CA1195645A - Chromage par electrodeposition rapide - Google Patents
Chromage par electrodeposition rapideInfo
- Publication number
- CA1195645A CA1195645A CA000394931A CA394931A CA1195645A CA 1195645 A CA1195645 A CA 1195645A CA 000394931 A CA000394931 A CA 000394931A CA 394931 A CA394931 A CA 394931A CA 1195645 A CA1195645 A CA 1195645A
- Authority
- CA
- Canada
- Prior art keywords
- chromium
- cathode
- iron
- ions
- nickel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000007747 plating Methods 0.000 title claims abstract description 29
- 229910000599 Cr alloy Inorganic materials 0.000 title claims abstract description 19
- 239000000788 chromium alloy Substances 0.000 title claims abstract description 19
- 239000011651 chromium Substances 0.000 claims abstract description 52
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 48
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 47
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 42
- 238000000576 coating method Methods 0.000 claims abstract description 24
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 20
- 239000010941 cobalt Substances 0.000 claims abstract description 8
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 56
- 229910052742 iron Inorganic materials 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 19
- 239000002253 acid Substances 0.000 claims description 14
- 238000004070 electrodeposition Methods 0.000 claims description 8
- 150000001450 anions Chemical class 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 claims description 7
- -1 iron ions Chemical class 0.000 claims description 6
- 229910021645 metal ion Inorganic materials 0.000 claims description 6
- 229910001430 chromium ion Inorganic materials 0.000 claims description 5
- 230000000536 complexating effect Effects 0.000 claims description 4
- 229910001453 nickel ion Inorganic materials 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 3
- 235000010338 boric acid Nutrition 0.000 claims description 3
- 125000005619 boric acid group Chemical class 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 235000011007 phosphoric acid Nutrition 0.000 claims description 3
- 235000011167 hydrochloric acid Nutrition 0.000 claims description 2
- 230000005012 migration Effects 0.000 claims description 2
- 238000013508 migration Methods 0.000 claims description 2
- 238000005275 alloying Methods 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 230000002401 inhibitory effect Effects 0.000 claims 1
- UPHIPHFJVNKLMR-UHFFFAOYSA-N chromium iron Chemical compound [Cr].[Fe] UPHIPHFJVNKLMR-UHFFFAOYSA-N 0.000 abstract description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052802 copper Inorganic materials 0.000 abstract description 4
- 239000010949 copper Substances 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 4
- 229910000640 Fe alloy Inorganic materials 0.000 abstract description 2
- 229940107218 chromium Drugs 0.000 description 43
- 235000012721 chromium Nutrition 0.000 description 42
- 239000000243 solution Substances 0.000 description 27
- 229910045601 alloy Inorganic materials 0.000 description 22
- 239000000956 alloy Substances 0.000 description 22
- 239000000203 mixture Substances 0.000 description 16
- 239000003792 electrolyte Substances 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 238000000151 deposition Methods 0.000 description 9
- 206010001497 Agitation Diseases 0.000 description 8
- 238000013019 agitation Methods 0.000 description 8
- 230000008021 deposition Effects 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000001464 adherent effect Effects 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 239000008151 electrolyte solution Substances 0.000 description 4
- 229940021013 electrolyte solution Drugs 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000004448 titration Methods 0.000 description 3
- 239000010963 304 stainless steel Substances 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 2
- 229910017060 Fe Cr Inorganic materials 0.000 description 2
- 229910002544 Fe-Cr Inorganic materials 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 229910000589 SAE 304 stainless steel Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 239000010951 brass Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 2
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 235000002908 manganese Nutrition 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 241000861718 Chloris <Aves> Species 0.000 description 1
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- SHKRVHDCIPIPIN-UHFFFAOYSA-H [Cl-].[Cl-].[Cl-].[Cr+3].Cl[Cr](Cl)Cl Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3].Cl[Cr](Cl)Cl SHKRVHDCIPIPIN-UHFFFAOYSA-H 0.000 description 1
- NOGBENJVEVQHKG-UHFFFAOYSA-K [Cr+3].NS([O-])(=O)=O.NS([O-])(=O)=O.NS([O-])(=O)=O Chemical compound [Cr+3].NS([O-])(=O)=O.NS([O-])(=O)=O.NS([O-])(=O)=O NOGBENJVEVQHKG-UHFFFAOYSA-K 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- OXSWKJLAKXNIFG-UHFFFAOYSA-N azane sulfuric acid Chemical compound N.N.N.OS(O)(=O)=O OXSWKJLAKXNIFG-UHFFFAOYSA-N 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- GHXRKGHKMRZBJH-UHFFFAOYSA-N boric acid Chemical compound OB(O)O.OB(O)O GHXRKGHKMRZBJH-UHFFFAOYSA-N 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- BIJOYKCOMBZXAE-UHFFFAOYSA-N chromium iron nickel Chemical compound [Cr].[Fe].[Ni] BIJOYKCOMBZXAE-UHFFFAOYSA-N 0.000 description 1
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 229910001429 cobalt ion Inorganic materials 0.000 description 1
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910000358 iron sulfate Inorganic materials 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 210000004379 membrane Anatomy 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- LVIYYTJTOKJJOC-UHFFFAOYSA-N nickel phthalocyanine Chemical compound [Ni+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 LVIYYTJTOKJJOC-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-M sulfamate Chemical compound NS([O-])(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-M 0.000 description 1
- 230000007723 transport mechanism Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/04—Electroplating with moving electrodes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Electroplating Methods And Accessories (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US24166381A | 1981-03-09 | 1981-03-09 | |
| US241,663 | 1981-03-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1195645A true CA1195645A (fr) | 1985-10-22 |
Family
ID=22911661
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000394931A Expired CA1195645A (fr) | 1981-03-09 | 1982-01-26 | Chromage par electrodeposition rapide |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0073221B1 (fr) |
| JP (1) | JPS58500253A (fr) |
| CA (1) | CA1195645A (fr) |
| DE (1) | DE3268722D1 (fr) |
| WO (1) | WO1982003095A1 (fr) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8409073D0 (en) * | 1984-04-07 | 1984-05-16 | Inter Metals & Minerals Sa | Electrodeposition of chromium &c |
| JPS6156294A (ja) * | 1984-08-27 | 1986-03-20 | Nippon Kokan Kk <Nkk> | クロム合金メツキ浴 |
| JP2002206189A (ja) * | 2000-12-28 | 2002-07-26 | Nippon Platec Co Ltd | 鉄系下地金属へのクロムメッキ方法 |
| CN101410556B (zh) | 2006-03-31 | 2010-12-29 | 爱托特奇德国股份有限公司 | 结晶态功能性铬镀层 |
| FR2901496A1 (fr) * | 2006-05-24 | 2007-11-30 | Fivalec Electronic Sarl | Alliage pour revetir des pieces de soudage et son procede d'obtention |
| BRPI0817924B1 (pt) | 2007-10-02 | 2019-02-12 | Atotech Deutschland Gmbh | Depósito de liga de cromo funcional cristalino eletrodepositado, banho de eletrodeposição para eletrodepositar um depósito de liga de cromo funcional cristalinonanogranular, e processo para eletrodepositar um depósito de liga de cromo cristalino funcional nanogranular em um substrato |
| US7780840B2 (en) * | 2008-10-30 | 2010-08-24 | Trevor Pearson | Process for plating chromium from a trivalent chromium plating bath |
| FI129420B (en) * | 2020-04-23 | 2022-02-15 | Savroc Ltd | AQUATIC ELECTRIC COATING BATH |
| CN111910226A (zh) * | 2020-07-15 | 2020-11-10 | 南昌航空大学 | 一种无裂纹Fe-Cr合金镀层及其制备方法和应用 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2766196A (en) * | 1953-11-09 | 1956-10-09 | Yoshida Tadashi | Process for the electrodeposition of iron-chromium alloys |
| US2990343A (en) * | 1955-02-11 | 1961-06-27 | William H Safranek | Chromium alloy plating |
| US2822326A (en) * | 1955-03-22 | 1958-02-04 | Rockwell Spring & Axle Co | Bright chromium alloy plating |
| US2927066A (en) * | 1955-12-30 | 1960-03-01 | Glenn R Schaer | Chromium alloy plating |
| US2938842A (en) * | 1959-03-16 | 1960-05-31 | Yawata Iron & Steel Co | Electrodeposition of fe-cr alloy |
| GB1482747A (en) * | 1973-10-10 | 1977-08-10 | Bnf Metals Tech Centre | Chromium plating baths |
| GB1455580A (en) * | 1973-12-13 | 1976-11-17 | Albright & Wilson | Electrodeposition of chromium |
| JPS539236A (en) * | 1976-07-13 | 1978-01-27 | Nippon Piston Ring Co Ltd | High speed chromium plating method |
| JPS53106348A (en) * | 1977-02-28 | 1978-09-16 | Toyo Soda Mfg Co Ltd | Electrolytic bath for chromium plating |
| AU513298B2 (en) * | 1978-06-02 | 1980-11-27 | International Lead Zinc Research Organization Inc. | Electrodeposition of black chromium |
-
1982
- 1982-01-21 WO PCT/US1982/000070 patent/WO1982003095A1/fr not_active Ceased
- 1982-01-21 EP EP82900730A patent/EP0073221B1/fr not_active Expired
- 1982-01-21 JP JP57500756A patent/JPS58500253A/ja active Pending
- 1982-01-21 DE DE8282900730T patent/DE3268722D1/de not_active Expired
- 1982-01-26 CA CA000394931A patent/CA1195645A/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| WO1982003095A1 (fr) | 1982-09-16 |
| EP0073221A1 (fr) | 1983-03-09 |
| JPS58500253A (ja) | 1983-02-17 |
| EP0073221B1 (fr) | 1986-01-29 |
| DE3268722D1 (en) | 1986-03-13 |
| EP0073221A4 (fr) | 1983-01-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |