CA1174032A - Methode de preparation de complexes de molybdene, produits ainsi obtenus, et lubrifiants qui les renferment - Google Patents

Methode de preparation de complexes de molybdene, produits ainsi obtenus, et lubrifiants qui les renferment

Info

Publication number: CA1174032A
Authority: CA; Canada
Prior art keywords: sulfur; molybdenum; added; mixture; prepared
Prior art date: 1979-06-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000351686A

Other languages

English (en)

Inventor

John M. King

Louis Devries

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Chevron USA Inc

Original Assignee

Chevron Research and Technology Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-06-28

Filing date

1980-05-12

Publication date

1984-09-11

1979-06-28 Priority claimed from US06/052,696 external-priority patent/US4263152A/en

1979-06-28 Priority claimed from US06/052,699 external-priority patent/US4272387A/en

1980-05-12 Application filed by Chevron Research and Technology Co filed Critical Chevron Research and Technology Co

1984-09-11 Application granted granted Critical

1984-09-11 Publication of CA1174032A publication Critical patent/CA1174032A/fr

Status Expired legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims description 37
230000008569 process Effects 0.000 title claims description 30
239000000314 lubricant Substances 0.000 title description 8
150000002751 molybdenum Chemical class 0.000 title description 2
239000000203 mixture Substances 0.000 claims abstract description 141
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 58
229910052717 sulfur Inorganic materials 0.000 claims abstract description 55
239000011593 sulfur Substances 0.000 claims abstract description 55
239000010687 lubricating oil Substances 0.000 claims abstract description 28
239000005078 molybdenum compound Substances 0.000 claims abstract description 20
150000002752 molybdenum compounds Chemical class 0.000 claims abstract description 20
229910017464 nitrogen compound Inorganic materials 0.000 claims abstract description 18
150000002830 nitrogen compounds Chemical class 0.000 claims abstract description 18
230000002378 acidificating effect Effects 0.000 claims abstract description 15
239000003963 antioxidant agent Substances 0.000 claims abstract description 5
PTISTKLWEJDJID-UHFFFAOYSA-N sulfanylidenemolybdenum Chemical compound [Mo]=S PTISTKLWEJDJID-UHFFFAOYSA-N 0.000 claims abstract description 3
KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 claims description 60
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 50
229910052750 molybdenum Inorganic materials 0.000 claims description 41
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 40
239000011733 molybdenum Substances 0.000 claims description 40
239000003921 oil Substances 0.000 claims description 33
-1 hydrocarbyl succinimide Chemical compound 0.000 claims description 32
229960002317 succinimide Drugs 0.000 claims description 27
229910052757 nitrogen Inorganic materials 0.000 claims description 24
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 19
125000001183 hydrocarbyl group Chemical group 0.000 claims description 19
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 17
229920000768 polyamine Polymers 0.000 claims description 17
125000004429 atom Chemical group 0.000 claims description 16
239000002585 base Substances 0.000 claims description 16
238000006243 chemical reaction Methods 0.000 claims description 15
150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 13
150000001875 compounds Chemical class 0.000 claims description 13
FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 claims description 13
VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 10
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 10
229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 10
229940014800 succinic anhydride Drugs 0.000 claims description 10
FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 claims description 9
125000000217 alkyl group Chemical group 0.000 claims description 9
239000012141 concentrate Substances 0.000 claims description 9
239000002270 dispersing agent Substances 0.000 claims description 8
230000001050 lubricating effect Effects 0.000 claims description 8
UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 8
APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims description 7
235000018660 ammonium molybdate Nutrition 0.000 claims description 7
239000011609 ammonium molybdate Substances 0.000 claims description 7
229940010552 ammonium molybdate Drugs 0.000 claims description 7
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 6
BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 claims description 6
150000001412 amines Chemical class 0.000 claims description 6
CYQAYERJWZKYML-UHFFFAOYSA-N phosphorus pentasulfide Chemical compound S1P(S2)(=S)SP3(=S)SP1(=S)SP2(=S)S3 CYQAYERJWZKYML-UHFFFAOYSA-N 0.000 claims description 6
239000005077 polysulfide Substances 0.000 claims description 6
229920001021 polysulfide Polymers 0.000 claims description 6
150000008117 polysulfides Polymers 0.000 claims description 6
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 5
229910052945 inorganic sulfide Inorganic materials 0.000 claims description 5
VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 claims description 5
YUKQRDCYNOVPGJ-UHFFFAOYSA-N thioacetamide Chemical compound CC(N)=S YUKQRDCYNOVPGJ-UHFFFAOYSA-N 0.000 claims description 5
DLFVBJFMPXGRIB-UHFFFAOYSA-N thioacetamide Natural products CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 claims description 5
CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 claims description 4
125000004433 nitrogen atom Chemical group N* 0.000 claims description 4
125000005541 phosphonamide group Chemical group 0.000 claims description 4
125000003342 alkenyl group Chemical group 0.000 claims description 3
DMSZORWOGDLWGN-UHFFFAOYSA-N ctk1a3526 Chemical compound NP(N)(N)=O DMSZORWOGDLWGN-UHFFFAOYSA-N 0.000 claims description 3
239000004952 Polyamide Substances 0.000 claims description 2
229910052783 alkali metal Inorganic materials 0.000 claims description 2
150000001340 alkali metals Chemical class 0.000 claims description 2
230000003078 antioxidant effect Effects 0.000 claims description 2
JLYVRXJEQTZZBE-UHFFFAOYSA-N ctk1c6083 Chemical compound NP(N)(N)=S JLYVRXJEQTZZBE-UHFFFAOYSA-N 0.000 claims description 2
238000004519 manufacturing process Methods 0.000 claims description 2
229920002647 polyamide Polymers 0.000 claims description 2
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims 2
125000000008 (C1-C10) alkyl group Chemical group 0.000 claims 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
150000001735 carboxylic acids Chemical class 0.000 claims 1
238000005461 lubrication Methods 0.000 claims 1
MZAVPBQCWWIYEQ-UHFFFAOYSA-N n-(6-chloro-1,3-benzothiazol-2-yl)-1-benzothiophene-2-sulfonamide Chemical compound C1=CC=C2SC(S(=O)(=O)NC3=NC4=CC=C(C=C4S3)Cl)=CC2=C1 MZAVPBQCWWIYEQ-UHFFFAOYSA-N 0.000 claims 1
239000004215 Carbon black (E152) Substances 0.000 description 56
229930195733 hydrocarbon Natural products 0.000 description 56
150000002430 hydrocarbons Chemical class 0.000 description 56
JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 49
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 41
239000000047 product Substances 0.000 description 35
235000019198 oils Nutrition 0.000 description 27
238000010992 reflux Methods 0.000 description 23
239000005909 Kieselgur Substances 0.000 description 20
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 20
239000000654 additive Substances 0.000 description 19
239000011541 reaction mixture Substances 0.000 description 19
238000012360 testing method Methods 0.000 description 18
238000001816 cooling Methods 0.000 description 15
239000000243 solution Substances 0.000 description 14
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 11
239000003795 chemical substances by application Substances 0.000 description 11
229910052760 oxygen Inorganic materials 0.000 description 11
239000001301 oxygen Substances 0.000 description 11
239000002904 solvent Substances 0.000 description 9
230000000996 additive effect Effects 0.000 description 8
125000004432 carbon atom Chemical group C* 0.000 description 8
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 8
230000007935 neutral effect Effects 0.000 description 7
150000003839 salts Chemical class 0.000 description 7
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 6
239000000463 material Substances 0.000 description 6
239000007858 starting material Substances 0.000 description 6
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
229910052802 copper Inorganic materials 0.000 description 5
239000010949 copper Substances 0.000 description 5
239000003085 diluting agent Substances 0.000 description 5
UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 description 5
239000001257 hydrogen Substances 0.000 description 5
229910052739 hydrogen Inorganic materials 0.000 description 5
229910052751 metal Inorganic materials 0.000 description 5
239000002184 metal Substances 0.000 description 5
CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 5
229910052982 molybdenum disulfide Inorganic materials 0.000 description 5
229920000642 polymer Polymers 0.000 description 5
RREANTFLPGEWEN-MBLPBCRHSA-N 7-[4-[[(3z)-3-[4-amino-5-[(3,4,5-trimethoxyphenyl)methyl]pyrimidin-2-yl]imino-5-fluoro-2-oxoindol-1-yl]methyl]piperazin-1-yl]-1-cyclopropyl-6-fluoro-4-oxoquinoline-3-carboxylic acid Chemical compound COC1=C(OC)C(OC)=CC(CC=2C(=NC(\N=C/3C4=CC(F)=CC=C4N(CN4CCN(CC4)C=4C(=CC=5C(=O)C(C(O)=O)=CN(C=5C=4)C4CC4)F)C\3=O)=NC=2)N)=C1 RREANTFLPGEWEN-MBLPBCRHSA-N 0.000 description 4
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
229910000831 Steel Inorganic materials 0.000 description 4
150000001336 alkenes Chemical class 0.000 description 4
150000001408 amides Chemical class 0.000 description 4
239000000908 ammonium hydroxide Substances 0.000 description 4
PXJJSXABGXMUSU-UHFFFAOYSA-N disulfur dichloride Chemical compound ClSSCl PXJJSXABGXMUSU-UHFFFAOYSA-N 0.000 description 4
150000002148 esters Chemical class 0.000 description 4
XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 4
239000010959 steel Substances 0.000 description 4
FWMUJAIKEJWSSY-UHFFFAOYSA-N sulfur dichloride Chemical compound ClSCl FWMUJAIKEJWSSY-UHFFFAOYSA-N 0.000 description 4
150000003568 thioethers Chemical class 0.000 description 4
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
239000005977 Ethylene Substances 0.000 description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
150000003973 alkyl amines Chemical class 0.000 description 3
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 3
239000004202 carbamide Substances 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
238000005260 corrosion Methods 0.000 description 3
235000014113 dietary fatty acids Nutrition 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
239000012990 dithiocarbamate Substances 0.000 description 3
150000004659 dithiocarbamates Chemical class 0.000 description 3
239000000194 fatty acid Substances 0.000 description 3
229930195729 fatty acid Natural products 0.000 description 3
239000000706 filtrate Substances 0.000 description 3
239000003112 inhibitor Substances 0.000 description 3
230000003647 oxidation Effects 0.000 description 3
238000007254 oxidation reaction Methods 0.000 description 3
KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical class OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
229920002367 Polyisobutene Polymers 0.000 description 2
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
125000002947 alkylene group Chemical group 0.000 description 2
229910021529 ammonia Inorganic materials 0.000 description 2
238000013459 approach Methods 0.000 description 2
239000002199 base oil Substances 0.000 description 2
229910052796 boron Inorganic materials 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
238000007796 conventional method Methods 0.000 description 2
230000007797 corrosion Effects 0.000 description 2
150000002194 fatty esters Chemical class 0.000 description 2
238000001914 filtration Methods 0.000 description 2
239000012530 fluid Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
239000012188 paraffin wax Substances 0.000 description 2
239000003208 petroleum Substances 0.000 description 2
150000008039 phosphoramides Chemical class 0.000 description 2
229910052698 phosphorus Inorganic materials 0.000 description 2
239000011574 phosphorus Substances 0.000 description 2
239000002243 precursor Substances 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
150000003335 secondary amines Chemical class 0.000 description 2
235000015393 sodium molybdate Nutrition 0.000 description 2
239000011684 sodium molybdate Substances 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
239000001384 succinic acid Substances 0.000 description 2
XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 2
235000021122 unsaturated fatty acids Nutrition 0.000 description 2
239000001993 wax Substances 0.000 description 2
AHAREKHAZNPPMI-AATRIKPKSA-N (3e)-hexa-1,3-diene Chemical compound CC\C=C\C=C AHAREKHAZNPPMI-AATRIKPKSA-N 0.000 description 1
229910019614 (NH4)6 Mo7 O24.4H2 O Inorganic materials 0.000 description 1
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
OILQNNHOQFRDJH-UHFFFAOYSA-N 1-hexadecylsulfanylhexadecane Chemical compound CCCCCCCCCCCCCCCCSCCCCCCCCCCCCCCCC OILQNNHOQFRDJH-UHFFFAOYSA-N 0.000 description 1
SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
FCEWRLVEPKVKBU-UHFFFAOYSA-N 2-[2-(tert-butylamino)-1-hydroxyethyl]phenol Chemical compound CC(C)(C)NCC(O)C1=CC=CC=C1O FCEWRLVEPKVKBU-UHFFFAOYSA-N 0.000 description 1
OHXAOPZTJOUYKM-UHFFFAOYSA-N 3-Chloro-2-methylpropene Chemical compound CC(=C)CCl OHXAOPZTJOUYKM-UHFFFAOYSA-N 0.000 description 1
NZXZINXFUSKTPH-UHFFFAOYSA-N 4-[4-(4-butylcyclohexyl)cyclohexyl]-1,2-difluorobenzene Chemical compound C1CC(CCCC)CCC1C1CCC(C=2C=C(F)C(F)=CC=2)CC1 NZXZINXFUSKTPH-UHFFFAOYSA-N 0.000 description 1
229910000851 Alloy steel Inorganic materials 0.000 description 1
208000023514 Barrett esophagus Diseases 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
229910001018 Cast iron Inorganic materials 0.000 description 1
CUDSBWGCGSUXDB-UHFFFAOYSA-N Dibutyl disulfide Chemical compound CCCCSSCCCC CUDSBWGCGSUXDB-UHFFFAOYSA-N 0.000 description 1
BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
LVGKNOAMLMIIKO-UHFFFAOYSA-N Elaidinsaeure-aethylester Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC LVGKNOAMLMIIKO-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
229910000640 Fe alloy Inorganic materials 0.000 description 1
244000043261 Hevea brasiliensis Species 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
OXPCWUWUWIWSGI-MSUUIHNZSA-N Lauryl oleate Chemical compound CCCCCCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC OXPCWUWUWIWSGI-MSUUIHNZSA-N 0.000 description 1
OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
241001465754 Metazoa Species 0.000 description 1
FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
OHLUUHNLEMFGTQ-UHFFFAOYSA-N N-methylacetamide Chemical compound CNC(C)=O OHLUUHNLEMFGTQ-UHFFFAOYSA-N 0.000 description 1
229930040373 Paraformaldehyde Natural products 0.000 description 1
235000019483 Peanut oil Nutrition 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
229920002396 Polyurea Polymers 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
229920002807 Thiomer Polymers 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
150000001242 acetic acid derivatives Chemical class 0.000 description 1
125000005595 acetylacetonate group Chemical group 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000009471 action Effects 0.000 description 1
230000004913 activation Effects 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
125000002723 alicyclic group Chemical group 0.000 description 1
150000001409 amidines Chemical class 0.000 description 1
IMUDHTPIFIBORV-UHFFFAOYSA-N aminoethylpiperazine Chemical compound NCCN1CCNCC1 IMUDHTPIFIBORV-UHFFFAOYSA-N 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
239000002518 antifoaming agent Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
FIXLYHHVMHXSCP-UHFFFAOYSA-H azane;dihydroxy(dioxo)molybdenum;trioxomolybdenum;tetrahydrate Chemical compound N.N.N.N.N.N.O.O.O.O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O[Mo](O)(=O)=O.O[Mo](O)(=O)=O.O[Mo](O)(=O)=O FIXLYHHVMHXSCP-UHFFFAOYSA-H 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
LUFPJJNWMYZRQE-UHFFFAOYSA-N benzylsulfanylmethylbenzene Chemical compound C=1C=CC=CC=1CSCC1=CC=CC=C1 LUFPJJNWMYZRQE-UHFFFAOYSA-N 0.000 description 1
238000005219 brazing Methods 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
159000000007 calcium salts Chemical class 0.000 description 1
ZMRQTIAUOLVKOX-UHFFFAOYSA-L calcium;diphenoxide Chemical compound [Ca+2].[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1 ZMRQTIAUOLVKOX-UHFFFAOYSA-L 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
238000005253 cladding Methods 0.000 description 1
239000003245 coal Substances 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
SZXCCXFNQHQRGF-UHFFFAOYSA-N di(propan-2-yloxy)-sulfanyl-sulfanylidene-$l^{5}-phosphane Chemical compound CC(C)OP(S)(=S)OC(C)C SZXCCXFNQHQRGF-UHFFFAOYSA-N 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
229940043237 diethanolamine Drugs 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
229940113088 dimethylacetamide Drugs 0.000 description 1
IUNMPGNGSSIWFP-UHFFFAOYSA-N dimethylaminopropylamine Chemical compound CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 description 1
GCMDLPXRCVHIMG-UHFFFAOYSA-N dioxomolybdenum(2+) Chemical compound O=[Mo+2]=O GCMDLPXRCVHIMG-UHFFFAOYSA-N 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
238000009713 electroplating Methods 0.000 description 1
NMBYRULZXULRQF-UHFFFAOYSA-N ethene;piperazine Chemical compound C=C.C1CNCCN1.C1CNCCN1 NMBYRULZXULRQF-UHFFFAOYSA-N 0.000 description 1
LVGKNOAMLMIIKO-QXMHVHEDSA-N ethyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC LVGKNOAMLMIIKO-QXMHVHEDSA-N 0.000 description 1
229940093471 ethyl oleate Drugs 0.000 description 1
239000003925 fat Substances 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
235000021323 fish oil Nutrition 0.000 description 1
230000004907 flux Effects 0.000 description 1
238000009472 formulation Methods 0.000 description 1
239000002816 fuel additive Substances 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
238000007306 functionalization reaction Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
239000004519 grease Substances 0.000 description 1
238000000227 grinding Methods 0.000 description 1
JYTMDBGMUIAIQH-UHFFFAOYSA-N hexadecyl oleate Natural products CCCCCCCCCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC JYTMDBGMUIAIQH-UHFFFAOYSA-N 0.000 description 1
230000036571 hydration Effects 0.000 description 1
238000006703 hydration reaction Methods 0.000 description 1
150000003949 imides Chemical class 0.000 description 1
230000002401 inhibitory effect Effects 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
229940049918 linoleate Drugs 0.000 description 1
235000021388 linseed oil Nutrition 0.000 description 1
239000000944 linseed oil Substances 0.000 description 1
HGPXWXLYXNVULB-UHFFFAOYSA-M lithium stearate Chemical compound [Li+].CCCCCCCCCCCCCCCCCC([O-])=O HGPXWXLYXNVULB-UHFFFAOYSA-M 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
AXOJRQLKMVSHHZ-UHFFFAOYSA-N methyl 1-methyl-1,2,3,6-tetrahydropyridin-1-ium-5-carboxylate;bromide Chemical compound Br.COC(=O)C1=CCCN(C)C1 AXOJRQLKMVSHHZ-UHFFFAOYSA-N 0.000 description 1
CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
244000005700 microbiome Species 0.000 description 1
239000006082 mold release agent Substances 0.000 description 1
MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
239000000178 monomer Substances 0.000 description 1
239000010705 motor oil Substances 0.000 description 1
229920003052 natural elastomer Polymers 0.000 description 1
229920005615 natural polymer Polymers 0.000 description 1
229920001194 natural rubber Polymers 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
235000015097 nutrients Nutrition 0.000 description 1
229940049964 oleate Drugs 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
239000004006 olive oil Substances 0.000 description 1
235000008390 olive oil Nutrition 0.000 description 1
125000004430 oxygen atom Chemical group O* 0.000 description 1
125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
JYTMDBGMUIAIQH-ZPHPHTNESA-N palmityl oleate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC JYTMDBGMUIAIQH-ZPHPHTNESA-N 0.000 description 1
239000000312 peanut oil Substances 0.000 description 1
229920001281 polyalkylene Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
235000007686 potassium Nutrition 0.000 description 1
NNFCIKHAZHQZJG-UHFFFAOYSA-N potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 description 1
ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
239000010499 rapseed oil Substances 0.000 description 1
238000007670 refining Methods 0.000 description 1
229940066675 ricinoleate Drugs 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
239000013049 sediment Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 description 1
239000007787 solid Substances 0.000 description 1
241000894007 species Species 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
125000001302 tertiary amino group Chemical group 0.000 description 1
238000010998 test method Methods 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
230000008719 thickening Effects 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
238000004448 titration Methods 0.000 description 1
238000011282 treatment Methods 0.000 description 1
150000004670 unsaturated fatty acids Chemical class 0.000 description 1
229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
235000015112 vegetable and seed oil Nutrition 0.000 description 1
239000008158 vegetable oil Substances 0.000 description 1
239000003643 water by type Substances 0.000 description 1
230000004580 weight loss Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/18—Complexes with metals
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
- C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/046—Overbased sulfonic acid salts
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/12—Groups 6 or 16
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
- C10N2070/02—Concentrating of additives

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Lubricants (AREA)

CA000351686A 1979-06-28 1980-05-12 Methode de preparation de complexes de molybdene, produits ainsi obtenus, et lubrifiants qui les renferment Expired CA1174032A (fr)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US52,699		1979-06-28
US06/052,696 US4263152A (en)	1979-06-28	1979-06-28	Process of preparing molybdenum complexes, the complexes so-produced and lubricants containing same
US52,696		1979-06-28
US06/052,699 US4272387A (en)	1979-06-28	1979-06-28	Process of preparing molybdenum complexes, the complexes so-produced and lubricants containing same

Publications (1)

Publication Number	Publication Date
CA1174032A true CA1174032A (fr)	1984-09-11

Family

ID=26730955

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000351686A Expired CA1174032A (fr)	1979-06-28	1980-05-12	Methode de preparation de complexes de molybdene, produits ainsi obtenus, et lubrifiants qui les renferment

Country Status (9)

Country	Link
AU (1)	AU531482B2 (fr)
BR (1)	BR8004018A (fr)
CA (1)	CA1174032A (fr)
DE (1)	DE3023555C2 (fr)
FR (1)	FR2460324B1 (fr)
GB (1)	GB2053267B (fr)
IT (1)	IT1198333B (fr)
NL (1)	NL8003282A (fr)
SE (1)	SE452017B (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1125735A (fr) *	1978-09-18	1982-06-15	Esther D. Winans	Complexes au molybdene d'agents dispersants azotes, sans cendres, utilises comme additifs anti-usure, reducteurs de friction, dans des huiles lubrifiantes
JPS5716095A (en) *	1980-06-13	1982-01-27	Texaco Development Corp	Production of lubricant additive
US4369119A (en) *	1981-04-03	1983-01-18	Chevron Research Company	Antioxidant combinations of molybdenum complexes and organic sulfur compounds for lubricating oils
US4370246A (en) *	1981-04-27	1983-01-25	Chevron Research Company	Antioxidant combinations of molybdenum complexes and aromatic amine compounds
FR2648473B1 (fr) *	1989-06-19	1994-04-01	Elf Aquitaine Ste Nale	Additifs surbases pour huiles lubrifiantes renfermant un complexe du molybdene, leur procede de preparation et compositions renfermant lesdits additifs
US6362355B1 (en)	2000-01-21	2002-03-26	The Lubrizol Corporation	Molybdated dispersants from heteropoly acids
US6696393B1 (en) *	2002-08-01	2004-02-24	Chevron Oronite Company Llc	Methods and compositions for reducing wear in internal combustion engines lubricated with a low phosphorus content lubricating oil
US7884059B2 (en) *	2004-10-20	2011-02-08	Afton Chemical Corporation	Oil-soluble molybdenum derivatives derived from hydroxyethyl-substituted Mannich bases
JP5094030B2 (ja)	2006-03-22	2012-12-12	Ｊｘ日鉱日石エネルギー株式会社	低灰エンジン油組成物
CA2773647C (fr) *	2009-09-30	2016-04-12	Chevron Oronite Company Llc	Preparation d'un complexe sulfure molybdene amide et compositions d'additif ayant une faible teneur en soufre actif residuel

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
BE591548A (fr) *	1959-06-05
GB1085903A (en) *	1964-11-19	1967-10-04	Castrol Ltd	Additives for lubricating compositions
BE868431A (fr) *	1978-06-23	1978-10-16	Thy Marcinelle Monceau Forges	Tuyere pour fond de convertisseur d'acierie
US4215773A (en) *	1978-08-17	1980-08-05	U.M.C. Industries, Inc.	Coin-handling device
CA1125735A (fr) *	1978-09-18	1982-06-15	Esther D. Winans	Complexes au molybdene d'agents dispersants azotes, sans cendres, utilises comme additifs anti-usure, reducteurs de friction, dans des huiles lubrifiantes
FR2460325A1 (fr) *	1979-06-28	1981-01-23	Chevron Res	Procede de production d'un compose sulfure de molybdene, produit obtenu et composition d'huile lubrifiante le contenant
US4283295A (en) *	1979-06-28	1981-08-11	Chevron Research Company	Process for preparing a sulfurized molybdenum-containing composition and lubricating oil containing said composition
US4285822A (en) *	1979-06-28	1981-08-25	Chevron Research Company	Process for preparing a sulfurized molybdenum-containing composition and lubricating oil containing the composition
CA1152315A (fr) *	1979-06-28	1983-08-23	Louis Devries	Composes du molybdene (vll)
JPS5716095A (en) *	1980-06-13	1982-01-27	Texaco Development Corp	Production of lubricant additive

1980
- 1980-05-12 CA CA000351686A patent/CA1174032A/fr not_active Expired
- 1980-06-05 NL NL8003282A patent/NL8003282A/nl not_active Application Discontinuation
- 1980-06-13 SE SE8004420A patent/SE452017B/sv not_active IP Right Cessation
- 1980-06-23 FR FR8013849A patent/FR2460324B1/fr not_active Expired
- 1980-06-23 AU AU59535/80A patent/AU531482B2/en not_active Ceased
- 1980-06-24 DE DE3023555A patent/DE3023555C2/de not_active Expired - Lifetime
- 1980-06-25 GB GB8020782A patent/GB2053267B/en not_active Expired
- 1980-06-26 BR BR8004018A patent/BR8004018A/pt not_active IP Right Cessation
- 1980-06-26 IT IT23094/80A patent/IT1198333B/it active

Also Published As

Publication number	Publication date
FR2460324A1 (fr)	1981-01-23
SE452017B (sv)	1987-11-09
AU5953580A (en)	1981-01-08
AU531482B2 (en)	1983-08-25
IT1198333B (it)	1988-12-21
GB2053267B (en)	1983-05-18
NL8003282A (nl)	1980-12-30
FR2460324B1 (fr)	1985-08-09
DE3023555A1 (de)	1981-01-22
BR8004018A (pt)	1981-01-21
GB2053267A (en)	1981-02-04
IT8023094A0 (it)	1980-06-26
DE3023555C2 (de)	1993-10-14
SE8004420L (sv)	1980-12-29

Legal Events

Date	Code	Title	Description
2001-09-11	MKEX	Expiry

Publication	Publication Date	Title
US4263152A (en)	1981-04-21	Process of preparing molybdenum complexes, the complexes so-produced and lubricants containing same
US4259195A (en)	1981-03-31	Reaction product of acidic molybdenum compound with basic nitrogen compound and lubricants containing same
US4283295A (en)	1981-08-11	Process for preparing a sulfurized molybdenum-containing composition and lubricating oil containing said composition
US4285822A (en)	1981-08-25	Process for preparing a sulfurized molybdenum-containing composition and lubricating oil containing the composition
US4272387A (en)	1981-06-09	Process of preparing molybdenum complexes, the complexes so-produced and lubricants containing same
US4265773A (en)	1981-05-05	Process of preparing molybdenum complexes, the complexes so-produced and lubricants containing same
US4259194A (en)	1981-03-31	Reaction product of ammonium tetrathiomolybdate with basic nitrogen compounds and lubricants containing same
US4261843A (en)	1981-04-14	Reaction product of acidic molybdenum compound with basic nitrogen compound and lubricants containing same
US4402840A (en)	1983-09-06	Antioxidant combinations of molybdenum complexes and organic sulfur compounds for lubricating oils
US4369119A (en)	1983-01-18	Antioxidant combinations of molybdenum complexes and organic sulfur compounds for lubricating oils
CA1176624A (fr)	1984-10-23	Combinaisons anti-oxydantes aux complexes du molybdene et aux amines aromatiques
US4395343A (en)	1983-07-26	Antioxidant combinations of sulfur containing molybdenum complexes and organic sulfur compounds
US8076275B2 (en)	2011-12-13	Reduced color molybdenum-containing composition and a method of making same
EP0616635B1 (fr)	1999-01-07	Composition de carburant pour moteurs deux-temps
GB2053267A (en)	1981-02-04	Sulfur- and molybdenum- containing additives for lubricating oils
CA1127171A (fr)	1982-07-06	Composes de molybdene (iii)
GB2053265A (en)	1981-02-04	Process for preparing a sulfurized molybdenum-containing composition and lubricating oil compositions containing the same
CA1152315A (fr)	1983-08-23	Composes du molybdene (vll)