CA1200338A - Composition de revetement a base de resine de silicone adaptee pour adherer sans couche primaire a des substrats de matieres plastiques; methode d'obtention de cette composition - Google Patents

Composition de revetement a base de resine de silicone adaptee pour adherer sans couche primaire a des substrats de matieres plastiques; methode d'obtention de cette composition

Info

Publication number: CA1200338A
Authority: CA; Canada
Prior art keywords: coating composition; silicone resin; prepared according; alkyl; hydrogen
Prior art date: 1983-02-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000420962A

Other languages

English (en)

Inventor

Howard A. Vaughn, Jr.

Ta-Yen Ching

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

General Electric Co

Original Assignee

General Electric Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-02-04

Filing date

1983-02-04

Publication date

1986-02-04

1983-02-04 Application filed by General Electric Co filed Critical General Electric Co

1983-02-04 Priority to CA000420962A priority Critical patent/CA1200338A/fr

1986-02-04 Application granted granted Critical

1986-02-04 Publication of CA1200338A publication Critical patent/CA1200338A/fr

Status Expired legal-status Critical Current

Links

239000008199 coating composition Substances 0.000 title claims abstract description 51
229920002050 silicone resin Polymers 0.000 title claims abstract description 36
229920003023 plastic Polymers 0.000 title claims abstract description 27
239000000758 substrate Substances 0.000 title claims abstract description 26
239000004033 plastic Substances 0.000 title claims abstract description 22
238000000034 method Methods 0.000 title claims description 21
238000012216 screening Methods 0.000 claims abstract description 15
230000005855 radiation Effects 0.000 claims abstract description 14
239000003795 chemical substances by application Substances 0.000 claims abstract description 10
239000000203 mixture Substances 0.000 claims description 44
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 31
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 29
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 22
238000006460 hydrolysis reaction Methods 0.000 claims description 19
239000008119 colloidal silica Substances 0.000 claims description 18
ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 18
229910052739 hydrogen Inorganic materials 0.000 claims description 16
-1 hydroxy, amino, carbethoxy Chemical group 0.000 claims description 16
239000011342 resin composition Substances 0.000 claims description 16
150000001875 compounds Chemical class 0.000 claims description 15
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 14
230000007062 hydrolysis Effects 0.000 claims description 14
239000001257 hydrogen Substances 0.000 claims description 13
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 13
239000007787 solid Substances 0.000 claims description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
229920005989 resin Polymers 0.000 claims description 11
239000011347 resin Substances 0.000 claims description 11
239000002253 acid Substances 0.000 claims description 10
229910052736 halogen Chemical group 0.000 claims description 10
150000002367 halogens Chemical group 0.000 claims description 10
SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 claims description 9
239000006185 dispersion Substances 0.000 claims description 8
230000032683 aging Effects 0.000 claims description 7
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
ZJBHFQKJEBGFNL-UHFFFAOYSA-N methylsilanetriol Chemical compound C[Si](O)(O)O ZJBHFQKJEBGFNL-UHFFFAOYSA-N 0.000 claims description 7
229920000515 polycarbonate Polymers 0.000 claims description 7
239000004417 polycarbonate Substances 0.000 claims description 7
230000002378 acidificating effect Effects 0.000 claims description 6
125000000217 alkyl group Chemical group 0.000 claims description 6
238000002845 discoloration Methods 0.000 claims description 6
125000003545 alkoxy group Chemical group 0.000 claims description 5
125000004432 carbon atom Chemical group C* 0.000 claims description 5
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 5
125000003118 aryl group Chemical group 0.000 claims description 3
239000007795 chemical reaction product Substances 0.000 claims description 3
125000004209 (C1-C8) alkyl group Chemical group 0.000 claims 8
CCGWVKHKHWKOIQ-UHFFFAOYSA-N [2-hydroxy-4-(3-triethoxysilylpropoxy)phenyl]-phenylmethanone Chemical compound OC1=CC(OCCC[Si](OCC)(OCC)OCC)=CC=C1C(=O)C1=CC=CC=C1 CCGWVKHKHWKOIQ-UHFFFAOYSA-N 0.000 claims 2
239000002152 aqueous-organic solution Substances 0.000 claims 2
238000006243 chemical reaction Methods 0.000 claims 2
238000004519 manufacturing process Methods 0.000 claims 1
238000000576 coating method Methods 0.000 abstract description 39
239000011248 coating agent Substances 0.000 abstract description 27
238000005299 abrasion Methods 0.000 abstract description 8
239000011253 protective coating Substances 0.000 abstract 1
239000003054 catalyst Substances 0.000 description 10
229960000583 acetic acid Drugs 0.000 description 8
238000009833 condensation Methods 0.000 description 7
230000005494 condensation Effects 0.000 description 7
239000002904 solvent Substances 0.000 description 7
229920004142 LEXAN™ Polymers 0.000 description 6
239000004418 Lexan Substances 0.000 description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
150000001298 alcohols Chemical class 0.000 description 5
239000011521 glass Substances 0.000 description 5
239000000377 silicon dioxide Substances 0.000 description 5
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 4
DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 4
239000006184 cosolvent Substances 0.000 description 4
239000011541 reaction mixture Substances 0.000 description 4
POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
229910052783 alkali metal Inorganic materials 0.000 description 3
238000013459 approach Methods 0.000 description 3
239000000463 material Substances 0.000 description 3
239000002245 particle Substances 0.000 description 3
229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
229920000642 polymer Polymers 0.000 description 3
229920001296 polysiloxane Polymers 0.000 description 3
238000012360 testing method Methods 0.000 description 3
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
239000004721 Polyphenylene oxide Substances 0.000 description 2
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
TVJPBVNWVPUZBM-UHFFFAOYSA-N [diacetyloxy(methyl)silyl] acetate Chemical compound CC(=O)O[Si](C)(OC(C)=O)OC(C)=O TVJPBVNWVPUZBM-UHFFFAOYSA-N 0.000 description 2
239000006096 absorbing agent Substances 0.000 description 2
239000000654 additive Substances 0.000 description 2
239000000908 ammonium hydroxide Substances 0.000 description 2
239000012736 aqueous medium Substances 0.000 description 2
239000002585 base Substances 0.000 description 2
229910052681 coesite Inorganic materials 0.000 description 2
230000000875 corresponding effect Effects 0.000 description 2
229910052906 cristobalite Inorganic materials 0.000 description 2
SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 2
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
230000003301 hydrolyzing effect Effects 0.000 description 2
238000011065 in-situ storage Methods 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000007791 liquid phase Substances 0.000 description 2
BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 2
229920000570 polyether Polymers 0.000 description 2
239000000047 product Substances 0.000 description 2
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
239000000376 reactant Substances 0.000 description 2
229940089952 silanetriol Drugs 0.000 description 2
235000012239 silicon dioxide Nutrition 0.000 description 2
239000004447 silicone coating Substances 0.000 description 2
229910052682 stishovite Inorganic materials 0.000 description 2
229910052905 tridymite Inorganic materials 0.000 description 2
VVLAIYIMMFWRFW-UHFFFAOYSA-N 2-hydroxyethylazanium;acetate Chemical compound CC(O)=O.NCCO VVLAIYIMMFWRFW-UHFFFAOYSA-N 0.000 description 1
101100126625 Caenorhabditis elegans itr-1 gene Proteins 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
239000004642 Polyimide Substances 0.000 description 1
VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
241000193803 Therea Species 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
ZXQYGBMAQZUVMI-QQDHXZELSA-N [cyano-(3-phenoxyphenyl)methyl] (1r,3r)-3-[(z)-2-chloro-3,3,3-trifluoroprop-1-enyl]-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)[C@@H](\C=C(/Cl)C(F)(F)F)[C@H]1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-QQDHXZELSA-N 0.000 description 1
239000003082 abrasive agent Substances 0.000 description 1
235000011054 acetic acid Nutrition 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
229920006397 acrylic thermoplastic Polymers 0.000 description 1
229920001893 acrylonitrile styrene Polymers 0.000 description 1
230000001464 adherent effect Effects 0.000 description 1
229910001854 alkali hydroxide Inorganic materials 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid group Chemical group C(C1=CC=CC=C1)(=O)O WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
239000012965 benzophenone Substances 0.000 description 1
FWYSSOIRLVHQNC-UHFFFAOYSA-M benzyl(trimethyl)azanium;acetate Chemical compound CC([O-])=O.C[N+](C)(C)CC1=CC=CC=C1 FWYSSOIRLVHQNC-UHFFFAOYSA-M 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
150000004648 butanoic acid derivatives Chemical class 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
150000007942 carboxylates Chemical class 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
QHNXEVRKFKHMRL-UHFFFAOYSA-N dimethylazanium;acetate Chemical compound CNC.CC(O)=O QHNXEVRKFKHMRL-UHFFFAOYSA-N 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
239000000428 dust Substances 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
230000003203 everyday effect Effects 0.000 description 1
239000012467 final product Substances 0.000 description 1
239000000446 fuel Substances 0.000 description 1
239000012362 glacial acetic acid Substances 0.000 description 1
229940093915 gynecological organic acid Drugs 0.000 description 1
239000008131 herbal destillate Substances 0.000 description 1
235000011167 hydrochloric acid Nutrition 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000002609 medium Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
XEDVYYJRECCCNM-UHFFFAOYSA-N n,n-dimethylaniline;formic acid Chemical compound OC=O.CN(C)C1=CC=CC=C1 XEDVYYJRECCCNM-UHFFFAOYSA-N 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
235000006408 oxalic acid Nutrition 0.000 description 1
239000012071 phase Substances 0.000 description 1
239000002798 polar solvent Substances 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920001707 polybutylene terephthalate Polymers 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920000139 polyethylene terephthalate Polymers 0.000 description 1
239000005020 polyethylene terephthalate Substances 0.000 description 1
229920001721 polyimide Polymers 0.000 description 1
239000004926 polymethyl methacrylate Substances 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
WFIZEGIEIOHZCP-UHFFFAOYSA-M potassium formate Chemical compound [K+].[O-]C=O WFIZEGIEIOHZCP-UHFFFAOYSA-M 0.000 description 1
230000037452 priming Effects 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
235000019260 propionic acid Nutrition 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
239000006120 scratch resistant coating Substances 0.000 description 1
238000006748 scratching Methods 0.000 description 1
230000002393 scratching effect Effects 0.000 description 1
230000035939 shock Effects 0.000 description 1
229910000077 silane Inorganic materials 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
150000004819 silanols Chemical class 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
239000001632 sodium acetate Substances 0.000 description 1
235000017281 sodium acetate Nutrition 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
239000001117 sulphuric acid Substances 0.000 description 1
235000011149 sulphuric acid Nutrition 0.000 description 1
229920005613 synthetic organic polymer Polymers 0.000 description 1
230000029305 taxis Effects 0.000 description 1
ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
MRYQZMHVZZSQRT-UHFFFAOYSA-M tetramethylazanium;acetate Chemical compound CC([O-])=O.C[N+](C)(C)C MRYQZMHVZZSQRT-UHFFFAOYSA-M 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
239000012780 transparent material Substances 0.000 description 1
KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1

Landscapes

Paints Or Removers (AREA)

CA000420962A 1983-02-04 1983-02-04 Composition de revetement a base de resine de silicone adaptee pour adherer sans couche primaire a des substrats de matieres plastiques; methode d'obtention de cette composition Expired CA1200338A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000420962A CA1200338A (fr)	1983-02-04	1983-02-04	Composition de revetement a base de resine de silicone adaptee pour adherer sans couche primaire a des substrats de matieres plastiques; methode d'obtention de cette composition

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000420962A CA1200338A (fr)	1983-02-04	1983-02-04	Composition de revetement a base de resine de silicone adaptee pour adherer sans couche primaire a des substrats de matieres plastiques; methode d'obtention de cette composition

Publications (1)

Publication Number	Publication Date
CA1200338A true CA1200338A (fr)	1986-02-04

Family

ID=4124498

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000420962A Expired CA1200338A (fr)	1983-02-04	1983-02-04	Composition de revetement a base de resine de silicone adaptee pour adherer sans couche primaire a des substrats de matieres plastiques; methode d'obtention de cette composition

Country Status (1)

Country	Link
CA (1)	CA1200338A (fr)

1983
- 1983-02-04 CA CA000420962A patent/CA1200338A/fr not_active Expired

Legal Events

Date	Code	Title	Description
2003-02-04	MKEX	Expiry

Publication	Publication Date	Title
US4309319A (en)	1982-01-05	Silicone resin coating composition
CA1164118A (fr)	1984-03-20	Enduit a base de resine de silicone
US4277287A (en)	1981-07-07	Silicone resin coating composition
US4324712A (en)	1982-04-13	Silicone resin coating composition
US4395463A (en)	1983-07-26	Article comprising silicone resin coated, methacrylate-primed substrate
US4373061A (en)	1983-02-08	Silicone coating for unprimed plastic substrate and coated articles
US4624870A (en)	1986-11-25	Sodium free silicone resin coating compositions
US4476281A (en)	1984-10-09	Silicone resin coating composition
US4373060A (en)	1983-02-08	Silicone coating for unprimed plastic substrate and coated articles
US4413088A (en)	1983-11-01	Silicone resin coating composition especially suited for primerless adhesion to cast acrylics
US4368235A (en)	1983-01-11	Silicone resin coating composition
CA1182350A (fr)	1985-02-12	Methode de production de polycarbonates enrobes de silicone, et articles ainsi produits
CA1159991A (fr)	1984-01-03	Enduit a base de resine de silicone
CA1164138A (fr)	1984-03-20	Enduit a base de resine de silicone
US4436851A (en)	1984-03-13	Silicone resin coating composition containing an ultraviolet light absorbing agent
US4367262A (en)	1983-01-04	Solid substrate coated with silicone resin coating composition
US4368236A (en)	1983-01-11	Silicone resin coating compositions
US4313979A (en)	1982-02-02	Method for improving adhesion of silicone resin coating composition
US4783347A (en)	1988-11-08	Method for primerless coating of plastics
US4414349A (en)	1983-11-08	Silicone resin coating composition adapted for primerless adhesion to plastic substrates and process for making same
US4539351A (en)	1985-09-03	Silicone resin coating composition with improved shelf life
US4486503A (en)	1984-12-04	Silicone resin coating composition
CA1156102A (fr)	1983-11-01	Methode de collage, sans agent d'accrochage, d'enduits de resins a base de silicone sur des pieces en acrylique moulee
US4477528A (en)	1984-10-16	Silicone resin coating composition especially suited for primerless adhesion to cast acrylics
CA1164139A (fr)	1984-03-20	Enduits a base de resine de silicone