CA1213550A - Support de catalyseur au zeolite pour le desazotage des charges de petrole brut - Google Patents

Support de catalyseur au zeolite pour le desazotage des charges de petrole brut

Info

Publication number: CA1213550A
Authority: CA; Canada
Prior art keywords: zeolite; zsm; catalyst; alumina; shale oil
Prior art date: 1982-12-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000442215A

Other languages

English (en)

Inventor

Philip J. Angevine

Robert C. Wilson, Jr.

Sadi Mizrahi

Stephen M. Oleck

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mobil Oil AS

Original Assignee

Mobil Oil AS

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-12-28

Filing date

1983-11-29

Publication date

1986-11-04

1983-11-29 Application filed by Mobil Oil AS filed Critical Mobil Oil AS

1986-11-04 Application granted granted Critical

1986-11-04 Publication of CA1213550A publication Critical patent/CA1213550A/fr

Status Expired legal-status Critical Current

Links

239000010457 zeolite Substances 0.000 title claims abstract description 94
239000003054 catalyst Substances 0.000 title claims abstract description 67
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims abstract description 67
229910021536 Zeolite Inorganic materials 0.000 title claims abstract description 58
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 26
239000003079 shale oil Substances 0.000 claims abstract description 25
229910052759 nickel Inorganic materials 0.000 claims abstract description 13
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 9
238000005984 hydrogenation reaction Methods 0.000 claims abstract description 9
229910052750 molybdenum Inorganic materials 0.000 claims abstract description 9
239000011733 molybdenum Substances 0.000 claims abstract description 9
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 42
238000000034 method Methods 0.000 claims description 32
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 30
230000008569 process Effects 0.000 claims description 27
229910052751 metal Inorganic materials 0.000 claims description 25
239000002184 metal Substances 0.000 claims description 25
239000001257 hydrogen Substances 0.000 claims description 23
229910052739 hydrogen Inorganic materials 0.000 claims description 23
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 22
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 18
239000000203 mixture Substances 0.000 claims description 15
239000000377 silicon dioxide Substances 0.000 claims description 14
230000000694 effects Effects 0.000 claims description 9
229910052757 nitrogen Inorganic materials 0.000 claims description 9
230000003197 catalytic effect Effects 0.000 claims description 8
150000002739 metals Chemical class 0.000 claims description 7
229910000323 aluminium silicate Inorganic materials 0.000 claims description 5
229910017052 cobalt Inorganic materials 0.000 claims description 5
239000010941 cobalt Substances 0.000 claims description 5
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
150000003568 thioethers Chemical class 0.000 claims description 4
229910052742 iron Inorganic materials 0.000 claims description 2
229910044991 metal oxide Inorganic materials 0.000 claims description 2
150000004706 metal oxides Chemical class 0.000 claims description 2
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
229910052721 tungsten Inorganic materials 0.000 claims description 2
239000010937 tungsten Substances 0.000 claims description 2
239000013078 crystal Substances 0.000 description 18
238000002441 X-ray diffraction Methods 0.000 description 10
239000011148 porous material Substances 0.000 description 9
150000001768 cations Chemical class 0.000 description 8
229930195733 hydrocarbon Natural products 0.000 description 8
150000002430 hydrocarbons Chemical class 0.000 description 8
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 7
238000001354 calcination Methods 0.000 description 7
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 7
229910052717 sulfur Inorganic materials 0.000 description 7
239000011593 sulfur Substances 0.000 description 7
238000006243 chemical reaction Methods 0.000 description 6
239000000463 material Substances 0.000 description 6
JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 6
239000004215 Carbon black (E152) Substances 0.000 description 5
229910052782 aluminium Inorganic materials 0.000 description 5
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
239000007788 liquid Substances 0.000 description 5
PFEOZHBOMNWTJB-UHFFFAOYSA-N 3-methylpentane Chemical compound CCC(C)CC PFEOZHBOMNWTJB-UHFFFAOYSA-N 0.000 description 4
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 4
239000002585 base Substances 0.000 description 4
230000005484 gravity Effects 0.000 description 4
125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
239000008186 active pharmaceutical agent Substances 0.000 description 3
150000001340 alkali metals Chemical group 0.000 description 3
JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
-1 ammonium ions Chemical class 0.000 description 3
125000000129 anionic group Chemical group 0.000 description 3
230000008901 benefit Effects 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
229910001603 clinoptilolite Inorganic materials 0.000 description 3
239000000356 contaminant Substances 0.000 description 3
239000007789 gas Substances 0.000 description 3
239000001307 helium Substances 0.000 description 3
229910052734 helium Inorganic materials 0.000 description 3
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 3
238000005342 ion exchange Methods 0.000 description 3
239000003921 oil Substances 0.000 description 3
150000002892 organic cations Chemical class 0.000 description 3
230000000737 periodic effect Effects 0.000 description 3
229910052710 silicon Inorganic materials 0.000 description 3
239000010703 silicon Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
238000012360 testing method Methods 0.000 description 3
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
229910003294 NiMo Inorganic materials 0.000 description 2
230000004913 activation Effects 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
150000003863 ammonium salts Chemical class 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
239000011575 calcium Substances 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
238000005336 cracking Methods 0.000 description 2
238000001035 drying Methods 0.000 description 2
229910052675 erionite Inorganic materials 0.000 description 2
238000011156 evaluation Methods 0.000 description 2
229910001657 ferrierite group Inorganic materials 0.000 description 2
229910052677 heulandite Inorganic materials 0.000 description 2
230000002209 hydrophobic effect Effects 0.000 description 2
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
229910052753 mercury Inorganic materials 0.000 description 2
229910052680 mordenite Inorganic materials 0.000 description 2
125000004430 oxygen atom Chemical group O* 0.000 description 2
229910052763 palladium Inorganic materials 0.000 description 2
239000002245 particle Substances 0.000 description 2
239000000843 powder Substances 0.000 description 2
229910052761 rare earth metal Inorganic materials 0.000 description 2
150000002910 rare earth metals Chemical class 0.000 description 2
239000012266 salt solution Substances 0.000 description 2
239000000243 solution Substances 0.000 description 2
238000011282 treatment Methods 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
239000011959 amorphous silica alumina Substances 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
238000009835 boiling Methods 0.000 description 1
238000010504 bond cleavage reaction Methods 0.000 description 1
UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 description 1
239000000969 carrier Substances 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
229910052676 chabazite Inorganic materials 0.000 description 1
230000000295 complement effect Effects 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
238000006356 dehydrogenation reaction Methods 0.000 description 1
238000006477 desulfuration reaction Methods 0.000 description 1
230000023556 desulfurization Effects 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
238000009826 distribution Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
229910001683 gmelinite Inorganic materials 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
230000002427 irreversible effect Effects 0.000 description 1
229910001711 laumontite Inorganic materials 0.000 description 1
239000010687 lubricating oil Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000011707 mineral Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
238000006902 nitrogenation reaction Methods 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000008188 pellet Substances 0.000 description 1
239000003209 petroleum derivative Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
230000036619 pore blockages Effects 0.000 description 1
238000002459 porosimetry Methods 0.000 description 1
239000002243 precursor Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
239000004576 sand Substances 0.000 description 1
230000007017 scission Effects 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
238000010025 steaming Methods 0.000 description 1
229910052678 stilbite Inorganic materials 0.000 description 1
230000002459 sustained effect Effects 0.000 description 1
239000011800 void material Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Landscapes

Catalysts (AREA)

CA000442215A 1982-12-28 1983-11-29 Support de catalyseur au zeolite pour le desazotage des charges de petrole brut Expired CA1213550A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US45396982A	1982-12-28	1982-12-28
US453,969		1982-12-28

Publications (1)

Publication Number	Publication Date
CA1213550A true CA1213550A (fr)	1986-11-04

Family

ID=23802766

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000442215A Expired CA1213550A (fr)	1982-12-28	1983-11-29	Support de catalyseur au zeolite pour le desazotage des charges de petrole brut

Country Status (2)

Country	Link
AU (1)	AU2212483A (fr)
CA (1)	CA1213550A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN114100670A (zh) *	2020-08-31	2022-03-01	中国石油化工股份有限公司	耐硫变换催化剂及其制备方法

1983
- 1983-11-29 CA CA000442215A patent/CA1213550A/fr not_active Expired
- 1983-12-06 AU AU22124/83A patent/AU2212483A/en not_active Abandoned

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN114100670A (zh) *	2020-08-31	2022-03-01	中国石油化工股份有限公司	耐硫变换催化剂及其制备方法
CN114100670B (zh) *	2020-08-31	2023-08-11	中国石油化工股份有限公司	耐硫变换催化剂及其制备方法

Also Published As

Publication number	Publication date
AU2212483A (en)	1984-07-05

Legal Events

Date	Code	Title	Description
2003-11-29	MKEX	Expiry

Publication	Publication Date	Title
US4458024A (en)	1984-07-03	Process for hydrotreating petroleum residua and catalyst therefor
US5500109A (en)	1996-03-19	Method for preparing catalysts comprising zeolites extruded with an alumina binder
US4827076A (en)	1989-05-02	Desulfurization and isomerization of N-paraffins
US4247388A (en)	1981-01-27	Hydrodewaxing catalyst performance
CA1151577A (fr)	1983-08-09	Hydrofractionnement basse pression de charges refractaires
US4358362A (en)	1982-11-09	Method for enhancing catalytic activity
US4568655A (en)	1986-02-04	Catalyst composition comprising Zeolite Beta
US5279726A (en)	1994-01-18	Catalyst containing zeolite beta and processes for its use
US4724066A (en)	1988-02-09	Composites of microporous aluminum phosphates and zeolites and conversions over these catalysts
US4440630A (en)	1984-04-03	Process for simultaneous hydrodesulfurization and hydrodewaxing with a catalyst of controlled pore size and metals content
CA1218618A (fr)	1987-03-03	Fractionnement catalytique
CZ293108B6 (cs)	2004-02-18	Způsob přeměny uhlovodíkové suroviny s obsahem vosku
US4816538A (en)	1989-03-28	Nickel-containing hydrocracking catalyst
US4867861A (en)	1989-09-19	Process and catalyst for the dewaxing of shale oil
EP0263228B2 (fr)	1996-12-11	Procédé pour la production d'un produit hydrocarboné avec une teneur réduite en paraffines normales
PL179172B1 (pl)	2000-07-31	Sposób wytwarzania bazy oleju smarowego PL PL PL
US4428825A (en)	1984-01-31	Catalytic hydrodewaxing process with added ammonia in the production of lubricating oils
US4210521A (en)	1980-07-01	Catalytic upgrading of refractory hydrocarbon stocks
JP2007506809A (ja)	2007-03-22	炭化水素転化法および触媒
US4648957A (en)	1987-03-10	Lube hydrodewaxing method and apparatus with light product removal and enhanced lube yields
US4711710A (en)	1987-12-08	Process for making improved lubricating oils from heavy feedstock
US4923836A (en)	1990-05-08	Ni/Cu absorbent/catalyst for desulfurization and isomerization of N-paraffins
US4743355A (en)	1988-05-10	Process for producing a high quality lube oil stock
US4510044A (en)	1985-04-09	Process for hydrotreating petroleum residua and catalyst therefor
US5053117A (en)	1991-10-01	Catalytic dewaxing