CA1222714A - Enlevement des conglomerats de sulfure insoluble aux interfaces eau et huile - Google Patents

Enlevement des conglomerats de sulfure insoluble aux interfaces eau et huile

Info

Publication number: CA1222714A
Authority: CA; Canada
Prior art keywords: oil; chlorine dioxide; sulfide; water; pad
Prior art date: 1983-10-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000461045A

Other languages

English (en)

Inventor

Martin Preus

Charles L. Kissel

Steven A. Mayer

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Magna Corp

Original Assignee

Magna Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-10-12

Filing date

1984-08-15

Publication date

1987-06-09

1984-08-15 Application filed by Magna Corp filed Critical Magna Corp

1987-06-09 Application granted granted Critical

1987-06-09 Publication of CA1222714A publication Critical patent/CA1222714A/fr

Status Expired legal-status Critical Current

Links

XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 49
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 title claims abstract description 39
238000000034 method Methods 0.000 title claims abstract description 27
OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims abstract description 119
239000004155 Chlorine dioxide Substances 0.000 claims abstract description 59
235000019398 chlorine dioxide Nutrition 0.000 claims abstract description 59
239000003208 petroleum Substances 0.000 claims description 14
238000006243 chemical reaction Methods 0.000 claims description 2
150000003568 thioethers Chemical class 0.000 claims 2
238000010438 heat treatment Methods 0.000 claims 1
239000003921 oil Substances 0.000 description 53
239000000243 solution Substances 0.000 description 19
150000004763 sulfides Chemical class 0.000 description 17
230000008569 process Effects 0.000 description 15
239000012071 phase Substances 0.000 description 10
239000007787 solid Substances 0.000 description 10
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 8
229910021578 Iron(III) chloride Inorganic materials 0.000 description 8
239000007983 Tris buffer Substances 0.000 description 8
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 8
239000000203 mixture Substances 0.000 description 8
LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 8
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
239000002480 mineral oil Substances 0.000 description 7
235000010446 mineral oil Nutrition 0.000 description 7
239000000126 substance Substances 0.000 description 7
238000012360 testing method Methods 0.000 description 7
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 6
238000000926 separation method Methods 0.000 description 6
229910019142 PO4 Inorganic materials 0.000 description 5
239000012736 aqueous medium Substances 0.000 description 5
239000012267 brine Substances 0.000 description 5
229910052751 metal Inorganic materials 0.000 description 5
239000002184 metal Substances 0.000 description 5
150000002739 metals Chemical class 0.000 description 5
239000010452 phosphate Substances 0.000 description 5
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
150000003839 salts Chemical class 0.000 description 5
229910052979 sodium sulfide Inorganic materials 0.000 description 5
GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 5
HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 5
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
238000013019 agitation Methods 0.000 description 4
239000000460 chlorine Substances 0.000 description 4
229910052801 chlorine Inorganic materials 0.000 description 4
239000010779 crude oil Substances 0.000 description 4
239000012530 fluid Substances 0.000 description 4
229910052742 iron Inorganic materials 0.000 description 4
239000008363 phosphate buffer Substances 0.000 description 4
230000009471 action Effects 0.000 description 3
239000008346 aqueous phase Substances 0.000 description 3
239000000872 buffer Substances 0.000 description 3
229910001919 chlorite Inorganic materials 0.000 description 3
229910052619 chlorite group Inorganic materials 0.000 description 3
239000011651 chromium Substances 0.000 description 3
230000000694 effects Effects 0.000 description 3
QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 3
239000011133 lead Substances 0.000 description 3
238000005191 phase separation Methods 0.000 description 3
238000007670 refining Methods 0.000 description 3
SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 3
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
239000008186 active pharmaceutical agent Substances 0.000 description 2
239000003945 anionic surfactant Substances 0.000 description 2
229910052793 cadmium Inorganic materials 0.000 description 2
229910052804 chromium Inorganic materials 0.000 description 2
238000011033 desalting Methods 0.000 description 2
239000007789 gas Substances 0.000 description 2
WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical class Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
229910052748 manganese Inorganic materials 0.000 description 2
239000011572 manganese Substances 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000000463 material Substances 0.000 description 2
239000002609 medium Substances 0.000 description 2
229910052976 metal sulfide Inorganic materials 0.000 description 2
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 2
239000011734 sodium Substances 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
229910052718 tin Inorganic materials 0.000 description 2
239000011135 tin Substances 0.000 description 2
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000002671 adjuvant Substances 0.000 description 1
239000003513 alkali Substances 0.000 description 1
230000004075 alteration Effects 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
230000003115 biocidal effect Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000007853 buffer solution Substances 0.000 description 1
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Inorganic materials [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 1
238000010276 construction Methods 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000018044 dehydration Effects 0.000 description 1
238000006297 dehydration reaction Methods 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
229910021641 deionized water Inorganic materials 0.000 description 1
238000004945 emulsification Methods 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
239000008241 heterogeneous mixture Substances 0.000 description 1
229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
239000012535 impurity Substances 0.000 description 1
229910001504 inorganic chloride Inorganic materials 0.000 description 1
229910052745 lead Inorganic materials 0.000 description 1
238000003760 magnetic stirring Methods 0.000 description 1
VCTOKJRTAUILIH-UHFFFAOYSA-N manganese(2+);sulfide Chemical class [S-2].[Mn+2] VCTOKJRTAUILIH-UHFFFAOYSA-N 0.000 description 1
239000007769 metal material Substances 0.000 description 1
150000001455 metallic ions Chemical class 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
HYWYRSMBCFDLJT-UHFFFAOYSA-N nimesulide Chemical compound CS(=O)(=O)NC1=CC=C([N+]([O-])=O)C=C1OC1=CC=CC=C1 HYWYRSMBCFDLJT-UHFFFAOYSA-N 0.000 description 1
229960000965 nimesulide Drugs 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
230000007096 poisonous effect Effects 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
239000000047 product Substances 0.000 description 1
238000011084 recovery Methods 0.000 description 1
238000005096 rolling process Methods 0.000 description 1
238000004062 sedimentation Methods 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000009987 spinning Methods 0.000 description 1
230000003068 static effect Effects 0.000 description 1
239000010959 steel Substances 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
229910052715 tantalum Inorganic materials 0.000 description 1
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 1
229910052716 thallium Inorganic materials 0.000 description 1
238000011144 upstream manufacturing Methods 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G33/00—Dewatering or demulsification of hydrocarbon oils
- C10G33/04—Dewatering or demulsification of hydrocarbon oils with chemical means
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
- B01D17/02—Separation of non-miscible liquids
- B01D17/04—Breaking emulsions
- B01D17/047—Breaking emulsions with separation aids
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G33/00—Dewatering or demulsification of hydrocarbon oils

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Physics & Mathematics (AREA)
Thermal Sciences (AREA)
Engineering & Computer Science (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Removal Of Floating Material (AREA)

CA000461045A 1983-10-12 1984-08-15 Enlevement des conglomerats de sulfure insoluble aux interfaces eau et huile Expired CA1222714A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US54110483A	1983-10-12	1983-10-12
US541,104		1983-10-12

Publications (1)

Publication Number	Publication Date
CA1222714A true CA1222714A (fr)	1987-06-09

Family

ID=24158188

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000461045A Expired CA1222714A (fr)	1983-10-12	1984-08-15	Enlevement des conglomerats de sulfure insoluble aux interfaces eau et huile

Country Status (4)

Country	Link
EP (1)	EP0157793A4 (fr)
JP (1)	JPS60501496A (fr)
CA (1)	CA1222714A (fr)
WO (1)	WO1985001722A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP2688836B1 (fr)	2011-03-22	2020-02-26	Sabre Intellectual Property Holdings LLC	Procédés d'utilisation de précurseur de dioxyde de chlore
US10442711B2 (en)	2013-03-15	2019-10-15	Sabre Intellectual Property Holdings Llc	Method and system for the treatment of produced water and fluids with chlorine dioxide for reuse
US9238587B2 (en)	2013-03-15	2016-01-19	Sabre Intellectual Property Holdings Llc	Method and system for the treatment of water and fluids with chlorine dioxide

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US310049A (en) *		1884-12-30		granger
US4077879A (en) *	1976-06-04	1978-03-07	Olin Corporation	Treatment of sulfide-bearing waters with chlorine dioxide

1984
- 1984-08-15 CA CA000461045A patent/CA1222714A/fr not_active Expired
- 1984-08-20 JP JP59503285A patent/JPS60501496A/ja active Granted
- 1984-08-20 EP EP19840903311 patent/EP0157793A4/fr not_active Ceased
- 1984-08-20 WO PCT/US1984/001335 patent/WO1985001722A1/fr not_active Ceased

Also Published As

Publication number	Publication date
WO1985001722A1 (fr)	1985-04-25
EP0157793A4 (fr)	1986-08-21
JPS6333404B2 (fr)	1988-07-05
EP0157793A1 (fr)	1985-10-16
JPS60501496A (ja)	1985-09-12

Legal Events

Date	Code	Title	Description
2004-08-15	MKEX	Expiry

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EP2969956B1 (fr)	2022-04-27	Methode pour éliminer des métaux lourds à partir de fluides
CA1159434A (fr)	1983-12-27	Compose et methode pour eliminer le sulfure d'hydrogene des courants gazeux
US8728304B2 (en)	2014-05-20	Process, method, and system for removing heavy metals from fluids
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US20120067785A1 (en)	2012-03-22	Process, Method, and System for Removing Heavy Metals from Fluids
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AU2016223189B2 (en)	2021-07-01	Method for removing mercury from crude oil
CA1222714A (fr)	1987-06-09	Enlevement des conglomerats de sulfure insoluble aux interfaces eau et huile
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EP1450930A1 (fr)	2004-09-01	Procede et installation permettant d'extraire des contaminants metalliques de flux de fertilisants
US4182689A (en)	1980-01-08	Treatment of oil-in-water emulsions
WO2005033249A1 (fr)	2005-04-14	Procedes permettant d'eliminer le calcium du petrole brut
EP0537143A1 (fr)	1993-04-21	Procede et composition de traitement d'eau contenant des ions metalliques et des impuretes organiques et/ou inorganiques.
CA1070504A (fr)	1980-01-29	Methode d'extraction de l'arsenic de solutions electrolytiques de cuivre, ou de solutions analogues
GB1563608A (en)	1980-03-26	Use of liquid membrane systems for selective ion transfer
US5017280A (en)	1991-05-21	Process for recovering metals and for removing sulfur from materials containing them by means of an oxidative extraction
US2267809A (en)	1941-12-30	Process for purifying aqueous solutions of caustic alkali containing dissolved sulphides
RU2119526C1 (ru)	1998-09-27	Способ очистки газоконденсата, нефти и нефтепродуктов от сероводорода