CA1152925A - Hydrofractionnement des petroles visqueux en presence de particules de pyrite - Google Patents

Hydrofractionnement des petroles visqueux en presence de particules de pyrite

Info

Publication number: CA1152925A
Authority: CA; Canada
Prior art keywords: pyrite; process according; hydrocracking; heavy; hydrocarbon oil
Prior art date: 1981-04-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000375826A

Other languages

English (en)

Inventor

Jean M. Denis

Chandra P. Khulbe

Keith Belinko

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Canada Minister of Energy Mines and Resources

Original Assignee

Canada Minister of Energy Mines and Resources

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-04-21

Filing date

1981-04-21

Publication date

1983-08-30

1981-04-21 Application filed by Canada Minister of Energy Mines and Resources filed Critical Canada Minister of Energy Mines and Resources

1981-04-21 Priority to CA000375826A priority Critical patent/CA1152925A/fr

1983-08-30 Application granted granted Critical

1983-08-30 Publication of CA1152925A publication Critical patent/CA1152925A/fr

Status Expired legal-status Critical Current

Links

229910052683 pyrite Inorganic materials 0.000 title claims abstract description 34
238000004517 catalytic hydrocracking Methods 0.000 title claims abstract description 33
239000011028 pyrite Substances 0.000 title claims abstract description 33
NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 title claims abstract description 33
239000002245 particle Substances 0.000 title claims abstract description 8
239000000295 fuel oil Substances 0.000 title abstract description 10
229930195733 hydrocarbon Natural products 0.000 claims abstract description 34
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 34
238000000034 method Methods 0.000 claims abstract description 28
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 26
239000001257 hydrogen Substances 0.000 claims abstract description 25
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 25
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 23
239000007788 liquid Substances 0.000 claims abstract description 9
239000002002 slurry Substances 0.000 claims abstract description 5
239000000654 additive Substances 0.000 claims description 21
230000000996 additive effect Effects 0.000 claims description 20
239000003245 coal Substances 0.000 claims description 16
229910052751 metal Inorganic materials 0.000 claims description 8
239000002184 metal Substances 0.000 claims description 8
239000007792 gaseous phase Substances 0.000 claims description 2
239000007791 liquid phase Substances 0.000 claims description 2
239000003921 oil Substances 0.000 abstract description 26
239000000571 coke Substances 0.000 abstract description 22
238000006243 chemical reaction Methods 0.000 abstract description 18
239000000463 material Substances 0.000 abstract description 17
238000009835 boiling Methods 0.000 abstract description 8
230000015572 biosynthetic process Effects 0.000 abstract description 5
239000002243 precursor Substances 0.000 abstract description 2
239000007789 gas Substances 0.000 description 13
239000000047 product Substances 0.000 description 13
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 8
229910052500 inorganic mineral Inorganic materials 0.000 description 7
239000011707 mineral Substances 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
239000005864 Sulphur Substances 0.000 description 6
150000002739 metals Chemical class 0.000 description 6
239000000203 mixture Substances 0.000 description 6
239000007787 solid Substances 0.000 description 6
238000012360 testing method Methods 0.000 description 6
ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical compound O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 description 6
239000012263 liquid product Substances 0.000 description 5
229910052759 nickel Inorganic materials 0.000 description 5
229910052952 pyrrhotite Inorganic materials 0.000 description 5
229910052720 vanadium Inorganic materials 0.000 description 5
239000005569 Iron sulphate Substances 0.000 description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
239000010426 asphalt Substances 0.000 description 4
239000010779 crude oil Substances 0.000 description 4
230000008021 deposition Effects 0.000 description 4
229910000359 iron(II) sulfate Inorganic materials 0.000 description 4
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
239000003054 catalyst Substances 0.000 description 3
238000004939 coking Methods 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
239000000356 contaminant Substances 0.000 description 3
230000007423 decrease Effects 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
229910001570 bauxite Inorganic materials 0.000 description 2
230000000694 effects Effects 0.000 description 2
230000005484 gravity Effects 0.000 description 2
239000003350 kerosene Substances 0.000 description 2
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
239000011368 organic material Substances 0.000 description 2
125000002524 organometallic group Chemical group 0.000 description 2
235000012239 silicon dioxide Nutrition 0.000 description 2
239000012265 solid product Substances 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
229910005432 FeSx Inorganic materials 0.000 description 1
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
208000036366 Sensation of pressure Diseases 0.000 description 1
229910052770 Uranium Inorganic materials 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
239000008186 active pharmaceutical agent Substances 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
229910052614 beryl Inorganic materials 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000003575 carbonaceous material Substances 0.000 description 1
239000000969 carrier Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
239000004927 clay Substances 0.000 description 1
229910052681 coesite Inorganic materials 0.000 description 1
229910052906 cristobalite Inorganic materials 0.000 description 1
230000003111 delayed effect Effects 0.000 description 1
230000001066 destructive effect Effects 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
238000004821 distillation Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000002737 fuel gas Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
238000005984 hydrogenation reaction Methods 0.000 description 1
239000012535 impurity Substances 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
150000002605 large molecules Chemical class 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
229910052960 marcasite Inorganic materials 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
230000003405 preventing effect Effects 0.000 description 1
238000012545 processing Methods 0.000 description 1
239000010453 quartz Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
230000003134 recirculating effect Effects 0.000 description 1
238000011084 recovery Methods 0.000 description 1
238000004064 recycling Methods 0.000 description 1
238000002407 reforming Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000004576 sand Substances 0.000 description 1
238000005201 scrubbing Methods 0.000 description 1
239000003079 shale oil Substances 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
239000003476 subbituminous coal Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000004227 thermal cracking Methods 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1
239000002699 waste material Substances 0.000 description 1
229910052845 zircon Inorganic materials 0.000 description 1
GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/06—Sulfides
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/24—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles
- C10G47/26—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles suspended in the oil, e.g. slurries

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Materials Engineering (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

CA000375826A 1981-04-21 1981-04-21 Hydrofractionnement des petroles visqueux en presence de particules de pyrite Expired CA1152925A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000375826A CA1152925A (fr)	1981-04-21	1981-04-21	Hydrofractionnement des petroles visqueux en presence de particules de pyrite

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000375826A CA1152925A (fr)	1981-04-21	1981-04-21	Hydrofractionnement des petroles visqueux en presence de particules de pyrite

Publications (1)

Publication Number	Publication Date
CA1152925A true CA1152925A (fr)	1983-08-30

Family

ID=4119773

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000375826A Expired CA1152925A (fr)	1981-04-21	1981-04-21	Hydrofractionnement des petroles visqueux en presence de particules de pyrite

Country Status (1)

Country	Link
CA (1)	CA1152925A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4695369A (en) *	1986-08-11	1987-09-22	Air Products And Chemicals, Inc.	Catalytic hydroconversion of heavy oil using two metal catalyst

1981
- 1981-04-21 CA CA000375826A patent/CA1152925A/fr not_active Expired

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4695369A (en) *	1986-08-11	1987-09-22	Air Products And Chemicals, Inc.	Catalytic hydroconversion of heavy oil using two metal catalyst

Legal Events

Date	Code	Title	Description
2000-08-30	MKEX	Expiry

Publication	Publication Date	Title
US4370221A (en)	1983-01-25	Catalytic hydrocracking of heavy oils
US5374348A (en)	1994-12-20	Hydrocracking of heavy hydrocarbon oils with heavy hydrocarbon recycle
US4299685A (en)	1981-11-10	Hydrocracking of heavy oils/fly ash slurries
AU711758B2 (en)	1999-10-21	Hydrotreating of heavy hydrocarbon oils with control of particle size of particulate additives
US4963247A (en)	1990-10-16	Hydrocracking of heavy oil in presence of ultrafine iron sulphate
US4066530A (en)	1978-01-03	Hydroconversion of heavy hydrocarbons
US4695369A (en)	1987-09-22	Catalytic hydroconversion of heavy oil using two metal catalyst
US4376695A (en)	1983-03-15	Simultaneous demetalization and hydrocracking of heavy hydrocarbon oils
US4606809A (en)	1986-08-19	Hydroconversion of heavy oils
CA1094492A (fr)	1981-01-27	Hydrocraquage d'huiles lourdes avec un catalyseur fer- charbon
US4192735A (en)	1980-03-11	Hydrocracking of hydrocarbons
US4252634A (en)	1981-02-24	Thermal hydrocracking of heavy hydrocarbon oils with heavy oil recycle
US4969988A (en)	1990-11-13	Antifoam to achieve high conversion in hydroconversion of heavy oils
US4067799A (en)	1978-01-10	Hydroconversion process
CA1317585C (fr)	1993-05-11	Procede d'hydrocraquage de produits petroliers lourds, en presence de bouillie de fer-charbon
US5296130A (en)	1994-03-22	Hydrocracking of heavy asphaltenic oil in presence of an additive to prevent coke formation
US4435280A (en)	1984-03-06	Hydrocracking of heavy hydrocarbon oils with high pitch conversion
CA1202588A (fr)	1986-04-01	Hydrofractionnement des petroles lourds par intervention d'additifs secs
CA1322746C (fr)	1993-10-05	Hydrocraquage de petrole lourd en presence de coke de petrole sous-produit de la cokefaction de petrole lourd
CA1117887A (fr)	1982-02-09	Hydrocraquage catalytique d'huiles lourdes
GB2120675A (en)	1983-12-07	Hydrocracking of heavy oils in presence of pyrite particles
JPS58219292A (ja)	1983-12-20	重質炭化水素油の水素添加分解方法
CA1095847A (fr)	1981-02-17	Traduction non-disponible
GB2096164A (en)	1982-10-13	Hydrocracking of heavy oils
NL8202298A (nl)	1984-01-02	Werkwijze voor het hydrokraken van zware olien in tegenwoordigheid van pyrietdeeltjes.

CA1152925A - Hydrofractionnement des petroles visqueux en presence de particules de pyrite - Google Patents

Info

Links

Classifications

Landscapes

Priority Applications (1)

Applications Claiming Priority (1)

Publications (1)

Family

ID=4119773

Family Applications (1)

Country Status (1)

Cited By (1)

Cited By (1)

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Legal Events