CA1217342A - Emulsion stable de sautage, et ses agents constitutifs - Google Patents

Emulsion stable de sautage, et ses agents constitutifs

Info

Publication number: CA1217342A
Authority: CA; Canada
Prior art keywords: emulsion; fatty acid; oil; blend; salt
Prior art date: 1983-05-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000454071A

Other languages

English (en)

Inventor

Lawrence A. Cescon

Nolan J. Millet, Jr.

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Explosives Technologies International Canada Ltd

ETI Explosive Technologies International Ltd

Original Assignee

EI Du Pont de Nemours and Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-05-12

Filing date

1984-05-10

Publication date

1987-02-03

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27051230&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA1217342(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1984-05-10 Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co

1987-02-03 Application granted granted Critical

1987-02-03 Publication of CA1217342A publication Critical patent/CA1217342A/fr

Status Expired legal-status Critical Current

Links

239000000839 emulsion Substances 0.000 title claims abstract description 270
239000002360 explosive Substances 0.000 title claims abstract description 31
239000000203 mixture Substances 0.000 claims abstract description 164
235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 100
239000000194 fatty acid Substances 0.000 claims abstract description 100
229930195729 fatty acid Natural products 0.000 claims abstract description 100
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 83
239000003995 emulsifying agent Substances 0.000 claims abstract description 44
-1 fatty acid salt Chemical class 0.000 claims abstract description 43
239000002245 particle Substances 0.000 claims abstract description 36
239000007788 liquid Substances 0.000 claims abstract description 35
238000011065 in-situ storage Methods 0.000 claims abstract description 21
238000005086 pumping Methods 0.000 claims abstract description 21
230000001050 lubricating effect Effects 0.000 claims abstract description 13
239000007762 w/o emulsion Substances 0.000 claims abstract description 7
PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 144
239000003921 oil Substances 0.000 claims description 107
150000004665 fatty acids Chemical class 0.000 claims description 65
238000000034 method Methods 0.000 claims description 47
150000003839 salts Chemical class 0.000 claims description 29
239000000243 solution Substances 0.000 claims description 28
239000000446 fuel Substances 0.000 claims description 26
230000001804 emulsifying effect Effects 0.000 claims description 24
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 23
239000002585 base Substances 0.000 claims description 20
238000002156 mixing Methods 0.000 claims description 18
239000007864 aqueous solution Substances 0.000 claims description 17
230000001590 oxidative effect Effects 0.000 claims description 16
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 15
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 15
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 15
239000005642 Oleic acid Substances 0.000 claims description 15
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 15
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 15
239000007789 gas Substances 0.000 claims description 13
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 10
229910052783 alkali metal Inorganic materials 0.000 claims description 10
150000001340 alkali metals Chemical group 0.000 claims description 9
125000004432 carbon atom Chemical group C* 0.000 claims description 9
150000002763 monocarboxylic acids Chemical class 0.000 claims description 9
229910052760 oxygen Inorganic materials 0.000 claims description 8
125000005210 alkyl ammonium group Chemical group 0.000 claims description 7
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
238000009792 diffusion process Methods 0.000 claims description 7
239000001301 oxygen Substances 0.000 claims description 7
235000021588 free fatty acids Nutrition 0.000 claims description 6
229920006395 saturated elastomer Polymers 0.000 claims description 6
230000001235 sensitizing effect Effects 0.000 claims description 6
238000012360 testing method Methods 0.000 claims description 5
FVFJGQJXAWCHIE-UHFFFAOYSA-N [4-(bromomethyl)phenyl]methanamine Chemical group NCC1=CC=C(CBr)C=C1 FVFJGQJXAWCHIE-UHFFFAOYSA-N 0.000 claims description 4
238000013019 agitation Methods 0.000 claims description 4
239000011248 coating agent Substances 0.000 claims description 4
238000000576 coating method Methods 0.000 claims description 4
239000011343 solid material Substances 0.000 claims description 4
239000003795 chemical substances by application Substances 0.000 claims description 3
230000006872 improvement Effects 0.000 claims description 3
235000019198 oils Nutrition 0.000 claims description 2
230000000153 supplemental effect Effects 0.000 claims description 2
230000015572 biosynthetic process Effects 0.000 abstract description 2
125000000129 anionic group Chemical group 0.000 abstract 2
239000012071 phase Substances 0.000 description 37
239000008346 aqueous phase Substances 0.000 description 18
239000007787 solid Substances 0.000 description 14
239000004927 clay Substances 0.000 description 12
239000000126 substance Substances 0.000 description 12
239000002253 acid Substances 0.000 description 10
VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 10
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
230000008901 benefit Effects 0.000 description 9
238000002425 crystallisation Methods 0.000 description 8
230000008025 crystallization Effects 0.000 description 8
230000002950 deficient Effects 0.000 description 8
230000000694 effects Effects 0.000 description 8
ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 6
238000010521 absorption reaction Methods 0.000 description 6
238000005474 detonation Methods 0.000 description 6
239000001593 sorbitan monooleate Substances 0.000 description 6
235000011069 sorbitan monooleate Nutrition 0.000 description 6
229940035049 sorbitan monooleate Drugs 0.000 description 6
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
239000000295 fuel oil Substances 0.000 description 5
230000002209 hydrophobic effect Effects 0.000 description 5
239000000463 material Substances 0.000 description 5
239000007800 oxidant agent Substances 0.000 description 5
229910052708 sodium Inorganic materials 0.000 description 5
239000011734 sodium Substances 0.000 description 5
239000004317 sodium nitrate Substances 0.000 description 5
235000010344 sodium nitrate Nutrition 0.000 description 5
238000012546 transfer Methods 0.000 description 5
230000003247 decreasing effect Effects 0.000 description 4
239000010881 fly ash Substances 0.000 description 4
239000004615 ingredient Substances 0.000 description 4
239000004530 micro-emulsion Substances 0.000 description 4
238000010899 nucleation Methods 0.000 description 4
229940049964 oleate Drugs 0.000 description 4
239000008188 pellet Substances 0.000 description 4
229910052700 potassium Inorganic materials 0.000 description 4
238000002360 preparation method Methods 0.000 description 4
239000012266 salt solution Substances 0.000 description 4
238000003860 storage Methods 0.000 description 4
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 3
238000001816 cooling Methods 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
150000002500 ions Chemical class 0.000 description 3
239000000314 lubricant Substances 0.000 description 3
239000012188 paraffin wax Substances 0.000 description 3
239000011591 potassium Substances 0.000 description 3
238000010008 shearing Methods 0.000 description 3
229910002651 NO3 Inorganic materials 0.000 description 2
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
239000000654 additive Substances 0.000 description 2
230000004888 barrier function Effects 0.000 description 2
230000009286 beneficial effect Effects 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
239000004568 cement Substances 0.000 description 2
239000013078 crystal Substances 0.000 description 2
230000007423 decrease Effects 0.000 description 2
230000001419 dependent effect Effects 0.000 description 2
238000009472 formulation Methods 0.000 description 2
239000011521 glass Substances 0.000 description 2
239000008187 granular material Substances 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000004005 microsphere Substances 0.000 description 2
239000010743 number 2 fuel oil Substances 0.000 description 2
239000000344 soap Substances 0.000 description 2
229950004959 sorbitan oleate Drugs 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
239000011800 void material Substances 0.000 description 2
JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
WWVFJJKBBZXWFV-UHFFFAOYSA-N 2-naphthalen-1-yl-5-phenyl-1,3-oxazole Chemical compound C=1N=C(C=2C3=CC=CC=C3C=CC=2)OC=1C1=CC=CC=C1 WWVFJJKBBZXWFV-UHFFFAOYSA-N 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
238000003109 Karl Fischer titration Methods 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
101100059652 Mus musculus Cetn1 gene Proteins 0.000 description 1
101100059655 Mus musculus Cetn2 gene Proteins 0.000 description 1
SNIOPGDIGTZGOP-UHFFFAOYSA-N Nitroglycerin Chemical compound [O-][N+](=O)OCC(O[N+]([O-])=O)CO[N+]([O-])=O SNIOPGDIGTZGOP-UHFFFAOYSA-N 0.000 description 1
239000000006 Nitroglycerin Substances 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
206010070834 Sensitisation Diseases 0.000 description 1
IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 1
HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
230000032683 aging Effects 0.000 description 1
229910001963 alkali metal nitrate Inorganic materials 0.000 description 1
229910001964 alkaline earth metal nitrate Inorganic materials 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
230000008859 change Effects 0.000 description 1
230000002301 combined effect Effects 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
230000002939 deleterious effect Effects 0.000 description 1
230000000368 destabilizing effect Effects 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
238000007710 freezing Methods 0.000 description 1
230000008014 freezing Effects 0.000 description 1
229960003711 glyceryl trinitrate Drugs 0.000 description 1
230000005484 gravity Effects 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
238000010952 in-situ formation Methods 0.000 description 1
238000003780 insertion Methods 0.000 description 1
230000037431 insertion Effects 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
238000011068 loading method Methods 0.000 description 1
230000007774 longterm Effects 0.000 description 1
239000010687 lubricating oil Substances 0.000 description 1
238000005461 lubrication Methods 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000002480 mineral oil Substances 0.000 description 1
235000010446 mineral oil Nutrition 0.000 description 1
239000012875 nonionic emulsifier Substances 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
229920001568 phenolic resin Polymers 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
230000002028 premature Effects 0.000 description 1
230000037452 priming Effects 0.000 description 1
230000008569 process Effects 0.000 description 1
230000009467 reduction Effects 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
230000035945 sensitivity Effects 0.000 description 1
230000008313 sensitization Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000001570 sorbitan monopalmitate Substances 0.000 description 1
235000011071 sorbitan monopalmitate Nutrition 0.000 description 1
229940031953 sorbitan monopalmitate Drugs 0.000 description 1
239000001587 sorbitan monostearate Substances 0.000 description 1
235000011076 sorbitan monostearate Nutrition 0.000 description 1
229940035048 sorbitan monostearate Drugs 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
239000010959 steel Substances 0.000 description 1
230000008961 swelling Effects 0.000 description 1
229920001059 synthetic polymer Polymers 0.000 description 1
230000007704 transition Effects 0.000 description 1
230000000007 visual effect Effects 0.000 description 1
239000003643 water by type Substances 0.000 description 1
230000004580 weight loss Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
- C06B47/14—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase comprising a solid component and an aqueous phase
- C06B47/145—Water in oil emulsion type explosives in which a carbonaceous fuel forms the continuous phase
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B31/00—Compositions containing an inorganic nitrogen-oxygen salt

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Oil, Petroleum & Natural Gas (AREA)
Inorganic Chemistry (AREA)
Liquid Carbonaceous Fuels (AREA)
Colloid Chemistry (AREA)
Silicon Compounds (AREA)

CA000454071A 1983-05-12 1984-05-10 Emulsion stable de sautage, et ses agents constitutifs Expired CA1217342A (fr)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date
US49391683A	1983-05-12	1983-05-12
US493,916		1983-05-12
US57660284A	1984-02-03	1984-02-03
US576,602		1984-02-03

Publications (1)

Publication Number	Publication Date
CA1217342A true CA1217342A (fr)	1987-02-03

Family

ID=27051230

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000454071A Expired CA1217342A (fr)	1983-05-12	1984-05-10	Emulsion stable de sautage, et ses agents constitutifs

Country Status (21)

Country	Link
EP (1)	EP0131355B1 (fr)
KR (1)	KR910003094B1 (fr)
AU (1)	AU573217B2 (fr)
BR (1)	BR8402200A (fr)
CA (1)	CA1217342A (fr)
CS (1)	CS345884A3 (fr)
DE (1)	DE3481767D1 (fr)
ES (1)	ES8703394A1 (fr)
GB (1)	GB2140404B (fr)
HK (1)	HK17988A (fr)
IE (1)	IE57411B1 (fr)
IN (1)	IN162344B (fr)
MA (1)	MA20117A1 (fr)
MX (1)	MX162156A (fr)
MY (1)	MY100182A (fr)
NO (1)	NO841906L (fr)
NZ (1)	NZ208130A (fr)
OA (1)	OA07771A (fr)
PT (1)	PT78579B (fr)
TR (1)	TR22230A (fr)
ZW (1)	ZW7684A1 (fr)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
MW2884A1 (en) *	1984-02-08	1986-08-13	Aeci Ltd	An explosive which includes an explosive emulsion
CA1259492A (fr) *	1985-10-15	1989-09-19	Lawrence A. Cescon	Compositions de sautage a teneur d'emulsion
ZA888819B (en) *	1987-12-02	1990-07-25	Ici Australia Operations	Process for preparing explosive
ZA891501B (en) *	1988-03-02	1989-11-29	Ici Australia Operations	Explosive composition
GB9003613D0 (en) *	1990-02-16	1990-04-11	Explosives Tech Eti	Method of reducing the overloading of a borehole and explosive composition used therefor
DE19649763A1 (de) *	1996-11-30	1998-06-04	Appenzeller Albert	Sprengstoff für zivile, insbesondere bergmännische Zwecke
ES2123468B1 (es) *	1997-06-26	2000-02-01	Espanola Explosivos	Procedimiento e instalacion para la sensibilizacion in situ de explosivos de base acuosa.
AUPQ105299A0 (en) *	1999-06-18	1999-07-08	Orica Australia Pty Ltd	Emulsion explosive
AUPR024400A0 (en) *	2000-09-20	2000-10-12	Orica Explosives Technology Pty Ltd	Sensitisation of emulsion explosives
RU2252926C2 (ru) *	2003-08-25	2005-05-27	ОАО "Знамя"	Состав эмульсионного взрывчатого вещества
RU2446134C1 (ru) *	2010-07-23	2012-03-27	Федеральное Казенное Предприятие "Бийский Олеумный Завод"	Состав эмульсионного взрывчатого вещества
CN105272783A (zh) *	2015-11-10	2016-01-27	天津宏泰华凯科技有限公司	一种乳化炸药的乳化制药系统

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3161551A (en) *	1961-04-07	1964-12-15	Commercial Solvents Corp	Ammonium nitrate-containing emulsion sensitizers for blasting agents
US3447978A (en) *	1967-08-03	1969-06-03	Atlas Chem Ind	Ammonium nitrate emulsion blasting agent and method of preparing same
GB1306546A (en) *	1970-06-09	1973-02-14	Explosives & Chem Prod	Blasting explosive composition
US4181546A (en) *	1977-09-19	1980-01-01	Clay Robert B	Water resistant blasting agent and method of use
US4111727A (en) *	1977-09-19	1978-09-05	Clay Robert B	Water-in-oil blasting composition
NZ192888A (en) *	1979-04-02	1982-03-30	Canadian Ind	Water-in-oil microemulsion explosive compositions
US4259977A (en) *	1979-04-16	1981-04-07	Atlas Powder Company	Transportation and placement of water-in-oil emulsion explosives and blasting agents
US4287010A (en) *	1979-08-06	1981-09-01	E. I. Du Pont De Nemours & Company	Emulsion-type explosive composition and method for the preparation thereof
DE3375475D1 (en) *	1982-07-21	1988-03-03	Ici Plc	Emulsion explosive composition
US4404050A (en) *	1982-09-29	1983-09-13	C-I-L Inc.	Water-in-oil emulsion blasting agents containing unrefined or partly refined petroleum product as fuel component

1984
- 1984-05-09 BR BR8402200A patent/BR8402200A/pt not_active IP Right Cessation
- 1984-05-09 ES ES532316A patent/ES8703394A1/es not_active Expired
- 1984-05-10 IN IN323/CAL/84A patent/IN162344B/en unknown
- 1984-05-10 CS CS843458A patent/CS345884A3/cs unknown
- 1984-05-10 AU AU27894/84A patent/AU573217B2/en not_active Ceased
- 1984-05-10 CA CA000454071A patent/CA1217342A/fr not_active Expired
- 1984-05-11 NZ NZ208130A patent/NZ208130A/en unknown
- 1984-05-11 DE DE8484303208T patent/DE3481767D1/de not_active Expired - Lifetime
- 1984-05-11 GB GB08412026A patent/GB2140404B/en not_active Expired
- 1984-05-11 MX MX201324A patent/MX162156A/es unknown
- 1984-05-11 IE IE1170/84A patent/IE57411B1/en unknown
- 1984-05-11 PT PT78579A patent/PT78579B/pt unknown
- 1984-05-11 OA OA58297A patent/OA07771A/fr unknown
- 1984-05-11 TR TR22230A patent/TR22230A/xx unknown
- 1984-05-11 MA MA20339A patent/MA20117A1/fr unknown
- 1984-05-11 ZW ZW76/84A patent/ZW7684A1/xx unknown
- 1984-05-11 NO NO841906A patent/NO841906L/no unknown
- 1984-05-11 EP EP84303208A patent/EP0131355B1/fr not_active Expired - Lifetime
- 1984-05-12 KR KR1019840002561A patent/KR910003094B1/ko not_active Expired
1986
- 1986-10-23 MY MYPI86000028A patent/MY100182A/en unknown
1988
- 1988-03-03 HK HK179/88A patent/HK17988A/xx unknown

Also Published As

Publication number	Publication date
GB2140404A (en)	1984-11-28
GB8412026D0 (en)	1984-06-20
ES532316A0 (es)	1987-02-16
MX162156A (es)	1991-04-03
AU573217B2 (en)	1988-06-02
NZ208130A (en)	1990-04-26
TR22230A (tr)	1986-10-09
BR8402200A (pt)	1984-12-18
PT78579A (en)	1984-06-01
NO841906L (no)	1984-11-13
MY100182A (en)	1990-03-29
EP0131355B1 (fr)	1990-03-28
KR910003094B1 (ko)	1991-05-18
DE3481767D1 (de)	1990-05-03
AU2789484A (en)	1984-11-15
IN162344B (fr)	1988-05-07
EP0131355A2 (fr)	1985-01-16
OA07771A (fr)	1985-08-30
GB2140404B (en)	1987-09-03
IE841170L (en)	1984-11-12
PT78579B (en)	1986-06-26
MA20117A1 (fr)	1984-12-31
EP0131355A3 (en)	1985-05-29
ZW7684A1 (en)	1984-07-25
IE57411B1 (en)	1992-08-26
CS345884A3 (en)	1992-11-18
KR850002250A (ko)	1985-05-10
HK17988A (en)	1988-03-11
ES8703394A1 (es)	1987-02-16

Legal Events

Date	Code	Title	Description
2004-05-10	MKEX	Expiry

Publication	Publication Date	Title
US4555278A (en)	1985-11-26	Stable nitrate/emulsion explosives and emulsion for use therein
US3447978A (en)	1969-06-03	Ammonium nitrate emulsion blasting agent and method of preparing same
CA1217342A (fr)	1987-02-03	Emulsion stable de sautage, et ses agents constitutifs
US5076867A (en)	1991-12-31	Stabilized emulsion explosive and method
EP0107368B1 (fr)	1988-05-04	Composition explosive à base d'émulsion
PL117150B1 (en)	1981-07-31	Water explosive mixture of inverted phase and method of making the samerigotovlenija vodnojj wzryvchatojj smesi z obratnojj fazojj
GB2055358A (en)	1981-03-04	Emulsion-type explosive composition and method for the preparation thereof
EP0107407B1 (fr)	1988-12-21	Composition explosive à base d'émulsion
EP0028908A2 (fr)	1981-05-20	Composition explosive en émulsion
EP0194774A1 (fr)	1986-09-17	Procédé pour la production d'explosifs sous forme de suspensions aqueuses de particules solides à haute densité dans des trous de mines
US4426238A (en)	1984-01-17	Blasting composition containing particulate oxidizer salts
US4775431A (en)	1988-10-04	Macroemulsion for preparing high density explosive compositions
US4784706A (en)	1988-11-15	Emulsion explosive containing phenolic emulsifier derivative
EP0250224B1 (fr)	1993-06-09	Composition explosive coulée et procédé
US4600450A (en)	1986-07-15	Microknit composite explosives and processes for making same
US4548659A (en)	1985-10-22	Cast emulsion explosive composition
US5346564A (en)	1994-09-13	Method of safely preparing an explosive emulsion composition
JP4138661B2 (ja)	2008-08-27	敏感化されたエマルジョン爆発物の調製方法
US4509998A (en)	1985-04-09	Emulsion blasting agent with amine-based emulsifier
US4500370A (en)	1985-02-19	Emulsion blasting agent
EP0044664A2 (fr)	1982-01-27	Agent de sautage du type émulsion contenant du mononitrate d'hydrazine
US6022428A (en)	2000-02-08	Gassed emulsion explosive
JPS6253478B2 (fr)	1987-11-10
JPS6222959B2 (fr)	1987-05-20
CA1203690A (fr)	1986-04-29	Emulsion de sautage avec emulsifiant a base d'amine