CA1157412A - Methode et installation de demetallisation des hydrocarbures - Google Patents

Methode et installation de demetallisation des hydrocarbures

Info

Publication number: CA1157412A
Authority: CA; Canada
Prior art keywords: catalyst; hydrocarbon oil; demetallization; hydrogen; beds
Prior art date: 1979-09-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000358662A

Other languages

English (en)

Inventor

Wouter C. Van Zijll Langhout

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Shell Canada Ltd

Original Assignee

Shell Canada Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-09-26

Filing date

1980-08-20

Publication date

1983-11-22

1980-08-20 Application filed by Shell Canada Ltd filed Critical Shell Canada Ltd

1983-11-22 Application granted granted Critical

1983-11-22 Publication of CA1157412A publication Critical patent/CA1157412A/fr

Status Expired legal-status Critical Current

Links

239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 51
229930195733 hydrocarbon Natural products 0.000 title claims abstract description 51
150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 51
238000000034 method Methods 0.000 title claims abstract description 28
239000003054 catalyst Substances 0.000 claims abstract description 92
239000001257 hydrogen Substances 0.000 claims abstract description 36
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 36
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 33
229910052751 metal Inorganic materials 0.000 claims description 34
239000002184 metal Substances 0.000 claims description 34
239000011148 porous material Substances 0.000 claims description 25
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 18
239000007789 gas Substances 0.000 claims description 15
238000011282 treatment Methods 0.000 claims description 10
229910052759 nickel Inorganic materials 0.000 claims description 9
229910052720 vanadium Inorganic materials 0.000 claims description 9
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 9
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 7
229910052750 molybdenum Inorganic materials 0.000 claims description 7
239000011733 molybdenum Substances 0.000 claims description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
239000002245 particle Substances 0.000 claims description 6
239000010941 cobalt Substances 0.000 claims description 5
229910017052 cobalt Inorganic materials 0.000 claims description 5
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 5
229910052721 tungsten Inorganic materials 0.000 claims description 5
239000010937 tungsten Substances 0.000 claims description 5
229910052757 nitrogen Inorganic materials 0.000 claims description 3
238000000746 purification Methods 0.000 claims description 3
238000002955 isolation Methods 0.000 claims description 2
150000002431 hydrogen Chemical class 0.000 abstract description 4
239000003921 oil Substances 0.000 description 45
150000002739 metals Chemical class 0.000 description 16
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
239000005864 Sulphur Substances 0.000 description 7
230000008929 regeneration Effects 0.000 description 7
238000011069 regeneration method Methods 0.000 description 7
239000002253 acid Substances 0.000 description 6
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
239000000571 coke Substances 0.000 description 6
239000000377 silicon dioxide Substances 0.000 description 6
239000000969 carrier Substances 0.000 description 5
238000005984 hydrogenation reaction Methods 0.000 description 5
229910052500 inorganic mineral Inorganic materials 0.000 description 5
239000011707 mineral Substances 0.000 description 5
239000002480 mineral oil Substances 0.000 description 5
239000007864 aqueous solution Substances 0.000 description 4
230000000694 effects Effects 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 3
239000003638 chemical reducing agent Substances 0.000 description 3
239000000446 fuel Substances 0.000 description 3
235000010446 mineral oil Nutrition 0.000 description 3
238000005292 vacuum distillation Methods 0.000 description 3
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
239000010426 asphalt Substances 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
238000004523 catalytic cracking Methods 0.000 description 2
239000010779 crude oil Substances 0.000 description 2
230000009849 deactivation Effects 0.000 description 2
230000008021 deposition Effects 0.000 description 2
238000004821 distillation Methods 0.000 description 2
238000000605 extraction Methods 0.000 description 2
WTEVQBCEXWBHNA-YFHOEESVSA-N neral Chemical compound CC(C)=CCC\C(C)=C/C=O WTEVQBCEXWBHNA-YFHOEESVSA-N 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
150000003568 thioethers Chemical class 0.000 description 2
WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
WTEVQBCEXWBHNA-JXMROGBWSA-N citral A Natural products CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000005336 cracking Methods 0.000 description 1
-1 eobalt Chemical compound 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000000203 mixture Substances 0.000 description 1
HBVFXTAPOLSOPB-UHFFFAOYSA-N nickel vanadium Chemical compound [V].[Ni] HBVFXTAPOLSOPB-UHFFFAOYSA-N 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
238000007670 refining Methods 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
239000003079 shale oil Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
235000010269 sulphur dioxide Nutrition 0.000 description 1
239000004291 sulphur dioxide Substances 0.000 description 1
239000001117 sulphuric acid Substances 0.000 description 1
235000011149 sulphuric acid Nutrition 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

CA000358662A 1979-09-26 1980-08-20 Methode et installation de demetallisation des hydrocarbures Expired CA1157412A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
NL7907142A NL191763C (nl)	1979-09-26	1979-09-26	Werkwijze voor ontmetalliseren van een koolwaterstofolie.
NL7907142		1979-09-26

Publications (1)

Publication Number	Publication Date
CA1157412A true CA1157412A (fr)	1983-11-22

Family

ID=19833914

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000358662A Expired CA1157412A (fr)	1979-09-26	1980-08-20	Methode et installation de demetallisation des hydrocarbures

Country Status (9)

Country	Link
EP (1)	EP0026508B1 (fr)
JP (1)	JPS5655489A (fr)
AU (1)	AU538217B2 (fr)
CA (1)	CA1157412A (fr)
DE (1)	DE3064280D1 (fr)
MX (1)	MX155344A (fr)
NL (1)	NL191763C (fr)
NZ (1)	NZ195045A (fr)
SG (1)	SG32384G (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2570385B1 (fr) *	1984-09-14	1987-08-21	Raffinage Cie Francaise	Procede d'hydrotraitement de charges d'hydrocarbures et catalyseur pour la mise en oeuvre de ce procede
FR2650759B1 (fr) *	1989-08-08	1991-10-31	Inst Francais Du Petrole	Masse de captation a base de nickel pour l'elimination de l'arsenic et du phosphore contenus dans les coupes d'hydrocarbures liquides, sa preparation et son utilisation
FR2686617B1 (fr) *	1992-01-28	1994-03-18	Institut Francais Petrole	Procede d'hydrogenation selective de charge hydrocarbonee avec des lets catalytiques mis en óoeuvre successivement.
EP0712922B1 (fr)	1994-11-16	2000-02-23	Shell Internationale Researchmaatschappij B.V.	Procédé pour améliorer la qualité d'huile lubrifiante de base
AU688610B2 (en) *	1994-11-16	1998-03-12	Shell Internationale Research Maatschappij B.V.	Process for improving lubricating base oil quality
US20060070918A1 (en) *	2004-10-01	2006-04-06	Mayis Seapan	Method to extend the utilization of a catalyst in a multistage reactor system
DE102007059243A1 (de) *	2007-12-07	2009-06-10	Uhde Gmbh	Verfahren zur Entschwefelung olefinhaltiger Einsatzstoffe
DE102009032802A1 (de) *	2009-07-10	2011-01-13	Uhde Gmbh	Verfahren zur Entschwefelung olefinhaltiger Einsatzstoffe durch Regelung des Olefinanteils
FR2970260B1 (fr) *	2011-01-10	2014-07-25	IFP Energies Nouvelles	Procede d'hydrotraitement de charges lourdes d'hydrocarbures avec des reacteurs permutables incluant au moins une etape de court-circuitage d'un lit catalytique
FR3015514B1 (fr) *	2013-12-23	2016-10-28	Total Marketing Services	Procede ameliore de desaromatisation de coupes petrolieres
EP3325575A1 (fr) *	2015-07-17	2018-05-30	ExxonMobil Research and Engineering Company	Production d'essence à faible teneur en soufre

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3206395A (en) *	1963-01-21	1965-09-14	Pullman Inc	Desulfurization product recovery process
US3563887A (en) *	1968-10-25	1971-02-16	Gulf Research Development Co	Asphaltene hydrodesulfurization with small catalyst particles disposed in a guard chamber-main reactor system
GB1388714A (en) *	1971-04-01	1975-03-26	Exxon Research Engineering Co	Process for the conversion of metal-contaminated hydrocarbon feedstocks
NL175732C (nl) *	1972-07-07		Shell Int Research	Werkwijze voor het katalytisch demetalliseren van residuale koolwaterstofolien en het verder katalytisch omzetten van de hierbij verkregen olie.
DE2329700C3 (de) *	1973-06-09	1982-04-15	Basf Ag, 6700 Ludwigshafen	Verfahren zur hydrierenden Raffination und/oder hydrierenden Spaltung kohlenwasserstoffhaltigem Einsatzmaterial
US4017382A (en) *	1975-11-17	1977-04-12	Gulf Research & Development Company	Hydrodesulfurization process with upstaged reactor zones

1979
- 1979-09-26 NL NL7907142A patent/NL191763C/xx not_active IP Right Cessation
1980
- 1980-08-20 CA CA000358662A patent/CA1157412A/fr not_active Expired
- 1980-08-28 DE DE8080200807T patent/DE3064280D1/de not_active Expired
- 1980-08-28 EP EP19800200807 patent/EP0026508B1/fr not_active Expired
- 1980-09-24 JP JP13179680A patent/JPS5655489A/ja active Granted
- 1980-09-24 AU AU62664/80A patent/AU538217B2/en not_active Ceased
- 1980-09-24 NZ NZ19504580A patent/NZ195045A/xx unknown
- 1980-09-24 MX MX18406280A patent/MX155344A/es unknown
1984
- 1984-04-23 SG SG32384A patent/SG32384G/en unknown

Also Published As

Publication number	Publication date
AU6266480A (en)	1981-04-09
NL191763B (nl)	1996-03-01
NZ195045A (en)	1983-02-15
SG32384G (en)	1985-06-07
NL7907142A (nl)	1981-03-30
JPS5655489A (en)	1981-05-16
AU538217B2 (en)	1984-08-02
NL191763C (nl)	1996-07-02
DE3064280D1 (en)	1983-08-25
MX155344A (es)	1988-02-19
JPH0138157B2 (fr)	1989-08-11
EP0026508A1 (fr)	1981-04-08
EP0026508B1 (fr)	1983-07-20

Legal Events

Date	Code	Title	Description
2000-11-22	MKEX	Expiry

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US9650312B2 (en)	2017-05-16	Integration of residue hydrocracking and hydrotreating
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JPS5850636B2 (ja)	1983-11-11	重質炭化水素油の脱硫処理方法
JPH0235936A (ja)	1990-02-06	炭化水素仕込原料の水素化ビスブレーキング方法
CA1157412A (fr)	1983-11-22	Methode et installation de demetallisation des hydrocarbures
GB2167430A (en)	1986-05-29	Process for hydroconversion and upgrading of heavy crudes of high metal and asphaltene content
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