CA1148497A - Electrolyse d'halo-acide obtenu a partir d'halogene et d'eau avec presence de carbone - Google Patents

Electrolyse d'halo-acide obtenu a partir d'halogene et d'eau avec presence de carbone

Info

Publication number: CA1148497A
Authority: CA; Canada
Prior art keywords: halogen; acid; hydrogen; cell; electrode
Prior art date: 1978-07-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000330835A

Other languages

English (en)

Inventor

Thomas G. Hart

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Energy Development Associates Inc

Original Assignee

Energy Development Associates Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-07-19

Filing date

1979-06-29

Publication date

1983-06-21

1978-07-19 Priority claimed from US05/925,980 external-priority patent/US4182662A/en

1979-06-29 Application filed by Energy Development Associates Inc filed Critical Energy Development Associates Inc

1983-06-21 Application granted granted Critical

1983-06-21 Publication of CA1148497A publication Critical patent/CA1148497A/fr

Status Expired legal-status Critical Current

Links

229910052736 halogen Inorganic materials 0.000 title claims abstract description 212
150000002367 halogens Chemical class 0.000 title claims abstract description 206
239000002253 acid Substances 0.000 title claims abstract description 154
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 127
229910052799 carbon Inorganic materials 0.000 title claims abstract description 126
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 102
238000005868 electrolysis reaction Methods 0.000 title claims abstract description 67
238000000034 method Methods 0.000 claims abstract description 113
239000001257 hydrogen Substances 0.000 claims abstract description 96
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 96
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 92
238000006243 chemical reaction Methods 0.000 claims abstract description 73
239000002245 particle Substances 0.000 claims abstract description 48
239000003054 catalyst Substances 0.000 claims abstract description 15
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 73
239000000243 solution Substances 0.000 claims description 56
239000003792 electrolyte Substances 0.000 claims description 53
238000000354 decomposition reaction Methods 0.000 claims description 26
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 17
229910017604 nitric acid Inorganic materials 0.000 claims description 16
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 15
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 15
239000010936 titanium Substances 0.000 claims description 15
229910052719 titanium Inorganic materials 0.000 claims description 15
-1 halogen halide Chemical class 0.000 claims description 9
238000009835 boiling Methods 0.000 claims description 6
229910000039 hydrogen halide Inorganic materials 0.000 claims description 6
239000012433 hydrogen halide Substances 0.000 claims description 6
239000011244 liquid electrolyte Substances 0.000 claims description 5
230000003647 oxidation Effects 0.000 claims description 3
238000007254 oxidation reaction Methods 0.000 claims description 3
239000000725 suspension Substances 0.000 claims description 3
238000005406 washing Methods 0.000 claims 2
239000007864 aqueous solution Substances 0.000 claims 1
230000008569 process Effects 0.000 description 50
238000005984 hydrogenation reaction Methods 0.000 description 42
229960000443 hydrochloric acid Drugs 0.000 description 29
235000011167 hydrochloric acid Nutrition 0.000 description 29
239000000460 chlorine Substances 0.000 description 28
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 27
229910052801 chlorine Inorganic materials 0.000 description 27
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 26
229910052740 iodine Inorganic materials 0.000 description 26
239000011630 iodine Substances 0.000 description 26
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 22
239000000571 coke Substances 0.000 description 20
239000001569 carbon dioxide Substances 0.000 description 11
229910002092 carbon dioxide Inorganic materials 0.000 description 11
229910000041 hydrogen chloride Inorganic materials 0.000 description 11
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 11
238000010438 heat treatment Methods 0.000 description 10
239000007789 gas Substances 0.000 description 8
238000004519 manufacturing process Methods 0.000 description 8
239000000463 material Substances 0.000 description 8
230000004048 modification Effects 0.000 description 7
238000012986 modification Methods 0.000 description 7
239000003795 chemical substances by application Substances 0.000 description 6
229940021013 electrolyte solution Drugs 0.000 description 6
239000008151 electrolyte solution Substances 0.000 description 6
239000000446 fuel Substances 0.000 description 6
239000012528 membrane Substances 0.000 description 6
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 5
229920000557 Nafion® Polymers 0.000 description 5
230000008901 benefit Effects 0.000 description 5
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 5
229910052794 bromium Inorganic materials 0.000 description 5
229910000043 hydrogen iodide Inorganic materials 0.000 description 5
239000007788 liquid Substances 0.000 description 5
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
230000009102 absorption Effects 0.000 description 4
238000010521 absorption reaction Methods 0.000 description 4
150000007513 acids Chemical class 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
229910002804 graphite Inorganic materials 0.000 description 4
239000010439 graphite Substances 0.000 description 4
150000002431 hydrogen Chemical class 0.000 description 4
230000006872 improvement Effects 0.000 description 4
150000002500 ions Chemical class 0.000 description 4
239000001301 oxygen Substances 0.000 description 4
229910052760 oxygen Inorganic materials 0.000 description 4
230000009467 reduction Effects 0.000 description 4
BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 description 3
229920006384 Airco Polymers 0.000 description 3
239000006227 byproduct Substances 0.000 description 3
238000010924 continuous production Methods 0.000 description 3
230000007062 hydrolysis Effects 0.000 description 3
238000006460 hydrolysis reaction Methods 0.000 description 3
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 3
239000000203 mixture Substances 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
238000001311 chemical methods and process Methods 0.000 description 2
239000003245 coal Substances 0.000 description 2
239000000470 constituent Substances 0.000 description 2
239000011780 sodium chloride Substances 0.000 description 2
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 2
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
241000543381 Cliftonia monophylla Species 0.000 description 1
230000009471 action Effects 0.000 description 1
230000002730 additional effect Effects 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
239000011260 aqueous acid Substances 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
150000001721 carbon Chemical class 0.000 description 1
230000008859 change Effects 0.000 description 1
XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 description 1
229940005991 chloric acid Drugs 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000005611 electricity Effects 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 description 1
230000008570 general process Effects 0.000 description 1
QFWPJPIVLCBXFJ-UHFFFAOYSA-N glymidine Chemical compound N1=CC(OCCOC)=CN=C1NS(=O)(=O)C1=CC=CC=C1 QFWPJPIVLCBXFJ-UHFFFAOYSA-N 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
229910000042 hydrogen bromide Inorganic materials 0.000 description 1
QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
239000012535 impurity Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
239000003607 modifier Substances 0.000 description 1
229940099990 ogen Drugs 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
230000003334 potential effect Effects 0.000 description 1
239000000843 powder Substances 0.000 description 1
230000036647 reaction Effects 0.000 description 1
YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000010802 sludge Substances 0.000 description 1
239000002002 slurry Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000002918 waste heat Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
Metallurgy (AREA)
Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Electrodes For Compound Or Non-Metal Manufacture (AREA)
Water Treatment By Electricity Or Magnetism (AREA)
Catalysts (AREA)

CA000330835A 1978-07-19 1979-06-29 Electrolyse d'halo-acide obtenu a partir d'halogene et d'eau avec presence de carbone Expired CA1148497A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US05/925,980 US4182662A (en)	1979-07-12	1978-07-19	Method of forming hydrogen
US925,980		1978-07-19

Publications (1)

Publication Number	Publication Date
CA1148497A true CA1148497A (fr)	1983-06-21

Family

ID=25452532

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000330835A Expired CA1148497A (fr)	1978-07-19	1979-06-29	Electrolyse d'halo-acide obtenu a partir d'halogene et d'eau avec presence de carbone

Country Status (9)

Country	Link
JP (2)	JPS5946315B2 (fr)
BE (1)	BE877794A (fr)
CA (1)	CA1148497A (fr)
DE (1)	DE2928983A1 (fr)
FR (3)	FR2431550A1 (fr)
GB (2)	GB2026033B (fr)
IT (1)	IT1117164B (fr)
NL (1)	NL7905559A (fr)
SE (2)	SE7906042L (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5915508U (ja) *	1982-07-22	1984-01-30	芝浦メカトロニクス株式会社	ダイヤモンド切断機
JPS63219593A (ja) *	1987-03-09	1988-09-13	Hitachi Ltd	水素製造方法
JP3132379B2 (ja) *	1995-03-01	2001-02-05	トヨタ自動車株式会社	酸素及び水素を製造する方法
JP3915139B2 (ja) *	1996-05-30	2007-05-16	トヨタ自動車株式会社	燃料電池発電装置
JP3279231B2 (ja) *	1997-10-13	2002-04-30	トヨタ自動車株式会社	ヨウ素ガスの分離方法
KR20030065857A (ko) *	2002-02-01	2003-08-09	주식회사 동우워터텍	염소-수산화나트륨 생산을 위한 전기분해조에서이온삼투막 설치구조
RU2241670C1 (ru) *	2003-07-21	2004-12-10	Открытое Акционерное Общество "Российский научно-исследовательский и проектный институт титана и магния" (ОАО "РИТМ")	Способ переработки серпентинита
JP5893637B2 (ja) *	2011-10-14	2016-03-23	浦安電設株式会社	水素−酸素ガス発生装置
DE102020005285A1 (de)	2020-08-28	2022-03-03	Textilforschungsinstitut Thüringen-Vogtland e.V. (TITV e.V.)	Verfahren zur Wasserelektrolyse und Wasserelektrolysezelle

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE313875C (fr) *
US1870308A (en) *	1931-06-15	1932-08-09	Behrman Abraham Sidney	Manufacture of hydrobromic acid
US2238896A (en) *	1939-03-10	1941-04-22	Mortimer M Gibbons	Process for halide preparation
US3848065A (en) *	1972-09-29	1974-11-12	Monsanto Co	Method for producing hydrogen iodide
LU71037A1 (fr) *	1974-10-03	1976-08-19
US4036776A (en) *	1976-02-10	1977-07-19	The Lummus Company	Recovery of chlorine values from a melt oxidation gas
JPS52105596A (en) *	1976-03-01	1977-09-05	Ajinomoto Co Inc	Production of hydrochloric acid
JPS5317088A (en) *	1976-07-30	1978-02-16	Fumio Kobayashi	System for indicating brake of vehicle or motor cycle or the like
CA1089632A (fr) *	1976-08-20	1980-11-18	Alfred J. Darnell	Production d'hydrogene

1979
- 1979-06-29 CA CA000330835A patent/CA1148497A/fr not_active Expired
- 1979-07-03 GB GB7923161A patent/GB2026033B/en not_active Expired
- 1979-07-11 SE SE7906042A patent/SE7906042L/xx not_active Application Discontinuation
- 1979-07-17 IT IT49785/79A patent/IT1117164B/it active
- 1979-07-17 NL NL7905559A patent/NL7905559A/nl not_active Application Discontinuation
- 1979-07-18 FR FR7918619A patent/FR2431550A1/fr active Granted
- 1979-07-18 DE DE19792928983 patent/DE2928983A1/de not_active Ceased
- 1979-07-19 BE BE0/196376A patent/BE877794A/fr not_active IP Right Cessation
- 1979-07-19 JP JP54092120A patent/JPS5946315B2/ja not_active Expired
1980
- 1980-04-21 FR FR8008867A patent/FR2446329A1/fr active Granted
- 1980-04-21 FR FR8008868A patent/FR2446251A1/fr active Granted
1982
- 1982-07-02 GB GB08219145A patent/GB2107295B/en not_active Expired
1984
- 1984-07-06 JP JP59140439A patent/JPS6024185B2/ja not_active Expired
- 1984-08-09 SE SE8404043A patent/SE8404043D0/xx not_active Application Discontinuation

Also Published As

Publication number	Publication date
GB2026033B (en)	1983-05-05
FR2446251A1 (fr)	1980-08-08
GB2026033A (en)	1980-01-30
FR2446251B1 (fr)	1984-04-27
NL7905559A (nl)	1980-01-22
IT7949785A0 (it)	1979-07-17
JPS6046383A (ja)	1985-03-13
GB2107295B (en)	1983-09-28
SE8404043L (sv)	1984-08-09
FR2446329B1 (fr)	1984-04-13
DE2928983A1 (de)	1980-01-31
SE7906042L (sv)	1980-01-20
SE8404043D0 (sv)	1984-08-09
JPS6024185B2 (ja)	1985-06-11
IT1117164B (it)	1986-02-17
FR2446329A1 (fr)	1980-08-08
JPS5521587A (en)	1980-02-15
GB2107295A (en)	1983-04-27
BE877794A (fr)	1979-11-16
JPS5946315B2 (ja)	1984-11-12
FR2431550A1 (fr)	1980-02-15
FR2431550B1 (fr)	1984-07-20

Legal Events

Date	Code	Title	Description
2000-06-21	MKEX	Expiry

Publication	Publication Date	Title
US4311569A (en)	1982-01-19	Device for evolution of oxygen with ternary electrocatalysts containing valve metals
US4182662A (en)	1980-01-08	Method of forming hydrogen
US4235863A (en)	1980-11-25	Method of and cell for generating hydrogen
US4528083A (en)	1985-07-09	Device for evolution of oxygen with ternary electrocatalysts containing valve metals
US5219671A (en)	1993-06-15	Hydrogen generation and utility load leveling system and the method therefor
US4707229A (en)	1987-11-17	Method for evolution of oxygen with ternary electrocatalysts containing valve metals
US4457824A (en)	1984-07-03	Method and device for evolution of oxygen with ternary electrocatalysts containing valve metals
US4699700A (en)	1987-10-13	Method for hydrogen production and metal winning, and a catalyst/cocatalyst composition useful therefor
US4455203A (en)	1984-06-19	Process for the electrolytic production of hydrogen peroxide
CA1148497A (fr)	1983-06-21	Electrolyse d'halo-acide obtenu a partir d'halogene et d'eau avec presence de carbone
EP0246957B1 (fr)	1992-09-30	Procédé pour le traitement de déchets organiques et catalyseur/co-catalyseur utile à cet effet
GB2316091A (en)	1998-02-18	Electrolytic treatment of aqueous salt solutions
EP0560740B1 (fr)	1997-07-30	Appareil et procédé pour la génération électrolytique d'ozone
US4288301A (en)	1981-09-08	Method of forming hydrogen
US4032415A (en)	1977-06-28	Method for promoting reduction oxidation of electrolytically produced gas
US4337237A (en)	1982-06-29	Catalytically increasing the obtainable concentration of halogen in water
US5186794A (en)	1993-02-16	Alkali metal hydroxide generation system and the method therefor
US1847435A (en)	1932-03-01	Electrolytic manufacture of chlorine
US3849278A (en)	1974-11-19	Electrolytic system
US3996118A (en)	1976-12-07	Method for promoting reduction-oxidation of electrolytically produced gases
FI76837B (fi)	1988-08-31	Elektrolyscell med horisontalt anordnade elektroder.
US3481847A (en)	1969-12-02	Electrolytic process of making chlorine
US344347A (en)	1886-06-29	Willaed e
JPH0666142B2 (ja)	1994-08-24	燃料電池等のｂｆｅ型電極
JPS5832002A (ja)	1983-02-24	ハロゲン化水素酸の製造方法