CA1221184A - Produit d'ensimage sans chrome pour meches de fibres de verres - Google Patents

Produit d'ensimage sans chrome pour meches de fibres de verres

Info

Publication number: CA1221184A
Authority: CA; Canada
Prior art keywords: glass fiber; fibers; weight; roving; coated
Prior art date: 1984-09-24
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000463912A

Other languages

English (en)

Inventor

Leonard J. Adzima

Jeffrey L. Antle

David E. Musick

Fred G. Krautz

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Owens Corning

Original Assignee

Owens Corning Fiberglas Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-09-24

Filing date

1984-09-24

Publication date

1987-04-28

1984-09-24 Application filed by Owens Corning Fiberglas Corp filed Critical Owens Corning Fiberglas Corp

1984-09-24 Priority to CA000463912A priority Critical patent/CA1221184A/fr

1987-04-28 Application granted granted Critical

1987-04-28 Publication of CA1221184A publication Critical patent/CA1221184A/fr

Status Expired legal-status Critical Current

Links

239000003365 glass fiber Substances 0.000 title claims abstract description 43
238000004513 sizing Methods 0.000 title claims abstract description 29
239000000203 mixture Substances 0.000 claims abstract description 41
229920000642 polymer Polymers 0.000 claims abstract description 18
239000000314 lubricant Substances 0.000 claims abstract description 9
125000002091 cationic group Chemical group 0.000 claims abstract description 7
RYSXWUYLAWPLES-MTOQALJVSA-N (Z)-4-hydroxypent-3-en-2-one titanium Chemical compound [Ti].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O RYSXWUYLAWPLES-MTOQALJVSA-N 0.000 claims abstract description 6
239000000835 fiber Substances 0.000 claims description 29
238000000576 coating method Methods 0.000 claims description 11
239000011248 coating agent Substances 0.000 claims description 10
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 9
229940117958 vinyl acetate Drugs 0.000 claims description 9
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 8
229920002554 vinyl polymer Polymers 0.000 claims description 8
239000000178 monomer Substances 0.000 claims description 6
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 5
239000005977 Ethylene Substances 0.000 claims description 5
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 5
239000002253 acid Substances 0.000 claims description 5
XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 4
239000011521 glass Substances 0.000 claims description 4
238000011065 in-situ storage Methods 0.000 claims description 4
239000004014 plasticizer Substances 0.000 claims description 4
229920001225 polyester resin Polymers 0.000 claims description 4
239000004645 polyester resin Substances 0.000 claims description 4
229920006337 unsaturated polyester resin Polymers 0.000 claims description 4
239000004952 Polyamide Substances 0.000 claims description 3
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
239000000413 hydrolysate Substances 0.000 claims description 3
229910000077 silane Inorganic materials 0.000 claims description 3
235000014113 dietary fatty acids Nutrition 0.000 claims description 2
239000000194 fatty acid Substances 0.000 claims description 2
229930195729 fatty acid Natural products 0.000 claims description 2
150000004665 fatty acids Chemical class 0.000 claims description 2
229920000768 polyamine Polymers 0.000 claims description 2
150000003839 salts Chemical class 0.000 claims description 2
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims 1
RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical group C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 claims 1
229920002647 polyamide Polymers 0.000 claims 1
UNIYDALVXFPINL-UHFFFAOYSA-N 3-(2-methylprop-2-enoyloxy)propylsilicon Chemical compound CC(=C)C(=O)OCCC[Si] UNIYDALVXFPINL-UHFFFAOYSA-N 0.000 abstract 1
239000007788 liquid Substances 0.000 description 10
239000011159 matrix material Substances 0.000 description 8
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
229920005989 resin Polymers 0.000 description 6
239000011347 resin Substances 0.000 description 6
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
239000006185 dispersion Substances 0.000 description 4
229910001651 emery Inorganic materials 0.000 description 4
239000000839 emulsion Substances 0.000 description 4
230000003014 reinforcing effect Effects 0.000 description 4
238000005507 spraying Methods 0.000 description 4
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical class [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
239000007822 coupling agent Substances 0.000 description 3
239000000463 material Substances 0.000 description 3
239000000243 solution Substances 0.000 description 3
239000003039 volatile agent Substances 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
229940022663 acetate Drugs 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
238000001816 cooling Methods 0.000 description 2
239000012530 fluid Substances 0.000 description 2
238000009472 formulation Methods 0.000 description 2
239000000155 melt Substances 0.000 description 2
238000000034 method Methods 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
229920003217 poly(methylsilsesquioxane) Polymers 0.000 description 2
239000011342 resin composition Substances 0.000 description 2
229910052719 titanium Inorganic materials 0.000 description 2
239000010936 titanium Substances 0.000 description 2
229920006305 unsaturated polyester Polymers 0.000 description 2
238000009736 wetting Methods 0.000 description 2
238000004804 winding Methods 0.000 description 2
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
238000005299 abrasion Methods 0.000 description 1
229960000583 acetic acid Drugs 0.000 description 1
150000001242 acetic acid derivatives Chemical class 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
238000009835 boiling Methods 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
229960000359 chromic chloride Drugs 0.000 description 1
150000001845 chromium compounds Chemical class 0.000 description 1
LJAOOBNHPFKCDR-UHFFFAOYSA-K chromium(3+) trichloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].[Cl-].[Cl-].[Cr+3] LJAOOBNHPFKCDR-UHFFFAOYSA-K 0.000 description 1
235000007831 chromium(III) chloride Nutrition 0.000 description 1
239000011636 chromium(III) chloride Substances 0.000 description 1
238000004581 coalescence Methods 0.000 description 1
230000001427 coherent effect Effects 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
230000001804 emulsifying effect Effects 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical group C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 1
229920001038 ethylene copolymer Polymers 0.000 description 1
150000002193 fatty amides Chemical class 0.000 description 1
230000009477 glass transition Effects 0.000 description 1
VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
238000007654 immersion Methods 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000006060 molten glass Substances 0.000 description 1
150000001282 organosilanes Chemical class 0.000 description 1
239000002245 particle Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000000047 product Substances 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
230000002787 reinforcement Effects 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1

Landscapes

Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Surface Treatment Of Glass Fibres Or Filaments (AREA)

CA000463912A 1984-09-24 1984-09-24 Produit d'ensimage sans chrome pour meches de fibres de verres Expired CA1221184A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000463912A CA1221184A (fr)	1984-09-24	1984-09-24	Produit d'ensimage sans chrome pour meches de fibres de verres

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000463912A CA1221184A (fr)	1984-09-24	1984-09-24	Produit d'ensimage sans chrome pour meches de fibres de verres

Publications (1)

Publication Number	Publication Date
CA1221184A true CA1221184A (fr)	1987-04-28

Family

ID=4128769

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000463912A Expired CA1221184A (fr)	1984-09-24	1984-09-24	Produit d'ensimage sans chrome pour meches de fibres de verres

Country Status (1)

Country	Link
CA (1)	CA1221184A (fr)

1984
- 1984-09-24 CA CA000463912A patent/CA1221184A/fr not_active Expired

Legal Events

Date	Code	Title	Description
2004-09-24	MKEX	Expiry

Publication	Publication Date	Title
EP0994978B1 (fr)	2004-10-06	Composition d'encollage non aqueuse pour fibres de verre et polymeres moulables par injection
AU759430B2 (en)	2003-04-17	Sizing for glass fibers having low nonionic and cationic lubricant content
US4246145A (en)	1981-01-20	Aqueous size for glass fibers
US4487797A (en)	1984-12-11	Glass fibers to reinforce polymeric materials
US4473618A (en)	1984-09-25	Chrome-free sizing composition containing titanium acetyl acetonate for glass fiber gun roving
JP3061413B2 (ja)	2000-07-10	熱可塑性樹脂粉末含浸ガラス繊維ロービングから成形されたチューブまたはパイプ
US4808478A (en)	1989-02-28	Chemically treated glass fibers for reinforcing thermosetting polymers
CA2354127C (fr)	2008-08-12	Systeme d'encollage non aqueux pour fibres de verre et polymeres moulable par injection
US4927869A (en)	1990-05-22	Chemically treated glass fibers for reinforcing polymers
MXPA03011651A (es)	2005-03-07	Fibras de vidrio aprestadas, composicion aprestante y compuestos que comprenden esas fibras.
CA1221184A (fr)	1987-04-28	Produit d'ensimage sans chrome pour meches de fibres de verres
WO2007044764A1 (fr)	2007-04-19	Ensimage pour fibres, elements de renfort ensimes, et articles renforces avec ces elements
US5312687A (en)	1994-05-17	Size composition for impregnating filament strands with a liquid crystal polymer and the strands produced thereby
EP1353993A2 (fr)	2003-10-22	Ensimage lubrifiant mixte
US4716080A (en)	1987-12-29	Size composition
CA1175972A (fr)	1984-10-09	Compositions aqueuse pour le traitement des files du verre, et files ainsi obtenus
WO1986001811A1 (fr)	1986-03-27	Parage sans chrome pour roving de fibres de verre a injection
US4694034A (en)	1987-09-15	Size composition
AU568687B2 (en)	1988-01-07	Chrome-free sizing for glass fiber gun roving
US5120780A (en)	1992-06-09	Glass fiber size composition and synthetic organosilane lubricants used therein
HK1008010B (en)	1999-04-30	Size composition
US4855341A (en)	1989-08-08	High-strength magnesium aluminosilicate glass fibers having size coating of epoxy resin with methacryloxyalkyl and aminoalkyl silanes
US5237083A (en)	1993-08-17	Synthetic organosilane compounds useful as lubricants in glass sizing compositions
JP2008540306A (ja)	2008-11-20	高ガラス含有率を有するガラスストランド顆粒のためのサイジング組成物
GB2030611A (en)	1980-04-10	Storage Stable Polyolefin Compatible Size for Fibre Glass Strands