CA1165039A - Laque acrylique dispersante a forte teneur en solides, renfermant un agent de coalescence comme solvant pour liant au-dessus de 50.sup.oc - Google Patents

Laque acrylique dispersante a forte teneur en solides, renfermant un agent de coalescence comme solvant pour liant au-dessus de 50.sup.oc

Info

Publication number: CA1165039A
Authority: CA; Canada
Prior art keywords: weight; copolymer; polymer; solvent; binder
Prior art date: 1980-06-06
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000378959A

Other languages

English (en)

Inventor

Wallace R. Brasen

Glenn E. Gerhardt

Basil V. Gregorovich

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

EIDP Inc

Original Assignee

EI Du Pont de Nemours and Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-06-06

Filing date

1981-06-03

Publication date

1984-04-03

1981-06-03 Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co

1984-04-03 Application granted granted Critical

1984-04-03 Publication of CA1165039A publication Critical patent/CA1165039A/fr

Status Expired legal-status Critical Current

Links

239000002904 solvent Substances 0.000 title claims abstract description 60
239000011230 binding agent Substances 0.000 title claims abstract description 34
239000004922 lacquer Substances 0.000 title claims abstract description 23
239000006185 dispersion Substances 0.000 title claims abstract description 22
239000007787 solid Substances 0.000 title claims abstract description 22
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 11
239000003795 chemical substances by application Substances 0.000 title description 4
229920000642 polymer Polymers 0.000 claims abstract description 52
239000000203 mixture Substances 0.000 claims abstract description 39
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 37
229920000578 graft copolymer Polymers 0.000 claims abstract description 37
229920001577 copolymer Polymers 0.000 claims abstract description 36
239000008199 coating composition Substances 0.000 claims abstract description 30
239000000178 monomer Substances 0.000 claims abstract description 28
229920000058 polyacrylate Polymers 0.000 claims abstract description 27
-1 alkyl amino alkyl methacrylate Chemical compound 0.000 claims abstract description 23
FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 claims abstract description 16
125000001931 aliphatic group Chemical group 0.000 claims abstract description 13
239000002491 polymer binding agent Substances 0.000 claims abstract description 8
125000005250 alkyl acrylate group Chemical group 0.000 claims abstract description 6
125000000217 alkyl group Chemical group 0.000 claims abstract description 5
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 4
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 30
239000000049 pigment Substances 0.000 claims description 25
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 15
GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 14
IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical group CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 claims description 14
239000004014 plasticizer Substances 0.000 claims description 13
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
GZMAAYIALGURDQ-UHFFFAOYSA-N 2-(2-hexoxyethoxy)ethanol Chemical compound CCCCCCOCCOCCO GZMAAYIALGURDQ-UHFFFAOYSA-N 0.000 claims description 11
239000003208 petroleum Substances 0.000 claims description 11
239000002685 polymerization catalyst Substances 0.000 claims description 10
229920005989 resin Polymers 0.000 claims description 8
239000011347 resin Substances 0.000 claims description 8
SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 claims description 7
229940063557 methacrylate Drugs 0.000 claims description 7
SENMPMXZMGNQAG-UHFFFAOYSA-N 3,4-dihydro-2,5-benzodioxocine-1,6-dione Chemical compound O=C1OCCOC(=O)C2=CC=CC=C12 SENMPMXZMGNQAG-UHFFFAOYSA-N 0.000 claims description 6
238000009835 boiling Methods 0.000 claims description 6
125000000864 peroxy group Chemical group O(O*)* 0.000 claims description 6
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 5
238000005227 gel permeation chromatography Methods 0.000 claims description 4
229920000562 Poly(ethylene adipate) Polymers 0.000 claims description 3
239000003240 coconut oil Substances 0.000 claims description 3
235000019864 coconut oil Nutrition 0.000 claims description 3
230000000379 polymerizing effect Effects 0.000 claims 4
YSCOODQOCWOXNL-UHFFFAOYSA-N diethylamino 2-methylprop-2-enoate Chemical compound CCN(CC)OC(=O)C(C)=C YSCOODQOCWOXNL-UHFFFAOYSA-N 0.000 claims 1
239000004210 ether based solvent Substances 0.000 claims 1
150000002576 ketones Chemical class 0.000 claims 1
238000004519 manufacturing process Methods 0.000 claims 1
239000011541 reaction mixture Substances 0.000 description 25
239000000243 solution Substances 0.000 description 18
229940102838 methylmethacrylate Drugs 0.000 description 17
239000004815 dispersion polymer Substances 0.000 description 15
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 14
238000006243 chemical reaction Methods 0.000 description 14
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
238000010992 reflux Methods 0.000 description 11
229910052500 inorganic mineral Inorganic materials 0.000 description 10
239000004611 light stabiliser Substances 0.000 description 10
239000011707 mineral Substances 0.000 description 10
235000015096 spirit Nutrition 0.000 description 10
YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 8
239000002585 base Substances 0.000 description 8
238000000034 method Methods 0.000 description 8
239000004576 sand Substances 0.000 description 7
HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 6
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
229910000831 Steel Inorganic materials 0.000 description 6
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 6
229910052782 aluminium Inorganic materials 0.000 description 6
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
239000003963 antioxidant agent Substances 0.000 description 6
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
238000002156 mixing Methods 0.000 description 6
239000010959 steel Substances 0.000 description 6
239000000758 substrate Substances 0.000 description 6
230000003078 antioxidant effect Effects 0.000 description 5
239000011248 coating agent Substances 0.000 description 5
238000000576 coating method Methods 0.000 description 5
239000002270 dispersing agent Substances 0.000 description 5
229950010765 pivalate Drugs 0.000 description 5
PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 4
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
239000002253 acid Substances 0.000 description 4
239000000470 constituent Substances 0.000 description 4
229930195733 hydrocarbon Natural products 0.000 description 4
150000002430 hydrocarbons Chemical class 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 description 4
229920001225 polyester resin Polymers 0.000 description 4
239000004645 polyester resin Substances 0.000 description 4
OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 4
RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 3
239000004215 Carbon black (E152) Substances 0.000 description 3
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
239000001361 adipic acid Substances 0.000 description 3
235000011037 adipic acid Nutrition 0.000 description 3
229920000180 alkyd Polymers 0.000 description 3
JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 3
KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
238000001704 evaporation Methods 0.000 description 3
IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 3
238000005507 spraying Methods 0.000 description 3
239000004408 titanium dioxide Substances 0.000 description 3
ARVUDIQYNJVQIW-UHFFFAOYSA-N (4-dodecoxy-2-hydroxyphenyl)-phenylmethanone Chemical group OC1=CC(OCCCCCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 ARVUDIQYNJVQIW-UHFFFAOYSA-N 0.000 description 2
NXQMCAOPTPLPRL-UHFFFAOYSA-N 2-(2-benzoyloxyethoxy)ethyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCCOCCOC(=O)C1=CC=CC=C1 NXQMCAOPTPLPRL-UHFFFAOYSA-N 0.000 description 2
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
238000013019 agitation Methods 0.000 description 2
238000003915 air pollution Methods 0.000 description 2
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
XSIFPSYPOVKYCO-UHFFFAOYSA-N butyl benzoate Chemical group CCCCOC(=O)C1=CC=CC=C1 XSIFPSYPOVKYCO-UHFFFAOYSA-N 0.000 description 2
150000001721 carbon Chemical group 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000006229 carbon black Substances 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 2
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
230000008020 evaporation Effects 0.000 description 2
CADNYOZXMIKYPR-UHFFFAOYSA-B ferric pyrophosphate Chemical compound [Fe+3].[Fe+3].[Fe+3].[Fe+3].[O-]P([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])([O-])=O CADNYOZXMIKYPR-UHFFFAOYSA-B 0.000 description 2
VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 2
238000000227 grinding Methods 0.000 description 2
125000004464 hydroxyphenyl group Chemical group 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
150000004702 methyl esters Chemical class 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
239000004926 polymethyl methacrylate Substances 0.000 description 2
229920001296 polysiloxane Polymers 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
239000007921 spray Substances 0.000 description 2
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
239000008096 xylene Substances 0.000 description 2
PIHNXSZDSNAEMJ-UHFFFAOYSA-N (2,4-dihydroxyphenyl)-(2-phenyltriazol-4-yl)methanone Chemical class OC1=CC(O)=CC=C1C(=O)C1=NN(C=2C=CC=CC=2)N=C1 PIHNXSZDSNAEMJ-UHFFFAOYSA-N 0.000 description 1
SGPDKAGVCMVLGQ-UHFFFAOYSA-N (2-dodecoxy-3-hydroxyphenyl)-phenylmethanone Chemical compound CCCCCCCCCCCCOC1=C(O)C=CC=C1C(=O)C1=CC=CC=C1 SGPDKAGVCMVLGQ-UHFFFAOYSA-N 0.000 description 1
HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 1
FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 description 1
ZXHQLEQLZPJIFG-UHFFFAOYSA-N 1-ethoxyhexane Chemical compound CCCCCCOCC ZXHQLEQLZPJIFG-UHFFFAOYSA-N 0.000 description 1
LISMVBJUACINFW-UHFFFAOYSA-N 1-n-hexyl-4-n-phenylbenzene-1,4-diamine Chemical compound C1=CC(NCCCCCC)=CC=C1NC1=CC=CC=C1 LISMVBJUACINFW-UHFFFAOYSA-N 0.000 description 1
BHKLONWXRPJNAE-UHFFFAOYSA-N 1-o-butyl 2-o-cyclohexyl benzene-1,2-dicarboxylate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OC1CCCCC1 BHKLONWXRPJNAE-UHFFFAOYSA-N 0.000 description 1
JCTXKRPTIMZBJT-UHFFFAOYSA-N 2,2,4-trimethylpentane-1,3-diol Chemical compound CC(C)C(O)C(C)(C)CO JCTXKRPTIMZBJT-UHFFFAOYSA-N 0.000 description 1
ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
PACBIGNRUWABMA-UHFFFAOYSA-N 2-(2,3-dihydro-1,3-benzothiazol-2-yl)-6-dodecyl-4-methylphenol Chemical compound CCCCCCCCCCCCC1=CC(C)=CC(C2SC3=CC=CC=C3N2)=C1O PACBIGNRUWABMA-UHFFFAOYSA-N 0.000 description 1
VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 description 1
XPGKJODLSAIDML-UHFFFAOYSA-N 2-(2-hexoxyethoxy)ethyl acetate Chemical compound CCCCCCOCCOCCOC(C)=O XPGKJODLSAIDML-UHFFFAOYSA-N 0.000 description 1
FANGQVKSFHFPBY-UHFFFAOYSA-N 2-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical class OC(=O)C(C)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 FANGQVKSFHFPBY-UHFFFAOYSA-N 0.000 description 1
HLFCGJSXMLQMMZ-UHFFFAOYSA-N 2-(3-ethyl-1-phenylheptoxy)carbonylbenzoic acid Chemical compound C=1C=CC=CC=1C(CC(CC)CCCC)OC(=O)C1=CC=CC=C1C(O)=O HLFCGJSXMLQMMZ-UHFFFAOYSA-N 0.000 description 1
NMGPHUOPSWFUEB-UHFFFAOYSA-N 2-(butylamino)ethyl 2-methylprop-2-enoate Chemical compound CCCCNCCOC(=O)C(C)=C NMGPHUOPSWFUEB-UHFFFAOYSA-N 0.000 description 1
JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
OBMRSUNAEQGDLK-UHFFFAOYSA-N 2-(dipropylamino)ethyl 2-methylprop-2-enoate Chemical compound CCCN(CCC)CCOC(=O)C(C)=C OBMRSUNAEQGDLK-UHFFFAOYSA-N 0.000 description 1
BEWCNXNIQCLWHP-UHFFFAOYSA-N 2-(tert-butylamino)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCNC(C)(C)C BEWCNXNIQCLWHP-UHFFFAOYSA-N 0.000 description 1
FTABYKMUGGJOES-UHFFFAOYSA-N 2-[6-(2-carboxybenzoyl)oxyhexoxycarbonyl]benzoic acid Chemical compound OC(=O)C1=CC=CC=C1C(=O)OCCCCCCOC(=O)C1=CC=CC=C1C(O)=O FTABYKMUGGJOES-UHFFFAOYSA-N 0.000 description 1
KMIBLTRIQHPHOZ-UHFFFAOYSA-N 2-butan-2-yloxypropan-2-ol Chemical compound CCC(C)OC(C)(C)O KMIBLTRIQHPHOZ-UHFFFAOYSA-N 0.000 description 1
POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
NQBXSWAWVZHKBZ-UHFFFAOYSA-N 2-butoxyethyl acetate Chemical compound CCCCOCCOC(C)=O NQBXSWAWVZHKBZ-UHFFFAOYSA-N 0.000 description 1
ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
239000004808 2-ethylhexylester Substances 0.000 description 1
FRKCZFUUIQCQPC-UHFFFAOYSA-N 2-propan-2-yloxypropan-2-ol Chemical compound CC(C)OC(C)(C)O FRKCZFUUIQCQPC-UHFFFAOYSA-N 0.000 description 1
PCUPXNDEQDWEMM-UHFFFAOYSA-N 3-(diethylamino)propyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCCOC(=O)C(C)=C PCUPXNDEQDWEMM-UHFFFAOYSA-N 0.000 description 1
WTNFILZMBZUFDX-UHFFFAOYSA-N 4-phenyl-1,2-dihydrotriazol-5-one Chemical class N1N=NC(C=2C=CC=CC=2)=C1O WTNFILZMBZUFDX-UHFFFAOYSA-N 0.000 description 1
VANVRUGNYQERIW-UHFFFAOYSA-N 6-(diethylamino)hexyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCCCCCOC(=O)C(C)=C VANVRUGNYQERIW-UHFFFAOYSA-N 0.000 description 1
BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 description 1
QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 1
239000005711 Benzoic acid Substances 0.000 description 1
229910000906 Bronze Inorganic materials 0.000 description 1
GOJCZVPJCKEBQV-UHFFFAOYSA-N Butyl phthalyl butylglycolate Chemical compound CCCCOC(=O)COC(=O)C1=CC=CC=C1C(=O)OCCCC GOJCZVPJCKEBQV-UHFFFAOYSA-N 0.000 description 1
NJIDLJRHMJCJIV-UHFFFAOYSA-N C.C(CC)(=O)O Chemical compound C.C(CC)(=O)O NJIDLJRHMJCJIV-UHFFFAOYSA-N 0.000 description 1
WTIPPIQGXVIOFB-UHFFFAOYSA-N CCC.OC(=O)CS.OC(=O)CS.OC(=O)CS Chemical compound CCC.OC(=O)CS.OC(=O)CS.OC(=O)CS WTIPPIQGXVIOFB-UHFFFAOYSA-N 0.000 description 1
VOWAEIGWURALJQ-UHFFFAOYSA-N Dicyclohexyl phthalate Chemical compound C=1C=CC=C(C(=O)OC2CCCCC2)C=1C(=O)OC1CCCCC1 VOWAEIGWURALJQ-UHFFFAOYSA-N 0.000 description 1
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
239000007983 Tris buffer Substances 0.000 description 1
SAMOITCGMRRXJU-UHFFFAOYSA-N [3-(2-hydroxybenzoyl)phenyl]-(2-hydroxyphenyl)methanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC(C(=O)C=2C(=CC=CC=2)O)=C1 SAMOITCGMRRXJU-UHFFFAOYSA-N 0.000 description 1
RUDUCNPHDIMQCY-UHFFFAOYSA-N [3-(2-sulfanylacetyl)oxy-2,2-bis[(2-sulfanylacetyl)oxymethyl]propyl] 2-sulfanylacetate Chemical compound SCC(=O)OCC(COC(=O)CS)(COC(=O)CS)COC(=O)CS RUDUCNPHDIMQCY-UHFFFAOYSA-N 0.000 description 1
MZVQCMJNVPIDEA-UHFFFAOYSA-N [CH2]CN(CC)CC Chemical group [CH2]CN(CC)CC MZVQCMJNVPIDEA-UHFFFAOYSA-N 0.000 description 1
VWMUIRZYORAIRX-UHFFFAOYSA-N acetic acid 1-(2-ethoxyethoxy)hexane Chemical compound C(C)(=O)O.C(CCCCC)OCCOCC VWMUIRZYORAIRX-UHFFFAOYSA-N 0.000 description 1
ZZBUVNXJSWHTGB-UHFFFAOYSA-N acetic acid 1-[2-(2-ethoxyethoxy)ethoxy]hexane Chemical compound C(C)(=O)O.C(CCCCC)OCCOCCOCC ZZBUVNXJSWHTGB-UHFFFAOYSA-N 0.000 description 1
229920005822 acrylic binder Polymers 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
239000003849 aromatic solvent Substances 0.000 description 1
238000000498 ball milling Methods 0.000 description 1
150000001555 benzenes Chemical class 0.000 description 1
235000010233 benzoic acid Nutrition 0.000 description 1
150000001558 benzoic acid derivatives Chemical class 0.000 description 1
STLIUYGMHKJHHB-UHFFFAOYSA-N benzoic acid;2,2-dimethylpropane-1,3-diol;hexanedioic acid Chemical compound OCC(C)(C)CO.OC(=O)C1=CC=CC=C1.OC(=O)CCCCC(O)=O STLIUYGMHKJHHB-UHFFFAOYSA-N 0.000 description 1
MGTXGHFEJRQCLB-UHFFFAOYSA-N benzoic acid;ethane-1,2-diol;hexanedioic acid Chemical compound OCCO.OC(=O)C1=CC=CC=C1.OC(=O)CCCCC(O)=O MGTXGHFEJRQCLB-UHFFFAOYSA-N 0.000 description 1
239000012965 benzophenone Substances 0.000 description 1
150000008366 benzophenones Chemical class 0.000 description 1
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
239000012964 benzotriazole Substances 0.000 description 1
150000001565 benzotriazoles Chemical class 0.000 description 1
LBKFHGHXATXEBY-UHFFFAOYSA-N bis(1-methylcyclohexyl) benzene-1,2-dicarboxylate Chemical compound C=1C=CC=C(C(=O)OC2(C)CCCCC2)C=1C(=O)OC1(C)CCCCC1 LBKFHGHXATXEBY-UHFFFAOYSA-N 0.000 description 1
239000010974 bronze Substances 0.000 description 1
230000001680 brushing effect Effects 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
229920006217 cellulose acetate butyrate Polymers 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
VVOLVFOSOPJKED-UHFFFAOYSA-N copper phthalocyanine Chemical compound [Cu].N=1C2=NC(C3=CC=CC=C33)=NC3=NC(C3=CC=CC=C33)=NC3=NC(C3=CC=CC=C33)=NC3=NC=1C1=CC=CC=C12 VVOLVFOSOPJKED-UHFFFAOYSA-N 0.000 description 1
KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
FWLDHHJLVGRRHD-UHFFFAOYSA-N decyl prop-2-enoate Chemical compound CCCCCCCCCCOC(=O)C=C FWLDHHJLVGRRHD-UHFFFAOYSA-N 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
UCVPKAZCQPRWAY-UHFFFAOYSA-N dibenzyl benzene-1,2-dicarboxylate Chemical compound C=1C=CC=C(C(=O)OCC=2C=CC=CC=2)C=1C(=O)OCC1=CC=CC=C1 UCVPKAZCQPRWAY-UHFFFAOYSA-N 0.000 description 1
QEFOHLDZJZYQEZ-UHFFFAOYSA-N dibutyl 2-(1,4-dibutoxy-1,4-dioxobutan-2-yl)sulfanylbutanedioate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)SC(C(=O)OCCCC)CC(=O)OCCCC QEFOHLDZJZYQEZ-UHFFFAOYSA-N 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
238000007590 electrostatic spraying Methods 0.000 description 1
FZWBABZIGXEXES-UHFFFAOYSA-N ethane-1,2-diol;hexanedioic acid Chemical compound OCCO.OC(=O)CCCCC(O)=O FZWBABZIGXEXES-UHFFFAOYSA-N 0.000 description 1
IGOFAIGWJGFDDZ-UHFFFAOYSA-N ethanesulfonamide;toluene Chemical compound CCS(N)(=O)=O.CC1=CC=CC=C1 IGOFAIGWJGFDDZ-UHFFFAOYSA-N 0.000 description 1
DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 1
239000010685 fatty oil Substances 0.000 description 1
239000011152 fibreglass Substances 0.000 description 1
239000001056 green pigment Substances 0.000 description 1
LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
229910000000 metal hydroxide Inorganic materials 0.000 description 1
150000004692 metal hydroxides Chemical class 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
125000002496 methyl group Chemical class [H]C([H])([H])* 0.000 description 1
239000010445 mica Substances 0.000 description 1
229910052618 mica group Inorganic materials 0.000 description 1
HKLPOBRVSAUJSG-UHFFFAOYSA-N n-(4-anilinophenyl)prop-2-enamide Chemical compound C1=CC(NC(=O)C=C)=CC=C1NC1=CC=CC=C1 HKLPOBRVSAUJSG-UHFFFAOYSA-N 0.000 description 1
MDYPDLBFDATSCF-UHFFFAOYSA-N nonyl prop-2-enoate Chemical compound CCCCCCCCCOC(=O)C=C MDYPDLBFDATSCF-UHFFFAOYSA-N 0.000 description 1
239000012860 organic pigment Substances 0.000 description 1
235000006408 oxalic acid Nutrition 0.000 description 1
ATGUVEKSASEFFO-UHFFFAOYSA-N p-aminodiphenylamine Chemical compound C1=CC(N)=CC=C1NC1=CC=CC=C1 ATGUVEKSASEFFO-UHFFFAOYSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
RUOPINZRYMFPBF-UHFFFAOYSA-N pentane-1,3-diol Chemical compound CCC(O)CCO RUOPINZRYMFPBF-UHFFFAOYSA-N 0.000 description 1
229940097156 peroxyl Drugs 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
229920000233 poly(alkylene oxides) Polymers 0.000 description 1
239000005056 polyisocyanate Substances 0.000 description 1
239000002952 polymeric resin Substances 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000000047 product Substances 0.000 description 1
230000003678 scratch resistant effect Effects 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
229920003051 synthetic elastomer Polymers 0.000 description 1
239000005061 synthetic rubber Substances 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
150000003918 triazines Chemical class 0.000 description 1
150000003852 triazoles Chemical class 0.000 description 1
QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000001052 yellow pigment Substances 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1
DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Paints Or Removers (AREA)
Polymerisation Methods In General (AREA)

CA000378959A 1980-06-06 1981-06-03 Laque acrylique dispersante a forte teneur en solides, renfermant un agent de coalescence comme solvant pour liant au-dessus de 50.sup.oc Expired CA1165039A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US15745580A	1980-06-06	1980-06-06
US157,455		1980-06-06

Publications (1)

Publication Number	Publication Date
CA1165039A true CA1165039A (fr)	1984-04-03

Family

ID=22563788

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000378959A Expired CA1165039A (fr)	1980-06-06	1981-06-03	Laque acrylique dispersante a forte teneur en solides, renfermant un agent de coalescence comme solvant pour liant au-dessus de 50.sup.oc

Country Status (9)

Country	Link
JP (1)	JPS5723663A (fr)
AU (1)	AU539914B2 (fr)
BE (1)	BE889121A (fr)
BR (1)	BR8103492A (fr)
CA (1)	CA1165039A (fr)
FR (1)	FR2483940A1 (fr)
GB (1)	GB2077276B (fr)
MX (1)	MX158613A (fr)
ZA (1)	ZA813743B (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3321797A1 (de) *	1983-06-16	1984-12-20	Röhm GmbH, 6100 Darmstadt	Heisssiegelfaehige beschichtungsmassen
GB2164050B (en) *	1984-08-06	1988-09-28	Ici Plc	Coating composition containing dispersed particles of ethyl acrylate copolymer

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4255308A (en) *	1979-07-12	1981-03-10	E. I. Du Pont De Nemours And Company	Water based acrylic lacquer composition

1981
- 1981-06-03 CA CA000378959A patent/CA1165039A/fr not_active Expired
- 1981-06-03 BR BR8103492A patent/BR8103492A/pt unknown
- 1981-06-04 ZA ZA00813743A patent/ZA813743B/xx unknown
- 1981-06-04 MX MX187690A patent/MX158613A/es unknown
- 1981-06-04 AU AU71345/81A patent/AU539914B2/en not_active Ceased
- 1981-06-05 GB GB8117303A patent/GB2077276B/en not_active Expired
- 1981-06-05 BE BE0/205019A patent/BE889121A/fr not_active IP Right Cessation
- 1981-06-05 FR FR8111164A patent/FR2483940A1/fr active Granted
- 1981-06-05 JP JP8582981A patent/JPS5723663A/ja active Granted

Also Published As

Publication number	Publication date
BR8103492A (pt)	1982-02-24
FR2483940B1 (fr)	1985-03-15
GB2077276B (en)	1983-09-07
GB2077276A (en)	1981-12-16
JPH0124184B2 (fr)	1989-05-10
AU539914B2 (en)	1984-10-25
FR2483940A1 (fr)	1981-12-11
JPS5723663A (en)	1982-02-06
BE889121A (fr)	1981-12-07
ZA813743B (en)	1983-01-26
MX158613A (es)	1989-02-20
AU7134581A (en)	1981-12-10

Legal Events

Date	Code	Title	Description
2001-04-03	MKEX	Expiry

Publication	Publication Date	Title
US4476270A (en)	1984-10-09	Process for making high solids acrylic dispersion lacquer
US4525521A (en)	1985-06-25	Coating composition of an acrylic polymer having amino ester groups and a glycidyl acrylic polymer
US4455331A (en)	1984-06-19	Coating composition containing a rheology control additive of silica and polyvinyl pyrrolidone
CA1162682A (fr)	1984-02-21	Composition de revetement a forte teneur en solides, constituee d'un polymere acrylique de faible poids moleculaire, d'un polymere acrylique de poids mole- culaire moyen, et d'un agent de reticulation a base de melamine alkylee
CA1195035A (fr)	1985-10-08	Composition de revetement, a forte teneur en solides, d'un email renfermant un produit d'addition a base de silice et de poly(ethyleneglycol) pour optimiser les proprietes rheologiques
US4404248A (en)	1983-09-13	Clear coat/color coat finish from a high solids coating composition of a blend of a low molecular weight acrylic polymer and a medium molecular weight acrylic polymer and an alkylated melamine cross-linking agent
US4378445A (en)	1983-03-29	High solids acrylic dispersion lacquer
BE897421A (fr)	1984-01-30	Additif de reglage rheologique pour des compositions de revetement
US5331050A (en)	1994-07-19	Low VOC clear epoxy acrylic coating composition for basecoat clear coat finish
EP1023412B1 (fr)	2003-01-15	Compositions de revetement contenant un polymere disperse non aqueux, un polymere acrylique a fonction silane et une triazine
CA1337308C (fr)	1995-10-10	Acide sulfonique aromatique bloque par un groupe aminomethylpropanol
JPH06501036A (ja)	1994-01-27	アクリロシラン、アクリルポリオール及び架橋剤の自動車用透明コーティング組成物
US4987177A (en)	1991-01-22	Coating composition of an acrylic polymer containing glycidyl groups and acetoacetoxy groups and an amino ester acrylic polymer
CA1208395A (fr)	1986-07-22	Additif renfermant un sel n-propylique d'acide sulfonique pour compositions de revetement
CN100462413C (zh)	2009-02-18	涂料组合物
CA2098616C (fr)	2002-01-29	Revetements contenant un polymere organosilicie et un polymere en emulsion reticule fonctionnel
GB2077276A (en)	1981-12-16	High Solids Acrylic Dispersion Lacquer
EP0029597A1 (fr)	1981-06-03	Composition de revêtement acrylique aqueuse thermoréticulable, objets ainsi revêtus, et procédé de préparation de ces objets revêtus
US20070190312A1 (en)	2007-08-16	Method of forming a multi-layer coating on automobile bodies without a primer bake
CA1213689A (fr)	1986-11-04	Additif ameliorant les proprietes rheologiques de compositions de revetement de silice et de polyvinylpyrrolidone
KR20030087449A (ko)	2003-11-14	도장 온습도 영역이 확대된 자동차용 수용성 상도 도료조성물
EP0029596A1 (fr)	1981-06-03	Composition de revêtement contenant un grand nombre de particules solides à base d'un polymère acrylique à bas poids moléculaire et un agent réticulant à base de résine azotée et substrat ainsi revêtu
CA1259730A (fr)	1989-09-19	Composition de revetement a base de polymere acrylique renfermant des groupes amino-esters et un polymere glycidylacrylique
CN115867392A (zh)	2023-03-28	制备多层涂漆体系的三涂一烘法
EP0179954A1 (fr)	1986-05-07	Composition de revêtement à base d'un polymère acrylique contenant un groupe aminoester et d'un polymère acrylique contenant un groupe glycidyl