CA1221484A - Melanges de caoutchoucs naturel et synthetique - Google Patents

Melanges de caoutchoucs naturel et synthetique

Info

Publication number: CA1221484A
Authority: CA; Canada
Prior art keywords: weight; rubber; parts; conjugated diene; blend
Prior art date: 1983-04-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000426320A

Other languages

English (en)

Inventor

Gary R. Hamed

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Bridgestone Firestone Inc

Firestone Polymers LLC

Original Assignee

Firestone Tire and Rubber Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-04-20

Filing date

1983-04-20

Publication date

1987-05-05

1983-04-20 Application filed by Firestone Tire and Rubber Co filed Critical Firestone Tire and Rubber Co

1983-04-20 Priority to CA000426320A priority Critical patent/CA1221484A/fr

1987-05-05 Application granted granted Critical

1987-05-05 Publication of CA1221484A publication Critical patent/CA1221484A/fr

Status Expired legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 49
229920003051 synthetic elastomer Polymers 0.000 title claims abstract description 49
239000005061 synthetic rubber Substances 0.000 title claims abstract description 48
229920003052 natural elastomer Polymers 0.000 title claims abstract description 45
229920001194 natural rubber Polymers 0.000 title claims abstract description 45
229920001971 elastomer Polymers 0.000 claims abstract description 35
244000043261 Hevea brasiliensis Species 0.000 claims abstract description 33
239000005060 rubber Substances 0.000 claims abstract description 33
150000001993 dienes Chemical class 0.000 claims abstract description 32
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 12
239000000178 monomer Substances 0.000 claims description 32
229920003048 styrene butadiene rubber Polymers 0.000 claims description 25
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 22
150000003926 acrylamides Chemical class 0.000 claims description 21
125000004432 carbon atom Chemical group C* 0.000 claims description 14
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 12
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 11
229920001577 copolymer Polymers 0.000 claims description 7
150000001875 compounds Chemical class 0.000 claims description 5
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
125000000217 alkyl group Chemical group 0.000 claims description 3
150000001491 aromatic compounds Chemical class 0.000 claims description 3
229920001519 homopolymer Polymers 0.000 claims description 3
229940117913 acrylamide Drugs 0.000 description 21
239000000306 component Substances 0.000 description 20
239000002174 Styrene-butadiene Substances 0.000 description 17
239000004816 latex Substances 0.000 description 16
229920000126 latex Polymers 0.000 description 16
IAXXETNIOYFMLW-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) 2-methylprop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C(=C)C)CC1C2(C)C IAXXETNIOYFMLW-UHFFFAOYSA-N 0.000 description 15
229920000642 polymer Polymers 0.000 description 14
239000003792 electrolyte Substances 0.000 description 8
229910052751 metal Inorganic materials 0.000 description 6
239000002184 metal Substances 0.000 description 6
238000002360 preparation method Methods 0.000 description 6
238000005345 coagulation Methods 0.000 description 5
230000015271 coagulation Effects 0.000 description 5
238000000034 method Methods 0.000 description 5
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
239000012190 activator Substances 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
239000003995 emulsifying agent Substances 0.000 description 4
230000006872 improvement Effects 0.000 description 4
239000003999 initiator Substances 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
229910021645 metal ion Inorganic materials 0.000 description 4
238000000465 moulding Methods 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
239000007864 aqueous solution Substances 0.000 description 3
SPTHWAJJMLCAQF-UHFFFAOYSA-M ctk4f8481 Chemical compound [O-]O.CC(C)C1=CC=CC=C1C(C)C SPTHWAJJMLCAQF-UHFFFAOYSA-M 0.000 description 3
239000000806 elastomer Substances 0.000 description 3
-1 fatty acid salts Chemical class 0.000 description 3
238000002156 mixing Methods 0.000 description 3
239000003607 modifier Substances 0.000 description 3
239000012266 salt solution Substances 0.000 description 3
239000007787 solid Substances 0.000 description 3
238000003786 synthesis reaction Methods 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
241001441571 Hiodontidae Species 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
239000005062 Polybutadiene Substances 0.000 description 2
DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
238000007600 charging Methods 0.000 description 2
238000002425 crystallisation Methods 0.000 description 2
230000008025 crystallization Effects 0.000 description 2
WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 2
238000007720 emulsion polymerization reaction Methods 0.000 description 2
230000005484 gravity Effects 0.000 description 2
239000000463 material Substances 0.000 description 2
230000007246 mechanism Effects 0.000 description 2
KCTMTGOHHMRJHZ-UHFFFAOYSA-N n-(2-methylpropoxymethyl)prop-2-enamide Chemical compound CC(C)COCNC(=O)C=C KCTMTGOHHMRJHZ-UHFFFAOYSA-N 0.000 description 2
210000003739 neck Anatomy 0.000 description 2
229920002857 polybutadiene Polymers 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
239000000047 product Substances 0.000 description 2
239000011347 resin Substances 0.000 description 2
229920005989 resin Polymers 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
235000019333 sodium laurylsulphate Nutrition 0.000 description 2
229920001897 terpolymer Polymers 0.000 description 2
FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 2
229920002554 vinyl polymer Polymers 0.000 description 2
238000004073 vulcanization Methods 0.000 description 2
KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
101100087530 Caenorhabditis elegans rom-1 gene Proteins 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
239000004908 Emulsion polymer Substances 0.000 description 1
244000212127 Gliricidia sepium Species 0.000 description 1
235000009664 Gliricidia sepium Nutrition 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
101100305983 Mus musculus Rom1 gene Proteins 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
229920000459 Nitrile rubber Polymers 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 1
229920006322 acrylamide copolymer Polymers 0.000 description 1
239000008186 active pharmaceutical agent Substances 0.000 description 1
238000013019 agitation Methods 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000003973 alkyl amines Chemical class 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
150000001450 anions Chemical group 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
230000008901 benefit Effects 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
238000009835 boiling Methods 0.000 description 1
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
229910052793 cadmium Inorganic materials 0.000 description 1
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
238000003490 calendering Methods 0.000 description 1
239000006229 carbon black Substances 0.000 description 1
150000007942 carboxylates Chemical class 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
238000012668 chain scission Methods 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
230000001112 coagulating effect Effects 0.000 description 1
239000008199 coating composition Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000013329 compounding Methods 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000000748 compression moulding Methods 0.000 description 1
230000000332 continued effect Effects 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
239000003599 detergent Substances 0.000 description 1
LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000005265 energy consumption Methods 0.000 description 1
DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000012467 final product Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
238000007710 freezing Methods 0.000 description 1
230000008014 freezing Effects 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
230000007774 longterm Effects 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
238000010077 mastication Methods 0.000 description 1
230000018984 mastication Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
125000005634 peroxydicarbonate group Chemical group 0.000 description 1
229920001568 phenolic resin Polymers 0.000 description 1
239000005011 phenolic resin Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
230000008569 process Effects 0.000 description 1
238000010926 purge Methods 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
229920005604 random copolymer Polymers 0.000 description 1
239000012260 resinous material Substances 0.000 description 1
230000004044 response Effects 0.000 description 1
XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
238000010058 rubber compounding Methods 0.000 description 1
150000003335 secondary amines Chemical class 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
238000005728 strengthening Methods 0.000 description 1
239000011115 styrene butadiene Substances 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
239000011135 tin Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)

CA000426320A 1983-04-20 1983-04-20 Melanges de caoutchoucs naturel et synthetique Expired CA1221484A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000426320A CA1221484A (fr)	1983-04-20	1983-04-20	Melanges de caoutchoucs naturel et synthetique

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000426320A CA1221484A (fr)	1983-04-20	1983-04-20	Melanges de caoutchoucs naturel et synthetique

Publications (1)

Publication Number	Publication Date
CA1221484A true CA1221484A (fr)	1987-05-05

Family

ID=4125059

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000426320A Expired CA1221484A (fr)	1983-04-20	1983-04-20	Melanges de caoutchoucs naturel et synthetique

Country Status (1)

Country	Link
CA (1)	CA1221484A (fr)

1983
- 1983-04-20 CA CA000426320A patent/CA1221484A/fr not_active Expired

Legal Events

Date	Code	Title	Description
2004-05-05	MKEX	Expiry

Publication	Publication Date	Title
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US2614093A (en)	1952-10-14	Preparation of synthetic polymeric materials
US5807941A (en)	1998-09-15	Unsaturated nitrile-conjugated diene copolymer process for producing same and vulcanizable rubber composition
EP0819731B1 (fr)	2002-01-30	Composition de caoutchouc dienique
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US5674940A (en)	1997-10-07	ABS molding compounds with improved toughness
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US4254013A (en)	1981-03-03	Green strength of elastomer blends
US4477612A (en)	1984-10-16	Lignin reinforced synthetic rubber
US3998998A (en)	1976-12-21	Novel copolymers of dicyano-substituted 1,3-dienes
US2698318A (en)	1954-12-28	Rubbery interpolymers of butadiene-1, 3 hydrocarbons with polyunsaturated carboxylic acids
US2785143A (en)	1957-03-12	Rubber reinforced with a butadiene 1, 3-methyl methacrylate copolymer
US4338425A (en)	1982-07-06	Process for preparing diene-containing rubbers having improved green strength
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CA1221484A (fr)	1987-05-05	Melanges de caoutchoucs naturel et synthetique
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US4124546A (en)	1978-11-07	Green strength of elastomers
US4052542A (en)	1977-10-04	Halo-acetyl high green strength rubbers
US2608541A (en)	1952-08-26	Method of incorporating rosin acid in polymeric materials
US4307210A (en)	1981-12-22	Thermally reversible copolymers and process for the preparation thereof
US4363897A (en)	1982-12-14	Thermally reversible copolymers and process for the preparation thereof
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