CA1216757A - Methode pour separer le fluorure de zinc ammoniacal, le chlorure de zinc, le sulfate de zinc et le nitrate de zinc, de materiaux solides bruts renfermant du zinc et du fer - Google Patents

Methode pour separer le fluorure de zinc ammoniacal, le chlorure de zinc, le sulfate de zinc et le nitrate de zinc, de materiaux solides bruts renfermant du zinc et du fer

Info

Publication number: CA1216757A
Authority: CA; Canada
Prior art keywords: zinc; organic solvent; ions; iron; aqueous solution
Prior art date: 1982-03-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000492112A

Other languages

English (en)

Inventor

Morio Watanabe

Sanji Nishimura

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Solex Research Corp

Original Assignee

Solex Research Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-03-25

Filing date

1985-10-02

Publication date

1987-01-20

1982-03-25 Priority claimed from JP57046261A external-priority patent/JPS58164738A/ja

1982-08-10 Priority claimed from JP57137954A external-priority patent/JPS5928536A/ja

1982-12-16 Priority claimed from CA000417954A external-priority patent/CA1207151A/fr

1985-10-02 Application filed by Solex Research Corp filed Critical Solex Research Corp

1985-10-02 Priority to CA000492112A priority Critical patent/CA1216757A/fr

1987-01-20 Application granted granted Critical

1987-01-20 Publication of CA1216757A publication Critical patent/CA1216757A/fr

Status Expired legal-status Critical Current

Links

XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 169
229910052742 iron Inorganic materials 0.000 title claims abstract description 97
239000011701 zinc Substances 0.000 title claims abstract description 72
229910052725 zinc Inorganic materials 0.000 title claims abstract description 61
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 60
239000002994 raw material Substances 0.000 title claims abstract description 39
239000007787 solid Substances 0.000 title claims abstract description 20
ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 title claims abstract description 19
238000011084 recovery Methods 0.000 title claims abstract description 15
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 title claims abstract description 12
229910000368 zinc sulfate Inorganic materials 0.000 title claims abstract description 11
NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 title claims abstract description 8
XVRKEHYQBKGNBA-UHFFFAOYSA-N azanium;zinc;fluoride Chemical compound [NH4+].[F-].[Zn] XVRKEHYQBKGNBA-UHFFFAOYSA-N 0.000 title claims abstract description 7
229960001763 zinc sulfate Drugs 0.000 title claims abstract description 7
239000011592 zinc chloride Substances 0.000 title claims abstract description 6
235000005074 zinc chloride Nutrition 0.000 title claims abstract description 6
239000003960 organic solvent Substances 0.000 claims abstract description 76
239000007864 aqueous solution Substances 0.000 claims abstract description 57
PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims abstract description 51
238000000034 method Methods 0.000 claims abstract description 42
230000008569 process Effects 0.000 claims abstract description 41
150000002500 ions Chemical class 0.000 claims abstract description 31
239000002253 acid Substances 0.000 claims abstract description 26
238000002386 leaching Methods 0.000 claims abstract description 20
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 19
150000001875 compounds Chemical class 0.000 claims abstract description 14
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims abstract description 13
238000004090 dissolution Methods 0.000 claims abstract description 13
229910017604 nitric acid Inorganic materials 0.000 claims abstract description 13
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 10
235000011149 sulphuric acid Nutrition 0.000 claims abstract description 10
150000007513 acids Chemical class 0.000 claims abstract description 9
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 8
239000003209 petroleum derivative Substances 0.000 claims abstract description 7
239000003085 diluting agent Substances 0.000 claims abstract description 6
150000001735 carboxylic acids Chemical class 0.000 claims abstract description 5
230000001172 regenerating effect Effects 0.000 claims abstract description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 7
229910052793 cadmium Inorganic materials 0.000 claims description 5
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims 2
-1 iron ions Chemical class 0.000 description 56
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 28
239000000243 solution Substances 0.000 description 24
239000012074 organic phase Substances 0.000 description 19
239000008346 aqueous phase Substances 0.000 description 17
238000000605 extraction Methods 0.000 description 17
239000011787 zinc oxide Substances 0.000 description 14
229910052751 metal Inorganic materials 0.000 description 13
239000002184 metal Substances 0.000 description 13
239000000428 dust Substances 0.000 description 11
239000000463 material Substances 0.000 description 8
NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
229910001868 water Inorganic materials 0.000 description 8
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
239000007789 gas Substances 0.000 description 7
150000001455 metallic ions Chemical class 0.000 description 7
229910000147 aluminium phosphate Inorganic materials 0.000 description 6
235000011007 phosphoric acid Nutrition 0.000 description 6
229960004838 phosphoric acid Drugs 0.000 description 6
238000005201 scrubbing Methods 0.000 description 6
229910000831 Steel Inorganic materials 0.000 description 5
239000011572 manganese Substances 0.000 description 5
230000003647 oxidation Effects 0.000 description 5
238000007254 oxidation reaction Methods 0.000 description 5
238000007747 plating Methods 0.000 description 5
239000010959 steel Substances 0.000 description 5
239000013078 crystal Substances 0.000 description 4
229910052745 lead Inorganic materials 0.000 description 4
239000000203 mixture Substances 0.000 description 4
229910052759 nickel Inorganic materials 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
OAOABCKPVCUNKO-UHFFFAOYSA-N 8-methyl Nonanoic acid Chemical compound CC(C)CCCCCCC(O)=O OAOABCKPVCUNKO-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
150000005840 aryl radicals Chemical class 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
229910017052 cobalt Inorganic materials 0.000 description 3
239000010941 cobalt Substances 0.000 description 3
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
230000003247 decreasing effect Effects 0.000 description 3
238000005246 galvanizing Methods 0.000 description 3
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
150000003014 phosphoric acid esters Chemical class 0.000 description 3
238000000926 separation method Methods 0.000 description 3
238000012360 testing method Methods 0.000 description 3
238000012546 transfer Methods 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
RYYWUUFWQRZTIU-UHFFFAOYSA-N Thiophosphoric acid Chemical compound OP(O)(S)=O RYYWUUFWQRZTIU-UHFFFAOYSA-N 0.000 description 2
125000002877 alkyl aryl group Chemical group 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
125000004414 alkyl thio group Chemical group 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
229910052802 copper Inorganic materials 0.000 description 2
239000010949 copper Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
235000014413 iron hydroxide Nutrition 0.000 description 2
NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 2
229910052748 manganese Inorganic materials 0.000 description 2
230000007935 neutral effect Effects 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000012071 phase Substances 0.000 description 2
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
239000002893 slag Substances 0.000 description 2
239000002904 solvent Substances 0.000 description 2
238000005979 thermal decomposition reaction Methods 0.000 description 2
150000003751 zinc Chemical class 0.000 description 2
RJYDMIMSSMCNIG-UHFFFAOYSA-N (2-octylphenyl) dihydrogen phosphate Chemical compound CCCCCCCCC1=CC=CC=C1OP(O)(O)=O RJYDMIMSSMCNIG-UHFFFAOYSA-N 0.000 description 1
KEQXNNJHMWSZHK-UHFFFAOYSA-L 1,3,2,4$l^{2}-dioxathiaplumbetane 2,2-dioxide Chemical compound [Pb+2].[O-]S([O-])(=O)=O KEQXNNJHMWSZHK-UHFFFAOYSA-L 0.000 description 1
229910002975 Cd Pb Inorganic materials 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
229910015400 FeC13 Inorganic materials 0.000 description 1
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
229910017665 NH4HF2 Inorganic materials 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
238000003723 Smelting Methods 0.000 description 1
235000011054 acetic acid Nutrition 0.000 description 1
238000005273 aeration Methods 0.000 description 1
239000003513 alkali Substances 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical compound [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 description 1
229910052924 anglesite Inorganic materials 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
229910052785 arsenic Inorganic materials 0.000 description 1
CXKCTMHTOKXKQT-UHFFFAOYSA-N cadmium oxide Inorganic materials [Cd]=O CXKCTMHTOKXKQT-UHFFFAOYSA-N 0.000 description 1
125000002843 carboxylic acid group Chemical group 0.000 description 1
235000015165 citric acid Nutrition 0.000 description 1
238000000975 co-precipitation Methods 0.000 description 1
229910052681 coesite Inorganic materials 0.000 description 1
238000000658 coextraction Methods 0.000 description 1
230000001276 controlling effect Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
229910052906 cristobalite Inorganic materials 0.000 description 1
238000005363 electrowinning Methods 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
238000004508 fractional distillation Methods 0.000 description 1
239000000446 fuel Substances 0.000 description 1
239000000174 gluconic acid Substances 0.000 description 1
235000012208 gluconic acid Nutrition 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000002440 industrial waste Substances 0.000 description 1
229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
239000003350 kerosene Substances 0.000 description 1
YADSGOSSYOOKMP-UHFFFAOYSA-N lead dioxide Inorganic materials O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 1
YEXPOXQUZXUXJW-UHFFFAOYSA-N lead(II) oxide Inorganic materials [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
229910001510 metal chloride Inorganic materials 0.000 description 1
239000011259 mixed solution Substances 0.000 description 1
239000003607 modifier Substances 0.000 description 1
238000009856 non-ferrous metallurgy Methods 0.000 description 1
238000006053 organic reaction Methods 0.000 description 1
235000006408 oxalic acid Nutrition 0.000 description 1
FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
238000012545 processing Methods 0.000 description 1
238000009853 pyrometallurgy Methods 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
238000007670 refining Methods 0.000 description 1
229960004889 salicylic acid Drugs 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000010802 sludge Substances 0.000 description 1
235000017550 sodium carbonate Nutrition 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000001117 sulphuric acid Substances 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
238000005406 washing Methods 0.000 description 1
125000005023 xylyl group Chemical group 0.000 description 1
239000011686 zinc sulphate Substances 0.000 description 1
235000009529 zinc sulphate Nutrition 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling

Landscapes

Manufacture And Refinement Of Metals (AREA)

CA000492112A 1982-03-25 1985-10-02 Methode pour separer le fluorure de zinc ammoniacal, le chlorure de zinc, le sulfate de zinc et le nitrate de zinc, de materiaux solides bruts renfermant du zinc et du fer Expired CA1216757A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000492112A CA1216757A (fr)	1982-03-25	1985-10-02	Methode pour separer le fluorure de zinc ammoniacal, le chlorure de zinc, le sulfate de zinc et le nitrate de zinc, de materiaux solides bruts renfermant du zinc et du fer

Applications Claiming Priority (6)

Application Number	Priority Date	Filing Date	Title
JP57046261A JPS58164738A (ja)	1982-03-25	1982-03-25	鉄と亜鉛との分離方法
JP57-46261		1982-03-25
JP57137954A JPS5928536A (ja)	1982-08-10	1982-08-10	固形状原料より亜鉛を回収する方法
JP57-137954		1982-08-10
CA000417954A CA1207151A (fr)	1982-03-25	1982-12-16	Methode de separation selective des ions du fer presents dans un solvant organique
CA000492112A CA1216757A (fr)	1982-03-25	1985-10-02	Methode pour separer le fluorure de zinc ammoniacal, le chlorure de zinc, le sulfate de zinc et le nitrate de zinc, de materiaux solides bruts renfermant du zinc et du fer

Related Parent Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000417954A Division CA1207151A (fr)	1982-03-25	1982-12-16	Methode de separation selective des ions du fer presents dans un solvant organique

Publications (1)

Publication Number	Publication Date
CA1216757A true CA1216757A (fr)	1987-01-20

Family

ID=27167313

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000492112A Expired CA1216757A (fr)	1982-03-25	1985-10-02	Methode pour separer le fluorure de zinc ammoniacal, le chlorure de zinc, le sulfate de zinc et le nitrate de zinc, de materiaux solides bruts renfermant du zinc et du fer

Country Status (1)

Country	Link
CA (1)	CA1216757A (fr)

1985
- 1985-10-02 CA CA000492112A patent/CA1216757A/fr not_active Expired

Legal Events

Date	Code	Title	Description
2004-01-20	MKEX	Expiry

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