CA1215036A - Faujasite de type nay a haut taux silice/alumine - Google Patents

Faujasite de type nay a haut taux silice/alumine

Info

Publication number: CA1215036A
Authority: CA; Canada
Prior art keywords: silica; alumina; soda; ratio; slurry
Prior art date: 1982-12-27
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000440381A

Other languages

English (en)

Inventor

Grant C. Edwards

Robert L. Chiang

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

WR Grace and Co

Original Assignee

WR Grace and Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-12-27

Filing date

1983-11-03

Publication date

1986-12-09

1983-11-03 Application filed by WR Grace and Co filed Critical WR Grace and Co

1986-12-09 Application granted granted Critical

1986-12-09 Publication of CA1215036A publication Critical patent/CA1215036A/fr

Status Expired legal-status Critical Current

Links

VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 224
239000000377 silicon dioxide Substances 0.000 title claims abstract description 104
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title claims abstract description 76
239000012013 faujasite Substances 0.000 title abstract description 26
239000002002 slurry Substances 0.000 claims abstract description 60
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 48
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 28
239000004115 Sodium Silicate Substances 0.000 claims abstract description 27
239000000376 reactant Substances 0.000 claims abstract description 27
229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 27
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 26
239000011734 sodium Substances 0.000 claims abstract description 26
229910052708 sodium Inorganic materials 0.000 claims abstract description 26
239000002253 acid Substances 0.000 claims abstract description 24
239000012452 mother liquor Substances 0.000 claims abstract description 22
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims abstract description 16
230000015572 biosynthetic process Effects 0.000 claims abstract description 15
238000003786 synthesis reaction Methods 0.000 claims abstract description 15
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims abstract description 14
239000010457 zeolite Substances 0.000 claims abstract description 11
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 9
229910021536 Zeolite Inorganic materials 0.000 claims abstract 8
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract 4
238000000034 method Methods 0.000 claims description 46
239000000203 mixture Substances 0.000 claims description 38
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 22
230000008569 process Effects 0.000 claims description 20
239000012066 reaction slurry Substances 0.000 claims description 20
239000000047 product Substances 0.000 claims description 19
238000002156 mixing Methods 0.000 claims description 16
238000001228 spectrum Methods 0.000 claims description 15
239000000499 gel Substances 0.000 claims description 14
239000005995 Aluminium silicate Substances 0.000 claims description 13
235000012211 aluminium silicate Nutrition 0.000 claims description 13
238000010438 heat treatment Methods 0.000 claims description 13
150000003839 salts Chemical class 0.000 claims description 12
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 11
229910052782 aluminium Inorganic materials 0.000 claims description 11
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 9
238000010899 nucleation Methods 0.000 claims description 9
230000006911 nucleation Effects 0.000 claims description 9
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 8
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 7
235000012239 silicon dioxide Nutrition 0.000 claims description 7
238000005004 MAS NMR spectroscopy Methods 0.000 claims description 6
239000000741 silica gel Substances 0.000 claims description 6
229910002027 silica gel Inorganic materials 0.000 claims description 6
BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims description 3
XUIMIQQOPSSXEZ-OUBTZVSYSA-N silicon-29 atom Chemical compound [29Si] XUIMIQQOPSSXEZ-OUBTZVSYSA-N 0.000 claims description 3
239000012535 impurity Substances 0.000 claims description 2
229910052593 corundum Inorganic materials 0.000 claims 3
229910001845 yogo sapphire Inorganic materials 0.000 claims 3
229910009112 xH2O Inorganic materials 0.000 claims 2
239000007795 chemical reaction product Substances 0.000 claims 1
239000000243 solution Substances 0.000 abstract description 56
239000003054 catalyst Substances 0.000 abstract description 50
229940037003 alum Drugs 0.000 abstract description 15
-1 ammonium ions Chemical class 0.000 abstract description 13
238000004519 manufacturing process Methods 0.000 abstract description 12
229910052761 rare earth metal Inorganic materials 0.000 abstract description 10
229910052751 metal Inorganic materials 0.000 abstract description 7
239000002184 metal Substances 0.000 abstract description 7
239000003208 petroleum Substances 0.000 abstract description 5
150000002910 rare earth metals Chemical class 0.000 abstract description 5
229910001423 beryllium ion Inorganic materials 0.000 abstract description 3
239000007858 starting material Substances 0.000 abstract description 3
239000012266 salt solution Substances 0.000 abstract description 2
ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 abstract 1
150000001768 cations Chemical class 0.000 abstract 1
239000012467 final product Substances 0.000 abstract 1
229910001388 sodium aluminate Inorganic materials 0.000 abstract 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 44
239000000463 material Substances 0.000 description 23
239000000126 substance Substances 0.000 description 19
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 17
238000004458 analytical method Methods 0.000 description 16
239000007787 solid Substances 0.000 description 16
229910052710 silicon Inorganic materials 0.000 description 14
239000010703 silicon Substances 0.000 description 14
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
230000009849 deactivation Effects 0.000 description 12
239000012065 filter cake Substances 0.000 description 11
238000005336 cracking Methods 0.000 description 9
238000012360 testing method Methods 0.000 description 9
238000006243 chemical reaction Methods 0.000 description 8
230000000694 effects Effects 0.000 description 8
150000002500 ions Chemical class 0.000 description 8
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
238000002425 crystallisation Methods 0.000 description 7
230000008025 crystallization Effects 0.000 description 7
229910052757 nitrogen Inorganic materials 0.000 description 7
239000003921 oil Substances 0.000 description 7
238000003756 stirring Methods 0.000 description 7
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000004927 clay Substances 0.000 description 6
239000008367 deionised water Substances 0.000 description 6
229910021641 deionized water Inorganic materials 0.000 description 6
229930195733 hydrocarbon Natural products 0.000 description 6
150000002430 hydrocarbons Chemical class 0.000 description 6
239000001257 hydrogen Substances 0.000 description 6
229910052739 hydrogen Inorganic materials 0.000 description 6
150000002739 metals Chemical class 0.000 description 6
239000007921 spray Substances 0.000 description 6
239000007789 gas Substances 0.000 description 5
125000004430 oxygen atom Chemical group O* 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
239000004743 Polypropylene Substances 0.000 description 4
239000011159 matrix material Substances 0.000 description 4
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
229920001155 polypropylene Polymers 0.000 description 4
239000011541 reaction mixture Substances 0.000 description 4
229910052720 vanadium Inorganic materials 0.000 description 4
238000004438 BET method Methods 0.000 description 3
239000004215 Carbon black (E152) Substances 0.000 description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
239000008119 colloidal silica Substances 0.000 description 3
239000013078 crystal Substances 0.000 description 3
238000009826 distribution Methods 0.000 description 3
230000005484 gravity Effects 0.000 description 3
229910052809 inorganic oxide Inorganic materials 0.000 description 3
238000005342 ion exchange Methods 0.000 description 3
229910052759 nickel Inorganic materials 0.000 description 3
239000000843 powder Substances 0.000 description 3
230000009467 reduction Effects 0.000 description 3
230000008929 regeneration Effects 0.000 description 3
238000011069 regeneration method Methods 0.000 description 3
CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 description 3
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical class [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
238000005481 NMR spectroscopy Methods 0.000 description 2
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
239000000654 additive Substances 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
238000009835 boiling Methods 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
239000000356 contaminant Substances 0.000 description 2
229910052802 copper Inorganic materials 0.000 description 2
239000010949 copper Substances 0.000 description 2
238000011038 discontinuous diafiltration by volume reduction Methods 0.000 description 2
238000001914 filtration Methods 0.000 description 2
238000009472 formulation Methods 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 2
239000007788 liquid Substances 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
229910052697 platinum Inorganic materials 0.000 description 2
230000005855 radiation Effects 0.000 description 2
239000002994 raw material Substances 0.000 description 2
238000013341 scale-up Methods 0.000 description 2
235000019795 sodium metasilicate Nutrition 0.000 description 2
150000004684 trihydrates Chemical class 0.000 description 2
238000005406 washing Methods 0.000 description 2
244000198134 Agave sisalana Species 0.000 description 1
101100042630 Caenorhabditis elegans sin-3 gene Proteins 0.000 description 1
241000282320 Panthera leo Species 0.000 description 1
241001122315 Polites Species 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
239000003463 adsorbent Substances 0.000 description 1
230000002411 adverse Effects 0.000 description 1
230000032683 aging Effects 0.000 description 1
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
229910052921 ammonium sulfate Inorganic materials 0.000 description 1
235000011130 ammonium sulphate Nutrition 0.000 description 1
238000003556 assay Methods 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
238000001354 calcination Methods 0.000 description 1
238000004523 catalytic cracking Methods 0.000 description 1
238000004517 catalytic hydrocracking Methods 0.000 description 1
230000008859 change Effects 0.000 description 1
238000004587 chromatography analysis Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000011109 contamination Methods 0.000 description 1
238000012937 correction Methods 0.000 description 1
238000004163 cytometry Methods 0.000 description 1
239000010432 diamond Substances 0.000 description 1
229910003460 diamond Inorganic materials 0.000 description 1
230000009699 differential effect Effects 0.000 description 1
230000029087 digestion Effects 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
229910001385 heavy metal Inorganic materials 0.000 description 1
UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 1
229940073561 hexamethyldisiloxane Drugs 0.000 description 1
239000000017 hydrogel Substances 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
150000002603 lanthanum Chemical class 0.000 description 1
239000011268 mixed slurry Substances 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
125000005609 naphthenate group Chemical group 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000002245 particle Substances 0.000 description 1
235000011837 pasties Nutrition 0.000 description 1
238000005120 petroleum cracking Methods 0.000 description 1
239000003209 petroleum derivative Substances 0.000 description 1
231100000572 poisoning Toxicity 0.000 description 1
230000000607 poisoning effect Effects 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
238000000634 powder X-ray diffraction Methods 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
239000002243 precursor Substances 0.000 description 1
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
238000003672 processing method Methods 0.000 description 1
230000000750 progressive effect Effects 0.000 description 1
239000010453 quartz Substances 0.000 description 1
238000011084 recovery Methods 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
159000000000 sodium salts Chemical group 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
238000010998 test method Methods 0.000 description 1
125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000002699 waste material Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2838—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of faujasite type, or type X or Y (UNION CARBIDE trade names; correspond to GRACE's types Z-14 and Z-14HS, respectively)
- C01B33/2853—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of faujasite type, or type X or Y (UNION CARBIDE trade names; correspond to GRACE's types Z-14 and Z-14HS, respectively) of type Y
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/084—Y-type faujasite

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Crystallography & Structural Chemistry (AREA)
Geology (AREA)
Inorganic Chemistry (AREA)
General Life Sciences & Earth Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Catalysts (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

CA000440381A 1982-12-27 1983-11-03 Faujasite de type nay a haut taux silice/alumine Expired CA1215036A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US45360482A	1982-12-27	1982-12-27
US453,604		1982-12-27

Publications (1)

Publication Number	Publication Date
CA1215036A true CA1215036A (fr)	1986-12-09

Family

ID=23801244

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000440381A Expired CA1215036A (fr)	1982-12-27	1983-11-03	Faujasite de type nay a haut taux silice/alumine

Country Status (9)

Country	Link
JP (1)	JPS59121114A (fr)
AU (1)	AU562999B2 (fr)
CA (1)	CA1215036A (fr)
DE (1)	DE3347123A1 (fr)
ES (1)	ES8603159A1 (fr)
FR (1)	FR2538366A1 (fr)
GB (1)	GB2132597A (fr)
IT (1)	IT1170009B (fr)
NL (1)	NL8304446A (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS6121911A (ja) *	1984-07-11	1986-01-30	Toyo Soda Mfg Co Ltd	フオ−ジヤサイト型ゼオライトの製造方法
AU586244B2 (en) *	1985-05-08	1989-07-06	Mobil Oil Corporation	A method for producing zeolite-containing particles
ES2179113T3 (es) *	1994-08-31	2003-01-16	Huber Corp J M	Composiciones dentales economicas que contienen novedosos aluminosilicatos de sodio.
EP0758626A1 (fr)	1995-08-04	1997-02-19	Unilever Plc	Aluminosilicates
CN1058682C (zh) *	1996-12-25	2000-11-22	中国石油化工总公司	一种NaY沸石的高效合成方法
GB9816508D0 (en)	1998-07-29	1998-09-23	Exxon Chemical Patents Inc	Molecular sieves and processes for their manufacture
US9738538B2 (en)	2013-12-09	2017-08-22	Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences	Method for preparing NaY molecular sieve of high silica-alumina ratio and product thereof
KR101833322B1 (ko) *	2013-12-09	2018-02-28	달리안 인스티튜트 오브 케미컬 피직스, 차이니즈 아카데미 오브 사이언시즈	높은 실리카-대-알루미나 비를 가진 NaY 분자체의 제조방법 및 그의 생성물
TWI457173B (zh) *	2014-02-25	2014-10-21	Iner Aec Executive Yuan	吸附劑之造粒方法及該方法所製得之吸附劑顆粒
CN113511658A (zh) *	2020-04-10	2021-10-19	中国石油化工股份有限公司	一种提高单釜产率的NaY分子筛合成方法
CN116020523B (zh) *	2021-10-27	2024-08-09	中国石油化工股份有限公司	一种用于重油催化裂化的催化剂及其制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3639099A (en) *	1970-08-13	1972-02-01	Grace W R & Co	Preparation of high-silica faujasite
GB1450411A (en) *	1973-01-26	1976-09-22	Ici Ltd	Zeolites
CA1082671A (fr) *	1976-01-30	1980-07-29	Michael G. Barrett	Synthese de faujasite
US4164551A (en) *	1977-12-19	1979-08-14	W. R. Grace & Co.	Preparation of zeolite
JPS5624051A (en) *	1980-08-01	1981-03-07	Union Oil Co	Catalyst for acid catalysed hydrocarbon conversion reaction

1983
- 1983-10-28 AU AU20808/83A patent/AU562999B2/en not_active Ceased
- 1983-11-03 CA CA000440381A patent/CA1215036A/fr not_active Expired
- 1983-12-14 GB GB08333309A patent/GB2132597A/en not_active Withdrawn
- 1983-12-16 IT IT24224/83A patent/IT1170009B/it active
- 1983-12-22 JP JP58241103A patent/JPS59121114A/ja active Pending
- 1983-12-22 DE DE19833347123 patent/DE3347123A1/de not_active Withdrawn
- 1983-12-26 FR FR8320777A patent/FR2538366A1/fr not_active Withdrawn
- 1983-12-26 ES ES528391A patent/ES8603159A1/es not_active Expired
- 1983-12-27 NL NL8304446A patent/NL8304446A/nl not_active Application Discontinuation

Also Published As

Publication number	Publication date
IT1170009B (it)	1987-06-03
ES528391A0 (es)	1985-05-16
GB2132597A (en)	1984-07-11
JPS59121114A (ja)	1984-07-13
IT8324224A0 (it)	1983-12-16
IT8324224A1 (it)	1985-06-16
FR2538366A1 (fr)	1984-06-29
AU2080883A (en)	1984-07-05
ES8603159A1 (es)	1985-05-16
DE3347123A1 (de)	1984-07-05
GB8333309D0 (en)	1984-01-18
NL8304446A (nl)	1984-07-16
AU562999B2 (en)	1987-06-25

Legal Events

Date	Code	Title	Description
2003-12-09	MKEX	Expiry

Publication	Publication Date	Title
US5380690A (en)	1995-01-10	Cracking catalyst for the production of light olefins
US5232579A (en)	1993-08-03	Catalytic cracking process utilizing a zeolite beta catalyst synthesized with a chelating agent
CA2092938C (fr)	1999-01-19	Catalyseur zeolitique du type mfi, son obtention et son utilisation
AU2004244996B2 (en)	2009-06-04	In-situ ZSM-5 synthesis
CA1232258A (fr)	1988-02-02	Catalyseur a la zeolite caracterise par son rendement catalytique superieur; preparation et emploi dudit catalyseur
CA1152967A (fr)	1983-08-30	Synthese d'une nouvelle zeolite contenant du cesium, csz-1
EP0142350B1 (fr)	1991-05-08	Composition de zéolite cristalline ECR-2 et procédé de sa préparation
CA1215036A (fr)	1986-12-09	Faujasite de type nay a haut taux silice/alumine
NO177892B (no)	1995-09-04	Katalysatorblanding for fluidkrakking, samt fremgangsmåte for katalytisk fluidkrakking av hydrokarbonholdige utgangsmaterialer
JPS58208131A (ja)	1983-12-03	高シリカ質ゼオライト・ベータの製法
US6787123B2 (en)	2004-09-07	Rare earth zeolite Y and the preparation process thereof
CA1216835A (fr)	1987-01-20	Catalyseurs de conversion d'hydrocarbures
US4843052A (en)	1989-06-27	Acid-reacted metakaolin catalyst and catalyst support compositions
CA2067630A1 (fr)	1992-12-15	Synthese de zeolite beta
US3341284A (en)	1967-09-12	High-silica molecular sieve zeolites
US4940531A (en)	1990-07-10	Catalytic cracking process employing an acid-reacted metakaolin catalyst
US5273945A (en)	1993-12-28	Zeolite catalyst of hexagonal structure and its application
US5304601A (en)	1994-04-19	Catalysts based on a faujasite and its application
USH282H (en)	1987-06-02	High silica/alumina ratio faujasite type NaY
US4973461A (en)	1990-11-27	Crystalline zeolite composition
JP2759099B2 (ja)	1998-05-28	炭化水素油の流動接触分解用触媒組成物ならびにそれを用いる流動接解分解法
USH222H (en)	1987-03-03	Hydrocarbon conversion catalysts
US3692665A (en)	1972-09-19	Catalytic cracking with catalyst of high-activity zeolite stabilized by cation and thermal stabilization
JPH02273544A (ja)	1990-11-08	炭化水素転化触媒の調製方法
CN102614905A (zh)	2012-08-01	一种含钠介孔材料处理方法