CA1218237A - Separation de l'indium par extraction au solvant - Google Patents

Separation de l'indium par extraction au solvant

Info

Publication number: CA1218237A
Authority: CA; Canada
Prior art keywords: indium; tin; solution; fluoride; acid
Prior art date: 1983-10-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000439356A

Other languages

English (en)

Inventor

Roland Perri

Douwe Ybema

James A. Ross

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Teck Metals Ltd

Original Assignee

Teck Metals Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-10-20

Filing date

1983-10-20

Publication date

1987-02-24

1983-10-20 Application filed by Teck Metals Ltd filed Critical Teck Metals Ltd

1983-10-20 Priority to CA000439356A priority Critical patent/CA1218237A/fr

1987-02-24 Application granted granted Critical

1987-02-24 Publication of CA1218237A publication Critical patent/CA1218237A/fr

Status Expired legal-status Critical Current

Links

229910052738 indium Inorganic materials 0.000 title claims abstract description 117
APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 title claims abstract description 112
238000000034 method Methods 0.000 title claims abstract description 58
238000000638 solvent extraction Methods 0.000 title claims abstract description 18
238000011084 recovery Methods 0.000 title claims abstract description 13
239000000243 solution Substances 0.000 claims abstract description 112
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 101
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims abstract description 57
238000000605 extraction Methods 0.000 claims abstract description 27
239000000839 emulsion Substances 0.000 claims abstract description 16
-1 alkyl phosphoric acid Chemical group 0.000 claims abstract description 14
239000007864 aqueous solution Substances 0.000 claims abstract description 12
230000015572 biosynthetic process Effects 0.000 claims abstract description 12
NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 5
229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 4
229910052718 tin Inorganic materials 0.000 claims description 98
238000005201 scrubbing Methods 0.000 claims description 50
239000012074 organic phase Substances 0.000 claims description 45
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 41
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 37
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 36
239000007788 liquid Substances 0.000 claims description 25
239000012527 feed solution Substances 0.000 claims description 21
229910052742 iron Inorganic materials 0.000 claims description 20
STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical group CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 20
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 18
235000011167 hydrochloric acid Nutrition 0.000 claims description 15
229960000443 hydrochloric acid Drugs 0.000 claims description 15
239000000463 material Substances 0.000 claims description 15
235000011007 phosphoric acid Nutrition 0.000 claims description 14
239000007787 solid Substances 0.000 claims description 14
239000002253 acid Substances 0.000 claims description 13
239000003350 kerosene Substances 0.000 claims description 10
238000002386 leaching Methods 0.000 claims description 10
239000003607 modifier Substances 0.000 claims description 9
239000000203 mixture Substances 0.000 claims description 8
229910019142 PO4 Inorganic materials 0.000 claims description 7
239000012071 phase Substances 0.000 claims description 7
235000021317 phosphate Nutrition 0.000 claims description 7
238000000926 separation method Methods 0.000 claims description 7
229940093635 tributyl phosphate Drugs 0.000 claims description 7
239000003085 diluting agent Substances 0.000 claims description 6
239000007800 oxidant agent Substances 0.000 claims description 6
230000001590 oxidative effect Effects 0.000 claims description 6
239000010452 phosphate Substances 0.000 claims description 5
239000012286 potassium permanganate Substances 0.000 claims description 5
NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 claims description 4
PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims description 4
235000011149 sulphuric acid Nutrition 0.000 claims description 4
229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 3
125000001931 aliphatic group Chemical group 0.000 claims description 3
125000003118 aryl group Chemical group 0.000 claims description 3
238000009835 boiling Methods 0.000 claims description 3
238000004090 dissolution Methods 0.000 claims description 3
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 3
229960004838 phosphoric acid Drugs 0.000 claims description 3
DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 claims description 2
239000003517 fume Substances 0.000 claims description 2
235000003270 potassium fluoride Nutrition 0.000 claims description 2
239000011698 potassium fluoride Substances 0.000 claims description 2
239000002893 slag Substances 0.000 claims description 2
235000013024 sodium fluoride Nutrition 0.000 claims description 2
239000011775 sodium fluoride Substances 0.000 claims description 2
229940091249 fluoride supplement Drugs 0.000 description 32
239000008346 aqueous phase Substances 0.000 description 13
230000000536 complexating effect Effects 0.000 description 12
VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 9
238000005755 formation reaction Methods 0.000 description 8
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 8
230000014759 maintenance of location Effects 0.000 description 7
238000005191 phase separation Methods 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
238000004458 analytical method Methods 0.000 description 4
239000000306 component Substances 0.000 description 4
238000010790 dilution Methods 0.000 description 3
239000012895 dilution Substances 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
150000003016 phosphoric acids Chemical class 0.000 description 3
238000012545 processing Methods 0.000 description 3
230000009467 reduction Effects 0.000 description 3
238000006722 reduction reaction Methods 0.000 description 3
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
230000007423 decrease Effects 0.000 description 2
238000005868 electrolysis reaction Methods 0.000 description 2
239000003500 flue dust Substances 0.000 description 2
150000002222 fluorine compounds Chemical class 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
238000001556 precipitation Methods 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
239000002904 solvent Substances 0.000 description 2
230000001629 suppression Effects 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 1
235000008733 Citrus aurantifolia Nutrition 0.000 description 1
241000518994 Conta Species 0.000 description 1
235000011941 Tilia x europaea Nutrition 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
235000019270 ammonium chloride Nutrition 0.000 description 1
229910052785 arsenic Inorganic materials 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229910052793 cadmium Inorganic materials 0.000 description 1
239000003518 caustics Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
229910052681 coesite Inorganic materials 0.000 description 1
230000009918 complex formation Effects 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
229910052593 corundum Inorganic materials 0.000 description 1
229910052906 cristobalite Inorganic materials 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000010586 diagram Methods 0.000 description 1
150000005690 diesters Chemical class 0.000 description 1
239000000428 dust Substances 0.000 description 1
239000003792 electrolyte Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
229910001447 ferric ion Inorganic materials 0.000 description 1
230000004927 fusion Effects 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
239000012535 impurity Substances 0.000 description 1
230000002401 inhibitory effect Effects 0.000 description 1
230000005764 inhibitory process Effects 0.000 description 1
239000013067 intermediate product Substances 0.000 description 1
229910052745 lead Inorganic materials 0.000 description 1
239000004571 lime Substances 0.000 description 1
238000000622 liquid--liquid extraction Methods 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
238000002156 mixing Methods 0.000 description 1
150000002903 organophosphorus compounds Chemical class 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
231100000572 poisoning Toxicity 0.000 description 1
230000000607 poisoning effect Effects 0.000 description 1
238000010926 purge Methods 0.000 description 1
238000004064 recycling Methods 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000002002 slurry Substances 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
230000001180 sulfating effect Effects 0.000 description 1
MLGCXEBRWGEOQX-UHFFFAOYSA-N tetradifon Chemical compound C1=CC(Cl)=CC=C1S(=O)(=O)C1=CC(Cl)=C(Cl)C=C1Cl MLGCXEBRWGEOQX-UHFFFAOYSA-N 0.000 description 1
229910052716 thallium Inorganic materials 0.000 description 1
150000003606 tin compounds Chemical class 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1
150000005691 triesters Chemical class 0.000 description 1
229910001845 yogo sapphire Inorganic materials 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G15/00—Compounds of gallium, indium or thallium
- C01G15/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G19/00—Compounds of tin
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
- C22B3/3846—Phosphoric acid, e.g. (O)P(OH)3
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/40—Mixtures
- C22B3/408—Mixtures using a mixture of phosphorus-based acid derivatives of different types
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Geochemistry & Mineralogy (AREA)
Environmental & Geological Engineering (AREA)
General Life Sciences & Earth Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Geology (AREA)
Inorganic Chemistry (AREA)
Manufacturing & Machinery (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
Metallurgy (AREA)
Manufacture And Refinement Of Metals (AREA)

CA000439356A 1983-10-20 1983-10-20 Separation de l'indium par extraction au solvant Expired CA1218237A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000439356A CA1218237A (fr)	1983-10-20	1983-10-20	Separation de l'indium par extraction au solvant

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000439356A CA1218237A (fr)	1983-10-20	1983-10-20	Separation de l'indium par extraction au solvant

Publications (1)

Publication Number	Publication Date
CA1218237A true CA1218237A (fr)	1987-02-24

Family

ID=4126328

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000439356A Expired CA1218237A (fr)	1983-10-20	1983-10-20	Separation de l'indium par extraction au solvant

Country Status (1)

Country	Link
CA (1)	CA1218237A (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2623522A1 (fr) *	1987-11-24	1989-05-26	Metaleurop Sa	Procede de traitement hydrometallurgique d'une solution de chlorure d'indium
CN114441258A (zh) *	2021-12-30	2022-05-06	云锡文山锌铟冶炼有限公司	检测有机萃取剂中p204含量的方法

1983
- 1983-10-20 CA CA000439356A patent/CA1218237A/fr not_active Expired

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2623522A1 (fr) *	1987-11-24	1989-05-26	Metaleurop Sa	Procede de traitement hydrometallurgique d'une solution de chlorure d'indium
EP0318384A1 (fr) *	1987-11-24	1989-05-31	Metaleurop S.A.	Procédé de traitement hydrométallurgique d'une solution de chlorure d'indium
WO1989004877A1 (fr) *	1987-11-24	1989-06-01	Metaleurop S.A.	Procede de traitement hydrometallurgique d'une solution de chlorure d'indium
US5019363A (en) *	1987-11-24	1991-05-28	Metaleurop S.A.	Process for hydrometallurgical treatment of an indium chloride solution
CN114441258A (zh) *	2021-12-30	2022-05-06	云锡文山锌铟冶炼有限公司	检测有机萃取剂中p204含量的方法
CN114441258B (zh) *	2021-12-30	2023-08-04	云锡文山锌铟冶炼有限公司	检测有机萃取剂中p204含量的方法

Legal Events

Date	Code	Title	Description
2004-02-24	MKEX	Expiry

Publication	Publication Date	Title
CA1104350A (fr)	1981-07-07	Separation du cobalt et du nickel par extraction au solvent
Owusu	1998	Selective extractions of Zn and Cd from Zn Cd Co Ni sulphate solution using di-2-ethylhexyl phosphoric acid extractant
US4288304A (en)	1981-09-08	Hydrometallurgical process for treatment of sulphur ores
US5135652A (en)	1992-08-04	Method for the solvent extraction of zinc
US3399055A (en)	1968-08-27	Separation of cobalt by liquid extraction from acid solutions
US5492680A (en)	1996-02-20	Separation of scandium from tantalum residue using fractional liquid-liquid extraction
US4362607A (en)	1982-12-07	Recovery of copper and zinc from complex chloride solutions
US4292284A (en)	1981-09-29	Solvent extraction recovery process for indium
US4241027A (en)	1980-12-23	Reductive stripping process for the recovery of either or both uranium and vanadium
DK163673B (da)	1992-03-23	Fremgangsmaade til oparbejdning af jern- og zinkholdige saltsyrebejdser
DK149136B (da)	1986-02-10	Fremgangsmaade til selektiv udvinding af indium fra indiumholdige vandige sulfatoploesninger
US4915919A (en)	1990-04-10	Recovery of germanium from aqueous solutions by solvent extraction
Ritcey et al.	1982	Evaluation and selection of extractants for the separation of copper and zinc from chloride leach liquor
CA1218237A (fr)	1987-02-24	Separation de l'indium par extraction au solvant
EP0090119B1 (fr)	1988-03-09	Procédé d'élimination sélective des ions de fer à partir d'un solvant organique
EP2895633B1 (fr)	2020-05-27	Procédé d'extraction par solvant
Fletcher et al.	1991	Combining sulfate electrowinning with chloride leaching
CA1119819A (fr)	1982-03-16	Methode de separation et de recuperation du cobalt par voie chimique
US3573182A (en)	1971-03-30	Process for separating zinc and copper
Gotfryd et al.	2006	The selective recovery of cadmium (II) from sulfate solutions by a counter-current extraction–stripping process using a mixture of diisopropylsalicylic acid and Cyanex® 471X
JP2814507B2 (ja)	1998-10-22	塩化インジウム溶液の湿式精錬処理法
JPS621570B2 (fr)	1987-01-14
WO1997001649A1 (fr)	1997-01-16	Procede pour la separation selective du cadmium contenu dans une solution aqueuse acide
CA1098719A (fr)	1981-04-07	Separation au moyen d'un solvant des metaux non ferreux contenus dans une solution ferreuse
CA2168036A1 (fr)	1995-02-16	Procede de recuperation des metaux