CA1168216A - Matiere charbonneuse et methode de production d'un gaz a fort rendement thermique a partir de ladite matiere - Google Patents

Matiere charbonneuse et methode de production d'un gaz a fort rendement thermique a partir de ladite matiere

Info

Publication number: CA1168216A
Authority: CA; Canada
Prior art keywords: carbon; hydrogen; group metal; iron; carbonaceous material
Prior art date: 1977-07-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000393560A

Other languages

English (en)

Inventor

Maksymilian Burk

Jack L. Blumenthal

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Northrop Grumman Space and Mission Systems Corp

Original Assignee

TRW Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-07-21

Filing date

1982-01-04

Publication date

1984-05-29

1978-07-07 Priority claimed from CA000306997A external-priority patent/CA1136413A/fr

1982-01-04 Application filed by TRW Inc filed Critical TRW Inc

1982-01-04 Priority to CA000393560A priority Critical patent/CA1168216A/fr

1984-05-29 Application granted granted Critical

1984-05-29 Publication of CA1168216A publication Critical patent/CA1168216A/fr

Status Expired legal-status Critical Current

Links

239000003575 carbonaceous material Substances 0.000 title claims abstract description 175
239000000463 material Substances 0.000 title claims abstract description 79
238000000034 method Methods 0.000 title claims abstract description 70
230000008569 process Effects 0.000 title abstract description 37
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 227
229910052799 carbon Inorganic materials 0.000 claims abstract description 224
239000007789 gas Substances 0.000 claims abstract description 200
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 180
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 152
239000001257 hydrogen Substances 0.000 claims abstract description 151
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 142
229910052751 metal Inorganic materials 0.000 claims abstract description 114
239000002184 metal Substances 0.000 claims abstract description 114
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 92
229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 92
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical group [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims abstract description 87
239000003999 initiator Substances 0.000 claims abstract description 26
238000007323 disproportionation reaction Methods 0.000 claims abstract description 25
238000004519 manufacturing process Methods 0.000 claims abstract description 10
229910001092 metal group alloy Inorganic materials 0.000 claims abstract description 9
-1 ferrous group metals Chemical class 0.000 claims abstract description 8
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 199
229910052742 iron Inorganic materials 0.000 claims description 95
239000000835 fiber Substances 0.000 claims description 46
238000006243 chemical reaction Methods 0.000 claims description 44
239000000203 mixture Substances 0.000 claims description 41
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 37
239000003054 catalyst Substances 0.000 claims description 27
229910052759 nickel Inorganic materials 0.000 claims description 17
239000011159 matrix material Substances 0.000 claims description 16
239000010941 cobalt Substances 0.000 claims description 15
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 15
229910017052 cobalt Inorganic materials 0.000 claims description 14
150000002431 hydrogen Chemical class 0.000 claims description 13
229910045601 alloy Inorganic materials 0.000 claims description 10
239000000956 alloy Substances 0.000 claims description 10
239000000126 substance Substances 0.000 claims description 7
150000002739 metals Chemical class 0.000 claims description 5
230000000694 effects Effects 0.000 claims description 4
229930195733 hydrocarbon Natural products 0.000 claims description 4
150000002430 hydrocarbons Chemical class 0.000 claims description 4
239000007769 metal material Substances 0.000 claims description 4
239000004615 ingredient Substances 0.000 claims description 3
238000000151 deposition Methods 0.000 abstract description 42
239000003245 coal Substances 0.000 abstract description 14
150000001247 metal acetylides Chemical class 0.000 abstract description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 42
230000008021 deposition Effects 0.000 description 41
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 39
239000000306 component Substances 0.000 description 36
239000007787 solid Substances 0.000 description 35
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 28
239000000047 product Substances 0.000 description 22
229910002092 carbon dioxide Inorganic materials 0.000 description 21
235000013980 iron oxide Nutrition 0.000 description 18
239000001569 carbon dioxide Substances 0.000 description 17
230000009257 reactivity Effects 0.000 description 17
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
239000003570 air Substances 0.000 description 14
230000015572 biosynthetic process Effects 0.000 description 14
229910001868 water Inorganic materials 0.000 description 14
229910052757 nitrogen Inorganic materials 0.000 description 12
239000000428 dust Substances 0.000 description 10
VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 10
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
229910001567 cementite Inorganic materials 0.000 description 9
239000001301 oxygen Substances 0.000 description 9
229910052760 oxygen Inorganic materials 0.000 description 9
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
238000005984 hydrogenation reaction Methods 0.000 description 8
239000012530 fluid Substances 0.000 description 7
238000000926 separation method Methods 0.000 description 7
229910052717 sulfur Inorganic materials 0.000 description 7
239000011593 sulfur Substances 0.000 description 7
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 6
229910001030 Iron–nickel alloy Inorganic materials 0.000 description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
229910000037 hydrogen sulfide Inorganic materials 0.000 description 6
239000002245 particle Substances 0.000 description 6
229910000975 Carbon steel Inorganic materials 0.000 description 5
JZQOJFLIJNRDHK-CMDGGOBGSA-N alpha-irone Chemical compound CC1CC=C(C)C(\C=C\C(C)=O)C1(C)C JZQOJFLIJNRDHK-CMDGGOBGSA-N 0.000 description 5
238000004458 analytical method Methods 0.000 description 5
239000010962 carbon steel Substances 0.000 description 5
230000003197 catalytic effect Effects 0.000 description 5
239000003638 chemical reducing agent Substances 0.000 description 5
SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 5
NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 5
230000009467 reduction Effects 0.000 description 5
229910000859 α-Fe Inorganic materials 0.000 description 5
229910000640 Fe alloy Inorganic materials 0.000 description 4
229910000990 Ni alloy Inorganic materials 0.000 description 4
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
230000005611 electricity Effects 0.000 description 4
238000011065 in-situ storage Methods 0.000 description 4
230000001965 increasing effect Effects 0.000 description 4
238000001000 micrograph Methods 0.000 description 4
150000001721 carbon Chemical class 0.000 description 3
125000004122 cyclic group Chemical group 0.000 description 3
230000001351 cycling effect Effects 0.000 description 3
230000005294 ferromagnetic effect Effects 0.000 description 3
230000005291 magnetic effect Effects 0.000 description 3
239000000843 powder Substances 0.000 description 3
239000006104 solid solution Substances 0.000 description 3
150000003464 sulfur compounds Chemical class 0.000 description 3
238000011282 treatment Methods 0.000 description 3
230000004580 weight loss Effects 0.000 description 3
229910000531 Co alloy Inorganic materials 0.000 description 2
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
229910000831 Steel Inorganic materials 0.000 description 2
238000002441 X-ray diffraction Methods 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
VNWKTOKETHGBQD-AKLPVKDBSA-N carbane Chemical compound [15CH4] VNWKTOKETHGBQD-AKLPVKDBSA-N 0.000 description 2
JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 2
229910000428 cobalt oxide Inorganic materials 0.000 description 2
IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 2
238000001816 cooling Methods 0.000 description 2
230000000779 depleting effect Effects 0.000 description 2
239000012467 final product Substances 0.000 description 2
239000000446 fuel Substances 0.000 description 2
238000002309 gasification Methods 0.000 description 2
229910052595 hematite Inorganic materials 0.000 description 2
239000011019 hematite Substances 0.000 description 2
LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 2
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 2
238000007885 magnetic separation Methods 0.000 description 2
QMQXDJATSGGYDR-UHFFFAOYSA-N methylidyneiron Chemical compound [C].[Fe] QMQXDJATSGGYDR-UHFFFAOYSA-N 0.000 description 2
239000003345 natural gas Substances 0.000 description 2
229910000480 nickel oxide Inorganic materials 0.000 description 2
GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 2
239000011148 porous material Substances 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
239000000376 reactant Substances 0.000 description 2
239000004576 sand Substances 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000010959 steel Substances 0.000 description 2
238000003860 storage Methods 0.000 description 2
238000003786 synthesis reaction Methods 0.000 description 2
238000012546 transfer Methods 0.000 description 2
239000002918 waste heat Substances 0.000 description 2
229920000049 Carbon (fiber) Polymers 0.000 description 1
238000005169 Debye-Scherrer Methods 0.000 description 1
241000196324 Embryophyta Species 0.000 description 1
229910001209 Low-carbon steel Inorganic materials 0.000 description 1
241000220324 Pyrus Species 0.000 description 1
208000036366 Sensation of pressure Diseases 0.000 description 1
239000005864 Sulphur Substances 0.000 description 1
QVYYOKWPCQYKEY-UHFFFAOYSA-N [Fe].[Co] Chemical compound [Fe].[Co] QVYYOKWPCQYKEY-UHFFFAOYSA-N 0.000 description 1
239000006096 absorbing agent Substances 0.000 description 1
230000002411 adverse Effects 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
239000012080 ambient air Substances 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
238000004380 ashing Methods 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
239000004917 carbon fiber Substances 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
239000003610 charcoal Substances 0.000 description 1
238000001311 chemical methods and process Methods 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000000571 coke Substances 0.000 description 1
239000000567 combustion gas Substances 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
238000010960 commercial process Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
230000003467 diminishing effect Effects 0.000 description 1
229910001873 dinitrogen Inorganic materials 0.000 description 1
238000000921 elemental analysis Methods 0.000 description 1
230000003028 elevating effect Effects 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000011888 foil Substances 0.000 description 1
239000002803 fossil fuel Substances 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
230000005484 gravity Effects 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000012510 hollow fiber Substances 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000006148 magnetic separator Substances 0.000 description 1
239000002075 main ingredient Substances 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
229910052976 metal sulfide Inorganic materials 0.000 description 1
238000002156 mixing Methods 0.000 description 1
JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 1
235000021017 pears Nutrition 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
238000012545 processing Methods 0.000 description 1
BALXUFOVQVENIU-KXNXZCPBSA-N pseudoephedrine hydrochloride Chemical compound [H+].[Cl-].CN[C@@H](C)[C@@H](O)C1=CC=CC=C1 BALXUFOVQVENIU-KXNXZCPBSA-N 0.000 description 1
238000011160 research Methods 0.000 description 1
238000001878 scanning electron micrograph Methods 0.000 description 1
238000007086 side reaction Methods 0.000 description 1
238000004611 spectroscopical analysis Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
230000009897 systematic effect Effects 0.000 description 1
238000012360 testing method Methods 0.000 description 1
230000009466 transformation Effects 0.000 description 1
230000007704 transition Effects 0.000 description 1
239000002699 waste material Substances 0.000 description 1
230000004584 weight gain Effects 0.000 description 1
235000019786 weight gain Nutrition 0.000 description 1
210000002268 wool Anatomy 0.000 description 1

Landscapes

Catalysts (AREA)

CA000393560A 1977-07-21 1982-01-04 Matiere charbonneuse et methode de production d'un gaz a fort rendement thermique a partir de ladite matiere Expired CA1168216A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000393560A CA1168216A (fr)	1977-07-21	1982-01-04	Matiere charbonneuse et methode de production d'un gaz a fort rendement thermique a partir de ladite matiere

Applications Claiming Priority (6)

Application Number	Priority Date	Filing Date	Title
US81764777A	1977-07-21	1977-07-21
US817,647		1977-07-21
US91724078A	1978-06-20	1978-06-20
US917,240		1978-06-20
CA000306997A CA1136413A (fr)	1977-07-21	1978-07-07	Methode d'extraction d'un gaz a pouvoir calorifique eleve d'une matiere charbonneuse
CA000393560A CA1168216A (fr)	1977-07-21	1982-01-04	Matiere charbonneuse et methode de production d'un gaz a fort rendement thermique a partir de ladite matiere

Publications (1)

Publication Number	Publication Date
CA1168216A true CA1168216A (fr)	1984-05-29

Family

ID=27426092

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000393560A Expired CA1168216A (fr)	1977-07-21	1982-01-04	Matiere charbonneuse et methode de production d'un gaz a fort rendement thermique a partir de ladite matiere

Country Status (1)

Country	Link
CA (1)	CA1168216A (fr)

1982
- 1982-01-04 CA CA000393560A patent/CA1168216A/fr not_active Expired

Legal Events

Date	Code	Title	Description
2001-05-29	MKEX	Expiry

Publication	Publication Date	Title
US4710483A (en)	1987-12-01	Novel carbonaceous material and process for producing a high BTU gas from this material
CA1079972A (fr)	1980-06-24	Methode de fabrication de gaz synthetique
CA1187702A (fr)	1985-05-28	Methode de conversion de la houille ou des fractions lourdes du petrole en hydrogene ou en gaz d'ammonium de synthese
US4540681A (en)	1985-09-10	Catalyst for the methanation of carbon monoxide in sour gas
US4372755A (en)	1983-02-08	Production of a fuel gas with a stabilized metal carbide catalyst
US3746522A (en)	1973-07-17	Gasification of carbonaceous solids
US1964744A (en)	1934-07-03	Process of making carbon black
US3759677A (en)	1973-09-18	Catalytic synthesis gas manufacture
CA2340822C (fr)	2010-08-03	Procede de production d'hydrogene
CA1136413A (fr)	1982-11-30	Methode d'extraction d'un gaz a pouvoir calorifique eleve d'une matiere charbonneuse
GB2039518A (en)	1980-08-13	A process and a plant for preparing a gas rich in methane
US4341531A (en)	1982-07-27	Production of methane-rich gas
US4242103A (en)	1980-12-30	Cyclic two step process for production of methane from carbon monoxide
US3890432A (en)	1975-06-17	Catalytic hydrogen manufacture
US4242105A (en)	1980-12-30	Process for producing methane from gas streams containing carbon monoxide and hydrogen
US4242104A (en)	1980-12-30	Cyclic process for producing methane with catalyst regeneration
US3615299A (en)	1971-10-26	Hydrogen production by reaction of carbon with steam or steam and oxygen
EP0120590A1 (fr)	1984-10-03	Procédé pour la préparation de gaz de pipe-line à partir de gaz brut ou de gaz de synthèse contenant du soufre
Baker et al.	1985	Catalysis of gas-phase reactions in steam gasification of biomass
EP0004456B1 (fr)	1982-04-07	Méthanisation de monoxyde de carbone sans séparation préalable des gaz inertes
GB2045277A (en)	1980-10-29	Process for producing reducing gas from solid fuel for ore reduction
GB2237814A (en)	1991-05-15	A method and apparatus for co-generating power and hydrocarbons from coal derived synthesis gas using pressure swing absorption
US4873214A (en)	1989-10-10	Carbonaceous material for production of hydrogen from low heating value fuel gases
US3753671A (en)	1973-08-21	Production of synthetic natural gas and hydrogen from the gasification of carbonaceous materials
Jess et al.	2016	Industrial hydrogen production from hydrocarbon fuels and biomass