CA1189307A - Combinaisons de sel organique de metal de transition/detergent-dispersant sans cendres/ antioxydant phenolique - Google Patents

Combinaisons de sel organique de metal de transition/detergent-dispersant sans cendres/ antioxydant phenolique

Info

Publication number: CA1189307A
Authority: CA; Canada
Prior art keywords: composition; dispersant; fuel; hydrocarbon; transition metal
Prior art date: 1982-03-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000422950A

Other languages

English (en)

Inventor

Robert C. Tupa

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Lubrizol Corp

Original Assignee

Lubrizol Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-03-11

Filing date

1983-03-04

Publication date

1985-06-25

1983-03-04 Application filed by Lubrizol Corp filed Critical Lubrizol Corp

1985-06-25 Application granted granted Critical

1985-06-25 Publication of CA1189307A publication Critical patent/CA1189307A/fr

Status Expired legal-status Critical Current

Links

239000002270 dispersing agent Substances 0.000 title claims abstract description 44
-1 Organo transition metal salt Chemical class 0.000 title claims abstract description 41
239000002530 phenolic antioxidant Substances 0.000 title claims abstract description 25
229910052723 transition metal Inorganic materials 0.000 title claims abstract description 23
239000000203 mixture Substances 0.000 claims abstract description 79
239000000446 fuel Substances 0.000 claims abstract description 24
150000007524 organic acids Chemical class 0.000 claims abstract description 11
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims abstract description 10
239000011572 manganese Substances 0.000 claims abstract description 9
229910052748 manganese Inorganic materials 0.000 claims abstract description 7
239000002253 acid Substances 0.000 claims description 20
150000003839 salts Chemical class 0.000 claims description 20
125000004432 carbon atom Chemical group C* 0.000 claims description 16
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 15
150000002989 phenols Chemical class 0.000 claims description 10
229910052751 metal Inorganic materials 0.000 claims description 9
239000002184 metal Substances 0.000 claims description 9
150000003624 transition metals Chemical class 0.000 claims description 9
150000001735 carboxylic acids Chemical class 0.000 claims description 8
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 7
239000007788 liquid Substances 0.000 claims description 7
VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 claims description 6
229930185605 Bisphenol Natural products 0.000 claims description 6
239000000654 additive Substances 0.000 claims description 6
239000003085 diluting agent Substances 0.000 claims description 6
150000002148 esters Chemical class 0.000 claims description 6
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 5
229910052739 hydrogen Inorganic materials 0.000 claims description 5
229910052757 nitrogen Inorganic materials 0.000 claims description 5
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
239000010771 distillate fuel oil Substances 0.000 claims description 4
230000000996 additive effect Effects 0.000 claims description 3
239000012141 concentrate Substances 0.000 claims description 3
239000001257 hydrogen Substances 0.000 claims description 3
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
229910052804 chromium Inorganic materials 0.000 claims description 2
239000011651 chromium Substances 0.000 claims description 2
229910052802 copper Inorganic materials 0.000 claims description 2
239000010949 copper Substances 0.000 claims description 2
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150000002696 manganese Chemical class 0.000 claims description 2
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
229910052759 nickel Inorganic materials 0.000 claims description 2
229910052706 scandium Inorganic materials 0.000 claims description 2
SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims description 2
125000000446 sulfanediyl group Chemical group *S* 0.000 claims description 2
239000010936 titanium Substances 0.000 claims description 2
229910052719 titanium Inorganic materials 0.000 claims description 2
229910052720 vanadium Inorganic materials 0.000 claims description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
239000010941 cobalt Substances 0.000 claims 1
229910017052 cobalt Inorganic materials 0.000 claims 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
239000000314 lubricant Substances 0.000 abstract description 10
229930195733 hydrocarbon Natural products 0.000 description 22
239000004215 Carbon black (E152) Substances 0.000 description 21
150000002430 hydrocarbons Chemical class 0.000 description 19
239000003795 chemical substances by application Substances 0.000 description 13
150000007513 acids Chemical class 0.000 description 12
239000000463 material Substances 0.000 description 11
239000000295 fuel oil Substances 0.000 description 8
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125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 8
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
239000003963 antioxidant agent Substances 0.000 description 6
229910052799 carbon Inorganic materials 0.000 description 6
150000002500 ions Chemical class 0.000 description 6
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238000013019 agitation Methods 0.000 description 4
125000000217 alkyl group Chemical group 0.000 description 4
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238000006243 chemical reaction Methods 0.000 description 4
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
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NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 3
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
150000001412 amines Chemical class 0.000 description 3
239000003849 aromatic solvent Substances 0.000 description 3
125000003118 aryl group Chemical group 0.000 description 3
235000010354 butylated hydroxytoluene Nutrition 0.000 description 3
238000002485 combustion reaction Methods 0.000 description 3
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235000014113 dietary fatty acids Nutrition 0.000 description 3
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239000000194 fatty acid Substances 0.000 description 3
150000004665 fatty acids Chemical class 0.000 description 3
150000002440 hydroxy compounds Chemical class 0.000 description 3
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229910052698 phosphorus Inorganic materials 0.000 description 3
239000011574 phosphorus Substances 0.000 description 3
239000000243 solution Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
235000011044 succinic acid Nutrition 0.000 description 3
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229910052717 sulfur Chemical group 0.000 description 3
239000011593 sulfur Chemical group 0.000 description 3
238000011282 treatment Methods 0.000 description 3
FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 2
GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 2
IKEHOXWJQXIQAG-UHFFFAOYSA-N 2-tert-butyl-4-methylphenol Chemical compound CC1=CC=C(O)C(C(C)(C)C)=C1 IKEHOXWJQXIQAG-UHFFFAOYSA-N 0.000 description 2
MDWVSAYEQPLWMX-UHFFFAOYSA-N 4,4'-Methylenebis(2,6-di-tert-butylphenol) Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 MDWVSAYEQPLWMX-UHFFFAOYSA-N 0.000 description 2
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
241001441571 Hiodontidae Species 0.000 description 2
230000002152 alkylating effect Effects 0.000 description 2
125000002947 alkylene group Chemical group 0.000 description 2
150000008064 anhydrides Chemical class 0.000 description 2
230000003078 antioxidant effect Effects 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
239000012752 auxiliary agent Substances 0.000 description 2
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FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 2
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150000007942 carboxylates Chemical class 0.000 description 2
238000005260 corrosion Methods 0.000 description 2
150000001991 dicarboxylic acids Chemical class 0.000 description 2
125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 2
125000001183 hydrocarbyl group Chemical group 0.000 description 2
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239000003879 lubricant additive Substances 0.000 description 2
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
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229940014800 succinic anhydride Drugs 0.000 description 2
VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
PFEFOYRSMXVNEL-UHFFFAOYSA-N 2,4,6-tritert-butylphenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 PFEFOYRSMXVNEL-UHFFFAOYSA-N 0.000 description 1
OPLCSTZDXXUYDU-UHFFFAOYSA-N 2,4-dimethyl-6-tert-butylphenol Chemical compound CC1=CC(C)=C(O)C(C(C)(C)C)=C1 OPLCSTZDXXUYDU-UHFFFAOYSA-N 0.000 description 1
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KEGGEHPMMDYTGB-UHFFFAOYSA-N 2,6-Diisopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(C)C(C(C)C)=C1O KEGGEHPMMDYTGB-UHFFFAOYSA-N 0.000 description 1
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239000004094 surface-active agent Substances 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
HLCHESOMJVGDSJ-UHFFFAOYSA-N thiq Chemical group C1=CC(Cl)=CC=C1CC(C(=O)N1CCC(CN2N=CN=C2)(CC1)C1CCCCC1)NC(=O)C1NCC2=CC=CC=C2C1 HLCHESOMJVGDSJ-UHFFFAOYSA-N 0.000 description 1
230000007704 transition Effects 0.000 description 1
150000003628 tricarboxylic acids Chemical class 0.000 description 1
150000004670 unsaturated fatty acids Chemical class 0.000 description 1
235000021122 unsaturated fatty acids Nutrition 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
239000002966 varnish Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000002023 wood Substances 0.000 description 1

Landscapes

Liquid Carbonaceous Fuels (AREA)
Lubricants (AREA)

CA000422950A 1982-03-11 1983-03-04 Combinaisons de sel organique de metal de transition/detergent-dispersant sans cendres/ antioxydant phenolique Expired CA1189307A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US35734882A	1982-03-11	1982-03-11
US357,348		1982-03-11

Publications (1)

Publication Number	Publication Date
CA1189307A true CA1189307A (fr)	1985-06-25

Family

ID=23405228

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000422950A Expired CA1189307A (fr)	1982-03-11	1983-03-04	Combinaisons de sel organique de metal de transition/detergent-dispersant sans cendres/ antioxydant phenolique

Country Status (1)

Country	Link
CA (1)	CA1189307A (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AU578726B2 (en) *	1984-08-30	1988-11-03	Lubrizol Corporation, The	Organo transition metal/ashless detergent-dispersant/ phenolic anti-oxidant combinations
US5013467A (en) *	1987-09-16	1991-05-07	Exxon Chemical Patents Inc.	Novel oleaginous composition additives for improved rust inhibition
US5021173A (en) *	1988-02-26	1991-06-04	Exxon Chemical Patents, Inc.	Friction modified oleaginous concentrates of improved stability
US5439604A (en) *	1986-12-12	1995-08-08	Exxon Chemical Patents Inc.	Oil soluble additives useful in oleaginous compositions

1983
- 1983-03-04 CA CA000422950A patent/CA1189307A/fr not_active Expired

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AU578726B2 (en) *	1984-08-30	1988-11-03	Lubrizol Corporation, The	Organo transition metal/ashless detergent-dispersant/ phenolic anti-oxidant combinations
US5439604A (en) *	1986-12-12	1995-08-08	Exxon Chemical Patents Inc.	Oil soluble additives useful in oleaginous compositions
US5013467A (en) *	1987-09-16	1991-05-07	Exxon Chemical Patents Inc.	Novel oleaginous composition additives for improved rust inhibition
US5021173A (en) *	1988-02-26	1991-06-04	Exxon Chemical Patents, Inc.	Friction modified oleaginous concentrates of improved stability
US5282991A (en) *	1988-02-26	1994-02-01	Exxon Chemical Patents Inc.	Friction modified oleaginous concentrates of improved stability

Legal Events

Date	Code	Title	Description
2002-06-26	MKEC	Expiry (correction)
2003-03-04	MKEX	Expiry

Publication	Publication Date	Title
US4505718A (en)	1985-03-19	Organo transition metal salt/ashless detergent-dispersant combinations
US6156082A (en)	2000-12-05	Fuel additives
KR100422030B1 (ko)	2004-05-17	연료유조성물
US5207939A (en)	1993-05-04	Dihydrocarbyl substituted phenylenediamine-derived phenolic products as antioxidants
US2548347A (en)	1951-04-10	Fuel oil composition
EP0290534B1 (fr)	1990-12-19	Additif pour carburant, constitue d'un sel metallique et stabilise avec un thiadiazole
US2575003A (en)	1951-11-13	Fuel oil composition
JPS61500122A (ja)	1986-01-23	マンガン及び銅を含有する組成物
US4720350A (en)	1988-01-19	Oxidation and corrosion inhibiting additives for railway diesel crankcase lubricants
CA2010183A1 (fr)	1990-09-02	Distillat moyen a stabilite au stockage amelioree
US20050223627A1 (en)	2005-10-13	Additive for improving the thermal stability of hydrocarbon compositions
CA1189307A (fr)	1985-06-25	Combinaisons de sel organique de metal de transition/detergent-dispersant sans cendres/ antioxydant phenolique
JP2020164826A (ja)	2020-10-08	燃料油組成物
EP0780460B1 (fr)	2001-06-27	Concentré additif pour essence
UA52704C2 (uk)	2003-01-15	Важкі масла з покращеними властивостями і добавка до них
EP0391735B1 (fr)	1995-08-16	Compositions d'huiles combustibles
EP0388236B1 (fr)	1993-11-24	Compositions d'huile combustible
JPH01502990A (ja)	1989-10-12	改良燃料油組成物
JPS6164792A (ja)	1986-04-03	有機遷移金属塩／無灰清浄剤‐分散剤／フエノール性酸化防止剤組成物
CA1191833A (fr)	1985-08-13	Combinaison d'un sel metallique d'acide organique et d'un additif dispersant-detergent sans cendre
GB2261441A (en)	1993-05-19	Fuel compositions
JPS6028494A (ja)	1985-02-13	炭化水素可溶性組成物、燃料組成物および添加剤濃縮物
EP0117328A1 (fr)	1984-09-05	Combustibles liquides contenant des inhibiteurs de corrosion, et concentrés d'inhibiteurs
EP0385778A1 (fr)	1990-09-05	Compositions d'huile combustible
CZ5707U1 (cs)	1997-02-11	Ekologické palivo pro vznětové motory s vysokým stupněm biologické odbourá· telnosti