678 cellulose Polymers 0.000 description 3
239000011248 coating agent Substances 0.000 description 3
238000000576 coating method Methods 0.000 description 3
230000007423 decrease Effects 0.000 description 3
239000003999 initiator Substances 0.000 description 3
230000000670 limiting effect Effects 0.000 description 3
OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 3
239000005020 polyethylene terephthalate Substances 0.000 description 3
230000009467 reduction Effects 0.000 description 3
239000007787 solid Substances 0.000 description 3
230000003595 spectral effect Effects 0.000 description 3
239000004408 titanium dioxide Substances 0.000 description 3
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 2
229910019142 PO4 Inorganic materials 0.000 description 2
239000004372 Polyvinyl alcohol Substances 0.000 description 2
229920002472 Starch Polymers 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
125000005396 acrylic acid ester group Chemical group 0.000 description 2
230000002411 adverse Effects 0.000 description 2
229960005070 ascorbic acid Drugs 0.000 description 2
235000010323 ascorbic acid Nutrition 0.000 description 2
239000011668 ascorbic acid Substances 0.000 description 2
AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
229910000019 calcium carbonate Inorganic materials 0.000 description 2
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
239000006229 carbon black Substances 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
239000003995 emulsifying agent Substances 0.000 description 2
238000007720 emulsion polymerization reaction Methods 0.000 description 2
150000004820 halides Chemical group 0.000 description 2
239000000693 micelle Substances 0.000 description 2
230000007935 neutral effect Effects 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
235000021317 phosphate Nutrition 0.000 description 2
229920000139 polyethylene terephthalate Polymers 0.000 description 2
229920002451 polyvinyl alcohol Polymers 0.000 description 2
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
230000000717 retained effect Effects 0.000 description 2
230000035945 sensitivity Effects 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
239000008107 starch Substances 0.000 description 2
235000019698 starch Nutrition 0.000 description 2
239000004094 surface-active agent Substances 0.000 description 2
229920003002 synthetic resin Polymers 0.000 description 2
239000000057 synthetic resin Substances 0.000 description 2
229920002554 vinyl polymer Polymers 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
KFDVPJUYSDEJTH-UHFFFAOYSA-N 4-ethenylpyridine Chemical compound C=CC1=CC=NC=C1 KFDVPJUYSDEJTH-UHFFFAOYSA-N 0.000 description 1
SHVCSCWHWMSGTE-UHFFFAOYSA-N 6-methyluracil Chemical compound CC1=CC(=O)NC(=O)N1 SHVCSCWHWMSGTE-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
229920008347 Cellulose acetate propionate Polymers 0.000 description 1
239000001856 Ethyl cellulose Substances 0.000 description 1
ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
NWBJYWHLCVSVIJ-UHFFFAOYSA-N N-benzyladenine Chemical compound N=1C=NC=2NC=NC=2C=1NCC1=CC=CC=C1 NWBJYWHLCVSVIJ-UHFFFAOYSA-N 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
239000004721 Polyphenylene oxide Substances 0.000 description 1
CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000011149 active material Substances 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
125000005250 alkyl acrylate group Chemical group 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
239000012964 benzotriazole Substances 0.000 description 1
PVEOYINWKBTPIZ-UHFFFAOYSA-N but-3-enoic acid Chemical group OC(=O)CC=C PVEOYINWKBTPIZ-UHFFFAOYSA-N 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
238000005345 coagulation Methods 0.000 description 1
230000015271 coagulation Effects 0.000 description 1
229910052681 coesite Inorganic materials 0.000 description 1
239000008119 colloidal silica Substances 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
229910052906 cristobalite Inorganic materials 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
238000010410 dusting Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
229920001249 ethyl cellulose Polymers 0.000 description 1
235000019325 ethyl cellulose Nutrition 0.000 description 1
230000009477 glass transition Effects 0.000 description 1
239000008131 herbal destillate Substances 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
229910052809 inorganic oxide Inorganic materials 0.000 description 1
230000003993 interaction Effects 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
125000000896 monocarboxylic acid group Chemical group 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
238000012856 packing Methods 0.000 description 1
230000036961 partial effect Effects 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920000515 polycarbonate Polymers 0.000 description 1
239000004417 polycarbonate Substances 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920000570 polyether Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
239000013047 polymeric layer Substances 0.000 description 1
239000002952 polymeric resin Substances 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
239000011118 polyvinyl acetate Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
MSFPLIAKTHOCQP-UHFFFAOYSA-M silver iodide Chemical group I[Ag] MSFPLIAKTHOCQP-UHFFFAOYSA-M 0.000 description 1
239000002356 single layer Substances 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920003169 water-soluble polymer Polymers 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1

Landscapes

Silver Salt Photography Or Processing Solution Therefor (AREA)

CA000330673A 1979-06-27 1979-06-27 Elements photosensibles a couche d'halogenure d'argent renfermant des particules inertes et une matiere colorante captrice d'images Expired CA1148008A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000330673A CA1148008A (fr)	1979-06-27	1979-06-27	Elements photosensibles a couche d'halogenure d'argent renfermant des particules inertes et une matiere colorante captrice d'images

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000330673A CA1148008A (fr)	1979-06-27	1979-06-27	Elements photosensibles a couche d'halogenure d'argent renfermant des particules inertes et une matiere colorante captrice d'images

Publications (1)

Publication Number	Publication Date
CA1148008A true CA1148008A (fr)	1983-06-14

Family

ID=4114561

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000330673A Expired CA1148008A (fr)	1979-06-27	1979-06-27	Elements photosensibles a couche d'halogenure d'argent renfermant des particules inertes et une matiere colorante captrice d'images

Country Status (1)

Country	Link
CA (1)	CA1148008A (fr)

1979
- 1979-06-27 CA CA000330673A patent/CA1148008A/fr not_active Expired

Legal Events

Date	Code	Title	Description
2000-06-14	MKEX	Expiry

Publication	Publication Date	Title
CA1225796A (fr)	1987-08-18	Mordants polymeres
EP0115054B1 (fr)	1988-02-10	Polymères capables de subir l'élimination bêta comme couches de contrôle de diffusion dans des produits photographiques
EP0531839A1 (fr)	1993-03-17	Milieu de formation d'images avec couche à indice de réfraction bas
CA1154446A (fr)	1983-09-27	Mordants copolymeriques et produits et procedes photographiques utilisant ces composes
JPH0261022B2 (fr)	1990-12-18
US4131469A (en)	1978-12-26	Photographic element with polymeric ammonium mordant
US3833369A (en)	1974-09-03	Color diffusion transfer films and processes with polymer encapsulated reflecting agents
EP0011645B1 (fr)	1983-05-25	Elements photosensibles pour la mise en oeuvre dans une unite de film de transfert par diffusion
US4190447A (en)	1980-02-26	Cover sheets for integral imaging receiver elements
GB2054886A (en)	1981-02-18	Colour-diffusion-transfer photographic elements containing a polymeric mordant layer
CA1148008A (fr)	1983-06-14	Elements photosensibles a couche d'halogenure d'argent renfermant des particules inertes et une matiere colorante captrice d'images
EP0683430B1 (fr)	1999-03-31	Compositions de traitement photographiques incluant un agent éprassissant hydrophobiquement modifié
US4347301A (en)	1982-08-31	Novel diffusion transfer film units
EP0672268B1 (fr)	1997-02-05	ELEMENT RECEPTEUR D'IMAGES POUR PRODUITS DE FILMS PHOTOGRAPHIQUES à DIFFUSION-TRANSFERT
US4374919A (en)	1983-02-22	Diffusion transfer color photographic element with U.V. absorbing agent adjacent protective layer
JPS5930260B2 (ja)	1984-07-26	写真要素
US4546062A (en)	1985-10-08	Polymeric pH-sensitive optical filter agents and articles including same
EP0115053B1 (fr)	1987-09-02	Couches de contrôle de diffusion dans des produits photographiques pour diffusion-transfert
EP0066341B1 (fr)	1986-09-10	Elément photosensible et procédé photographique
EP0127787B1 (fr)	1989-03-15	Produits photographiques comprenant des couches de contrôle de la diffusion hydrolysables
CA1115109A (fr)	1981-12-29	Feuille de surface contenant une couche hydrophile permeable aux alcalis entre une couche a effet temporisateur et un element recepteur d'images
US4542087A (en)	1985-09-17	Use of reflecting agent in yellow dye image-providing material layer
EP0849624B1 (fr)	2001-03-21	Matériau photographique à l'halogénure d'argent contenant un polymère rendu non-diffusible par réticulation ayant un groupe photographiquement utile
JPS6149658B2 (fr)	1986-10-30
JP2604234B2 (ja)	1997-04-30	拡散転写写真要素