CA1178570A - Catalyseurs d'impregnation - Google Patents

Catalyseurs d'impregnation

Info

Publication number: CA1178570A
Authority: CA; Canada
Prior art keywords: catalyst; oxide complex; interim; elements; group
Prior art date: 1982-02-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000395801A

Other languages

English (en)

Inventor

Dev D. Suresh

Maria S. Friedrich

Robert K. Grasselli

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Standard Oil Co

Original Assignee

Standard Oil Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-02-08

Filing date

1982-02-08

Publication date

1984-11-27

1982-02-08 Application filed by Standard Oil Co filed Critical Standard Oil Co

1982-02-08 Priority to CA000395801A priority Critical patent/CA1178570A/fr

1984-11-27 Application granted granted Critical

1984-11-27 Publication of CA1178570A publication Critical patent/CA1178570A/fr

Status Expired legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 51
238000005470 impregnation Methods 0.000 claims abstract description 10
RDQSSKKUSGYZQB-UHFFFAOYSA-N bismuthanylidyneiron Chemical compound [Fe].[Bi] RDQSSKKUSGYZQB-UHFFFAOYSA-N 0.000 claims abstract description 7
238000000034 method Methods 0.000 claims description 14
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 7
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
229910052750 molybdenum Inorganic materials 0.000 claims description 6
239000011733 molybdenum Substances 0.000 claims description 6
229910052760 oxygen Inorganic materials 0.000 claims description 6
239000001301 oxygen Substances 0.000 claims description 6
239000012041 precatalyst Substances 0.000 claims description 6
230000003197 catalytic effect Effects 0.000 claims description 5
239000007789 gas Substances 0.000 claims description 5
238000001354 calcination Methods 0.000 claims description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
229910052787 antimony Inorganic materials 0.000 claims description 3
229910052785 arsenic Inorganic materials 0.000 claims description 3
MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims description 3
229910052698 phosphorus Inorganic materials 0.000 claims description 3
229910052714 tellurium Inorganic materials 0.000 claims description 3
229910021472 group 8 element Inorganic materials 0.000 claims description 2
230000000737 periodic effect Effects 0.000 claims description 2
229910052710 silicon Inorganic materials 0.000 claims description 2
239000010703 silicon Substances 0.000 claims description 2
229910052717 sulfur Inorganic materials 0.000 claims description 2
239000000243 solution Substances 0.000 description 14
239000007788 liquid Substances 0.000 description 13
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 8
229910052783 alkali metal Inorganic materials 0.000 description 7
150000001340 alkali metals Chemical class 0.000 description 7
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 6
235000016768 molybdenum Nutrition 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
229910052797 bismuth Inorganic materials 0.000 description 4
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 4
230000000052 comparative effect Effects 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
239000000463 material Substances 0.000 description 4
230000003647 oxidation Effects 0.000 description 4
238000007254 oxidation reaction Methods 0.000 description 4
239000002002 slurry Substances 0.000 description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
150000001336 alkenes Chemical class 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
239000010949 copper Substances 0.000 description 3
239000000047 product Substances 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
238000007796 conventional method Methods 0.000 description 2
229910052802 copper Inorganic materials 0.000 description 2
DKUYEPUUXLQPPX-UHFFFAOYSA-N dibismuth;molybdenum;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Mo].[Mo].[Bi+3].[Bi+3] DKUYEPUUXLQPPX-UHFFFAOYSA-N 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
229910052814 silicon oxide Inorganic materials 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
239000004111 Potassium silicate Substances 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
150000001242 acetic acid derivatives Chemical class 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
239000002585 base Substances 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
229910052792 caesium Inorganic materials 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
229940106681 chloroacetic acid Drugs 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 1
239000002178 crystalline material Substances 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
239000011707 mineral Substances 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
229960003903 oxygen Drugs 0.000 description 1
235000011007 phosphoric acid Nutrition 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
239000011148 porous material Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
235000011056 potassium acetate Nutrition 0.000 description 1
NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
229910052913 potassium silicate Inorganic materials 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
230000036647 reaction Effects 0.000 description 1
230000003716 rejuvenation Effects 0.000 description 1
229910052701 rubidium Inorganic materials 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
235000011149 sulphuric acid Nutrition 0.000 description 1
-1 tartaric Chemical class 0.000 description 1

Landscapes

Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

CA000395801A 1982-02-08 1982-02-08 Catalyseurs d'impregnation Expired CA1178570A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000395801A CA1178570A (fr)	1982-02-08	1982-02-08	Catalyseurs d'impregnation

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000395801A CA1178570A (fr)	1982-02-08	1982-02-08	Catalyseurs d'impregnation

Publications (1)

Publication Number	Publication Date
CA1178570A true CA1178570A (fr)	1984-11-27

Family

ID=4122002

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000395801A Expired CA1178570A (fr)	1982-02-08	1982-02-08	Catalyseurs d'impregnation

Country Status (1)

Country	Link
CA (1)	CA1178570A (fr)

1982
- 1982-02-08 CA CA000395801A patent/CA1178570A/fr not_active Expired

Legal Events

Date	Code	Title	Description
2001-11-28	MKEC	Expiry (correction)
2002-02-08	MKEX	Expiry

Publication	Publication Date	Title
US4424141A (en)	1984-01-03	Process for producing an oxide complex catalyst containing molybdenum and one of bismuth and tellurium
US6043184A (en)	2000-03-28	Heteropoly acids supported on polyoxometallate salts and their preparation
KR100247524B1 (ko)	2000-03-15	아크릴산 제조용 촉매 및 이 촉매를 이용한 아크릴산의 제조방법
US5990348A (en)	1999-11-23	Conversion of alkanes to unsaturated carboxylic acids over heteroploy acids supported on polyoxometallate salts
US4709070A (en)	1987-11-24	Process for improving activity of tellurium containing metal oxide catalysts
US5144090A (en)	1992-09-01	Method for preparing acrolein or methacrolein
US4871700A (en)	1989-10-03	Reactivating Mo-Bi-Fe catalyst used in production of unsaturated aldehydes
US5907052A (en)	1999-05-25	Process for producing acrylonitrile or methacrylonitrile from propane or isobutane by ammoxidation
US20070238608A1 (en)	2007-10-11	Catalyst compostion for the selective conversion of alkanes to unsaturated carboxylic acids, method of making and method of using thereof
KR100537591B1 (ko)	2005-12-19	몰리브덴 함유 산화물 유동층 촉매의 재생 방법
EP0006248A1 (fr)	1980-01-09	Procédé de préparation de l'acide méthacrylique et catalyseur
EP0574895B1 (fr)	1997-09-03	Cytalyseur supporté pour la synthèse d'aldéhydes insaturés et d'acides carboxyliques insaturés et procédé pour sa préparation
US4051180A (en)	1977-09-27	Preparation of acrylic acid and methacrylic acid
EP0109775B1 (fr)	1986-08-27	Procédé de régénération de catalyseurs à base d'oxydes métalliques de fer et d'antimoine
US4414134A (en)	1983-11-08	Impregnating catalysts
US4444906A (en)	1984-04-24	Method for the preparation of high activity phosphomolybdic acid based catalysts
US4855275A (en)	1989-08-08	Catalyst performance improvement via separate boron addition
US5104844A (en)	1992-04-14	Process of preparing catalysts for producing methacrylic acid
EP0350862B1 (fr)	1993-10-20	Procédé pour la fabrication de l'acide méthacrylique
CA1178570A (fr)	1984-11-27	Catalyseurs d'impregnation
EP0146099A2 (fr)	1985-06-26	Procédé de préparation d'acide acrylique par oxidation de l'acroléine ainsi qu'un nouveau catalyseur pour ledit procédé
US4443555A (en)	1984-04-17	Method for the preparation of high activity phosphomolybdic acid based catalysts
EP0086292B1 (fr)	1986-04-23	Production des catalyseurs par imprégnation et leur utilisation dans des réactions d'oxydation
US4378309A (en)	1983-03-29	Catalyst compositions for the preparation of unsaturated acids
GB2144049A (en)	1985-02-27	Process for improving activity of tellurium-containing metal oxide catalysts