CA1211245A - Amelioration de la resilience de polyesters thermoplastiques grace a un polyethylene lineaire de faible densite - Google Patents

Amelioration de la resilience de polyesters thermoplastiques grace a un polyethylene lineaire de faible densite

Info

Publication number: CA1211245A
Authority: CA; Canada
Prior art keywords: composition; poly; low density; density polyethylene; linear low
Prior art date: 1984-01-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000445709A

Other languages

English (en)

Inventor

Nan-I Liu

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

General Electric Co

Original Assignee

General Electric Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-01-20

Filing date

1984-01-20

Publication date

1986-09-09

1984-01-20 Application filed by General Electric Co filed Critical General Electric Co

1984-01-20 Priority to CA000445709A priority Critical patent/CA1211245A/fr

1986-09-09 Application granted granted Critical

1986-09-09 Publication of CA1211245A publication Critical patent/CA1211245A/fr

Status Expired legal-status Critical Current

Links

229920000092 linear low density polyethylene Polymers 0.000 title claims abstract description 43
239000004707 linear low-density polyethylene Substances 0.000 title claims abstract description 43
239000004609 Impact Modifier Substances 0.000 title claims abstract description 23
229920000728 polyester Polymers 0.000 title abstract description 28
229920001169 thermoplastic Polymers 0.000 title abstract description 14
239000004416 thermosoftening plastic Substances 0.000 title abstract description 14
239000000203 mixture Substances 0.000 claims abstract description 121
239000003365 glass fiber Substances 0.000 claims abstract description 14
-1 poly(ethylene terephthalate) Polymers 0.000 claims description 49
229920001634 Copolyester Polymers 0.000 claims description 30
229920000642 polymer Polymers 0.000 claims description 23
125000003118 aryl group Chemical group 0.000 claims description 21
239000004417 polycarbonate Substances 0.000 claims description 18
229920000515 polycarbonate Polymers 0.000 claims description 17
229920001577 copolymer Polymers 0.000 claims description 15
125000001931 aliphatic group Chemical group 0.000 claims description 12
125000004432 carbon atom Chemical group C* 0.000 claims description 12
229920000139 polyethylene terephthalate Polymers 0.000 claims description 12
239000005020 polyethylene terephthalate Substances 0.000 claims description 12
239000010445 mica Substances 0.000 claims description 11
229910052618 mica group Inorganic materials 0.000 claims description 11
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 10
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 9
239000005977 Ethylene Substances 0.000 claims description 9
239000003063 flame retardant Substances 0.000 claims description 9
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 8
239000000454 talc Substances 0.000 claims description 8
229910052623 talc Inorganic materials 0.000 claims description 8
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 7
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 6
239000004927 clay Substances 0.000 claims description 6
239000011258 core-shell material Substances 0.000 claims description 6
239000000945 filler Substances 0.000 claims description 6
239000002667 nucleating agent Substances 0.000 claims description 6
239000000654 additive Substances 0.000 claims description 5
150000002334 glycols Chemical class 0.000 claims description 5
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229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 5
229920005668 polycarbonate resin Polymers 0.000 claims description 5
239000004431 polycarbonate resin Substances 0.000 claims description 5
239000004711 α-olefin Substances 0.000 claims description 5
229920000800 acrylic rubber Polymers 0.000 claims description 4
239000005038 ethylene vinyl acetate Substances 0.000 claims description 4
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DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical group C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims description 3
239000003086 colorant Substances 0.000 claims description 3
239000007822 coupling agent Substances 0.000 claims description 3
229920000578 graft copolymer Polymers 0.000 claims description 3
239000003381 stabilizer Substances 0.000 claims description 3
QLZJUIZVJLSNDD-UHFFFAOYSA-N 2-(2-methylidenebutanoyloxy)ethyl 2-methylidenebutanoate Chemical group CCC(=C)C(=O)OCCOC(=O)C(=C)CC QLZJUIZVJLSNDD-UHFFFAOYSA-N 0.000 claims description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
239000005042 ethylene-ethyl acrylate Substances 0.000 claims description 2
238000009757 thermoplastic moulding Methods 0.000 claims description 2
229920006243 acrylic copolymer Polymers 0.000 claims 4
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims 3
229940102838 methylmethacrylate Drugs 0.000 claims 3
239000003340 retarding agent Substances 0.000 claims 3
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims 2
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims 1
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239000002174 Styrene-butadiene Substances 0.000 claims 1
230000000996 additive effect Effects 0.000 claims 1
FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical group C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 claims 1
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims 1
229920006158 high molecular weight polymer Polymers 0.000 claims 1
229920002587 poly(1,3-butadiene) polymer Polymers 0.000 claims 1
239000011115 styrene butadiene Substances 0.000 claims 1
229920003048 styrene butadiene rubber Polymers 0.000 claims 1
229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims 1
239000011521 glass Substances 0.000 description 25
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 20
238000000034 method Methods 0.000 description 14
238000000465 moulding Methods 0.000 description 12
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 11
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 10
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 9
229920005989 resin Polymers 0.000 description 9
239000011347 resin Substances 0.000 description 9
LLLVZDVNHNWSDS-UHFFFAOYSA-N 4-methylidene-3,5-dioxabicyclo[5.2.2]undeca-1(9),7,10-triene-2,6-dione Chemical compound C1(C2=CC=C(C(=O)OC(=C)O1)C=C2)=O LLLVZDVNHNWSDS-UHFFFAOYSA-N 0.000 description 8
239000002253 acid Substances 0.000 description 8
239000003054 catalyst Substances 0.000 description 8
230000000052 comparative effect Effects 0.000 description 7
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BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 6
239000004698 Polyethylene Substances 0.000 description 6
229920003232 aliphatic polyester Polymers 0.000 description 6
230000006872 improvement Effects 0.000 description 6
239000004615 ingredient Substances 0.000 description 6
239000007924 injection Substances 0.000 description 6
230000002787 reinforcement Effects 0.000 description 6
238000001125 extrusion Methods 0.000 description 5
238000010348 incorporation Methods 0.000 description 5
238000002347 injection Methods 0.000 description 5
229920000573 polyethylene Polymers 0.000 description 5
229920006230 thermoplastic polyester resin Polymers 0.000 description 5
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
125000000217 alkyl group Chemical group 0.000 description 4
150000002148 esters Chemical class 0.000 description 4
239000000835 fiber Substances 0.000 description 4
229920001684 low density polyethylene Polymers 0.000 description 4
239000004702 low-density polyethylene Substances 0.000 description 4
229940099514 low-density polyethylene Drugs 0.000 description 4
150000002989 phenols Chemical class 0.000 description 4
230000000704 physical effect Effects 0.000 description 4
230000008569 process Effects 0.000 description 4
230000009467 reduction Effects 0.000 description 4
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
238000007334 copolymerization reaction Methods 0.000 description 3
238000002425 crystallisation Methods 0.000 description 3
230000008025 crystallization Effects 0.000 description 3
230000000694 effects Effects 0.000 description 3
229920001971 elastomer Polymers 0.000 description 3
150000004820 halides Chemical class 0.000 description 3
239000000463 material Substances 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
229920001225 polyester resin Polymers 0.000 description 3
239000004645 polyester resin Substances 0.000 description 3
238000006116 polymerization reaction Methods 0.000 description 3
239000001294 propane Substances 0.000 description 3
229920002554 vinyl polymer Polymers 0.000 description 3
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
WSQZNZLOZXSBHA-UHFFFAOYSA-N 3,8-dioxabicyclo[8.2.2]tetradeca-1(12),10,13-triene-2,9-dione Chemical compound O=C1OCCCCOC(=O)C2=CC=C1C=C2 WSQZNZLOZXSBHA-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
229910014033 C-OH Inorganic materials 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
229910014570 C—OH Inorganic materials 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
229910010199 LiAl Inorganic materials 0.000 description 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
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RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
125000002947 alkylene group Chemical group 0.000 description 2
125000001118 alkylidene group Chemical group 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
238000007664 blowing Methods 0.000 description 2
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
238000013329 compounding Methods 0.000 description 2
238000004132 cross linking Methods 0.000 description 2
238000011161 development Methods 0.000 description 2
150000001991 dicarboxylic acids Chemical class 0.000 description 2
239000000806 elastomer Substances 0.000 description 2
239000012757 flame retardant agent Substances 0.000 description 2
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VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
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DMCTVRQBJMBEDT-UHFFFAOYSA-N phenol;1,1,1,2-tetrachloroethane Chemical compound ClCC(Cl)(Cl)Cl.OC1=CC=CC=C1 DMCTVRQBJMBEDT-UHFFFAOYSA-N 0.000 description 2
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
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CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
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XOJWAAUYNWGQAU-UHFFFAOYSA-N 4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCOC(=O)C(C)=C XOJWAAUYNWGQAU-UHFFFAOYSA-N 0.000 description 1
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239000004215 Carbon black (E152) Substances 0.000 description 1
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239000002243 precursor Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
238000011160 research Methods 0.000 description 1
229910000077 silane Inorganic materials 0.000 description 1
RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
239000000243 solution Substances 0.000 description 1
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
150000003504 terephthalic acids Chemical class 0.000 description 1
229920005992 thermoplastic resin Polymers 0.000 description 1
150000003608 titanium Chemical class 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
239000010936 titanium Substances 0.000 description 1
238000005809 transesterification reaction Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
238000004260 weight control Methods 0.000 description 1
239000004246 zinc acetate Substances 0.000 description 1

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CA000445709A 1984-01-20 1984-01-20 Amelioration de la resilience de polyesters thermoplastiques grace a un polyethylene lineaire de faible densite Expired CA1211245A (fr)

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Application Number	Priority Date	Filing Date	Title
CA000445709A CA1211245A (fr)	1984-01-20	1984-01-20	Amelioration de la resilience de polyesters thermoplastiques grace a un polyethylene lineaire de faible densite

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Application Number	Priority Date	Filing Date	Title
CA000445709A CA1211245A (fr)	1984-01-20	1984-01-20	Amelioration de la resilience de polyesters thermoplastiques grace a un polyethylene lineaire de faible densite

Publications (1)

Publication Number	Publication Date
CA1211245A true CA1211245A (fr)	1986-09-09

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ID=4126991

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CA000445709A Expired CA1211245A (fr)	1984-01-20	1984-01-20	Amelioration de la resilience de polyesters thermoplastiques grace a un polyethylene lineaire de faible densite

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CA (1)	CA1211245A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN115151604A (zh) *	2020-03-09	2022-10-04	索尔维特殊聚合物美国有限责任公司	聚酯组合物和相应的制品

1984
- 1984-01-20 CA CA000445709A patent/CA1211245A/fr not_active Expired

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN115151604A (zh) *	2020-03-09	2022-10-04	索尔维特殊聚合物美国有限责任公司	聚酯组合物和相应的制品

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Date	Code	Title	Description
2004-01-20	MKEX	Expiry

Publication	Publication Date	Title
US4476274A (en)	1984-10-09	Linear low density polyethylene impact modifier for thermoplastic polyesters
CA1263788A (fr)	1989-12-05	Composition de moulage a base de polyester thermoplastique et de polyethylene lineaire de faible densite
US4280949A (en)	1981-07-28	Modified polyester compositions containing mineral filler
EP0020605B1 (fr)	1985-01-09	Compositions polyester modifiees
EP0110222A1 (fr)	1984-06-13	Masses à mouler à base de polyester thermoplastique et de polyéthylène linéaire à basse densité
US4414352A (en)	1983-11-08	Thermoplastic molding compositions and process
EP0020737B1 (fr)	1985-02-13	Compositions de polyesters modifiees
US4239677A (en)	1980-12-16	Modified polyester compositions
US4639481A (en)	1987-01-27	Modified thermoplastic polyester molding compositions and articles molded therefrom
US4271064A (en)	1981-06-02	Modified polyester compositions
US4373067A (en)	1983-02-08	Molded articles of improved impact resistance and compositions therefor
GB2041383A (en)	1980-09-10	Block copolyester compositions
EP0105244A1 (fr)	1984-04-11	Masses à mouler modifiées à base de polyesters thermoplastiques et articles formés à partir de ces masses
US4267286A (en)	1981-05-12	Modified polyester compositions
EP0133993B1 (fr)	1991-06-19	Composition modifiée de polyester
US4322333A (en)	1982-03-30	Reinforced PBT-copolyaromatic/aliphatic block copolyesters
JPH0651835B2 (ja)	1994-07-06	ガラス繊維強化ポリカーボネート／ポリエステル配合物
EP0149192A2 (fr)	1985-07-24	E.P.D.M. époxydé comme modificateur de la résistance aux chocs pour polyester thermoplastique
CA1148291A (fr)	1983-06-14	Compositions thermoplastiques armees pour moulage
US4684686A (en)	1987-08-04	Glass fiber reinforced polyester molding compositions containing metal powders
US4629750A (en)	1986-12-16	Flame retarded polyester resin with improved impact strength
CA1211245A (fr)	1986-09-09	Amelioration de la resilience de polyesters thermoplastiques grace a un polyethylene lineaire de faible densite
EP0027464A1 (fr)	1981-04-29	Composition et procede de moulage thermoplastique
US4369282A (en)	1983-01-18	Modified polyester compositions
EP0020739B1 (fr)	1985-03-13	Compositions de moulage thermoplastique

CA1211245A - Amelioration de la resilience de polyesters thermoplastiques grace a un polyethylene lineaire de faible densite - Google Patents

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Priority Applications (1)

Applications Claiming Priority (1)

Publications (1)

Family

ID=4126991

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Country Status (1)

Cited By (1)

Cited By (1)

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