CA1192009A - Methode de defibrage de la lignocellulose avec intervention d'un compose de phenazine - Google Patents

Methode de defibrage de la lignocellulose avec intervention d'un compose de phenazine

Info

Publication number: CA1192009A
Authority: CA; Canada
Prior art keywords: amino; process according; hydrogen; phenazine; group
Prior art date: 1977-11-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000315209A

Other languages

English (en)

Inventor

Sven G. Lindenfors

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mo och Domsjo AB

Original Assignee

Mo och Domsjo AB

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-11-04

Filing date

1978-10-31

Publication date

1985-08-20

1978-10-31 Application filed by Mo och Domsjo AB filed Critical Mo och Domsjo AB

1985-08-20 Application granted granted Critical

1985-08-20 Publication of CA1192009A publication Critical patent/CA1192009A/fr

Status Expired legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 61
239000012978 lignocellulosic material Substances 0.000 title claims abstract description 20
125000001791 phenazinyl group Chemical class C1(=CC=CC2=NC3=CC=CC=C3N=C12)* 0.000 title claims abstract description 14
PCNDJXKNXGMECE-UHFFFAOYSA-N phenazine Chemical class C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 claims abstract description 25
229920002678 cellulose Polymers 0.000 claims abstract description 20
239000001913 cellulose Substances 0.000 claims abstract description 19
150000001875 compounds Chemical class 0.000 claims abstract description 16
229920005610 lignin Polymers 0.000 claims abstract description 14
238000004090 dissolution Methods 0.000 claims abstract description 5
230000029087 digestion Effects 0.000 claims description 48
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 42
239000002023 wood Substances 0.000 claims description 40
239000001257 hydrogen Substances 0.000 claims description 33
229910052739 hydrogen Inorganic materials 0.000 claims description 33
-1 phenoxy, amino Chemical group 0.000 claims description 33
125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 29
125000004432 carbon atom Chemical group C* 0.000 claims description 25
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 22
150000004820 halides Chemical group 0.000 claims description 20
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical group OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 19
VEPOHXYIFQMVHW-XOZOLZJESA-N 2,3-dihydroxybutanedioic acid (2S,3S)-3,4-dimethyl-2-phenylmorpholine Chemical compound OC(C(O)C(O)=O)C(O)=O.C[C@H]1[C@@H](OCCN1C)c1ccccc1 VEPOHXYIFQMVHW-XOZOLZJESA-N 0.000 claims description 17
239000003513 alkali Substances 0.000 claims description 16
125000003368 amide group Chemical group 0.000 claims description 15
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 15
238000004537 pulping Methods 0.000 claims description 14
125000003282 alkyl amino group Chemical group 0.000 claims description 13
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
125000003118 aryl group Chemical group 0.000 claims description 12
125000000623 heterocyclic group Chemical group 0.000 claims description 12
150000002988 phenazines Chemical class 0.000 claims description 11
125000001424 substituent group Chemical group 0.000 claims description 11
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 10
125000001931 aliphatic group Chemical group 0.000 claims description 10
125000003545 alkoxy group Chemical group 0.000 claims description 10
229910052736 halogen Inorganic materials 0.000 claims description 10
150000002367 halogens Chemical group 0.000 claims description 10
239000000126 substance Substances 0.000 claims description 10
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 9
125000002877 alkyl aryl group Chemical group 0.000 claims description 9
IQZPDFORWZTSKT-UHFFFAOYSA-N nitrosulphonic acid Chemical group OS(=O)(=O)[N+]([O-])=O IQZPDFORWZTSKT-UHFFFAOYSA-N 0.000 claims description 9
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 9
150000003839 salts Chemical class 0.000 claims description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 8
125000000217 alkyl group Chemical group 0.000 claims description 8
238000010411 cooking Methods 0.000 claims description 7
238000004519 manufacturing process Methods 0.000 claims description 7
239000000463 material Substances 0.000 claims description 7
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 claims description 6
150000001338 aliphatic hydrocarbons Chemical group 0.000 claims description 6
150000001450 anions Chemical class 0.000 claims description 6
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
239000002585 base Substances 0.000 claims description 6
239000001301 oxygen Substances 0.000 claims description 6
229910052760 oxygen Inorganic materials 0.000 claims description 6
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 5
239000004215 Carbon black (E152) Substances 0.000 claims description 5
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
125000002723 alicyclic group Chemical group 0.000 claims description 5
125000005605 benzo group Chemical group 0.000 claims description 5
125000004122 cyclic group Chemical group 0.000 claims description 5
229930195733 hydrocarbon Natural products 0.000 claims description 5
239000000203 mixture Substances 0.000 claims description 5
239000003265 pulping liquor Substances 0.000 claims description 5
125000001453 quaternary ammonium group Chemical group 0.000 claims description 5
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 4
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 4
BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 claims description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
FEWJPZIEWOKRBE-JCYAYHJZSA-L L-tartrate(2-) Chemical compound [O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O FEWJPZIEWOKRBE-JCYAYHJZSA-L 0.000 claims description 4
229910002651 NO3 Inorganic materials 0.000 claims description 4
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 4
IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 4
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 4
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 4
229920001131 Pulp (paper) Polymers 0.000 claims description 4
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 4
ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 claims description 4
150000001449 anionic compounds Chemical group 0.000 claims description 4
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 4
239000003795 chemical substances by application Substances 0.000 claims description 4
NZNMSOFKMUBTKW-UHFFFAOYSA-N cyclohexanecarboxylic acid Chemical compound OC(=O)C1CCCCC1 NZNMSOFKMUBTKW-UHFFFAOYSA-N 0.000 claims description 4
125000005842 heteroatom Chemical group 0.000 claims description 4
ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 claims description 4
229940049920 malate Drugs 0.000 claims description 4
BJEPYKJPYRNKOW-UHFFFAOYSA-L malate(2-) Chemical compound [O-]C(=O)C(O)CC([O-])=O BJEPYKJPYRNKOW-UHFFFAOYSA-L 0.000 claims description 4
229910052757 nitrogen Inorganic materials 0.000 claims description 4
150000002891 organic anions Chemical group 0.000 claims description 4
229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 4
229910052717 sulfur Inorganic materials 0.000 claims description 4
239000011593 sulfur Substances 0.000 claims description 4
229940095064 tartrate Drugs 0.000 claims description 4
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 3
229920003043 Cellulose fiber Polymers 0.000 claims description 3
229910052783 alkali metal Inorganic materials 0.000 claims description 3
150000008044 alkali metal hydroxides Chemical class 0.000 claims description 3
125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
229910001413 alkali metal ion Inorganic materials 0.000 claims description 2
125000004103 aminoalkyl group Chemical group 0.000 claims description 2
125000001769 aryl amino group Chemical group 0.000 claims description 2
YUFRAQHYKKPYLH-UHFFFAOYSA-N benzo[f]quinoxaline Chemical compound C1=CN=C2C3=CC=CC=C3C=CC2=N1 YUFRAQHYKKPYLH-UHFFFAOYSA-N 0.000 claims description 2
150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
239000004627 regenerated cellulose Substances 0.000 claims description 2
HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 claims description 2
HYHCSLBZRBJJCH-UHFFFAOYSA-N sodium polysulfide Chemical compound [Na+].S HYHCSLBZRBJJCH-UHFFFAOYSA-N 0.000 claims description 2
229910052979 sodium sulfide Inorganic materials 0.000 claims description 2
GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims description 2
235000010265 sodium sulphite Nutrition 0.000 claims description 2
125000003107 substituted aryl group Chemical group 0.000 claims description 2
150000002431 hydrogen Chemical group 0.000 claims 14
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims 2
XSCHRSMBECNVNS-UHFFFAOYSA-N quinoxaline Chemical compound N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 claims 2
PVTXJGJDOHYFOX-UHFFFAOYSA-N 2h-1,4-benzoxazine Chemical compound C1=CC=C2N=CCOC2=C1 PVTXJGJDOHYFOX-UHFFFAOYSA-N 0.000 claims 1
RXXCIBALSKQCAE-UHFFFAOYSA-N 3-methylbutoxymethylbenzene Chemical compound CC(C)CCOCC1=CC=CC=C1 RXXCIBALSKQCAE-UHFFFAOYSA-N 0.000 claims 1
FVHXGJPHXHNQTA-UHFFFAOYSA-N N1=CC=NC=2C=CC3=C(C12)C=CC=C3.N3=CC=NC1=CC=CC=C31 Chemical compound N1=CC=NC=2C=CC3=C(C12)C=CC=C3.N3=CC=NC1=CC=CC=C31 FVHXGJPHXHNQTA-UHFFFAOYSA-N 0.000 claims 1
229910001854 alkali hydroxide Inorganic materials 0.000 claims 1
150000001412 amines Chemical class 0.000 claims 1
238000010936 aqueous wash Methods 0.000 claims 1
229910000027 potassium carbonate Inorganic materials 0.000 claims 1
239000007787 solid Substances 0.000 description 10
239000000654 additive Substances 0.000 description 9
DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 description 8
235000008331 Pinus X rigitaeda Nutrition 0.000 description 7
241000018646 Pinus brutia Species 0.000 description 7
235000011613 Pinus brutia Nutrition 0.000 description 7
UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 6
230000000996 additive effect Effects 0.000 description 6
238000010438 heat treatment Methods 0.000 description 6
125000000542 sulfonic acid group Chemical group 0.000 description 6
235000018185 Betula X alpestris Nutrition 0.000 description 5
235000018212 Betula X uliginosa Nutrition 0.000 description 5
238000006243 chemical reaction Methods 0.000 description 5
230000000875 corresponding effect Effects 0.000 description 5
230000007423 decrease Effects 0.000 description 5
230000000694 effects Effects 0.000 description 5
239000007788 liquid Substances 0.000 description 5
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
239000002253 acid Substances 0.000 description 4
239000000835 fiber Substances 0.000 description 4
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 4
238000012216 screening Methods 0.000 description 4
229910052708 sodium Inorganic materials 0.000 description 4
239000011734 sodium Substances 0.000 description 4
230000015556 catabolic process Effects 0.000 description 3
238000006731 degradation reaction Methods 0.000 description 3
239000012634 fragment Substances 0.000 description 3
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 3
239000003112 inhibitor Substances 0.000 description 3
125000000468 ketone group Chemical group 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
230000035484 reaction time Effects 0.000 description 3
239000002699 waste material Substances 0.000 description 3
JAJIPIAHCFBEPI-UHFFFAOYSA-N 9,10-dioxoanthracene-1-sulfonic acid Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2S(=O)(=O)O JAJIPIAHCFBEPI-UHFFFAOYSA-N 0.000 description 2
240000000731 Fagus sylvatica Species 0.000 description 2
235000010099 Fagus sylvatica Nutrition 0.000 description 2
229920002488 Hemicellulose Polymers 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 description 2
241000218657 Picea Species 0.000 description 2
244000305267 Quercus macrolepis Species 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
238000007792 addition Methods 0.000 description 2
238000003915 air pollution Methods 0.000 description 2
PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 2
150000004056 anthraquinones Chemical class 0.000 description 2
238000010923 batch production Methods 0.000 description 2
238000004061 bleaching Methods 0.000 description 2
238000007664 blowing Methods 0.000 description 2
125000002837 carbocyclic group Chemical group 0.000 description 2
OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
OGNVQLDIPUXYDH-ZPKKHLQPSA-N (2R,3R,4S)-3-(2-methylpropanoylamino)-4-(4-phenyltriazol-1-yl)-2-[(1R,2R)-1,2,3-trihydroxypropyl]-3,4-dihydro-2H-pyran-6-carboxylic acid Chemical compound CC(C)C(=O)N[C@H]1[C@H]([C@H](O)[C@H](O)CO)OC(C(O)=O)=C[C@@H]1N1N=NC(C=2C=CC=CC=2)=C1 OGNVQLDIPUXYDH-ZPKKHLQPSA-N 0.000 description 1
HXMGWECMEAEGBY-UHFFFAOYSA-N 8-aminophenazin-2-ol Chemical compound NC1=CC=C2N=C3C=CC(=CC3=NC2=C1)O HXMGWECMEAEGBY-UHFFFAOYSA-N 0.000 description 1
RZVHIXYEVGDQDX-UHFFFAOYSA-N 9,10-anthraquinone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 RZVHIXYEVGDQDX-UHFFFAOYSA-N 0.000 description 1
244000283070 Abies balsamea Species 0.000 description 1
235000007173 Abies balsamea Nutrition 0.000 description 1
241000208140 Acer Species 0.000 description 1
240000004731 Acer pseudoplatanus Species 0.000 description 1
235000002754 Acer pseudoplatanus Nutrition 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
241000219495 Betulaceae Species 0.000 description 1
241000167854 Bourreria succulenta Species 0.000 description 1
241000723418 Carya Species 0.000 description 1
241001070941 Castanea Species 0.000 description 1
235000014036 Castanea Nutrition 0.000 description 1
241000218645 Cedrus Species 0.000 description 1
239000004155 Chlorine dioxide Substances 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
244000166124 Eucalyptus globulus Species 0.000 description 1
HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 description 1
101000657326 Homo sapiens Protein TANC2 Proteins 0.000 description 1
241000721662 Juniperus Species 0.000 description 1
229930194542 Keto Natural products 0.000 description 1
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
235000006485 Platanus occidentalis Nutrition 0.000 description 1
241000219000 Populus Species 0.000 description 1
241000183024 Populus tremula Species 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
102100034784 Protein TANC2 Human genes 0.000 description 1
229920000297 Rayon Polymers 0.000 description 1
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical group C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 description 1
229940022663 acetate Drugs 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
125000000033 alkoxyamino group Chemical group 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
150000001555 benzenes Chemical group 0.000 description 1
239000007844 bleaching agent Substances 0.000 description 1
239000000872 buffer Substances 0.000 description 1
VNWKTOKETHGBQD-AKLPVKDBSA-N carbane Chemical group [15CH4] VNWKTOKETHGBQD-AKLPVKDBSA-N 0.000 description 1
238000009993 causticizing Methods 0.000 description 1
KWBJTBKOXIZLGY-UHFFFAOYSA-N chembl15653 Chemical compound C1=C(O)C=C2N=C(C=C(C(C)=C3)N)C3=NC2=C1 KWBJTBKOXIZLGY-UHFFFAOYSA-N 0.000 description 1
235000019693 cherries Nutrition 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
235000019398 chlorine dioxide Nutrition 0.000 description 1
229910001919 chlorite Inorganic materials 0.000 description 1
229910052619 chlorite group Inorganic materials 0.000 description 1
QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 1
229940001468 citrate Drugs 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
229910001882 dioxygen Inorganic materials 0.000 description 1
238000005265 energy consumption Methods 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
235000013312 flour Nutrition 0.000 description 1
239000008187 granular material Substances 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
239000011121 hardwood Substances 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
229910003002 lithium salt Inorganic materials 0.000 description 1
159000000002 lithium salts Chemical class 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
239000011572 manganese Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
244000005700 microbiome Species 0.000 description 1
XONPDZSGENTBNJ-UHFFFAOYSA-N molecular hydrogen;sodium Chemical compound [Na].[H][H] XONPDZSGENTBNJ-UHFFFAOYSA-N 0.000 description 1
229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
235000019796 monopotassium phosphate Nutrition 0.000 description 1
HYWYRSMBCFDLJT-UHFFFAOYSA-N nimesulide Chemical compound CS(=O)(=O)NC1=CC=C([N+]([O-])=O)C=C1OC1=CC=CC=C1 HYWYRSMBCFDLJT-UHFFFAOYSA-N 0.000 description 1
229960000965 nimesulide Drugs 0.000 description 1
125000004433 nitrogen atom Chemical group N* 0.000 description 1
239000006259 organic additive Substances 0.000 description 1
229940039748 oxalate Drugs 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000002245 particle Substances 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
239000004033 plastic Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
230000007096 poisonous effect Effects 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
235000015497 potassium bicarbonate Nutrition 0.000 description 1
229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
239000011736 potassium bicarbonate Substances 0.000 description 1
TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
235000019252 potassium sulphite Nutrition 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
238000005086 pumping Methods 0.000 description 1
238000005956 quaternization reaction Methods 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
230000002441 reversible effect Effects 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
239000011122 softwood Substances 0.000 description 1
241000894007 species Species 0.000 description 1
238000003756 stirring Methods 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/22—Other features of pulping processes
- D21C3/222—Use of compounds accelerating the pulping processes

Landscapes

Paper (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)

CA000315209A 1977-11-04 1978-10-31 Methode de defibrage de la lignocellulose avec intervention d'un compose de phenazine Expired CA1192009A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
SE7712486A SE408718B (sv)	1977-11-04	1977-11-04	Anvendning av heterocykliska foreningar som utbyteshojande tillsatsmedel vid delignifiering
SE7712486-5		1977-11-04

Publications (1)

Publication Number	Publication Date
CA1192009A true CA1192009A (fr)	1985-08-20

Family

ID=20332783

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000315209A Expired CA1192009A (fr)	1977-11-04	1978-10-31	Methode de defibrage de la lignocellulose avec intervention d'un compose de phenazine

Country Status (3)

Country	Link
CA (1)	CA1192009A (fr)
FI (1)	FI783336A7 (fr)
SE (1)	SE408718B (fr)

1977
- 1977-11-04 SE SE7712486A patent/SE408718B/sv not_active IP Right Cessation
1978
- 1978-10-31 CA CA000315209A patent/CA1192009A/fr not_active Expired
- 1978-11-01 FI FI783336A patent/FI783336A7/fi unknown

Also Published As

Publication number	Publication date
SE7712486L (sv)	1979-05-05
FI783336A7 (fi)	1979-05-05
SE408718B (sv)	1979-07-02

Legal Events

Date	Code	Title	Description
2002-08-20	MKEX	Expiry

Publication	Publication Date	Title
US5595628A (en)	1997-01-21	Production of pulp by the soda-anthraquinone process (SAP) with recovery of the cooking chemicals
US3944463A (en)	1976-03-16	Pulping of lignocellulosic material with oxygen in two stages at increasing pH
US5529663A (en)	1996-06-25	Delignification of lignocellulosic materials with peroxymonophosphoric acid
US5004523A (en)	1991-04-02	Delignification of lignocellulosic materials with monoperoxysulfuric acid
CA1110412A (fr)	1981-10-13	Obtention de pates a l'aide d'une solution alcaline renfermant une cetone cyclique et une amine
BRPI0618527A2 (pt)	2011-09-06	uma nova polpa celulósica e processo para polpação
US4113553A (en)	1978-09-12	Sodium sulfide pulping with hydrogen sulfide generation
US5385641A (en)	1995-01-31	Delignification of cellulosic raw materials using acetic acid, nitric acid and ozone
CA1192009A (fr)	1985-08-20	Methode de defibrage de la lignocellulose avec intervention d'un compose de phenazine
US5785811A (en)	1998-07-28	Process for treating lignocellulosic material with soybean peroxidase in the presence of peroxide
FI68868B (fi)	1985-07-31	Foerfarande foer framstaellning av pappersmassa
US3645840A (en)	1972-02-29	Method for peroxide bleaching of pulp
US3795574A (en)	1974-03-05	Impregnation of wood with a formaldehyde free alkaline solution of sodium hydroxide at a ph between 12.4 and 13
US3773611A (en)	1973-11-20	Two-stage sodium sulfite-oxygen pulping
US4750973A (en)	1988-06-14	Process for reducing carbohydrate losses in the sulfate pulping of wood by pretreating the wood with oxygen and nitrogen oxides
US3663358A (en)	1972-05-16	A METHOD FOR INCREASING BISULFITE PULP YIELD COMPRISING TREATING LIGNOCELLULOSIC MATERIAL WITH CYANIDE IONS AT A pH OF 7{14 12 PRIOR TO DIGESTION
US4134787A (en)	1979-01-16	Delignification of lignocellulosic material with an alkaline liquor containing a cyclic amino compound
DE4107357C1 (fr)	1992-11-05
CA1094264A (fr)	1981-01-27	Delignification de materiel lignocellulosique par une liqueur a la soude contenant un compose cyclique du type ceto- et un compose nitroaromatique
JP2003522844A (ja)	2003-07-29	パルプ化方法
SU1509468A1 (ru)	1989-09-23	Способ облагораживани целлюлозы
US4451333A (en)	1984-05-29	Process for cooking lignocellulosic materials intended for the production of paper pulp with 1,2,3,4-tetrahydro-9,10-anthracenediol
CA1309562C (fr)	1992-11-03	Procede chimio-mecanique de fabrication de pate a papier utilisant du carbonate de sodium et du sulfite de sodium
US3929559A (en)	1975-12-30	Stabilization of cellulosic material by treatment with ferricyanide ion
CA1229334A (fr)	1987-11-17	Fractionnement de la biomasse