CA1219203A - Methode et dispositif de determination des biphenyls polyhalogenes - Google Patents

Methode et dispositif de determination des biphenyls polyhalogenes

Info

Publication number: CA1219203A
Authority: CA; Canada
Prior art keywords: halide; kit; measuring; extractant; concentration
Prior art date: 1983-03-31
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000448694A

Other languages

English (en)

Inventor

John C. Johnson

David F. Tompkins

Edward D. Handel

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

McGraw Edison Co

Original Assignee

McGraw Edison Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-03-31

Filing date

1984-03-02

Publication date

1987-03-17

1984-03-02 Application filed by McGraw Edison Co filed Critical McGraw Edison Co

1987-03-17 Application granted granted Critical

1987-03-17 Publication of CA1219203A publication Critical patent/CA1219203A/fr

Status Expired legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 67
235000010290 biphenyl Nutrition 0.000 title claims abstract description 15
150000004074 biphenyls Chemical class 0.000 title claims abstract description 11
230000008569 process Effects 0.000 claims abstract description 49
150000004820 halides Chemical class 0.000 claims abstract description 45
238000012360 testing method Methods 0.000 claims abstract description 38
239000000203 mixture Substances 0.000 claims abstract description 26
229910052783 alkali metal Inorganic materials 0.000 claims abstract description 21
150000001340 alkali metals Chemical class 0.000 claims abstract description 21
-1 halide ion Chemical class 0.000 claims description 28
229910052736 halogen Inorganic materials 0.000 claims description 25
150000002367 halogens Chemical class 0.000 claims description 25
239000003153 chemical reaction reagent Substances 0.000 claims description 22
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 21
238000006243 chemical reaction Methods 0.000 claims description 21
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 19
238000000605 extraction Methods 0.000 claims description 19
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 16
239000012530 fluid Substances 0.000 claims description 16
229910052708 sodium Inorganic materials 0.000 claims description 16
239000011734 sodium Substances 0.000 claims description 16
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 12
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 12
AEBYJSOWHQYRPK-UHFFFAOYSA-N 1,1'-biphenyl;sodium Chemical group [Na].C1=CC=CC=C1C1=CC=CC=C1 AEBYJSOWHQYRPK-UHFFFAOYSA-N 0.000 claims description 10
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 9
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 9
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229910000147 aluminium phosphate Inorganic materials 0.000 claims description 6
IWZKICVEHNUQTL-UHFFFAOYSA-M potassium hydrogen phthalate Chemical compound [K+].OC(=O)C1=CC=CC=C1C([O-])=O IWZKICVEHNUQTL-UHFFFAOYSA-M 0.000 claims description 6
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238000005191 phase separation Methods 0.000 claims description 5
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URXNVXOMQQCBHS-UHFFFAOYSA-N naphthalene;sodium Chemical compound [Na].C1=CC=CC2=CC=CC=C21 URXNVXOMQQCBHS-UHFFFAOYSA-N 0.000 claims 2
239000000376 reactant Substances 0.000 claims 2
150000001335 aliphatic alkanes Chemical class 0.000 claims 1
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AHJKRLASYNVKDZ-UHFFFAOYSA-N DDD Chemical compound C=1C=C(Cl)C=CC=1C(C(Cl)Cl)C1=CC=C(Cl)C=C1 AHJKRLASYNVKDZ-UHFFFAOYSA-N 0.000 description 2
UCNVFOCBFJOQAL-UHFFFAOYSA-N DDE Chemical group C=1C=C(Cl)C=CC=1C(=C(Cl)Cl)C1=CC=C(Cl)C=C1 UCNVFOCBFJOQAL-UHFFFAOYSA-N 0.000 description 2
XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
238000004566 IR spectroscopy Methods 0.000 description 2
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150000001298 alcohols Chemical class 0.000 description 2
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JHRWWRDRBPCWTF-OLQVQODUSA-N captafol Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)C(Cl)Cl)C(=O)[C@H]21 JHRWWRDRBPCWTF-OLQVQODUSA-N 0.000 description 2
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BIWJNBZANLAXMG-YQELWRJZSA-N chloordaan Chemical compound ClC1=C(Cl)[C@@]2(Cl)C3CC(Cl)C(Cl)C3[C@]1(Cl)C2(Cl)Cl BIWJNBZANLAXMG-YQELWRJZSA-N 0.000 description 2
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229910001873 dinitrogen Inorganic materials 0.000 description 2
HKIOYBQGHSTUDB-UHFFFAOYSA-N folpet Chemical compound C1=CC=C2C(=O)N(SC(Cl)(Cl)Cl)C(=O)C2=C1 HKIOYBQGHSTUDB-UHFFFAOYSA-N 0.000 description 2
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ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
239000004973 liquid crystal related substance Substances 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
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150000003071 polychlorinated biphenyls Chemical class 0.000 description 2
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
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VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
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LDVVMCZRFWMZSG-OLQVQODUSA-N (3ar,7as)-2-(trichloromethylsulfanyl)-3a,4,7,7a-tetrahydroisoindole-1,3-dione Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)Cl)C(=O)[C@H]21 LDVVMCZRFWMZSG-OLQVQODUSA-N 0.000 description 1
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JPOPEORRMSDUIP-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(2,3,5,6-tetrachlorophenyl)benzene Chemical group ClC1=CC(Cl)=C(Cl)C(C=2C(=C(Cl)C=C(Cl)C=2Cl)Cl)=C1Cl JPOPEORRMSDUIP-UHFFFAOYSA-N 0.000 description 1
VGVIKVCCUATMNG-UHFFFAOYSA-N 1,2,4-trichloro-5-phenylbenzene Chemical group C1=C(Cl)C(Cl)=CC(Cl)=C1C1=CC=CC=C1 VGVIKVCCUATMNG-UHFFFAOYSA-N 0.000 description 1
GBUCDGDROYMOAN-UHFFFAOYSA-N 1,2,5-trichloro-3-phenylbenzene Chemical group ClC1=CC(Cl)=C(Cl)C(C=2C=CC=CC=2)=C1 GBUCDGDROYMOAN-UHFFFAOYSA-N 0.000 description 1
XOMKZKJEJBZBJJ-UHFFFAOYSA-N 1,2-dichloro-3-phenylbenzene Chemical group ClC1=CC=CC(C=2C=CC=CC=2)=C1Cl XOMKZKJEJBZBJJ-UHFFFAOYSA-N 0.000 description 1
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239000000295 fuel oil Substances 0.000 description 1
238000001030 gas--liquid chromatography Methods 0.000 description 1
238000000574 gas--solid chromatography Methods 0.000 description 1
229940052308 general anesthetics halogenated hydrocarbons Drugs 0.000 description 1
238000007429 general method Methods 0.000 description 1
125000001188 haloalkyl group Chemical group 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
238000005658 halogenation reaction Methods 0.000 description 1
239000001307 helium Substances 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
238000011534 incubation Methods 0.000 description 1
230000002401 inhibitory effect Effects 0.000 description 1
230000002452 interceptive effect Effects 0.000 description 1
229940035429 isobutyl alcohol Drugs 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
239000003350 kerosene Substances 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
235000019421 lipase Nutrition 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
239000010687 lubricating oil Substances 0.000 description 1
238000012423 maintenance Methods 0.000 description 1
239000002480 mineral oil Substances 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
238000005065 mining Methods 0.000 description 1
KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
150000002896 organic halogen compounds Chemical class 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
239000000575 pesticide Substances 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
230000003389 potentiating effect Effects 0.000 description 1
230000002265 prevention Effects 0.000 description 1
238000012545 processing Methods 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
229940056910 silver sulfide Drugs 0.000 description 1
XUARKZBEFFVFRG-UHFFFAOYSA-N silver sulfide Chemical compound [S-2].[Ag+].[Ag+] XUARKZBEFFVFRG-UHFFFAOYSA-N 0.000 description 1
238000003756 stirring Methods 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
KPHOBSTVDZCCAU-UHFFFAOYSA-N tetracyclo[6.4.0.02,4.05,7]dodeca-1(12),2(4),5(7),8,10-pentaene Chemical compound C1=CC=CC2=C3CC3=C(C3)C3=C21 KPHOBSTVDZCCAU-UHFFFAOYSA-N 0.000 description 1
238000004448 titration Methods 0.000 description 1
OEJNXTAZZBRGDN-UHFFFAOYSA-N toxaphene Chemical compound ClC1C(Cl)C2(Cl)C(CCl)(CCl)C(=C)C1(Cl)C2(Cl)Cl OEJNXTAZZBRGDN-UHFFFAOYSA-N 0.000 description 1
238000012549 training Methods 0.000 description 1
238000012546 transfer Methods 0.000 description 1
UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
229940116269 uric acid Drugs 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Landscapes

Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)

CA000448694A 1983-03-31 1984-03-02 Methode et dispositif de determination des biphenyls polyhalogenes Expired CA1219203A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US48071283A	1983-03-31	1983-03-31
US480,712		1983-03-31

Publications (1)

Publication Number	Publication Date
CA1219203A true CA1219203A (fr)	1987-03-17

Family

ID=23909049

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000448694A Expired CA1219203A (fr)	1983-03-31	1984-03-02	Methode et dispositif de determination des biphenyls polyhalogenes

Country Status (1)

Country	Link
CA (1)	CA1219203A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2013014311A1 (fr) *	2011-07-26	2013-01-31	Universidad De Alicante	Procédé d'élimination de pcb présents dans des huiles minérales

1984
- 1984-03-02 CA CA000448694A patent/CA1219203A/fr not_active Expired

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2013014311A1 (fr) *	2011-07-26	2013-01-31	Universidad De Alicante	Procédé d'élimination de pcb présents dans des huiles minérales
ES2395113A1 (es) *	2011-07-26	2013-02-08	Universidad De Alicante	PROCESO PARA ELIMINACIÓN DE PCBs EN ACEITES MINERALES.

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2004-03-17	MKEX	Expiry

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